CN110305254A - 一种超亲水性聚氯乙烯薄膜材料及其反应挤出生产方法 - Google Patents
一种超亲水性聚氯乙烯薄膜材料及其反应挤出生产方法 Download PDFInfo
- Publication number
- CN110305254A CN110305254A CN201910646647.4A CN201910646647A CN110305254A CN 110305254 A CN110305254 A CN 110305254A CN 201910646647 A CN201910646647 A CN 201910646647A CN 110305254 A CN110305254 A CN 110305254A
- Authority
- CN
- China
- Prior art keywords
- superhydrophilic
- polyvinyl chloride
- film material
- chloride film
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000004800 polyvinyl chloride Substances 0.000 title claims abstract description 51
- 229920000915 polyvinyl chloride Polymers 0.000 title claims abstract description 50
- 239000000463 material Substances 0.000 title claims abstract description 30
- 238000004519 manufacturing process Methods 0.000 title abstract description 7
- 239000003999 initiator Substances 0.000 claims abstract description 11
- 239000003381 stabilizer Substances 0.000 claims abstract description 11
- 239000011837 N,N-methylenebisacrylamide Substances 0.000 claims abstract description 10
- ZIUHHBKFKCYYJD-UHFFFAOYSA-N n,n'-methylenebisacrylamide Chemical compound C=CC(=O)NCNC(=O)C=C ZIUHHBKFKCYYJD-UHFFFAOYSA-N 0.000 claims abstract description 10
- -1 Methyl stannum Chemical compound 0.000 claims abstract description 8
- 235000021355 Stearic acid Nutrition 0.000 claims abstract description 7
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims abstract description 7
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000004014 plasticizer Substances 0.000 claims abstract description 7
- 235000012424 soybean oil Nutrition 0.000 claims abstract description 7
- 239000003549 soybean oil Substances 0.000 claims abstract description 7
- 239000008117 stearic acid Substances 0.000 claims abstract description 7
- 239000000203 mixture Substances 0.000 claims description 12
- 238000003756 stirring Methods 0.000 claims description 12
- 238000002360 preparation method Methods 0.000 claims description 9
- IHBCFWWEZXPPLG-UHFFFAOYSA-N [Ca].[Zn] Chemical group [Ca].[Zn] IHBCFWWEZXPPLG-UHFFFAOYSA-N 0.000 claims description 6
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical group CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 claims description 6
- 239000002131 composite material Substances 0.000 claims description 6
- 239000000178 monomer Substances 0.000 claims description 6
- 238000010792 warming Methods 0.000 claims description 6
- DMWVYCCGCQPJEA-UHFFFAOYSA-N 2,5-bis(tert-butylperoxy)-2,5-dimethylhexane Chemical group CC(C)(C)OOC(C)(C)CCC(C)(C)OOC(C)(C)C DMWVYCCGCQPJEA-UHFFFAOYSA-N 0.000 claims description 5
- DZSVIVLGBJKQAP-UHFFFAOYSA-N 1-(2-methyl-5-propan-2-ylcyclohex-2-en-1-yl)propan-1-one Chemical compound CCC(=O)C1CC(C(C)C)CC=C1C DZSVIVLGBJKQAP-UHFFFAOYSA-N 0.000 claims description 4
- 238000002156 mixing Methods 0.000 claims description 4
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 claims description 2
- 229920001596 poly (chlorostyrenes) Polymers 0.000 claims description 2
- 239000010408 film Substances 0.000 claims 11
- 150000001336 alkenes Chemical class 0.000 claims 1
- 238000007599 discharging Methods 0.000 claims 1
- 239000010409 thin film Substances 0.000 claims 1
- 230000010148 water-pollination Effects 0.000 abstract description 5
- 238000005516 engineering process Methods 0.000 abstract description 3
- 239000000126 substance Substances 0.000 abstract description 3
- 238000000034 method Methods 0.000 description 7
- 238000001125 extrusion Methods 0.000 description 5
- 230000000052 comparative effect Effects 0.000 description 4
- 150000001408 amides Chemical class 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 229920002301 cellulose acetate Polymers 0.000 description 2
- 229920001477 hydrophilic polymer Polymers 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 238000012856 packing Methods 0.000 description 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 239000005864 Sulphur Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/03—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
- B29C48/07—Flat, e.g. panels
- B29C48/08—Flat, e.g. panels flexible, e.g. films
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/285—Feeding the extrusion material to the extruder
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/36—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die
- B29C48/395—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using screws surrounded by a cooperating barrel, e.g. single screw extruders
- B29C48/40—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using screws surrounded by a cooperating barrel, e.g. single screw extruders using two or more parallel screws or at least two parallel non-intermeshing screws, e.g. twin screw extruders
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/36—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die
- B29C48/50—Details of extruders
- B29C48/505—Screws
- B29C48/625—Screws characterised by the ratio of the threaded length of the screw to its outside diameter [L/D ratio]
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/92—Measuring, controlling or regulating
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F259/00—Macromolecular compounds obtained by polymerising monomers on to polymers of halogen containing monomers as defined in group C08F14/00
- C08F259/02—Macromolecular compounds obtained by polymerising monomers on to polymers of halogen containing monomers as defined in group C08F14/00 on to polymers containing chlorine
- C08F259/04—Macromolecular compounds obtained by polymerising monomers on to polymers of halogen containing monomers as defined in group C08F14/00 on to polymers containing chlorine on to polymers of vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92504—Controlled parameter
- B29C2948/92704—Temperature
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92819—Location or phase of control
- B29C2948/92857—Extrusion unit
- B29C2948/92876—Feeding, melting, plasticising or pumping zones, e.g. the melt itself
- B29C2948/92895—Barrel or housing
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2351/00—Characterised by the use of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives of such polymers
- C08J2351/06—Characterised by the use of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives of such polymers grafted on to homopolymers or copolymers of aliphatic hydrocarbons containing only one carbon-to-carbon double bond
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Mechanical Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Extrusion Moulding Of Plastics Or The Like (AREA)
Abstract
Description
1# | 2# | 3# | 4# |
70℃~80℃ | 120℃~130℃ | 130℃~140℃ | 140℃~150℃ |
5# | 6# | 7# | 8# |
150℃~160℃ | 150℃~160℃ | 160℃~170℃ | 160℃~170℃ |
9# | 10# | 11# | 12# |
150℃~160℃ | 140℃~150℃ | 130℃~140℃ | 120℃~130℃ |
1# | 2# | 3# | 4# |
70℃~80℃ | 110℃~120℃ | 130℃~140℃ | 150℃~160℃ |
5# | 6# | 7# | 8# |
160℃~170℃ | 140℃~150℃ | 130℃~140℃ | 120℃~130℃ |
机头 | |||
130℃~135℃ |
Claims (10)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN201910646647.4A CN110305254B (zh) | 2019-07-17 | 2019-07-17 | 一种超亲水性聚氯乙烯薄膜材料及其反应挤出生产方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201910646647.4A CN110305254B (zh) | 2019-07-17 | 2019-07-17 | 一种超亲水性聚氯乙烯薄膜材料及其反应挤出生产方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN110305254A true CN110305254A (zh) | 2019-10-08 |
CN110305254B CN110305254B (zh) | 2021-06-08 |
Family
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Family Applications (1)
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CN201910646647.4A Active CN110305254B (zh) | 2019-07-17 | 2019-07-17 | 一种超亲水性聚氯乙烯薄膜材料及其反应挤出生产方法 |
Country Status (1)
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Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102558712A (zh) * | 2011-12-30 | 2012-07-11 | 福建思嘉环保材料科技有限公司 | 一种纳米高气密性抗压膜及其制备方法 |
CN103880989A (zh) * | 2014-04-04 | 2014-06-25 | 中国科学院长春应用化学研究所 | 一种改性氯化聚乙烯、其制备方法、氯化聚乙烯硫化胶及其制备方法 |
CN105602138A (zh) * | 2015-12-21 | 2016-05-25 | 江苏宝安电缆有限公司 | 高稳定聚氯乙烯材料及其制备方法 |
CN106745507A (zh) * | 2016-12-30 | 2017-05-31 | 常州碳星科技有限公司 | 一种抗污染的油水分离网膜及其制备方法 |
CN108727602A (zh) * | 2018-07-04 | 2018-11-02 | 柴建锋 | 一种水性环氧改性聚氯乙烯基树脂及其制备方法 |
CN109233153A (zh) * | 2018-09-29 | 2019-01-18 | 吴加松 | 一种疏水聚氯乙烯材料及其制备方法 |
CN109569331A (zh) * | 2018-12-18 | 2019-04-05 | 万华化学集团股份有限公司 | 一种亲水性抗菌滤膜的制备方法 |
-
2019
- 2019-07-17 CN CN201910646647.4A patent/CN110305254B/zh active Active
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102558712A (zh) * | 2011-12-30 | 2012-07-11 | 福建思嘉环保材料科技有限公司 | 一种纳米高气密性抗压膜及其制备方法 |
CN103880989A (zh) * | 2014-04-04 | 2014-06-25 | 中国科学院长春应用化学研究所 | 一种改性氯化聚乙烯、其制备方法、氯化聚乙烯硫化胶及其制备方法 |
CN105602138A (zh) * | 2015-12-21 | 2016-05-25 | 江苏宝安电缆有限公司 | 高稳定聚氯乙烯材料及其制备方法 |
CN106745507A (zh) * | 2016-12-30 | 2017-05-31 | 常州碳星科技有限公司 | 一种抗污染的油水分离网膜及其制备方法 |
CN108727602A (zh) * | 2018-07-04 | 2018-11-02 | 柴建锋 | 一种水性环氧改性聚氯乙烯基树脂及其制备方法 |
CN109233153A (zh) * | 2018-09-29 | 2019-01-18 | 吴加松 | 一种疏水聚氯乙烯材料及其制备方法 |
CN109569331A (zh) * | 2018-12-18 | 2019-04-05 | 万华化学集团股份有限公司 | 一种亲水性抗菌滤膜的制备方法 |
Non-Patent Citations (1)
Title |
---|
S. S. PESETSKII,ET AL.: ""Free radical grafting of itaconic acid and glycidyl methacrylate onto PP initiated by organic peroxides"", 《J APPL POLYM SCI》 * |
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Publication number | Publication date |
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Denomination of invention: A super hydrophilic PVC film material and its reactive extrusion production method Effective date of registration: 20221209 Granted publication date: 20210608 Pledgee: Jiangsu Yixing rural commercial bank Limited by Share Ltd. Branch Park Branch Pledgor: JIANGSU BAOAN CABLE Co.,Ltd. Registration number: Y2022980026157 |
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Address after: 214205 west side of huankeyuan chaquan Road, Xinjie street, Yixing City, Wuxi City, Jiangsu Province Patentee after: Jiangsu Bao'an Cable Co.,Ltd. Address before: 214205 west side of huankeyuan chaquan Road, Xinjie street, Yixing City, Wuxi City, Jiangsu Province Patentee before: JIANGSU BAOAN CABLE Co.,Ltd. |