CN112609449A - 一种阻燃抗油拒水多功能防护面料及其制备方法 - Google Patents

一种阻燃抗油拒水多功能防护面料及其制备方法 Download PDF

Info

Publication number
CN112609449A
CN112609449A CN202011393358.7A CN202011393358A CN112609449A CN 112609449 A CN112609449 A CN 112609449A CN 202011393358 A CN202011393358 A CN 202011393358A CN 112609449 A CN112609449 A CN 112609449A
Authority
CN
China
Prior art keywords
flame
water
retardant
repellent
drying
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN202011393358.7A
Other languages
English (en)
Other versions
CN112609449B (zh
Inventor
魏田裕
龚建
黄才文
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mianyang Jialian Printing & Dyeing Co ltd
Mianyang Jiaxi Printing & Dyeing Co ltd
Original Assignee
Mianyang Jialian Printing & Dyeing Co ltd
Mianyang Jiaxi Printing & Dyeing Co ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mianyang Jialian Printing & Dyeing Co ltd, Mianyang Jiaxi Printing & Dyeing Co ltd filed Critical Mianyang Jialian Printing & Dyeing Co ltd
Priority to CN202011393358.7A priority Critical patent/CN112609449B/zh
Publication of CN112609449A publication Critical patent/CN112609449A/zh
Application granted granted Critical
Publication of CN112609449B publication Critical patent/CN112609449B/zh
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/38—Oxides or hydroxides of elements of Groups 1 or 11 of the Periodic Table
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/07—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof
    • D06M11/11—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof with halogen acids or salts thereof
    • D06M11/155—Halides of elements of Groups 2 or 12 of the Periodic Table
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/50—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with hydrogen peroxide or peroxides of metals; with persulfuric, permanganic, pernitric, percarbonic acids or their salts
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/68—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with phosphorus or compounds thereof, e.g. with chlorophosphonic acid or salts thereof
    • D06M11/70—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with phosphorus or compounds thereof, e.g. with chlorophosphonic acid or salts thereof with oxides of phosphorus; with hypophosphorous, phosphorous or phosphoric acids or their salts
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/77—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof
    • D06M11/79—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof with silicon dioxide, silicic acids or their salts
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/10—Repellency against liquids
    • D06M2200/11—Oleophobic properties
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/10—Repellency against liquids
    • D06M2200/12—Hydrophobic properties
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/30—Flame or heat resistance, fire retardancy properties
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/50—Modified hand or grip properties; Softening compositions
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
    • Y02P70/62—Manufacturing or production processes characterised by the final manufactured product related technologies for production or treatment of textile or flexible materials or products thereof, including footwear

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Coloring (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

本发明提供了一种阻燃抗油拒水多功能防护面料及其制备方法，制备方法包括以下步骤：面料翻布和坯布缝头，烧毛，堆置，浸轧练漂工作液中，蒸箱堆置，热水洗，经烘干、丝光机进布、浸轧碱液、水洗、烘干和落布，得半制品；将半制品经过染色处理，得染色布；将染色布进布，浸轧阻燃工作液，烘焙，经热水洗、皂洗、热水洗和滚筒烘干，浸轧三防工作液，烘干，再依次经光电整纬、烘焙、冷水辊、水雾给湿、预缩、呢毯、烘干、冷水辊和落布，得面料。本发明还包括此案有上述方法制得的面料。本发明在后处理中通过CP法阻燃整理和三防整理，有效解决了现有技术中三防性能与阻燃性能不兼容、织物强力损失率高和阻燃整理对织物强力的不利影响。

Description

一种阻燃抗油拒水多功能防护面料及其制备方法
技术领域
本发明属于面料印染技术领域，具体涉及一种阻燃抗油拒水多功能防护面料及其制备方法。
背景技术
阻燃、抗油、拒水等性能是火灾救护、野外作业、军事训练、家纺家装、交通运输、冶炼煅铸等行业对防护服装的基本要求。国内外针对具有单一防护性能面料的研发有很多，但在传统后整理工艺中，由于三防与阻燃的不兼容性，三防整理后，会破坏已形成的阻燃体系，织物强力损失率较高、使助燃性能消失殆尽。由于各性能的赋予技术之间存在冲突，未能较好地将阻燃、抗油、拒水的功能同时赋予一块面料。因此，急需一种能够同时在同一面料上完成阻燃、抗油、拒水功能赋予的制备方法。
发明内容
针对现有技术中存在的上述问题，本发明提供一种阻燃抗油拒水多功能防护面料及其制备方法，在后处理中通过CP法阻燃整理和三防整理，有效解决了现有技术中三防性能与阻燃性能不兼容、织物强力损失率高和阻燃整理对织物强力的不利影响。
为实现上述目的，本发明解决其技术问题所采用的技术方案是：提供一种阻燃抗油拒水多功能防护面料的制备方法，包括以下步骤：
(1)前处理：将面料依次经翻布和坯布缝头，然后以70-90m/min车速烧毛，在室温下浸轧冷堆工作液堆置20-28h，再浸轧练漂工作液中，带液率为80-90％，在98-100℃温度下蒸箱堆置50-70min，80-90℃热水洗，最后依次经烘干、丝光机进布、浸轧碱液、水洗、烘干和落布，得半制品；冷堆工作液包括以下组分：烧碱35-45g/L、双氧水8-12g/L和精炼剂3-5g/L；练漂工作液包括以下组分：烧碱7-8g/L、双氧水7-8g/L、精炼剂3-5g/L、螯合剂1-3g/L和水玻璃8-12g/L；
(2)染色：将步骤(1)所得半制品进布后在室温下浸轧染液，带液率40-45％，然后依次经红外线烘干、热风烘躁、烘干、冷水辊和浸轧还原液，在100-102℃温度下还原汽蒸，最后依次经冷水洗、双氧水氧化、皂洗、中和水洗、水洗、烘干和落布，得染色布；
(3)后整理：将步骤(2)所得染色布进布后浸轧阻燃工作液，在160-180℃温度下烘焙1-3min，然后依次经热水洗、皂洗、热水洗和滚筒烘干，浸轧三防工作液，在110-130℃烘干，再依次经光电整纬、拉幅机烘焙、冷水辊、水雾给湿、橡毯预缩整理、呢毯整理、烘干、冷水辊和落布，得阻燃抗油拒水多功能防护面料；阻燃工作液包括以下组分：阻燃剂ZRS-2400-600g/L、氯化镁6-10g/L、磷酸15-25g/L、纤维保护剂ST-650 15-25g/L和交联剂GL-1002-4g/L；三防工作液包括以下组分：三防整理剂JK-365 50-70g/L、增强剂JK-12 10-20g/L和pH中和剂1-3g/L。
进一步，步骤(1)中，烧毛时，采用四道火口，两个正向火口，两个反向火口。
进一步，步骤(1)中，浸轧碱液时，碱液浓度为180-200g/L。
进一步，冷堆工作液包括以下组分：烧碱40g/L、双氧水10g/L和精炼剂4g/L；练漂工作液包括以下组分：烧碱7g/L、双氧水8g/L、精炼剂4g/L、螯合剂2g/L和水玻璃10g/L。
进一步，步骤(2)中，热风烘躁时，风室温度依次为90℃、140℃和170℃。
进一步，步骤(3)中，在70-80℃热水洗，在70-80℃混合液中皂洗，再在70-80℃热水洗。
进一步，混合液包括以下组分：洗衣粉3-5g/L和尿素8-12g/L。
进一步，阻燃工作液包括以下组分：阻燃剂ZRS-2 500g/L、氯化镁8g/L、磷酸20g/L、纤维保护剂ST-650 20g/L和交联剂GL-100 3g/L。
进一步，三防工作液包括以下组分：三防整理剂JK-365 60g/L、增强剂JK-12 15g/L和pH中和剂2g/L。
上述的阻燃抗油拒水多功能防护面料的制备方法制得的阻燃抗油拒水多功能防护面料。
综上所述，本发明具备以下优点：
1、本发明通过前处理、染色和后处理赋予了面料阻燃抗油拒水的功能，在后处理中通过CP法阻燃整理和三防整理，克服了阻燃整理方法对织物强力的不利影响，使得同一面料上具有优异的多功能性能，且织物强力损失率<10％，有效解决了现有技术中三防性能与阻燃性能不兼容、织物强力损失率高和阻燃整理对织物强力的不利影响。
2、冷堆工作液有良好的耐碱性和润湿性，在堆置过程中与烧碱和双氧水发挥协同效应，实现对棉纤维杂质的降解、膨化、扩散、乳化、脱脂等效果。练漂有良好的耐碱性和润湿性，在蒸箱堆置的过程中，去除坯布上的天然杂志、浆料和油污等，使织物具有柔软的手感，良好的吸水性，为后续的加工提供合格的半成品。还在后整理过程中优选了阻燃工作液，减小阻燃工作液与三防工作液之间的影响，增强两者之间的兼容性，使得同一面料能够同时具备阻燃、抗油和拒水功能。
附图说明
图1为实验例所用阻燃工作液和三防工作液以及测试结果。
具体实施方式
实施例1
一种阻燃抗油拒水多功能防护面料，其制备方法包括以下步骤：
(1)前处理：将面料依次经翻布和坯布缝头，然后以80m/min车速，采用四道火口，两个正向火口，两个反向火口烧毛，在室温下浸轧冷堆工作液堆置24h，再浸轧练漂工作液中，带液率为85％，在98℃温度下蒸箱堆置60min，80℃热水洗，最后依次经烘干、丝光机进布、浸轧碱液(190g/L)、水洗、烘干和落布，得半制品；冷堆工作液包括以下组分：烧碱40g/L、双氧水10g/L和精炼剂4g/L；练漂工作液包括以下组分：烧碱7g/L、双氧水8g/L、精炼剂4g/L、螯合剂2g/L和水玻璃10g/L；
(2)染色：将步骤(1)所得半制品进布后在室温下浸轧染液，带液率44.5％，然后依次经红外线烘干、热风烘躁(风室温度依次为90℃、140℃和170℃)、烘干、冷水辊和浸轧还原液，在100℃温度下还原汽蒸，最后依次经冷水洗、双氧水氧化、皂洗、中和水洗、水洗、烘干和落布，得染色布；
(3)后整理：将步骤(2)所得染色布进布后浸轧阻燃工作液，在170℃温度下烘焙2min，然后依次经热水洗(70℃)、混合液中皂洗(70℃)、热水洗(70℃)和滚筒烘干，浸轧三防工作液，在120℃烘干，再依次经光电整纬、拉幅机烘焙、冷水辊、水雾给湿、橡毯预缩整理、呢毯整理、烘干、冷水辊和落布，得阻燃抗油拒水多功能防护面料；阻燃工作液包括以下组分：阻燃剂ZRS-2 500g/L、氯化镁8g/L、磷酸20g/L、纤维保护剂ST-650 20g/L和交联剂GL-100 3g/L；混合液包括以下组分：洗衣粉4g/L和尿素10g/L；三防工作液包括以下组分：三防整理剂JK-365 60g/L、增强剂JK-12 15g/L和pH中和剂2g/L。
测定实施例1所得阻燃抗油拒水多功能防护面料的阻燃性能和三防性能，其所用标准和测试结果见表1。
表1实施例1所得面料测试标准和测试结果
Figure BDA0002813536480000051
由表1可知，实施例1所得阻燃抗油拒水多功能防护面料同时具有阻燃抗油拒水功能，且性能优异。
实施例2
一种阻燃抗油拒水多功能防护面料，其制备方法包括以下步骤：
(1)前处理：将面料依次经翻布和坯布缝头，然后以80m/min车速，采用四道火口，两个正向火口，两个反向火口烧毛，在室温下浸轧冷堆工作液堆置20-28h，再浸轧练漂工作液中，带液率为85％，在100℃温度下蒸箱堆置60min，90℃热水洗，最后依次经烘干、丝光机进布、浸轧碱液(190g/L)、水洗、烘干和落布，得半制品；冷堆工作液包括以下组分：烧碱40g/L、双氧水10g/L和精炼剂4g/L；练漂工作液包括以下组分：烧碱7g/L、双氧水8g/L、精炼剂4g/L、螯合剂2g/L和水玻璃10g/L；
(2)染色：将步骤(1)所得半制品进布后在室温下浸轧染液，带液率44.5％，然后依次经红外线烘干、热风烘躁(风室温度依次为90℃、140℃和170℃)、烘干、冷水辊和浸轧还原液，在101℃温度下还原汽蒸，最后依次经冷水洗、双氧水氧化、皂洗、中和水洗、水洗、烘干和落布，得染色布；
(3)后整理：将步骤(2)所得染色布进布后浸轧阻燃工作液，在170℃温度下烘焙2min，然后依次经热水洗(75℃)、混合液中皂洗(75℃)、热水洗(75℃)和滚筒烘干，浸轧三防工作液，在120℃烘干，再依次经光电整纬、拉幅机烘焙、冷水辊、水雾给湿、橡毯预缩整理、呢毯整理、烘干、冷水辊和落布，得阻燃抗油拒水多功能防护面料；阻燃工作液包括以下组分：阻燃剂ZRS-2 500g/L、氯化镁8g/L、磷酸20g/L、纤维保护剂ST-650 20g/L和交联剂GL-100 3g/L；混合液包括以下组分：洗衣粉4g/L和尿素10g/L；三防工作液包括以下组分：三防整理剂JK-365 60g/L、增强剂JK-12 15g/L和pH中和剂2g/L。
测定实施例2所得阻燃抗油拒水多功能防护面料的阻燃性能和三防性能，其所用标准和测试结果见表2。
表2实施例2所得面料测试标准和测试结果
Figure BDA0002813536480000061
由表2可知，实施例2所得阻燃抗油拒水多功能防护面料同时具有阻燃抗油拒水功能，且性能优异。
实施例3
一种阻燃抗油拒水多功能防护面料，其制备方法包括以下步骤：
(1)前处理：将面料依次经翻布和坯布缝头，然后以90m/min车速，采用四道火口，两个正向火口，两个反向火口烧毛，在室温下浸轧冷堆工作液堆置24h，再浸轧练漂工作液中，带液率为90％，在100℃温度下蒸箱堆置70min，90℃热水洗，最后依次经烘干、丝光机进布、浸轧碱液(200g/L)、水洗、烘干和落布，得半制品；冷堆工作液包括以下组分：烧碱40g/L、双氧水10g/L和精炼剂4g/L；练漂工作液包括以下组分：烧碱7g/L、双氧水8g/L、精炼剂4g/L、螯合剂2g/L和水玻璃10g/L；
(2)染色：将步骤(1)所得半制品进布后在室温下浸轧染液，带液率45％，然后依次经红外线烘干、热风烘躁(风室温度依次为90℃、140℃和170℃)、烘干、冷水辊和浸轧还原液，在102℃温度下还原汽蒸，最后依次经冷水洗、双氧水氧化、皂洗、中和水洗、水洗、烘干和落布，得染色布；
(3)后整理：将步骤(2)所得染色布进布后浸轧阻燃工作液，在180℃温度下烘焙3min，然后依次经热水洗(80℃)、混合液中皂洗(80℃)、热水洗(80℃)和滚筒烘干，浸轧三防工作液，在130℃烘干，再依次经光电整纬、拉幅机烘焙、冷水辊、水雾给湿、橡毯预缩整理、呢毯整理、烘干、冷水辊和落布，得阻燃抗油拒水多功能防护面料；阻燃工作液包括以下组分：阻燃剂ZRS-2 600g/L、氯化镁10g/L、磷酸25g/L、纤维保护剂ST-650 25g/L和交联剂GL-100 4g/L；混合液包括以下组分：洗衣粉5g/L和尿素12g/L；三防工作液包括以下组分：三防整理剂JK-365 70g/L、增强剂JK-12 20g/L和pH中和剂3g/L。
测定实施例3所得阻燃抗油拒水多功能防护面料的阻燃性能和三防性能，其所用标准和测试结果见表3。
表3实施例3所得面料测试标准和测试结果
Figure BDA0002813536480000081
由表3可知，实施例3所得阻燃抗油拒水多功能防护面料同时具有阻燃抗油拒水功能，且性能优异。
实验例
按实施例所示方法，分别在步骤3中采用不同的阻燃工作液和三防工作液(见图1)，并制得阻燃抗油拒水多功能防护面料，同时测定其阻燃性能和三防性能，所用标准和测试结果均见图1。
由图1可知，阻燃工作液能够使得面料具有较好的阻燃性能，阻燃性能能够大幅度提高，且三防工作液的使用并不会大幅度降低面料的阻燃性能，三防性能与阻燃性能相兼容，能够同时具有阻燃抗油拒水功能，同时织物强力损失率低。
虽然结合附图对本发明的具体实施方式进行了详细地描述，但不应理解为对本专利的保护范围的限定。在权利要求书所描述的范围内，本领域技术人员不经创造性劳动即可作出的各种修改和变形仍属本专利的保护范围。

Claims (10)

1.一种阻燃抗油拒水多功能防护面料的制备方法，其特征在于，包括以下步骤：
(1)前处理：将面料依次经翻布和坯布缝头，然后以70-90m/min车速烧毛，在室温下浸轧冷堆工作液堆置20-28h，再浸轧练漂工作液中，带液率为80-90％，在98-100℃温度下蒸箱堆置50-70min，80-90℃热水洗，最后依次经烘干、丝光机进布、浸轧碱液、水洗、烘干和落布，得半制品；所述冷堆工作液包括以下组分：烧碱35-45g/L、双氧水8-12g/L和精炼剂3-5g/L；所述练漂工作液包括以下组分：烧碱7-8g/L、双氧水7-8g/L、精炼剂3-5g/L、螯合剂1-3g/L和水玻璃8-12g/L；
(2)染色：将步骤(1)所得半制品进布后在室温下浸轧染液，带液率40-45％，然后依次经红外线烘干、热风烘躁、烘干、冷水辊和浸轧还原液，在100-102℃温度下还原汽蒸，最后依次经冷水洗、双氧水氧化、皂洗、中和水洗、水洗、烘干和落布，得染色布；
(3)后整理：将步骤(2)所得染色布进布后浸轧阻燃工作液，在160-180℃温度下烘焙1-3min，然后依次经热水洗、皂洗、热水洗和滚筒烘干，浸轧三防工作液，在110-130℃烘干，再依次经光电整纬、拉幅机烘焙、冷水辊、水雾给湿、橡毯预缩整理、呢毯整理、烘干、冷水辊和落布，得阻燃抗油拒水多功能防护面料；所述阻燃工作液包括以下组分：阻燃剂ZRS-2 400-600g/L、氯化镁6-10g/L、磷酸15-25g/L、纤维保护剂ST-650 15-25g/L和交联剂GL-100 2-4g/L；所述三防工作液包括以下组分：三防整理剂JK-365 50-70g/L、增强剂JK-12 10-20g/L和pH中和剂1-3g/L。
2.如权利要求1所述的阻燃抗油拒水多功能防护面料的制备方法，其特征在于，步骤(1)中，烧毛时，采用四道火口，两个正向火口，两个反向火口。
3.如权利要求1所述的阻燃抗油拒水多功能防护面料的制备方法，其特征在于，步骤(1)中，浸轧碱液时，碱液浓度为180-200g/L。
4.如权利要求1所述的阻燃抗油拒水多功能防护面料的制备方法，其特征在于，所述冷堆工作液包括以下组分：烧碱40g/L、双氧水10g/L和精炼剂4g/L；所述练漂工作液包括以下组分：烧碱7g/L、双氧水8g/L、精炼剂4g/L、螯合剂2g/L和水玻璃10g/L。
5.如权利要求1所述的阻燃抗油拒水多功能防护面料的制备方法，其特征在于，步骤(2)中，热风烘躁时，风室温度依次为90℃、140℃和170℃。
6.如权利要求1所述的阻燃抗油拒水多功能防护面料的制备方法，其特征在于，步骤(3)中，在70-80℃热水洗，在70-80℃混合液中皂洗，再在70-80℃热水洗。
7.如权利要求6所述的阻燃抗油拒水多功能防护面料的制备方法，其特征在于，所述混合液包括以下组分：洗衣粉3-5g/L和尿素8-12g/L。
8.如权利要求1所述的阻燃抗油拒水多功能防护面料的制备方法，其特征在于，所述阻燃工作液包括以下组分：阻燃剂ZRS-2 500g/L、氯化镁8g/L、磷酸20g/L、纤维保护剂ST-65020g/L和交联剂GL-100 3g/L。
9.如权利要求1所述的阻燃抗油拒水多功能防护面料的制备方法，其特征在于，所述三防工作液包括以下组分：三防整理剂JK-365 60g/L、增强剂JK-12 15g/L和pH中和剂2g/L。
10.权利要求1-9任一项所述的阻燃抗油拒水多功能防护面料的制备方法制得的阻燃抗油拒水多功能防护面料。
CN202011393358.7A 2020-12-03 2020-12-03 一种阻燃抗油拒水多功能防护面料及其制备方法 Active CN112609449B (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202011393358.7A CN112609449B (zh) 2020-12-03 2020-12-03 一种阻燃抗油拒水多功能防护面料及其制备方法

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202011393358.7A CN112609449B (zh) 2020-12-03 2020-12-03 一种阻燃抗油拒水多功能防护面料及其制备方法

Publications (2)

Publication Number Publication Date
CN112609449A true CN112609449A (zh) 2021-04-06
CN112609449B CN112609449B (zh) 2023-12-19

Family

ID=75228516

Family Applications (1)

Application Number Title Priority Date Filing Date
CN202011393358.7A Active CN112609449B (zh) 2020-12-03 2020-12-03 一种阻燃抗油拒水多功能防护面料及其制备方法

Country Status (1)

Country Link
CN (1) CN112609449B (zh)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113265877A (zh) * 2021-06-11 2021-08-17 江苏康乃馨纺织科技有限公司 一种三防阻燃多功能防羽布的制备方法
CN115897240A (zh) * 2022-12-28 2023-04-04 新乡市新星特种织物有限公司 一种阻燃防水面料阻燃性能不合格的回修方法

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2008098518A1 (fr) * 2007-02-15 2008-08-21 Weiguo Ou Procédé de traitement ignifugeant pour matière légère en fibres naturelles
CN102535159A (zh) * 2011-12-30 2012-07-04 大连宏丰控股有限公司 棉织物的防水防油阻燃整理工艺
CN103061000A (zh) * 2013-01-16 2013-04-24 江苏悦达纺织集团有限公司 煤矿防护服面料及其制备方法
WO2015101312A1 (zh) * 2013-12-31 2015-07-09 广东德美精细化工股份有限公司 一种阻燃工作液及纯棉织物和/或涤棉混纺织物的阻燃整理方法
CN106192423A (zh) * 2016-07-12 2016-12-07 绵阳佳联印染有限责任公司 一种阻燃拒油水抗静电织物的制备方法及静电织物
CN107201644A (zh) * 2017-07-07 2017-09-26 常熟市宝沣特种纤维有限公司 耐化学喷溅阻燃面料的制备方法
CN109853220A (zh) * 2018-12-26 2019-06-07 绵阳佳联印染有限责任公司 一种耐洗、抗菌、三防、阻燃织物的制备工艺

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2008098518A1 (fr) * 2007-02-15 2008-08-21 Weiguo Ou Procédé de traitement ignifugeant pour matière légère en fibres naturelles
CN102535159A (zh) * 2011-12-30 2012-07-04 大连宏丰控股有限公司 棉织物的防水防油阻燃整理工艺
CN103061000A (zh) * 2013-01-16 2013-04-24 江苏悦达纺织集团有限公司 煤矿防护服面料及其制备方法
WO2015101312A1 (zh) * 2013-12-31 2015-07-09 广东德美精细化工股份有限公司 一种阻燃工作液及纯棉织物和/或涤棉混纺织物的阻燃整理方法
CN106192423A (zh) * 2016-07-12 2016-12-07 绵阳佳联印染有限责任公司 一种阻燃拒油水抗静电织物的制备方法及静电织物
CN107201644A (zh) * 2017-07-07 2017-09-26 常熟市宝沣特种纤维有限公司 耐化学喷溅阻燃面料的制备方法
CN109853220A (zh) * 2018-12-26 2019-06-07 绵阳佳联印染有限责任公司 一种耐洗、抗菌、三防、阻燃织物的制备工艺

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113265877A (zh) * 2021-06-11 2021-08-17 江苏康乃馨纺织科技有限公司 一种三防阻燃多功能防羽布的制备方法
CN115897240A (zh) * 2022-12-28 2023-04-04 新乡市新星特种织物有限公司 一种阻燃防水面料阻燃性能不合格的回修方法

Also Published As

Publication number Publication date
CN112609449B (zh) 2023-12-19

Similar Documents

Publication Publication Date Title
CN101353842B (zh) 超低缩水率纯棉衬布及其生产方法
CN101082155B (zh) 一种包芯纱织物的染整方法
CN112609449B (zh) 一种阻燃抗油拒水多功能防护面料及其制备方法
CN103556368A (zh) 一种棉涤交织氨纶包芯弹力面料的生产方法
CN110592973A (zh) 一种服装用布料的染整工艺
CN106192423A (zh) 一种阻燃拒油水抗静电织物的制备方法及静电织物
CN105926312A (zh) 一种防蚊抗菌防红外迷彩面料的印染方法及迷彩面料
CN110670341A (zh) 一种cvc/t400交织布连续染整工艺
CN103541182A (zh) 一种氨纶包芯弹力织物的生产方法
CN111926572B (zh) 提升高温免烫树脂整理机织面料折皱回复角的整理方法
CN109837771A (zh) 一种t/c织物分散、活性染色生产的工艺
CN106436269A (zh) 一种服装面料的染整工艺
CN102912661B (zh) 一种织物的固色处理方法
CN104963061A (zh) 一种高阻燃混纺面料的制备方法
CN110804881A (zh) 一种全棉面料染色处理方法
CN103233315A (zh) 竹纤维与吸湿排汗涤纶交织面料及生产方法
CN104404761B (zh) 一种防沾色纤维素纤维纱线、面料、成衣及其制备方法
CN106012507A (zh) 一种防红外防水防油防污迷彩面料的印染方法及迷彩面料
CN103556367A (zh) 一种氨纶包芯弹力面料
JPH0860563A (ja) 染色編織物の製造方法およびこの方法により製造される編織物
CN110699977A (zh) 棉、粘涤织物溢流染色与长车染色结合的染色方法
CN112522969A (zh) 一种红色油田工作服面料制作工艺及面料
CN109371716A (zh) 一种仿丝光汗布的染整工艺
CN108708029A (zh) 一种段染窗帘阁的制作工艺
CN112626675A (zh) Easemax色织面料及其生产方法

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant