CN110267932B - 用于自复分解连同受控异构化和裂化的多级催化剂系统 - Google Patents
用于自复分解连同受控异构化和裂化的多级催化剂系统 Download PDFInfo
- Publication number
- CN110267932B CN110267932B CN201880010205.4A CN201880010205A CN110267932B CN 110267932 B CN110267932 B CN 110267932B CN 201880010205 A CN201880010205 A CN 201880010205A CN 110267932 B CN110267932 B CN 110267932B
- Authority
- CN
- China
- Prior art keywords
- catalyst
- silica
- butene
- zone
- alumina
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/24—Chromium, molybdenum or tungsten
- B01J23/28—Molybdenum
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
- C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
- C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
- C07C2/08—Catalytic processes
- C07C2/12—Catalytic processes with crystalline alumino-silicates or with catalysts comprising molecular sieves
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
- B01J21/08—Silica
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/12—Silica and alumina
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/24—Chromium, molybdenum or tungsten
- B01J23/30—Tungsten
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/32—Manganese, technetium or rhenium
- B01J23/36—Rhenium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/03—Catalysts comprising molecular sieves not having base-exchange properties
- B01J29/035—Microporous crystalline materials not having base exchange properties, such as silica polymorphs, e.g. silicalites
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/19—Catalysts containing parts with different compositions
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
- B01J35/34—Mechanical properties
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/61—Surface area
- B01J35/615—100-500 m2/g
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/61—Surface area
- B01J35/617—500-1000 m2/g
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/63—Pore volume
- B01J35/635—0.5-1.0 ml/g
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/63—Pore volume
- B01J35/638—Pore volume more than 1.0 ml/g
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/64—Pore diameter
- B01J35/647—2-50 nm
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/70—Catalysts, in general, characterised by their form or physical properties characterised by their crystalline properties, e.g. semi-crystalline
- B01J35/77—Compounds characterised by their crystallite size
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0201—Impregnation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/08—Heat treatment
- B01J37/082—Decomposition and pyrolysis
- B01J37/088—Decomposition of a metal salt
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C11/00—Aliphatic unsaturated hydrocarbons
- C07C11/02—Alkenes
- C07C11/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C11/00—Aliphatic unsaturated hydrocarbons
- C07C11/02—Alkenes
- C07C11/08—Alkenes with four carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
- C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
- C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
- C07C2/08—Catalytic processes
- C07C2/10—Catalytic processes with metal oxides
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C4/00—Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms
- C07C4/02—Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms by cracking a single hydrocarbon or a mixture of individually defined hydrocarbons or a normally gaseous hydrocarbon fraction
- C07C4/06—Catalytic processes
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
- C07C5/22—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
- C07C5/23—Rearrangement of carbon-to-carbon unsaturated bonds
- C07C5/25—Migration of carbon-to-carbon double bonds
- C07C5/2506—Catalytic processes
- C07C5/2512—Catalytic processes with metal oxides
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
- C07C5/22—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
- C07C5/23—Rearrangement of carbon-to-carbon unsaturated bonds
- C07C5/25—Migration of carbon-to-carbon double bonds
- C07C5/2506—Catalytic processes
- C07C5/2518—Catalytic processes with crystalline alumino-silicates, e.g. molecular sieves
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C6/00—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions
- C07C6/02—Metathesis reactions at an unsaturated carbon-to-carbon bond
- C07C6/04—Metathesis reactions at an unsaturated carbon-to-carbon bond at a carbon-to-carbon double bond
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
- B01J2235/15—X-ray diffraction
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
- B01J29/48—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing arsenic, antimony, bismuth, vanadium, niobium tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
- C07C2521/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
- C07C2521/08—Silica
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
- C07C2521/12—Silica and alumina
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- C07C2523/24—Chromium, molybdenum or tungsten
- C07C2523/30—Tungsten
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2529/00—Catalysts comprising molecular sieves
- C07C2529/03—Catalysts comprising molecular sieves not having base-exchange properties
- C07C2529/035—Crystalline silica polymorphs, e.g. silicalites
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2529/00—Catalysts comprising molecular sieves
- C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
- C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- C07C2529/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Crystallography & Structural Chemistry (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Nanotechnology (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201762448478P | 2017-01-20 | 2017-01-20 | |
| US62/448,478 | 2017-01-20 | ||
| PCT/US2018/014367 WO2018136707A1 (en) | 2017-01-20 | 2018-01-19 | Multiple-stage catalyst system for self-metathesis with controlled isomerization and cracking |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN110267932A CN110267932A (zh) | 2019-09-20 |
| CN110267932B true CN110267932B (zh) | 2022-03-25 |
Family
ID=61913519
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201880010205.4A Active CN110267932B (zh) | 2017-01-20 | 2018-01-19 | 用于自复分解连同受控异构化和裂化的多级催化剂系统 |
Country Status (8)
| Country | Link |
|---|---|
| US (2) | US10550048B2 (enExample) |
| EP (1) | EP3571178B1 (enExample) |
| JP (1) | JP7179429B2 (enExample) |
| KR (1) | KR20190104064A (enExample) |
| CN (1) | CN110267932B (enExample) |
| SA (1) | SA519402263B1 (enExample) |
| SG (1) | SG11201906566UA (enExample) |
| WO (1) | WO2018136707A1 (enExample) |
Families Citing this family (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US10550048B2 (en) | 2017-01-20 | 2020-02-04 | Saudi Arabian Oil Company | Multiple-stage catalyst system for self-metathesis with controlled isomerization and cracking |
| US10975004B2 (en) | 2019-01-03 | 2021-04-13 | Saudi Arabian Oil Company | Integrated process for production of ethylene from propylene |
| CN111905800A (zh) * | 2019-05-10 | 2020-11-10 | 中国石油天然气股份有限公司 | 含钼及含镍或/和锌的多级结构zsm-5分子筛及其制备方法和其应用 |
| EP3822244A1 (de) * | 2019-11-14 | 2021-05-19 | Evonik Operations GmbH | Verfahren zur isomerisierung von olefinen |
| US11311869B2 (en) | 2019-12-03 | 2022-04-26 | Saudi Arabian Oil Company | Methods of producing isomerization catalysts |
| US11517892B2 (en) | 2019-12-03 | 2022-12-06 | Saudi Arabian Oil Company | Methods of producing isomerization catalysts |
| US11339332B2 (en) | 2020-01-29 | 2022-05-24 | Saudi Arabian Oil Company | Systems and processes integrating fluidized catalytic cracking with metathesis for producing olefins |
| US11572516B2 (en) | 2020-03-26 | 2023-02-07 | Saudi Arabian Oil Company | Systems and processes integrating steam cracking with dual catalyst metathesis for producing olefins |
| CN116075493A (zh) * | 2020-09-15 | 2023-05-05 | 利安德化学技术有限公司 | 用于将萃余液丁烯转化为丙烯的方法 |
| US11679378B2 (en) | 2021-02-25 | 2023-06-20 | Saudi Arabian Oil Company | Methods of producing isomerization catalysts |
| US11319263B1 (en) * | 2021-03-03 | 2022-05-03 | Saudi Arabian Oil Company | Methods for low temperature production of 1-butene |
| US11845705B2 (en) | 2021-08-17 | 2023-12-19 | Saudi Arabian Oil Company | Processes integrating hydrocarbon cracking with metathesis for producing propene |
| JP2025506532A (ja) * | 2022-02-18 | 2025-03-11 | シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー | 異性化及び不均化触媒組成物 |
| CN118056615A (zh) * | 2022-11-21 | 2024-05-21 | 中国科学院大连化学物理研究所 | 一种负载型Mo基催化剂及其制备方法和应用 |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101098839A (zh) * | 2004-11-08 | 2008-01-02 | Abb路慕斯全球股份有限公司 | 乙烯与丁烯复分解生产丙烯的催化剂和方法 |
| CN101514135A (zh) * | 2008-02-20 | 2009-08-26 | 中国石油化工股份有限公司 | 碳四混合物催化异构制1-丁烯的方法 |
| CN102649671A (zh) * | 2011-02-25 | 2012-08-29 | 中国石油化工股份有限公司 | 丁烯异构化反应的方法 |
| CN105272800A (zh) * | 2014-07-24 | 2016-01-27 | 中国石油化工股份有限公司 | 丁烯-2异构化为丁烯-1的方法 |
| CN105461500A (zh) * | 2014-09-05 | 2016-04-06 | 中国科学院生态环境研究中心 | 一种在室温条件下催化1-丁烯异构化合成2-丁烯的方法 |
| WO2017003812A1 (en) * | 2015-07-02 | 2017-01-05 | Saudi Arabian Oil Company | Dual catalyst system for propylene production |
| WO2017003821A1 (en) * | 2015-07-02 | 2017-01-05 | Saudi Arabian Oil Company | Propylene production using a mesoporous silica foam metathesis catalyst |
Family Cites Families (78)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3442821A (en) * | 1966-09-29 | 1969-05-06 | Universal Oil Prod Co | Manufacture of spheroidal silica-alumina particles |
| US3546313A (en) | 1967-04-03 | 1970-12-08 | Phillips Petroleum Co | Conversion of olefins |
| NL135562C (enExample) | 1967-04-03 | |||
| GB1205677A (en) | 1968-01-19 | 1970-09-16 | Ici Ltd | Disproportionation of olefines |
| US3702886A (en) | 1969-10-10 | 1972-11-14 | Mobil Oil Corp | Crystalline zeolite zsm-5 and method of preparing the same |
| US3728415A (en) | 1971-03-25 | 1973-04-17 | Petro Tex Chem Corp | Production of n-butenes from ethylene |
| GB1489300A (en) | 1974-08-26 | 1977-10-19 | Agency Ind Science Techn | Process for the selective disproportionation reaction of olefins |
| US4071471A (en) | 1974-12-23 | 1978-01-31 | Phillips Petroleum Company | Catalysts for conversion of olefins |
| IT1190839B (it) * | 1982-05-27 | 1988-02-24 | Anic Spa | Procedimento per la isomerizzazione di legame delle olefine |
| DE3775059D1 (de) | 1983-03-10 | 1992-01-16 | Dow Chemical Co | Verfahren zur disproportionierung von alkenen. |
| US4609769A (en) | 1984-02-15 | 1986-09-02 | Phillips Petroleum Company | Olefin conversion |
| US4575575A (en) | 1984-04-05 | 1986-03-11 | Phillips Petroleum Company | Catalysts and process for olefin conversion |
| NL8403050A (nl) | 1984-10-06 | 1986-05-01 | Stamicarbon | Katalysatorsysteem, geschikt voor de metathese van gefunktionaliseerde olefinen. |
| US5191131A (en) | 1988-12-05 | 1993-03-02 | Research Association For Utilization Of Light Oil | Process for preparation of lower aliphatic hydrocarbons |
| US5026936A (en) | 1989-10-02 | 1991-06-25 | Arco Chemical Technology, Inc. | Enhanced production of propylene from higher hydrocarbons |
| US5026935A (en) | 1989-10-02 | 1991-06-25 | Arco Chemical Technology, Inc. | Enhanced production of ethylene from higher hydrocarbons |
| US5439859A (en) | 1992-04-27 | 1995-08-08 | Sun Company, Inc. (R&M) | Process and catalyst for dehydrogenation of organic compounds |
| US5523502A (en) | 1993-11-10 | 1996-06-04 | Stone & Webster Engineering Corp. | Flexible light olefins production |
| FR2733986B1 (fr) | 1995-05-11 | 1997-06-13 | Inst Francais Du Petrole | Procede et installation pour la conversion de coupes c4 olefiniques en polyisobutenes et en propylene |
| US6159433A (en) | 1995-05-11 | 2000-12-12 | Institut Francais Du Petrole | Plant for the conversion of olefinic C4 and C5 cuts to an ether and to propylene |
| NO319519B1 (no) | 1997-10-15 | 2005-08-22 | Res Inst Petroleum Processing | Fremgangsmate for fremstilling av etylen og propylen ved katalytisk pyrolyse av tunge hydrokarboner |
| DE19746040A1 (de) | 1997-10-17 | 1999-04-22 | Basf Ag | Verfahren zur Herstellung von Propen |
| EP0921181A1 (en) | 1997-12-05 | 1999-06-09 | Fina Research S.A. | Production of propylene |
| EP0920911A1 (en) | 1997-12-05 | 1999-06-09 | Fina Research S.A. | Production of catalysts for olefin conversion |
| FR2773558B1 (fr) * | 1998-01-14 | 2000-02-18 | Inst Francais Du Petrole | Procede pour l'obtention de 1-butene |
| US6586649B1 (en) | 1998-09-04 | 2003-07-01 | Sasol Technology (Proprietary) Limited | Production of propylene |
| KR20020010149A (ko) | 1999-05-20 | 2002-02-02 | 엑손모빌 케미칼 패턴츠 인코포레이티드 | 다공성 무기 산화물의 금속 함유 거대 구조체, 그의제조방법 및 용도 |
| DE19932060A1 (de) | 1999-07-12 | 2001-01-18 | Basf Ag | Verfahren zur Herstellung von C¶5¶-/C¶6¶-Olefinen |
| DE10013253A1 (de) | 2000-03-17 | 2001-09-20 | Basf Ag | Verfahren zur flexiblen Herstellung von Propen und Hexen |
| US7566799B2 (en) | 2001-10-01 | 2009-07-28 | Basf Aktiengesellschaft | Process for the preparation of alkylaryl compounds and sulfonates thereof |
| US6777582B2 (en) | 2002-03-07 | 2004-08-17 | Abb Lummus Global Inc. | Process for producing propylene and hexene from C4 olefin streams |
| CN100402148C (zh) | 2002-08-16 | 2008-07-16 | Sasol技术股份有限公司 | 复分解催化剂及方法 |
| DE10319439A1 (de) | 2003-04-30 | 2004-11-18 | Basf Ag | Aktivierte Metathesekatalysatoren |
| US7214841B2 (en) | 2003-07-15 | 2007-05-08 | Abb Lummus Global Inc. | Processing C4 olefin streams for the maximum production of propylene |
| ITMI20040855A1 (it) | 2004-04-29 | 2004-07-29 | Polimeri Europa Spa | Catalizzatore di renio supportato su allimuna modificata e suo impiego nella reazione di metatesi delle olefine |
| TWI371440B (en) | 2004-07-16 | 2012-09-01 | Asahi Kasei Chemicals Corp | Method of producing ethylene and propylene |
| US20060047176A1 (en) | 2004-08-25 | 2006-03-02 | Gartside Robert J | Butane removal in C4 upgrading processes |
| DE102004041850A1 (de) | 2004-08-27 | 2006-03-02 | Basf Ag | Verfahren zur Herstellung von C5-Aldehyden und Propen aus einem 1-Buten- und 2-Buten-haltigen C4-Strom |
| DE102004049940A1 (de) | 2004-10-13 | 2006-04-20 | Basf Ag | Verfahren zur Herstellung eines C4-Olefin-Gemisches durch Selektivhydrierung und Metatheseverfahren zur Verwendung dieses Stroms |
| FR2880018B1 (fr) * | 2004-12-27 | 2007-02-23 | Inst Francais Du Petrole | Production de propylene mettant en oeuvre la dimerisation de l'ethylene en butene-1, l'hydro-isomerisation en butene-2 et la metathese par l'ethylene |
| DE102005009596A1 (de) | 2005-02-28 | 2006-08-31 | Basf Ag | Verfahren zur Metathese umfassend die Reinigung der Ausgangsstoffe |
| RU2367644C2 (ru) | 2005-03-03 | 2009-09-20 | Мицуи Кемикалз, Инк. | Способ получения олефинов |
| US7692057B2 (en) | 2005-08-15 | 2010-04-06 | China Petroleum & Chemical Corporation | Process for producing lower olefins by using multiple reaction zones |
| WO2007141277A1 (de) | 2006-06-06 | 2007-12-13 | Basf Se | Herstellung reaktiver, im wesentlichen halogenfreier polyisobutene aus isobuten-armen c4-kohlenwasserstoff-gemischen |
| WO2008071640A2 (en) | 2006-12-12 | 2008-06-19 | Shell Internationale Research Maatschappij B.V. | Process for preparing a catalyst |
| MY146409A (en) | 2007-04-27 | 2012-08-15 | Mitsui Chemicals Inc | Process for producing olefins |
| US7728185B2 (en) | 2007-07-23 | 2010-06-01 | Uop Llc | Integration of olefin cracking with metathesis to increase light olefins production |
| RU2370314C1 (ru) | 2008-02-27 | 2009-10-20 | Общество с ограниченной ответственностью "Объединенный центр исследований и разработок" | Катализатор и способ получения пропилена |
| CN101531558B (zh) | 2008-03-13 | 2013-04-24 | 中国石油化工股份有限公司 | 一种制取丙烯和芳烃的催化转化方法 |
| US20090240010A1 (en) | 2008-03-20 | 2009-09-24 | Mcdaniel Max P | Alumina-silica activator-supports for metallocene catalyst compositions |
| CA2733890C (en) | 2008-08-12 | 2013-10-01 | Lummus Technology Inc. | Integrated propylene production |
| CN102131752A (zh) | 2008-08-28 | 2011-07-20 | 三井化学株式会社 | 烯烃制造方法 |
| EP2331488B1 (en) * | 2008-09-04 | 2025-02-26 | Lummus Technology Inc. | Olefin isomerization and metathesis catalyst |
| US8119849B2 (en) | 2008-12-29 | 2012-02-21 | Lyondell Chemical Technology, L.P. | Propylene production |
| US8586813B2 (en) | 2009-07-21 | 2013-11-19 | Lummus Technology Inc. | Catalyst for metathesis of ethylene and 2-butene and/or double bond isomerization |
| US8324440B2 (en) | 2010-02-05 | 2012-12-04 | Uop Llc | Support properties of silica supported catalysts and their use in olefin metathesis |
| US8895795B2 (en) | 2010-02-05 | 2014-11-25 | Uop Llc | Acid washed silica supported catalysts and their use in olefin metathesis |
| US8722950B2 (en) | 2010-04-26 | 2014-05-13 | Saudi Basic Industries Corporation | Process for producing propylene and aromatics from butenes by metathesis and aromatization |
| US9079159B2 (en) | 2011-04-14 | 2015-07-14 | Uop Llc | Olefin metathesis process using a treated tungsten oxide catalyst |
| US20120289617A1 (en) | 2011-05-10 | 2012-11-15 | Saudi Arabian Oil Company | Hybrid Catalyst for Olefin Metathesis |
| KR101286273B1 (ko) | 2011-06-10 | 2013-07-15 | 주식회사 동양매직 | 이온수기 유로 시스템의 제어 방법 |
| US20130085311A1 (en) | 2011-09-29 | 2013-04-04 | Honam Petrochemical Corporation | Zsm-5 catalyst with micropores and mesopores, preparation method thereof and production method of light olefins through catalytic cracking of hydrocarbons using the catalyst |
| US8575406B2 (en) | 2011-12-22 | 2013-11-05 | Celanese International Corporation | Catalysts having promoter metals and process for producing ethanol |
| KR20140139224A (ko) | 2013-05-27 | 2014-12-05 | 이창길 | 온수매트 제조방법 및 이를 통해 제조된 온수매트 |
| EP2862629A1 (en) | 2013-10-15 | 2015-04-22 | Borealis AG | Catalyst and process for olefin metathesis reaction |
| CN105764875B (zh) * | 2013-11-20 | 2018-05-22 | 鲁姆斯科技公司 | 烯烃转化方法 |
| PL3071538T3 (pl) | 2013-11-20 | 2021-09-06 | Lummus Technology Llc | Katalizator izomeryzacji podwójnego wiązania olefiny o wysokiej odporności na zatrucie |
| CN104370676B (zh) | 2014-11-11 | 2016-06-08 | 中国石油天然气集团公司 | 一种以碳四烯烃为原料生产丙烯副产乙烯的方法 |
| US9656928B2 (en) | 2014-11-12 | 2017-05-23 | King Fahd University Of Petroleum And Minerals | Processes and catalysts for production of light olefins |
| WO2017003817A1 (en) | 2015-07-02 | 2017-01-05 | Saudi Arabian Oil Company | Systems and methods for producing propylene |
| EP3317237B1 (en) | 2015-07-02 | 2024-09-25 | Saudi Arabian Oil Company | Systems and methods for producing propylene |
| FR3039543B1 (fr) | 2015-07-31 | 2019-04-12 | IFP Energies Nouvelles | Procede de metathese des olefines utilisant un catalyseur contenant de l'aluminium et du molybdene incorpores au moyen d'au moins deux precurseurs |
| KR101840378B1 (ko) | 2016-11-09 | 2018-03-21 | 한국화학연구원 | 올레핀 복분해 반응용 촉매 및 이의 제조방법 |
| US20180142167A1 (en) | 2016-11-21 | 2018-05-24 | Saudi Arabian Oil Company | Process and system for conversion of crude oil to chemicals and fuel products integrating steam cracking and fluid catalytic cracking |
| CN110088067A (zh) | 2016-12-21 | 2019-08-02 | 沙特基础全球技术有限公司 | 由催化裂化的烃料流生产烯烃的方法 |
| US10550048B2 (en) | 2017-01-20 | 2020-02-04 | Saudi Arabian Oil Company | Multiple-stage catalyst system for self-metathesis with controlled isomerization and cracking |
| US10934231B2 (en) | 2017-01-20 | 2021-03-02 | Saudi Arabian Oil Company | Multiple-stage catalyst systems and processes for propene production |
| US10329225B2 (en) | 2017-01-20 | 2019-06-25 | Saudi Arabian Oil Company | Dual catalyst processes and systems for propylene production |
-
2018
- 2018-01-17 US US15/873,421 patent/US10550048B2/en active Active
- 2018-01-19 JP JP2019539269A patent/JP7179429B2/ja active Active
- 2018-01-19 KR KR1020197024304A patent/KR20190104064A/ko not_active Ceased
- 2018-01-19 SG SG11201906566UA patent/SG11201906566UA/en unknown
- 2018-01-19 EP EP18716691.3A patent/EP3571178B1/en active Active
- 2018-01-19 WO PCT/US2018/014367 patent/WO2018136707A1/en not_active Ceased
- 2018-01-19 CN CN201880010205.4A patent/CN110267932B/zh active Active
-
2019
- 2019-07-21 SA SA519402263A patent/SA519402263B1/ar unknown
- 2019-12-12 US US16/712,280 patent/US11242297B2/en active Active
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101098839A (zh) * | 2004-11-08 | 2008-01-02 | Abb路慕斯全球股份有限公司 | 乙烯与丁烯复分解生产丙烯的催化剂和方法 |
| CN101514135A (zh) * | 2008-02-20 | 2009-08-26 | 中国石油化工股份有限公司 | 碳四混合物催化异构制1-丁烯的方法 |
| CN102649671A (zh) * | 2011-02-25 | 2012-08-29 | 中国石油化工股份有限公司 | 丁烯异构化反应的方法 |
| CN105272800A (zh) * | 2014-07-24 | 2016-01-27 | 中国石油化工股份有限公司 | 丁烯-2异构化为丁烯-1的方法 |
| CN105461500A (zh) * | 2014-09-05 | 2016-04-06 | 中国科学院生态环境研究中心 | 一种在室温条件下催化1-丁烯异构化合成2-丁烯的方法 |
| WO2017003812A1 (en) * | 2015-07-02 | 2017-01-05 | Saudi Arabian Oil Company | Dual catalyst system for propylene production |
| WO2017003821A1 (en) * | 2015-07-02 | 2017-01-05 | Saudi Arabian Oil Company | Propylene production using a mesoporous silica foam metathesis catalyst |
Also Published As
| Publication number | Publication date |
|---|---|
| EP3571178A1 (en) | 2019-11-27 |
| SA519402263B1 (ar) | 2022-04-21 |
| US10550048B2 (en) | 2020-02-04 |
| CN110267932A (zh) | 2019-09-20 |
| JP2020505370A (ja) | 2020-02-20 |
| KR20190104064A (ko) | 2019-09-05 |
| US20200131099A1 (en) | 2020-04-30 |
| SG11201906566UA (en) | 2019-08-27 |
| JP7179429B2 (ja) | 2022-11-29 |
| US20180208524A1 (en) | 2018-07-26 |
| EP3571178B1 (en) | 2021-01-13 |
| US11242297B2 (en) | 2022-02-08 |
| WO2018136707A1 (en) | 2018-07-26 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN110267932B (zh) | 用于自复分解连同受控异构化和裂化的多级催化剂系统 | |
| KR102513667B1 (ko) | 다단계 촉매 시스템 및 프로펜 생산 방법 | |
| US10583423B2 (en) | Dual catalyst system for propylene production | |
| US10919822B2 (en) | Dual catalyst processes and systems for propylene production | |
| JP2020500710A (ja) | 触媒系および前記触媒系を利用する炭化水素フィードの変換方法 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |