CN111094439B - 氟化共聚物及其组合物以及包含氟化共聚物的制品 - Google Patents

氟化共聚物及其组合物以及包含氟化共聚物的制品 Download PDF

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CN111094439B
CN111094439B CN201880059563.4A CN201880059563A CN111094439B CN 111094439 B CN111094439 B CN 111094439B CN 201880059563 A CN201880059563 A CN 201880059563A CN 111094439 B CN111094439 B CN 111094439B
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copolymer
ocf
formula
present disclosure
copolymers
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CN111094439A (zh
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利萨·P·陈
格雷格·D·达尔克
丹尼斯·杜谢恩
史蒂文·J·汉罗克
克劳斯·辛策
马库斯·E·希尔施贝格
阿尔内·塔勒
蒂尔曼·C·兹普利斯
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3M Innovative Properties Co
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CN201880059563.4A 2017-09-14 2018-09-14 氟化共聚物及其组合物以及包含氟化共聚物的制品 Expired - Fee Related CN111094439B (zh)

Applications Claiming Priority (7)

Application Number Priority Date Filing Date Title
US201762558655P 2017-09-14 2017-09-14
US201762558671P 2017-09-14 2017-09-14
US62/558,655 2017-09-14
US62/558,671 2017-09-14
US201862730648P 2018-09-13 2018-09-13
US62/730,648 2018-09-13
PCT/US2018/051104 WO2019055799A1 (en) 2017-09-14 2018-09-14 FLUORINATED COPOLYMER AND COMPOSITIONS AND ARTICLES USING THE SAME

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CN111094439A CN111094439A (zh) 2020-05-01
CN111094439B true CN111094439B (zh) 2022-11-08

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CN201880059563.4A Expired - Fee Related CN111094439B (zh) 2017-09-14 2018-09-14 氟化共聚物及其组合物以及包含氟化共聚物的制品
CN201880059876.XA Expired - Fee Related CN111133015B (zh) 2017-09-14 2018-09-14 含氟聚合物分散体、用于制备含氟聚合物分散体的方法、催化剂油墨和聚合物电解质膜
CN201880059351.6A Expired - Fee Related CN111094438B (zh) 2017-09-14 2018-09-14 具有磺酰基侧基的氟化共聚物以及包含其的组合物和制品

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CN201880059876.XA Expired - Fee Related CN111133015B (zh) 2017-09-14 2018-09-14 含氟聚合物分散体、用于制备含氟聚合物分散体的方法、催化剂油墨和聚合物电解质膜
CN201880059351.6A Expired - Fee Related CN111094438B (zh) 2017-09-14 2018-09-14 具有磺酰基侧基的氟化共聚物以及包含其的组合物和制品

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US (3) US11377510B2 (enExample)
EP (3) EP3681917A1 (enExample)
JP (3) JP2020534402A (enExample)
KR (3) KR20200052896A (enExample)
CN (3) CN111094439B (enExample)
WO (3) WO2019055791A1 (enExample)

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9474282B2 (en) 2013-12-13 2016-10-25 Tony John Hall Acid-solubilized copper-ammonium complexes and copper-zinc-ammonium complexes, compositions, preparations, methods, and uses
WO2019055791A1 (en) * 2017-09-14 2019-03-21 3M Innovative Properties Company FLUORINATED COPOLYMER HAVING SULFONYL PENDANT GROUPS AND COMPOSITIONS AND ARTICLES COMPRISING SAID FLUORINATED COPOLYMER
WO2020183306A1 (en) * 2019-03-12 2020-09-17 3M Innovative Properties Company Dispersible perfluorosulfonic acid ionomer compositions
KR20220119048A (ko) * 2019-12-20 2022-08-26 쓰리엠 이노베이티브 프로퍼티즈 컴파니 플루오르화 공중합체 및 이를 포함하는 조성물 및 물품
CN115667332B (zh) * 2020-03-30 2024-08-16 3M创新有限公司 包含具有离子双(磺酰基)酰亚胺部分和全氟醚末端基团的侧基的含氟聚合物
US11746169B2 (en) 2020-07-06 2023-09-05 Asahi Kasei Kabushiki Kaisha Polymer composition and ion-exchange membrane
WO2022118215A1 (en) 2020-12-02 2022-06-09 3M Innovative Properties Company White polytetrafluoroethylene powders
EP4019580A1 (en) 2020-12-28 2022-06-29 3M Innovative Properties Company Reduction of fluorinated acid in fluoropolymers
US20240347751A1 (en) * 2021-07-28 2024-10-17 3M Innovative Properties Company Making an Electrochemical Membrane from Low T(alpha) Fluorinated Ionomer Salts
CN113937303B (zh) * 2021-10-14 2023-07-21 中汽创智科技有限公司 一种催化层电极组合物及包含其的催化层电极、膜电极
CN116265492B (zh) * 2021-12-17 2024-05-14 济南大学 一类氢键增强型全氟共轭阳离子树脂及其合成方法以及阴离子交换膜和膜电极
US20250167273A1 (en) * 2022-06-03 2025-05-22 Celadyne Technologies, Inc. Composite polyelectrolyte-ceramic membranes
CN115132961A (zh) * 2022-06-27 2022-09-30 蜂巢能源科技(无锡)有限公司 一种钠离子电池正极极片及其制备方法和应用
WO2024189366A1 (en) 2023-03-16 2024-09-19 Johnson Matthey Hydrogen Technologies Limited Reinforced ion-conducting membrane
GB2641268A (en) 2024-05-23 2025-11-26 Johnson Matthey Hydrogen Technologies Ltd Water electrolyser membrane

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103732680A (zh) * 2011-08-04 2014-04-16 3M创新有限公司 低当量重量聚合物
CN106459294A (zh) * 2014-05-28 2017-02-22 大金工业株式会社 高透氧性离聚物

Family Cites Families (96)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2559752A (en) 1951-03-06 1951-07-10 Du Pont Aqueous colloidal dispersions of polymers
US3282875A (en) 1964-07-22 1966-11-01 Du Pont Fluorocarbon vinyl ether polymers
US3718627A (en) 1968-11-26 1973-02-27 Du Pont Cf{11 {32 cfcf{11 cf{11 so{11 {11 f and derivatives and polymers thereof
GB1286859A (en) 1968-11-26 1972-08-23 Du Pont Solutions of fluorinated polymers
SE7712836L (sv) 1976-12-02 1978-06-03 Du Pont Polyfluoroallyloxiforeningar
US4267364A (en) 1977-04-20 1981-05-12 E. I. Dupont De Nemours And Company Fluorinated ion exchange polymer containing carboxylic groups, process for making same, and film and membrane thereof
US4349650A (en) 1979-03-14 1982-09-14 E. I. Du Pont De Nemours And Company Polyfluoroallyloxy compounds, their preparation and copolymers therefrom
US4292449A (en) 1979-03-14 1981-09-29 E. I. Du Pont De Nemours And Company Polyfluoroallyloxy compounds, their preparation and copolymers therefrom
US4273729A (en) 1979-03-14 1981-06-16 E. I. Du Pont De Nemours And Company Polyfluoroallyloxy compounds, their preparation and copolymers therefrom
US4275225A (en) 1979-03-14 1981-06-23 E. I. Du Pont De Nemours And Company Polyfluoroallyloxy compounds, their preparation and copolymers therefrom
US4273728A (en) 1979-03-14 1981-06-16 E. I. Du Pont De Nemours And Company Polyfluoroallyloxy compounds, their preparation and copolymers therefrom
US4358545A (en) 1980-06-11 1982-11-09 The Dow Chemical Company Sulfonic acid electrolytic cell having flourinated polymer membrane with hydration product less than 22,000
US4433082A (en) 1981-05-01 1984-02-21 E. I. Du Pont De Nemours And Company Process for making liquid composition of perfluorinated ion exchange polymer, and product thereof
US4423197A (en) 1981-12-01 1983-12-27 Minnesota Mining And Manufacturing Company Cyclic perfluoroaliphatic-disulfonic acid anhydrides and sulfonamide derivatives thereof
US4621116A (en) 1984-12-07 1986-11-04 E. I. Du Pont De Nemours And Company Process for copolymerization of tetrafluoroethylene in the presence of a dispersing agent comprising a perfluoroalkoxybenzene sulfonic acid or salt
US5093409A (en) 1988-05-27 1992-03-03 E. I. Du Pont De Nemours And Company Process for the stabilization of fluoropolymers
JPH027384A (ja) 1988-06-27 1990-01-11 Toshiba Corp 調理器
IT1230718B (it) 1989-02-13 1991-10-29 Ausimont Srl Fluorurazione diretta di fluoro b sultoni ai corrispondenti fluorossi fluorosulfonil fluorocomposti.
US5089200A (en) 1989-10-06 1992-02-18 E. I. Dupont De Nemours And Company Process for melt extrusion of polymers
US5010130A (en) 1990-05-15 1991-04-23 E. I. Du Pont De Nemours And Company High melt viscosity fluoropolymer process aid
US5182342A (en) 1992-02-28 1993-01-26 E. I. Du Pont De Nemours And Company Hydrofluorocarbon solvents for fluoromonomer polymerization
DE4233824A1 (de) 1992-10-08 1994-04-14 Hoechst Ag Verfahren zur Aufarbeitung wäßriger Dispersionen von Fluorthermoplasten
US5285002A (en) 1993-03-23 1994-02-08 Minnesota Mining And Manufacturing Company Fluorine-containing polymers and preparation and use thereof
DE4402694A1 (de) 1993-06-02 1995-08-03 Hoechst Ag Verfahren zur Rückgewinnung von fluorierten Carbonsäuren
US6133389A (en) 1995-02-06 2000-10-17 E. I. Du Pont De Nemours And Company Amorphous tetrafluoroethylene-hexafluoropropylene copolymers
US5780552A (en) 1996-09-13 1998-07-14 E. I. Du Pont De Nemours And Company Fluoropolymers having core/shell structure with functional units in the shell
US5912280A (en) 1996-12-27 1999-06-15 E. I. Du Pont De Nemours And Company Ink jet inks containing emulsion-polymer additives to improve water-fastness
DE69835366T2 (de) * 1997-03-31 2007-07-19 Daikin Industries, Ltd. Verfahren zur herstellung von perfluorvinylethersulfonsäure-derivaten
JPH1167274A (ja) 1997-08-22 1999-03-09 Daikin Ind Ltd リチウム二次電池及び高分子ゲル電解質並びにリチウム二次電池用結着剤
US6388139B1 (en) 1997-11-05 2002-05-14 E. I. Du Pont De Nemours And Company Production of perfluoro (alkyl vinyl) ethers
JP4150867B2 (ja) * 1998-05-13 2008-09-17 ダイキン工業株式会社 燃料電池に使用するのに適した固体高分子電解質用材料
DE19824614A1 (de) 1998-06-02 1999-12-09 Dyneon Gmbh Verfahren zur Rückgewinnung von fluorierten Alkansäuren aus Abwässern
US6294627B1 (en) 1998-08-31 2001-09-25 Dyneon Llc Low temperature fluorocarbon elastomers
MY135964A (en) 1998-10-26 2008-07-31 Du Pont Ionomers and polymers for electrochemical uses
IT1303779B1 (it) 1998-11-23 2001-02-23 Ausimont Spa Preparazione di soluzioni di polimeri fluorurati solfonici.
JP2000188111A (ja) 1998-12-22 2000-07-04 Asahi Glass Co Ltd 固体高分子電解質型燃料電池
US6429258B1 (en) 1999-05-20 2002-08-06 E. I. Du Pont De Nemours & Company Polymerization of fluoromonomers
DE19933696A1 (de) 1999-07-17 2001-01-18 Dyneon Gmbh Verfahren zur Rückgewinnung fluorierter Emulgatoren aus wässrigen Phasen
US6255536B1 (en) 1999-12-22 2001-07-03 Dyneon Llc Fluorine containing vinyl ethers
JP5028711B2 (ja) * 2000-02-15 2012-09-19 旭硝子株式会社 固体高分子型燃料電池
JP4792640B2 (ja) * 2000-02-15 2011-10-12 旭硝子株式会社 ブロックポリマー、重合体の製造方法及びブロックポリマーを含む液状組成物
EP1126537B1 (en) * 2000-02-15 2010-12-15 Asahi Glass Company Ltd. Block polymer, process for producing a polymer, and polymer electrolyte fuel cell
WO2001060876A1 (en) 2000-02-16 2001-08-23 Daikin Industries, Ltd. Process for producing fluoroionomer, method for purification and concentration of the ionomer, and method of film formation
US6794550B2 (en) 2000-04-14 2004-09-21 3M Innovative Properties Company Method of making an aqueous dispersion of fluoropolymers
KR100337889B1 (ko) 2000-06-22 2002-05-24 김순택 리튬 2차전지
DE60135080D1 (de) 2000-12-26 2008-09-11 Asahi Glass Co Ltd Festpolymer-Elektrolyt Material, flüssige Zusammensetzung, Festpolymer Brennstoffzelle und Fluorpolymer
US20020160272A1 (en) 2001-02-23 2002-10-31 Kabushiki Kaisha Toyota Chuo Process for producing a modified electrolyte and the modified electrolyte
US6743508B2 (en) 2002-01-17 2004-06-01 Daikin America, Inc. Fep pellet
US20040107869A1 (en) 2002-12-10 2004-06-10 3M Innovative Properties Company Catalyst ink
US6624328B1 (en) 2002-12-17 2003-09-23 3M Innovative Properties Company Preparation of perfluorinated vinyl ethers having a sulfonyl fluoride end-group
US7589234B2 (en) 2003-07-02 2009-09-15 Daikin Industries, Ltd. Fluoroalkyl carboxylic acid derivative, method for producing fluorine-containing polymer, and aqueous dispersion of fluorine-containing polymer
WO2005007707A1 (ja) 2003-07-16 2005-01-27 Daikin Industries, Ltd. 含フッ素重合体の製造方法、含フッ素重合体水性分散液、２−アシルオキシカルボン酸誘導体及び界面活性剤
US20050037265A1 (en) 2003-08-14 2005-02-17 Asahi Glass Company, Limited Polymer electrolyte fuel cell, electrolyte material therefore and method for its production
EP2452955B1 (en) 2003-09-10 2016-12-14 Asahi Kasei Kabushiki Kaisha Stabilized fluoropolymer and method for producing same
CN100404566C (zh) 2003-10-22 2008-07-23 大金工业株式会社 四氟乙烯聚合物水性分散液、其制造方法、四氟乙烯聚合物粉末以及四氟乙烯聚合物成型体
US7071271B2 (en) 2003-10-30 2006-07-04 3M Innovative Properties Company Aqueous emulsion polymerization of functionalized fluoromonomers
US7265162B2 (en) 2003-11-13 2007-09-04 3M Innovative Properties Company Bromine, chlorine or iodine functional polymer electrolytes crosslinked by e-beam
EP1561729A1 (en) 2004-02-05 2005-08-10 3M Innovative Properties Company Removal of fluorinated surfactants from waste water
US7304101B2 (en) 2004-07-19 2007-12-04 3M Innovative Properties Company Method of purifying a dispersion of ionic fluoropolymer
JP2006036986A (ja) 2004-07-28 2006-02-09 Asahi Glass Co Ltd 含フッ素ポリマーラテックス、その製造方法および含フッ素ポリマー
US7572534B2 (en) 2004-09-20 2009-08-11 3M Innovative Properties Company Fuel cell membrane electrode assembly
JP2006232704A (ja) 2005-02-23 2006-09-07 Asahi Glass Co Ltd 新規なフルオロスルホニル基含有化合物
JP5061446B2 (ja) 2005-03-04 2012-10-31 旭硝子株式会社 含フッ素エラストマーラテックス、その製造方法、含フッ素エラストマーおよび含フッ素ゴム成形品
US7214740B2 (en) 2005-05-03 2007-05-08 3M Innovative Properties Company Fluorinated ionomers with reduced amounts of carbonyl end groups
GB0514387D0 (en) 2005-07-15 2005-08-17 3M Innovative Properties Co Aqueous emulsion polymerization of fluorinated monomers using a perfluoropolyether surfactant
GB0525978D0 (en) 2005-12-21 2006-02-01 3M Innovative Properties Co Fluorinated Surfactants For Making Fluoropolymers
US7795332B2 (en) 2005-07-15 2010-09-14 3M Innovative Properties Company Method of removing fluorinated carboxylic acid from aqueous liquid
US8367267B2 (en) 2005-10-28 2013-02-05 3M Innovative Properties Company High durability fuel cell components with cerium oxide additives
US8628871B2 (en) 2005-10-28 2014-01-14 3M Innovative Properties Company High durability fuel cell components with cerium salt additives
US20070142513A1 (en) 2005-12-21 2007-06-21 Daikin Industries, Ltd. Surfactant, method of producing a fluoropolymer, fluoropolymer aqueous dispersion
ITMI20052509A1 (it) * 2005-12-28 2007-06-29 Solvay Solexis Spa Assemblati per dispositivi elettrochimici
EP1985636B1 (en) 2006-02-03 2019-07-17 Daikin Industries, Ltd. Method for producing -so3h group-containing fluoropolymer
EP1914251A1 (en) 2006-10-17 2008-04-23 Solvay Solexis S.p.A. Process for stabilizing fluoropolymer having ion exchange groups
US7456314B2 (en) * 2006-12-21 2008-11-25 E.I. Du Pont De Nemours And Company Partially fluorinated ionic compounds
US7575534B2 (en) 2006-12-22 2009-08-18 Torvec, Inc. Transmission with resistance torque control
GB0714361D0 (en) 2007-07-24 2007-09-05 3M Innovative Properties Co Cation conductive membranes comprising polysulfonic acid polymers and metal salts having an F-containing anion
CN101821301B (zh) * 2007-10-12 2012-06-27 3M创新有限公司 制备纯净含氟聚合物的方法
GB0801194D0 (en) 2008-01-23 2008-02-27 3M Innovative Properties Co Processing aid compositions comprising fluoropolymers having long-chain branches
JP5217708B2 (ja) 2008-07-09 2013-06-19 旭硝子株式会社 ポリマー、その製造方法、固体高分子形燃料電池用電解質膜および膜電極接合体
US8436053B2 (en) 2008-12-23 2013-05-07 E.I. Du Pont De Nemours And Company Fluorinated ionomer produced by aqueous polymerization using dispersed particulate of fluorinated ionomer
US8058376B2 (en) * 2008-12-23 2011-11-15 E. I. Du Pont De Nemours And Company Fluoropolymer produced by aqueous polymerization using dispersed particulate of fluorinated lonomer produced in situ
JP5540681B2 (ja) 2009-07-14 2014-07-02 株式会社豊田中央研究所 改質電解質及びその製造方法、並びに、改質剤
CN103228708B (zh) 2010-11-26 2015-09-02 索尔维特殊聚合物意大利有限公司 (全)氟化的离子交换聚合物的液体组合物
EP2656425B1 (en) 2010-12-20 2014-12-10 E.I. Du Pont De Nemours And Company Ionomers and ionically conductive compositions for use as one or more electrode of a fuel cell
JP2014500392A (ja) 2010-12-20 2014-01-09 イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー アイオノマー及びイオン伝導性組成物
WO2012088176A1 (en) 2010-12-20 2012-06-28 E. I. Du Pont De Nemours And Company High molecular weight ionomers and ionically conductive compositions for use as one or more electrode of a fuel cell
JP5862372B2 (ja) 2012-03-02 2016-02-16 旭硝子株式会社 ポリマーの製造方法、固体高分子形燃料電池用電解質膜の製造方法および膜電極接合体の製造方法
EP2882705B1 (en) 2012-08-10 2018-02-21 Solvay Specialty Polymers Italy S.p.A. Allyl-bearing fluorinated ionomers
US20150303517A1 (en) 2012-11-08 2015-10-22 Sumitomo Chemical Company, Limited Sodium secondary battery
WO2014088820A1 (en) * 2012-12-04 2014-06-12 3M Innovative Properties Company Highly fluorinated polymers
US20140255703A1 (en) 2013-03-05 2014-09-11 E I Du Pont De Nemours And Company Adhesion of Fluoropolymer to Metal
WO2016130900A1 (en) 2015-02-12 2016-08-18 3M Innovative Properties Company Tetrafluoroethylene/hexafluoropropylene copolymers having pendant sulfonyl groups
GB201505311D0 (en) 2015-03-27 2015-05-13 Johnson Matthey Fuel Cells Ltd Process
US11155661B2 (en) 2015-09-23 2021-10-26 3M Innovative Properties Company Method of making a copolymer of tetrafluoroethylene having sulfonyl pendant groups
CN108779209A (zh) 2016-03-07 2018-11-09 3M创新有限公司 具有磺酰侧基的氟化共聚物和制备离聚物的方法
WO2019055791A1 (en) 2017-09-14 2019-03-21 3M Innovative Properties Company FLUORINATED COPOLYMER HAVING SULFONYL PENDANT GROUPS AND COMPOSITIONS AND ARTICLES COMPRISING SAID FLUORINATED COPOLYMER

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103732680A (zh) * 2011-08-04 2014-04-16 3M创新有限公司 低当量重量聚合物
CN106459294A (zh) * 2014-05-28 2017-02-22 大金工业株式会社 高透氧性离聚物

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