WO2008098518A1 - Procédé de traitement ignifugeant pour matière légère en fibres naturelles - Google Patents

Procédé de traitement ignifugeant pour matière légère en fibres naturelles Download PDF

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Publication number
WO2008098518A1
WO2008098518A1 PCT/CN2008/070297 CN2008070297W WO2008098518A1 WO 2008098518 A1 WO2008098518 A1 WO 2008098518A1 CN 2008070297 W CN2008070297 W CN 2008070297W WO 2008098518 A1 WO2008098518 A1 WO 2008098518A1
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Prior art keywords
flame retardant
flame
jsj
fiber material
cross
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PCT/CN2008/070297
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English (en)
Chinese (zh)
Inventor
Weiguo Ou
Zhiguo Wei
Jianhua Xu
Original Assignee
Weiguo Ou
Zhiguo Wei
Jianhua Xu
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Application filed by Weiguo Ou, Zhiguo Wei, Jianhua Xu filed Critical Weiguo Ou
Publication of WO2008098518A1 publication Critical patent/WO2008098518A1/fr

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Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M23/00—Treatment of fibres, threads, yarns, fabrics or fibrous goods made from such materials, characterised by the process
    • D06M23/08—Processes in which the treating agent is applied in powder or granular form
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/44—Oxides or hydroxides of elements of Groups 2 or 12 of the Periodic Table; Zincates; Cadmates
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/46—Oxides or hydroxides of elements of Groups 4 or 14 of the Periodic Table; Titanates; Zirconates; Stannates; Plumbates
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/30—Flame or heat resistance, fire retardancy properties

Definitions

  • the invention relates to a post-treatment method for light and thin natural fiber materials, in particular to a flame retardant and clean treatment method. Background technique
  • the ecological properties of fiber materials have been the focus of the world, and Europe, the United States and China have developed strict ecological standards.
  • the fiber material with the ecological performance meets the requirements can ensure the health of the user and promote the harmonious development of the society.
  • the production of flame-retardant cotton fabrics in foreign countries is mainly based on the technology of Pykovetex CP New and Proban, and most of them are medium-thick fabrics.
  • the inventions of light-weight natural fiber flame retardant materials are rarely reported, and the specific performance is unknown.
  • the flame retardant processing technology of flame retardant viscose fiber is relatively mature abroad.
  • countries such as Europe, the United States, and Japan are keen on the invention and development of special high temperature resistant flame retardant fibers and materials.
  • the invention and production of flame retardant natural fiber materials have a tendency to shift to foreign countries. In short, the flame retardant lightweight natural fiber materials are less invented at home and abroad and are more difficult.
  • a heat-resistant flame-retardant fabric and a preparation method thereof the heat-resistant flame-retardant fabric is blended from two flame-retardant fibers,
  • the flame retardant fiber is aramid 1313 fiber, and the other flame retardant fiber is flame retardant viscose fiber.
  • the flame retardant content of various fibers in the flame retardant fabric is: aramid fiber: 20% ⁇ 80%, flame retardant adhesive Fiber: 20% ⁇ 80%.
  • CN01813559 5 Fireproof yarn and fabric made thereof, comprising: a) 5-90wt.% melamine fiber, b) 5-90wt.% natural fiber, c) 0. l-30wt.% by polyamide 66, polyamide 6 or a polyamide fiber made from a mixture thereof.
  • CN03811280 9 High fireproof blend fabric prepared by co-braiding: 30% ⁇ 70% by weight of strand (A), and 70% ⁇ 30% by weight of cellulose fiber yarn (B), the strand (A)
  • the halogen-containing fireproof fiber (a-1) is obtained by combining the halogen-containing fireproof fiber (a-1) and the other fiber (a_2), and contains 25 to 50 parts of hydrazine in 100 parts by weight of the acrylic-based copolymer.
  • the compound, the acrylic-based copolymer is obtained by polymerizing a monomer mixture comprising 30% to 70% by weight of acrylonitrile, 30% to 70% by weight of a halogen-containing vinyl monomer, 0% ⁇ 10% by weight of the vinyl monomer copolymerizable with them, the strand (A) has an elongation of less than 5% at a load of 300 mg/metric metric No. 17, at a temperature ranging from 100 T to 500 °C. rate.
  • the method for finishing the vapor-permeable acid-proof and oil-proof waterproof fabric using the method of pre-coating and finishing to improve the acid-proof permeability of the fabric;
  • the polymer materials used for the fabric coating mainly include polyacrylic water-based or solvent-based Resin or polyurethane water-based or solvent-based resin; acid-proof finishing using fluoropolymer materials.
  • CN200310112733 6 Method for manufacturing antistatic flame retardant waterproof and oilproof natural fiber fabric, antistatic fabric, weaving, flame retardant, baking, soaping, deodorizing, waterproofing, oil proofing, tentering, finished product inspection; Electrostatic grey cloth test The antistatic method of weaving natural fiber fabrics is an organic conductive fiber or a metal conductive fiber.
  • the object of the present invention is to: propose a flame-retardant treatment method for a light and thin natural fiber material, and further propose a method for cleaning a fabric; thereby obtaining an ultra-thin, ultra-light, ultra-fine, ultra-soft natural fiber material to obtain a good flame retardant effect; Ultra-thin, ultra-light, ultra-fine and ultra-soft fiber materials have self-cleaning properties (sterilization and sterilization).
  • the technical solution of the invention is: a flame-retardant treatment method for light and thin natural fiber materials, which is treated by the following processes: Ultra-microfiber material fabric (light-weight cotton fabric) - bleaching treatment or dyeing - low temperature infiltration (flame retardant) One-to-one baking cross-linking one-to-one oxidation, neutralization, water washing one by one product inspection; wherein the low temperature infiltration conditions are: 15-30 °C, 10-30 seconds; puffing temperature 35-60 °C and 20-40 minutes Baking crosslinking temperature: 145-185 V, time: 2 to 8 minutes.
  • the fabric is low-temperature infiltrated and expanded, high-temperature baking and cross-linking;
  • the flame retardant is Pyrovatex CP New or flame retardant JSJ-111:
  • the cross-linked resin is mostly modified thiol melamine derivative with reactive groups, cross-linked resin Especially for JS J-302. 5-20%, the use concentration of flame retardant is 25% - 38%; ultra-fine fiber material low temperature (15-30 °0 with flame retardant, cross-linking resin, penetrant and other materials infiltration, time 20-30 Seconds; and parked at 20-80 ° C for 20-40 minutes; baking process using baking cross-linking temperature: 135-185 V, time: 2-8 minutes. Infiltration temperature 20-30 ° C, time 20-30 seconds And puff at 40-60 ° C and 20-40 minutes.
  • the kt%, dispersing agent 0. 2 - 1 The weight ratio of the titanium dioxide (Ti02) or / ZnO to zinc oxide ZnO, the weight ratio is 1-12. (kt%, dispersing agent 0. 2 - 1 5wt%; and adding nanocomposite dispersant to treat in aqueous solution. Dispersing agent and adding water, mixing and mixing at high speed for 20-60 minutes under stirring; or adding
  • Flame retardant formula flame retardant JSJ-11125— 38, crosslinked resin JSJ-302 5—10, auxiliary crosslinked resin JSJ-303 0.5—2.0, formaldehyde elimination agent JSJ-504 0.3—1.5; softener JSJ-1512 3; Catalyst JSJ-523 1-2; penetrant JSJ-312 1-2; cold water balance, the above is the percentage by weight, total 100%.
  • Cleaner nanocomposite dispersion formulation nanomaterial titanium dioxide 0.2-2.0, adsorption material zinc oxide 0.9-12.0, dispersant surface activity, cosolvent JSJ-701 0.8-7.0; 30% NaOH aqueous solution 1.0-10.0; Softener JSJ-312 E; penetrant JSJ-151 F; E, F are 1-10; water is the balance, the above is the percentage by weight, total 100%.
  • the invention is characterized in that: this is a clean and flame-retardant treatment method for light and thin natural fiber materials; thereby obtaining a good flame retardant effect on ultra-thin, ultra-light, ultra-fine and ultra-soft natural fiber materials.
  • the ultra-thin, ultra-light, ultra-fine and ultra-soft fiber materials have self-cleaning properties (sterilization and sterilization).
  • the invention adopts the low-temperature infiltration expansion and high-temperature baking cross-linking technology and the harmonious arrangement technology of flame retardancy, durability and hand feeling softness, and the processing of the fiber materials with the weight of 90-150 g/m2 has achieved the expected result.
  • the nano-materials with photocatalytic properties, materials with adsorption and chemical reaction properties for odor and formaldehyde are made into a stable composite dispersion by special methods, and then the dispersion is used.
  • FIG 1 shows the effect of flame retardant concentration on fabric weight gain
  • Figure 1 and Figure 2 1-cotton plain cloth 128.4g/m 2 (133X 100), 2-cotton twill 119. lg/m 2 (128X68) Figure 3.
  • the effect of the amount of flame retardant on the flame retardancy and softness of fiber materials Due to the thinness, bulkiness, softness and large specific surface area of the ultrafine fiber material, the fiber material per unit mass contains a large amount of air, and the oxygen supply during combustion is sufficient, so that the ultrafine fiber material is relatively easy to ignite.
  • the eco-efficient flame retardant is selected and the amount of the flame retardant is appropriately increased.
  • the durable flame retardants which can be used for natural and mixed materials at home and abroad mainly include condensates of N-hydroxymethyl-3-dimethylphospholpropamide (Pyrovatex CP) and tetramethylolphosphonium chloride-urea.
  • Proban type because Proban flame retardant is ammonia-cured when processing natural fiber materials, the degree of crosslinking is difficult to control, and the finishing products are harder, and the ultra-fine fiber materials cannot be used in flame-retardant processing.
  • Pyrovatex CP flame retardants have a large number of domestic and foreign manufacturers and brands, and there is a certain gap in quality. Table 1 shows the performance comparison of six flame retardants.
  • the fabric is 119. Ig/m2 cotton twill.
  • the amount of flame retardant used directly affects the flame retardancy, feel and production cost of the fiber material.
  • natural materials such as flame retardant JSJ-111, infiltrated with a high temperature baking cross-linking process, processing two natural fiber materials according to orthogonal test
  • Figure 1 gives the effect of the concentration of the flame retardant on the weight gain of the fabric
  • Figure 2 shows the relationship between the weight gain of the fabric and the length of the damage
  • Table 2 shows the effect of the flame retardant on the fabric properties. It can be seen from Figure 1 that as the concentration of the flame retardant is used, the fabric gains weight.
  • the cross-linking resin is JSJ 302, and the dosage is the same.
  • the concentration of the agent also has a certain influence on the strength and color change of the fabric. Based on the above analysis, the concentration of the flame retardant used is 25% - 38% is an optimum value.
  • the commonly used cross-linking resin is mostly a modified thiol melamine derivative with a reactive group, but its performance is also different due to the difference in chemical structure, molecular weight and reactive group content. Large differences, Table 3 lists the performance comparison of the five crosslinked resins. Table 3 Comparison of properties of five crosslinked resins
  • the fabric is 119. lg/m 2 of cotton twill; the flame retardant is domestic JSJ-111.
  • the cross-linked resin can not only form a strong chemical bond with the active groups of the flame retardant and the fiber material, but also adhere to the surface of the fine structure of the fiber material by permeation, relying on the intermolecular secondary bond force. Strongly combined.
  • the amount of cross-linking resin directly affects the washing fastness, weight gain, and feel of the finished fabric.
  • Figure 3 shows the effect of the amount of cross-linking resin on the washability and weight gain of the fabric.
  • Table 4 lists the relationship between the cross-linking resin and the fabric feel, strength, color change and other indicators.
  • the fabric is cotton twill (119. lg/m 2 ); the flame retardant is JSJ-111, the same amount of use; the cross-linked resin is JSJ-302. Coordination of indicators, the use concentration of cross-linked resin is 5.0% - 10% is most suitable.
  • the ultra-microfiber material is infiltrated with a flame retardant, a cross-linking resin, a penetrating agent, etc. at a low temperature (15-30 ° C), and is parked at a lower temperature (20-80 ° C) for a certain period of time, at which time the fiber material is puffed.
  • the loose and low-molecular additives are easily penetrated into the fine structure of the fiber material, and when dried and cross-linked, the surface resin is not formed, thereby greatly improving the hand feeling and strength of the flame-retardant fiber material.
  • Table 5 shows the effect of the expansion temperature and time on the properties of the fabric.
  • the fiber material is: cotton twill (40 s X40 s 119. lg/m 2 ).
  • High temperature baking cross-linking is a key process in the flame retardant processing of fiber materials, which largely determines the hand of the finished product. Sense, washability, loss of strength and color change.
  • High temperature baking cross-linking is a very complicated physical and chemical process; it has cross-linking between flame retardant and fiber material, cross-linking between fiber material, flame retardant and cross-linking resin, as well as flame retardant and cross-linking.
  • the co-resin penetrates and adheres to the inside of the fiber material, and forms a very strong physical adsorption by the intermolecular bond force.
  • the key parameters of high temperature baking cross-linking are baking temperature and baking time: high temperature and long time.
  • the chemical reaction is thorough, the degree of crosslinking is high, and the fabric has good washing durability, it will make the hand feel hard and the strength loss is large.
  • the side reaction is increased, and the formed compound reacts with free formaldehyde to form a fatty amine substance with fishy smell; if the baking temperature is too low and the time is too short, the crosslinking is insufficient, thereby affecting the washing resistance of the fiber material. Fastness and flame retardancy, a large number of tests have proved: the baking temperature is 145-185 °C, and the baking time is -8 minutes, which is a reasonable high-temperature baking crosslinking condition.
  • Ultrafine fiber materials produce trace amounts of free formaldehyde and fatty amines with fishy odor during flame retardant processing, and fatty amines with fishy odors, during storage and transportation of products, such as encountering suitable temperatures and Humidity will also be produced in small amounts.
  • heavy metal content, limited flame retardant and ra value are easier to solve, while odor and free formaldehyde have become key indicators, and these two indicators are largely interrelated.
  • Ultra-fine flame-retardant fiber materials can generate free electrons and holes under the irradiation of sunlight or light after introducing nano-scale zinc oxide (ZnO) or titanium dioxide (Ti0 2 ), and oxygen and water molecules in the air.
  • the reaction produces a highly oxidizing ability of hydroxyl radicals and active oxygen, and thus has a strong photo-oxidation-reduction function.
  • Harmful organic matter formaldehyde, fatty amines, etc.
  • odors, bacteria, etc. which are adsorbed by active oxygen, are immediately reduced to harmless carbon dioxide, water and oxygen.
  • the flame retardant fiber material is not visible or the light is weak during packaging or transportation, which will affect the photocatalytic effect of the nano material.
  • the odor or formaldehyde on the ultrafine flame retardant material is adsorbed by a material having micropores, voids or a large specific surface area, and stored in its internal structure.
  • the problem with this method is that the adsorption has a saturation process, and at the same time, during the water washing, desorption occurs and some of the gas is released again.
  • a substance that can react chemically with fatty amines and formaldehyde is applied to the ultra-fine flame-retardant fiber material, which can easily remove odor and formaldehyde, but the adhesion and use of the material to the fiber material is incomprehensible.
  • the ultra-viral flame retardant fiber materials were treated with three ecological cleanliness theories and five cleansers were selected. The results are shown in Table 6.
  • the fiber material is: flame retardant cotton flat cloth ( 40 s X 40 s 128. 4g/m 2 );
  • Nanocomposite dispersion formulation is a nanocomposite dispersion formulation
  • Dispersing agent JSJ- 504 0. 2—1. 5
  • Aqueous NaOH solution (30%) 1. 0— 10. 0
  • the nano-composite dispersion uses a conventional impregnation-drying-bake process for the ecological clean processing of ultra-fine flame-retardant fiber materials.
  • the results are shown in Table 7.
  • Nano-composite clean liquid does not stratify, not demulsification, and no precipitation during use.
  • Ultra-microfiber material (light-weight cotton fabric) Bleaching or dyeing - low temperature infiltration (flame retardant) - one baking cross-linking - oxidation, neutralization, water washing - nano-ecological clean - finished product inspection
  • Crosslinked resin JSJ-302 Auxiliary crosslinked resin JSJ-303 0.5-2.0
  • Cleaner JSJ-605 (Adsorbed material) 0.9—12.0 Cleaner JSJ-601 (Reactive material) 0.5— 5.2
  • the fiber material is: Eco-flame-retardant cotton flat cloth (40 S X40 S , 133X100).
  • the fiber material is: Eco-flame-retardant cotton flat cloth (40 S X40 S , 133X100). As can be seen from Table 9 and Table 10:
  • nano-material dispersion-nano-composite cleaner directly affects the ecological properties of the fiber material, the softness of the hand, and the production cost.
  • Table 11 shows the effect of the nano-composite cleaner on the properties of the fiber material.
  • the fiber material is: cotton flat cloth (40sX40s, 128.4g/m 2 )

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

L'invention concerne un procédé de traitement ignifugeant pour matière légère en fibres naturelles. Ledit procédé présente les étapes de traitement suivantes : blanchiment ou coloration du tissu de matière à ultra-microfibres, ignifugeage par trempe à basse température et expansion; cuisson pour réticulation; oxydation, neutralisation, lavage à l'eau; inspection de produits, les conditions de la trempe à basse température étant de 15-30°C, 10-30 secondes et l'expansion étant réalisée à 35-60°C pendant 20-40 minutes. La cuisson pour réticulation est réalisée à 145-185°C pendant 2-8 minutes. Ensuite, la matière à ultra-microfibres ignifugée est traitée par un agent de purification, à savoir le dioxyde de titane (TiO2) et/ou le dioxyde de zinc (ZnO) à l'échelle nanométrique et son rapport en poids est de 1-12,0 % en poids, entre 0,2-1,5 % en poids d'un dispersant ajouté dans la solution d'eau pour le traitement.
PCT/CN2008/070297 2007-02-15 2008-02-13 Procédé de traitement ignifugeant pour matière légère en fibres naturelles WO2008098518A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CNB2007100203735A CN100545343C (zh) 2007-02-15 2007-02-15 轻薄天然纤维材料的阻燃处理方法
CN200710020373.5 2007-02-15

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CN112127171A (zh) * 2020-09-08 2020-12-25 浙江理工大学 一种水性含磷聚合物纳米复合织物耐久阻燃涂层的制备方法
CN112609449A (zh) * 2020-12-03 2021-04-06 绵阳佳禧印染有限责任公司 一种阻燃抗油拒水多功能防护面料及其制备方法

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CN101885859B (zh) * 2009-05-11 2014-10-08 中国科学院化学研究所 阻燃微胶囊及其应用
CN101812737B (zh) * 2010-04-23 2012-12-05 江苏开利地毯股份有限公司 阻燃涤纶bcf长丝的生产方法及所得阻燃涤纶bcf长丝在地毯织造中的应用
CN103290502B (zh) * 2012-02-24 2016-02-10 聚隆纤维股份有限公司 具耐燃功能的天然纤维素纤维的制法
TW201335450A (zh) * 2012-02-24 2013-09-01 Acelon Chem & Fiber Corp 具耐燃功能之天然纖維素纖維的製法
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TWI596247B (zh) * 2012-03-01 2017-08-21 Preparation of natural cellulose meltblown nonwovens with flame resistance
CN102704222A (zh) * 2012-06-05 2012-10-03 江苏格玛斯特种织物有限公司 一种阻燃平绒面料的制备工艺
EP3037574B1 (fr) 2013-08-23 2019-05-29 Kaneka Corporation Tissu ignifuge, procédé permettant de produire ce dernier et vêtements de protection contre le feu comprenant ce dernier
CN106400461B (zh) * 2016-10-17 2018-09-28 新乡市新科防护科技有限公司 一种提升thpc阻燃面料耐光照牢度的方法
CN106367961A (zh) * 2016-10-17 2017-02-01 新乡市新科防护科技有限公司 一种无鱼腥味cp阻燃面料的生产方法
CN112318951A (zh) * 2020-10-14 2021-02-05 江苏海涛纺织有限公司 一种具有自清洁防紫外线功能的弹性泡泡面料

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CN112127171B (zh) * 2020-09-08 2023-07-07 浙江理工大学 一种水性含磷聚合物纳米复合织物耐久阻燃涂层的制备方法
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