GB1205677A - Disproportionation of olefines - Google Patents

Disproportionation of olefines

Info

Publication number
GB1205677A
GB1205677A GB9468/68A GB946868A GB1205677A GB 1205677 A GB1205677 A GB 1205677A GB 9468/68 A GB9468/68 A GB 9468/68A GB 946868 A GB946868 A GB 946868A GB 1205677 A GB1205677 A GB 1205677A
Authority
GB
United Kingdom
Prior art keywords
butene
pentene
cis
trans
disproportionation
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB9468/68A
Inventor
Roy John Sampson
Ivan James Samuel Lake
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Imperial Chemical Industries Ltd
Original Assignee
Imperial Chemical Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Imperial Chemical Industries Ltd filed Critical Imperial Chemical Industries Ltd
Priority to GB9468/68A priority Critical patent/GB1205677A/en
Priority to FR1600597D priority patent/FR1600597A/fr
Priority to BE726673D priority patent/BE726673A/xx
Priority to NL6900368A priority patent/NL6900368A/xx
Priority to DE19691901648 priority patent/DE1901648A1/en
Publication of GB1205677A publication Critical patent/GB1205677A/en
Expired legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C6/00—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions
    • C07C6/02—Metathesis reactions at an unsaturated carbon-to-carbon bond
    • C07C6/04—Metathesis reactions at an unsaturated carbon-to-carbon bond at a carbon-to-carbon double bond
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/64—Platinum group metals with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/8933—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/02—Boron or aluminium; Oxides or hydroxides thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/02—Boron or aluminium; Oxides or hydroxides thereof
    • C07C2521/04—Alumina
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • C07C2521/08—Silica
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/10—Magnesium; Oxides or hydroxides thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/12—Silica and alumina
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/24—Chromium, molybdenum or tungsten
    • C07C2523/28—Molybdenum
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/24—Chromium, molybdenum or tungsten
    • C07C2523/30—Tungsten
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/32—Manganese, technetium or rhenium
    • C07C2523/36—Rhenium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
    • C07C2523/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals of the platinum group metals
    • C07C2523/42—Platinum
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
    • C07C2523/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals of the platinum group metals
    • C07C2523/44—Palladium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
    • C07C2523/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals of the platinum group metals
    • C07C2523/46—Ruthenium, rhodium, osmium or iridium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
    • C07C2523/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals combined with metals, oxides or hydroxides provided for in groups C07C2523/02 - C07C2523/36
    • C07C2523/56—Platinum group metals
    • C07C2523/64—Platinum group metals with arsenic, antimony, bismuth, vanadium, niobium, tatalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

1,205,677. Olefin conversion. IMPERIAL CHEMICAL INDUSTRIES Ltd. 20 Dec., 1968 [19 Jan., 1968; 27 Feb., 1968], Nos. 3025/68 and 9468/68. Heading C5E. An olefin feed is brought into contact with a catalyst which includes a disproportionation agent i.e. a noble metal of Group VIII and a double bond isomerization agent e.g. MoO 3 (optionally associated with CoO), WO 3 or Re 2 O 7 . Examples describe the passage of (1) cis-butene-2 through such a catalyst bed to yield propylene, butene-1, trans-butene-2, pentene-1 and cis and trams pentene-2; and (2) a mixture of cis-butene-2 and isobutene to yield propylene, butene-1, trans-butene-2, pentene-1, cis and trans and pentene-2, isopentene. Reference has been directed by the Comptroller to Specification 1,117,968.
GB9468/68A 1968-01-19 1968-01-19 Disproportionation of olefines Expired GB1205677A (en)

Priority Applications (5)

Application Number Priority Date Filing Date Title
GB9468/68A GB1205677A (en) 1968-01-19 1968-01-19 Disproportionation of olefines
FR1600597D FR1600597A (en) 1968-01-19 1968-12-30
BE726673D BE726673A (en) 1968-01-19 1969-01-09
NL6900368A NL6900368A (en) 1968-01-19 1969-01-09
DE19691901648 DE1901648A1 (en) 1968-01-19 1969-01-14 Catalyst and process for the disproportionation of olefins

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB302568 1968-01-19
GB9468/68A GB1205677A (en) 1968-01-19 1968-01-19 Disproportionation of olefines

Publications (1)

Publication Number Publication Date
GB1205677A true GB1205677A (en) 1970-09-16

Family

ID=26237943

Family Applications (1)

Application Number Title Priority Date Filing Date
GB9468/68A Expired GB1205677A (en) 1968-01-19 1968-01-19 Disproportionation of olefines

Country Status (5)

Country Link
BE (1) BE726673A (en)
DE (1) DE1901648A1 (en)
FR (1) FR1600597A (en)
GB (1) GB1205677A (en)
NL (1) NL6900368A (en)

Cited By (30)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3728415A (en) * 1971-03-25 1973-04-17 Petro Tex Chem Corp Production of n-butenes from ethylene
EP0016852A1 (en) * 1976-05-21 1980-10-15 The Dow Chemical Company Process for producing C2-C4 hydrocarbons from carbon monoxide and hydrogen
US4419527A (en) 1982-07-29 1983-12-06 Monsanto Company Catalyst and reverse disproportionation process
US4419526A (en) 1982-07-29 1983-12-06 Monsanto Company Catalyst and reverse disproportionation process
US4439626A (en) * 1982-07-29 1984-03-27 Monsanto Company Catalyst and reverse disproportionation process
US4439628A (en) * 1982-07-29 1984-03-27 Monsanto Company Catalyst and reverse disproportionation process
US4439627A (en) * 1982-07-29 1984-03-27 Monsanto Company Catalyst and reverse disproportionation process
US4440968A (en) * 1982-07-29 1984-04-03 Monsanto Company Catalyst and reverse disproportionation process
US4440967A (en) * 1982-07-29 1984-04-03 Monsanto Company Catalyst and reverse disproportionation process
US4448894A (en) * 1982-07-29 1984-05-15 Monsanto Company Catalyst and reverse disproportionation process
US4474897A (en) * 1982-07-29 1984-10-02 Monsanto Company Catalyst useable in a reverse disproportionation process
US4487849A (en) * 1982-07-29 1984-12-11 Monsanto Company Catalyst for the reverse disproportionation process
US4490477A (en) * 1982-07-29 1984-12-25 Monsanto Company Catalyst and reverse disproportionation process
US4511672A (en) * 1982-07-29 1985-04-16 Monsanto Company Catalyst and reverse disproportionation process
US4514519A (en) * 1982-07-29 1985-04-30 Monsanto Company Catalyst and reverse disproportionation process
US4996386A (en) * 1989-12-21 1991-02-26 Shell Oil Company Concurrent isomerization and disproportionation of olefins
EP0442159A1 (en) * 1989-12-21 1991-08-21 Shell Internationale Researchmaatschappij B.V. Concurrent isomerization and disproportionation of olefins
US5087780A (en) * 1988-10-31 1992-02-11 Chemical Research & Licensing Company Hydroisomerization process
US5120896A (en) * 1989-12-21 1992-06-09 Shell Oil Company Concurrent isomerization and disproportionation of olefins
US5243120A (en) * 1991-10-30 1993-09-07 Shell Oil Company Process for the production of olefins
US5321163A (en) * 1993-09-09 1994-06-14 Chemical Research & Licensing Company Multi-purpose catalytic distillation column and eterification process using same
US7977522B2 (en) 2005-03-03 2011-07-12 Mitsui Chemicals, Inc. Process of producing olefins
WO2020076590A1 (en) * 2018-10-10 2020-04-16 Saudi Arabian Oil Company Catalysts that include metal oxide co-catalysts for the production of propylene
WO2020076589A1 (en) * 2018-10-10 2020-04-16 Saudi Arabian Oil Company Catalysts that include metal oxide co-catalysts for the production of propylene
US10919822B2 (en) 2017-01-20 2021-02-16 Saudi Arabian Oil Company Dual catalyst processes and systems for propylene production
US10934231B2 (en) 2017-01-20 2021-03-02 Saudi Arabian Oil Company Multiple-stage catalyst systems and processes for propene production
US11242297B2 (en) 2017-01-20 2022-02-08 Saudi Arabian Oil Company Multiple-stage catalyst system for self-metathesis with controlled isomerization and cracking
US11339332B2 (en) 2020-01-29 2022-05-24 Saudi Arabian Oil Company Systems and processes integrating fluidized catalytic cracking with metathesis for producing olefins
US11572516B2 (en) 2020-03-26 2023-02-07 Saudi Arabian Oil Company Systems and processes integrating steam cracking with dual catalyst metathesis for producing olefins
US11845705B2 (en) 2021-08-17 2023-12-19 Saudi Arabian Oil Company Processes integrating hydrocarbon cracking with metathesis for producing propene

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2909381C2 (en) * 1979-03-09 1984-02-02 Dzeržinskij filial gosudarstvennogo naučno-issledovatel'skogo i proektnogo instituta azotnoj promyšlennosti i produktov organičeskogo sinteza, Dzeržinsk, Gor'kovskaja oblast' Use of a metal oxide mixture as a catalyst for the carbonylation of aromatic nitro compounds
EP0231401B1 (en) * 1984-06-29 1992-09-09 Exxon Research And Engineering Company Ruthenium-rhenium-titania catalysts, and use thereof for fischer-tropsch synthesis
GB8705564D0 (en) * 1987-03-10 1987-04-15 Bp Chem Int Ltd Chemical process

Cited By (37)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3728415A (en) * 1971-03-25 1973-04-17 Petro Tex Chem Corp Production of n-butenes from ethylene
EP0016852A1 (en) * 1976-05-21 1980-10-15 The Dow Chemical Company Process for producing C2-C4 hydrocarbons from carbon monoxide and hydrogen
US4419527A (en) 1982-07-29 1983-12-06 Monsanto Company Catalyst and reverse disproportionation process
US4419526A (en) 1982-07-29 1983-12-06 Monsanto Company Catalyst and reverse disproportionation process
US4439626A (en) * 1982-07-29 1984-03-27 Monsanto Company Catalyst and reverse disproportionation process
US4439628A (en) * 1982-07-29 1984-03-27 Monsanto Company Catalyst and reverse disproportionation process
US4439627A (en) * 1982-07-29 1984-03-27 Monsanto Company Catalyst and reverse disproportionation process
US4440968A (en) * 1982-07-29 1984-04-03 Monsanto Company Catalyst and reverse disproportionation process
US4440967A (en) * 1982-07-29 1984-04-03 Monsanto Company Catalyst and reverse disproportionation process
US4448894A (en) * 1982-07-29 1984-05-15 Monsanto Company Catalyst and reverse disproportionation process
US4474897A (en) * 1982-07-29 1984-10-02 Monsanto Company Catalyst useable in a reverse disproportionation process
US4487849A (en) * 1982-07-29 1984-12-11 Monsanto Company Catalyst for the reverse disproportionation process
US4490477A (en) * 1982-07-29 1984-12-25 Monsanto Company Catalyst and reverse disproportionation process
US4511672A (en) * 1982-07-29 1985-04-16 Monsanto Company Catalyst and reverse disproportionation process
US4514519A (en) * 1982-07-29 1985-04-30 Monsanto Company Catalyst and reverse disproportionation process
US5087780A (en) * 1988-10-31 1992-02-11 Chemical Research & Licensing Company Hydroisomerization process
EP0442159A1 (en) * 1989-12-21 1991-08-21 Shell Internationale Researchmaatschappij B.V. Concurrent isomerization and disproportionation of olefins
US5043520A (en) * 1989-12-21 1991-08-27 Shell Oil Company Concurrent isomerization and disproportionation of olefins
US4996386A (en) * 1989-12-21 1991-02-26 Shell Oil Company Concurrent isomerization and disproportionation of olefins
US5120896A (en) * 1989-12-21 1992-06-09 Shell Oil Company Concurrent isomerization and disproportionation of olefins
US5243120A (en) * 1991-10-30 1993-09-07 Shell Oil Company Process for the production of olefins
US5321163A (en) * 1993-09-09 1994-06-14 Chemical Research & Licensing Company Multi-purpose catalytic distillation column and eterification process using same
US7977522B2 (en) 2005-03-03 2011-07-12 Mitsui Chemicals, Inc. Process of producing olefins
US10934231B2 (en) 2017-01-20 2021-03-02 Saudi Arabian Oil Company Multiple-stage catalyst systems and processes for propene production
US11242297B2 (en) 2017-01-20 2022-02-08 Saudi Arabian Oil Company Multiple-stage catalyst system for self-metathesis with controlled isomerization and cracking
US10919822B2 (en) 2017-01-20 2021-02-16 Saudi Arabian Oil Company Dual catalyst processes and systems for propylene production
US11242300B2 (en) 2018-10-10 2022-02-08 Saudi Arabian Oil Company Catalyst systems that include metal co-catalysts for the production of propylene
US10961171B2 (en) 2018-10-10 2021-03-30 Saudi Arabian Oil Company Catalysts systems that include metal co-catalysts for the production of propylene
CN112839734A (en) * 2018-10-10 2021-05-25 沙特阿拉伯石油公司 Catalyst comprising metal oxide promoter for propylene production
US11242299B2 (en) 2018-10-10 2022-02-08 Saudi Arabian Oil Company Catalyst systems that include metal oxide co-catalysts for the production of propylene
WO2020076589A1 (en) * 2018-10-10 2020-04-16 Saudi Arabian Oil Company Catalysts that include metal oxide co-catalysts for the production of propylene
WO2020076590A1 (en) * 2018-10-10 2020-04-16 Saudi Arabian Oil Company Catalysts that include metal oxide co-catalysts for the production of propylene
CN112839734B (en) * 2018-10-10 2024-06-04 沙特阿拉伯石油公司 Catalyst comprising a metal oxide promoter for propylene production
US11339332B2 (en) 2020-01-29 2022-05-24 Saudi Arabian Oil Company Systems and processes integrating fluidized catalytic cracking with metathesis for producing olefins
US11572516B2 (en) 2020-03-26 2023-02-07 Saudi Arabian Oil Company Systems and processes integrating steam cracking with dual catalyst metathesis for producing olefins
US11939540B2 (en) 2020-03-26 2024-03-26 Saudi Arabian Oil Company Systems and processes integrating steam cracking with dual catalyst metathesis for producing olefins
US11845705B2 (en) 2021-08-17 2023-12-19 Saudi Arabian Oil Company Processes integrating hydrocarbon cracking with metathesis for producing propene

Also Published As

Publication number Publication date
DE1901648A1 (en) 1969-11-13
NL6900368A (en) 1969-07-22
BE726673A (en) 1969-07-09
FR1600597A (en) 1970-07-27

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