CN109957059A - 导热树脂、树脂组合物、预浸料及铜箔基板 - Google Patents

导热树脂、树脂组合物、预浸料及铜箔基板 Download PDF

Info

Publication number
CN109957059A
CN109957059A CN201810178681.9A CN201810178681A CN109957059A CN 109957059 A CN109957059 A CN 109957059A CN 201810178681 A CN201810178681 A CN 201810178681A CN 109957059 A CN109957059 A CN 109957059A
Authority
CN
China
Prior art keywords
resin
heat
prepreg
resin combination
butyl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN201810178681.9A
Other languages
English (en)
Other versions
CN109957059B (zh
Inventor
曾峰柏
丁文彬
邱国展
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Industrial Technology Research Institute ITRI
ITEQ Corp
Original Assignee
Industrial Technology Research Institute ITRI
ITEQ Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Industrial Technology Research Institute ITRI, ITEQ Corp filed Critical Industrial Technology Research Institute ITRI
Publication of CN109957059A publication Critical patent/CN109957059A/zh
Application granted granted Critical
Publication of CN109957059B publication Critical patent/CN109957059B/zh
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G61/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G61/02—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes
    • C08G61/10—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aromatic carbon atoms, e.g. polyphenylenes
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B15/00—Layered products comprising a layer of metal
    • B32B15/04—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B15/08—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B15/00—Layered products comprising a layer of metal
    • B32B15/14—Layered products comprising a layer of metal next to a fibrous or filamentary layer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B15/00—Layered products comprising a layer of metal
    • B32B15/16—Layered products comprising a layer of metal next to a particulate layer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B15/00—Layered products comprising a layer of metal
    • B32B15/20—Layered products comprising a layer of metal comprising aluminium or copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/061—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of metal
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/067—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of fibres or filaments
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/068—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of particles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/12—Layered products comprising a layer of synthetic resin next to a fibrous or filamentary layer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/14—Layered products comprising a layer of synthetic resin next to a particulate layer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B33/00—Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
    • B32B5/08—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer the fibres or filaments of a layer being of different substances, e.g. conjugate fibres, mixture of different fibres
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/16—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by features of a layer formed of particles, e.g. chips, powder or granules
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/22—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed
    • B32B5/24—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/22—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed
    • B32B5/24—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer
    • B32B5/26—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer another layer next to it also being fibrous or filamentary
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/22—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed
    • B32B5/30—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being formed of particles, e.g. chips, granules, powder
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B9/00—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
    • B32B9/005—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising one layer of ceramic material, e.g. porcelain, ceramic tile
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B9/00—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
    • B32B9/005—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising one layer of ceramic material, e.g. porcelain, ceramic tile
    • B32B9/007—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising one layer of ceramic material, e.g. porcelain, ceramic tile comprising carbon, e.g. graphite, composite carbon
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B9/00—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
    • B32B9/04—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising such particular substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B9/00—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
    • B32B9/04—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising such particular substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B9/041—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising such particular substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material of metal
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B9/00—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
    • B32B9/04—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising such particular substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B9/045—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising such particular substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B9/00—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
    • B32B9/04—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising such particular substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B9/047—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising such particular substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material made of fibres or filaments
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B9/00—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
    • B32B9/04—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising such particular substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B9/048—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising such particular substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material made of particles
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F212/34—Monomers containing two or more unsaturated aliphatic radicals
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F216/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical
    • C08F216/12—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical by an ether radical
    • C08F216/125—Monomers containing two or more unsaturated aliphatic radicals, e.g. trimethylolpropane triallyl ether or pentaerythritol triallyl ether
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/20—Esters of polyhydric alcohols or phenols, e.g. 2-hydroxyethyl (meth)acrylate or glycerol mono-(meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/24—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs
    • C08J5/241—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs using inorganic fibres
    • C08J5/243—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs using inorganic fibres using carbon fibres
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/24—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs
    • C08J5/241—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs using inorganic fibres
    • C08J5/244—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs using inorganic fibres using glass fibres
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/24—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs
    • C08J5/246—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs using polymer based synthetic fibres
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/24—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs
    • C08J5/247—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs using fibres of at least two types
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/24—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs
    • C08J5/249—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs characterised by the additives used in the prepolymer mixture
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
    • C08K5/0025—Crosslinking or vulcanising agents; including accelerators
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/14—Peroxides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/16—Nitrogen-containing compounds
    • C08K5/17—Amines; Quaternary ammonium compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/16—Nitrogen-containing compounds
    • C08K5/22—Compounds containing nitrogen bound to another nitrogen atom
    • C08K5/23—Azo-compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/16—Nitrogen-containing compounds
    • C08K5/34—Heterocyclic compounds having nitrogen in the ring
    • C08K5/3467—Heterocyclic compounds having nitrogen in the ring having more than two nitrogen atoms in the ring
    • C08K5/3477—Six-membered rings
    • C08K5/3492—Triazines
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/54—Silicon-containing compounds
    • C08K5/541—Silicon-containing compounds containing oxygen
    • C08K5/5415—Silicon-containing compounds containing oxygen containing at least one Si—O bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L29/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical; Compositions of hydrolysed polymers of esters of unsaturated alcohols with saturated carboxylic acids; Compositions of derivatives of such polymers
    • C08L29/10—Homopolymers or copolymers of unsaturated ethers
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D125/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Coating compositions based on derivatives of such polymers
    • C09D125/18—Homopolymers or copolymers of aromatic monomers containing elements other than carbon and hydrogen
    • H—ELECTRICITY
    • H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
    • H05K1/00—Printed circuits
    • H05K1/02—Details
    • H05K1/03—Use of materials for the substrate
    • H05K1/05—Insulated conductive substrates, e.g. insulated metal substrate
    • H05K1/056—Insulated conductive substrates, e.g. insulated metal substrate the metal substrate being covered by an organic insulating layer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2250/00—Layers arrangement
    • B32B2250/40—Symmetrical or sandwich layers, e.g. ABA, ABCBA, ABCCBA
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2260/00—Layered product comprising an impregnated, embedded, or bonded layer wherein the layer comprises an impregnation, embedding, or binder material
    • B32B2260/02—Composition of the impregnated, bonded or embedded layer
    • B32B2260/021—Fibrous or filamentary layer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2260/00—Layered product comprising an impregnated, embedded, or bonded layer wherein the layer comprises an impregnation, embedding, or binder material
    • B32B2260/02—Composition of the impregnated, bonded or embedded layer
    • B32B2260/025—Particulate layer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2260/00—Layered product comprising an impregnated, embedded, or bonded layer wherein the layer comprises an impregnation, embedding, or binder material
    • B32B2260/04—Impregnation, embedding, or binder material
    • B32B2260/044—Water-setting substance, e.g. concrete, plaster
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2260/00—Layered product comprising an impregnated, embedded, or bonded layer wherein the layer comprises an impregnation, embedding, or binder material
    • B32B2260/04—Impregnation, embedding, or binder material
    • B32B2260/046—Synthetic resin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/02—Synthetic macromolecular fibres
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/10—Inorganic fibres
    • B32B2262/101—Glass fibres
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/10—Inorganic fibres
    • B32B2262/105—Ceramic fibres
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/10—Inorganic fibres
    • B32B2262/106—Carbon fibres, e.g. graphite fibres
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/14—Mixture of at least two fibres made of different materials
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2264/00—Composition or properties of particles which form a particulate layer or are present as additives
    • B32B2264/02—Synthetic macromolecular particles
    • B32B2264/0214—Particles made of materials belonging to B32B27/00
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2264/00—Composition or properties of particles which form a particulate layer or are present as additives
    • B32B2264/10—Inorganic particles
    • B32B2264/101—Glass
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2264/00—Composition or properties of particles which form a particulate layer or are present as additives
    • B32B2264/10—Inorganic particles
    • B32B2264/107—Ceramic
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2264/00—Composition or properties of particles which form a particulate layer or are present as additives
    • B32B2264/10—Inorganic particles
    • B32B2264/107—Ceramic
    • B32B2264/108—Carbon, e.g. graphite particles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2264/00—Composition or properties of particles which form a particulate layer or are present as additives
    • B32B2264/12—Mixture of at least two particles made of different materials
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/30—Properties of the layers or laminate having particular thermal properties
    • B32B2307/302—Conductive
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2311/00—Metals, their alloys or their compounds
    • B32B2311/12—Copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2457/00—Electrical equipment
    • B32B2457/08—PCBs, i.e. printed circuit boards
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F222/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides, or nitriles thereof
    • C08F222/10—Esters
    • C08F222/1006—Esters of polyhydric alcohols or polyhydric phenols
    • C08F222/102—Esters of polyhydric alcohols or polyhydric phenols of dialcohols, e.g. ethylene glycol di(meth)acrylate or 1,4-butanediol dimethacrylate
    • C08F222/1025—Esters of polyhydric alcohols or polyhydric phenols of dialcohols, e.g. ethylene glycol di(meth)acrylate or 1,4-butanediol dimethacrylate of aromatic dialcohols
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2347/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds; Derivatives of such polymers
    • H—ELECTRICITY
    • H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
    • H05K1/00—Printed circuits
    • H05K1/02—Details
    • H05K1/03—Use of materials for the substrate
    • H05K1/0313—Organic insulating material
    • H05K1/032—Organic insulating material consisting of one material
    • H05K1/0326—Organic insulating material consisting of one material containing O

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Manufacturing & Machinery (AREA)
  • Ceramic Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Reinforced Plastic Materials (AREA)
  • Laminated Bodies (AREA)

Abstract

本公开提供树脂组合物，包括：1重量份的导热树脂；0.001至0.05重量份的自由基起始剂；以及0.05至0.30重量份的交联剂，其中导热树脂的结构为： 其中R1为‑CH2‑、‑C(＝O)‑、或‑(CH2)‑(C6H5)‑；以及R2为H或CH3。

Description

导热树脂、树脂组合物、预浸料及铜箔基板
【技术领域】
本公开涉及树脂组合物，更特别是涉及其中的导热树脂。
【背景技术】
云端、互联、及物联网的兴起，以及4G、5G通讯技术与显示技术的提升，使得光电与半导体等产业所需的电路板与IC载板逐渐走向高速化、高密度化、密集化、与积层化，因此未来电路板与IC载板的特性需求除低介电与高绝缘性外，还需兼具低介电损失与高导热性。
以电路板为例，其结构中的铜箔基板的简易结构由上而下分别为铜箔、介电层、铜箔，然因中间介电层的组成多为导热性差的树脂、玻纤布、或绝缘纸，导致铜箔基板的导热性差。一般而言，为了增加介电层的导热性，常需添加大量的导热粉体。然而，导热粉体之间的树脂并不会导热，致使分散于树脂中的导热粉体的导热效果相当有限。
为解决上述问题，目前亟需新的导热树脂，以增加铜箔之间的介电层导热性。
【发明内容】
本公开的一实施例提供导热树脂，其结构为：
其中R1为-CH2-、-C(＝O)-或-(CH2)-(C6H5)-，以及R2为H或CH3。
本公开的另一实施例提供树脂组合物，其包括：1重量份的导热树脂、0.001至0.05重量份的自由基起始剂、以及0.05至0.30重量份的交联剂，其中导热树脂的结构为：
其中R1为-CH2-、-C(＝O)-、或-(CH2)-(C6H5)-，以及R2为H或CH3。
本公开的又一实施例提供预浸料(胶片，prepreg)，包括：补强材料，该预浸料是将该补强材料含浸于上述树脂组合物后硬化而成。
本公开的再一实施例提供包括上述预浸料的铜箔基板，该铜箔基板是由上述预浸料与铜箔压合而成。
【具体实施方式】
本公开的一实施例提供导热树脂，其结构如下：
在上式中，R1为-CH2-、-C(＝O)-、或-(CH2)-(C6H5)-，且R2为H或CH3。
本公开的另一实施例提供的树脂组合物，其包括：1重量份的导热树脂、0.001至0.05重量份的自由基起始剂、以及0.05至0.30重量份的交联剂。
在一实施例中，自由基起始剂可为光起始剂、热起始剂、或上述的组合。举例来说，自由基起始剂可为偶氮二异丁腈(Azodiisobutyrodinitrile，AIBN)、2,5-双(叔丁基过氧基)-2,5-二甲基己烷(2,5-bis(tert-butylperoxy)-2,5-dimethylhexane)、过氧化二异丙苯(Dicumyl peroxide，DCPO)、过氧化苯甲酰(Benzoyl peroxide)、2,2-双(叔丁基过氧)丁烷(2,2-Bis(tert-butylperoxy)butane)、2,5-二甲基-2,5-二(叔丁基过氧)己-3-炔(2,5-dimethyl-2,5-di(tert-butylperoxy)hex-3-yne)、1,1-双(叔丁基过氧)环己烷(1,1-Bis(tert-butylperoxy)cyclohexane)、1,1-双(叔丁基过氧)-3,3,5-三甲基环己烷(1,1-bis(tert-butylperoxy)-3,3,5-trimethylcyclohexane)、叔丁基氢过氧化物(tert-Butylhydroperoxide)、二叔丁基过氧化物(Di-tert-butyl peroxide)、过氧化苯甲酸叔丁基酯(tert-Butyl peroxybenzoate)、或上述的组合。若自由基起始剂的比例过高，将使树脂组合物交联后的分子量偏低，进而导致物性变差。若自由基起始剂的比例过低，则会导致树脂组合物的反应太慢，而不利于未来制程上的应用。
在一实施例中，交联剂可为三烯丙基异氰尿酸酯(Triallyl isocyanurate，TAIC)、三烯丙基氰尿酸酯(Triallyl cyanurate，TAC)、八乙烯基八硅倍半氧烷(Octavinyloctasilasesquioxane)、三乙烯基胺(trivinyl-amine)、或上述的组合。若交联剂比例过高，则会降低树脂组合物交联后的导热性质(比如降低热传导系数K值)。若交联剂的比例过低，则会导致树脂组合物交联后的热性值不佳(例如玻璃态转变温度Tg降低)。
在树脂组合物中，导热树脂的结构如下：
在上式中，R1为-CH2-、-C(＝O)-、或-(CH2)-(C6H5)-，以及R2为H或CH3。在一实施例中，
导热树脂为与
的组合，且两者的重量比例可介于1:3至3:1之间。
在一实施例中，树脂组合物可进一步包含其他添加剂，如导热粉体、界面活性剂、消泡剂、流平剂、颜料、或上述的组合，以调整树脂组合物交联后的性质或外观。
在一实施例中，可将上述的树脂组合物直接涂布后硬化成膜。在另一实施例中，可将补强材料含浸于上述的树脂组合物中，接着硬化树脂组合物以形成预浸料。
在一实施例中，补强材料可包括玻璃、陶瓷、碳材、树脂、或上述的组合，且补强材料的形态可为纤维、粉体、片状物、编织物、或上述的组合。举例来说，补强材料可为玻纤布。
在一实施例中，可将玻纤布含浸于树脂化合物中(A-阶段，A-stage)，接着将玻纤布置入烘箱加热以去除玻纤布的树脂组合物中的溶剂，并进一步硬化树脂组合物以形成预浸料(B-阶段，B-stage)。上述预浸料经更进一步加热硬化后(C-阶段，C-stage)，具有热传导性高、介电常数低、以及介电损失低等特性。
在一实施例中，可将上述预浸料与铜箔压合成铜箔基板(copper clad laminate，CCL)。举例来说，可取多个预浸料夹设于两片铜箔之间，接着热压合上述堆栈结构以形成铜箔基板。
为了让本公开的上述和其他目的、特征、和优点能更明显易懂，下文特举数个实施例并配合所附图示，作详细说明如下：
实施例
合成例1
取40g的4,4'-双(2,3,6-三甲基酚)(4,4'-Bi(2,3,6-trimethyl phenol)，TMP-BP，购自三菱化学)及33.9g的烯丙基氯(Allyl chloride，购自景明化工)，加入40g的二甲基亚砜(Dimethyl sulfoxide，DMSO)中，再加入微量的四正丁基铵盐(Tetra-n-butylammonium，购自景明化工)及氢氧化钠，加热至80℃后反应3小时。待完全反应后将温度降至室温，经过滤纯化得到产物。上述反应如下式：
上式产物的光谱如下：1H NMR(500MHz,CDCl3)：δ6.69(s,2H),6.12～6.04(m,2H),5.39(d,J＝17.5Hz,2H),5.20(d,J＝10.5Hz,2H),4.25(d,J＝5.5Hz,4H),2.18(s,6H),2.16(s,6H),1.83(s,6H)。
合成例2
取40g的TMP-BP及40.22g的丙烯酰氯(Acryloyl chloride，购自景明化工)，置入100g的四氢呋喃中，再加入微量的三乙胺(triethylamine，购自景明化工)及氢氧化钠，于-30℃以下进行反应，且持续搅拌直至温度达室温以上。待完全反应后，经过滤纯化得到产物。上述反应如下式：
上式产物的光谱如下：1H NMR(500MHz,CDCl3)：δ6.85(s,2H),6.66(d,J＝17.5Hz,2H),6.40(dd,J＝17.5Hz,J＝10.5Hz,2H),6.05(d,J＝10.5Hz,2H),2.12(s,6H),2.10(s,6H),1.94(s,6H)。
合成例3
取40g的TMP-BP及67.83g的4-乙烯基苄基氯(4-vinyl benzyl chloride，购自景明化工)，置入200g的甲乙酮(Methyl Ethyl Ketone，MEK)溶剂中，再加入微量的四正丁基铵盐(tetra-n-butylammonium)及碳酸钾(Potassium carbonate)，于90℃以下反应约4小时，待完全反应后，将温度降至室温，经过滤纯化后得产物。上述反应如下式所示：
上式产物的光谱如下：1H NMR(500MHz,CDCl3)：δ7.49～7.45(m,8H),6.81(s,2H),6.75(dd,J＝17.5Hz,J＝17.5Hz,2H),5.78(d,J＝17.5Hz,2H),5.27(d,J＝11Hz,2H),4.83(s,4H),2.30(s,6H),2.28(s,6H),1.94(s,6H)。
实施例1
取18g的合成例1的产物作为导热树脂、2g的交联剂三烯丙基异氰尿酸酯(TAIC)、与0.02g的自由基起始剂偶氮二异丁腈(AIBN)，再加入10g的DMSO后混合均匀，以形成树脂组合物。将上述树脂组合物涂布于铜箔上，待烘烤至210℃后的涂层性质如表1所示。
实施例2
取16g的合成例1的产物作为导热树脂、4g的交联剂TAIC、与0.02g的AIBN，再加入10g的DMSO后混合均匀，以形成树脂组合物。将上述树脂组合物涂布于铜箔上，待烘烤至210℃后的涂层性质如表1所示。
实施例3
取18g的合成例2的产物作为导热树脂、2g的交联剂TAIC、与0.02g的AIBN，再加入10g的DMSO后混合均匀，以形成树脂组合物。将上述树脂组合物涂布于铜箔上，待烘烤至210℃后的涂层性质如表1所示。
实施例4
取16g的合成例2的产物作为导热树脂、4g的交联剂TAIC、与0.02g的AIBN，再加入10g的DMSO后混合均匀，以形成树脂组合物。将上述树脂组合物涂布于铜箔上，待烘烤至210℃后的涂层性质如表1所示。
实施例5
取18g的合成例3的产物作为导热树脂、2g的交联剂TAIC、与0.02g的自由基起始剂101(2,5-双(叔丁基过氧基)-2,5-二甲基己烷，购自景明化工)，再加入10g的DMSO后混合均匀，以形成树脂组合物。将上述树脂组合物涂布于铜箔上，待烘烤至210℃后的涂层性质如表1所示。
实施例6
取16g的合成例3的产物作为导热树脂、4g的交联剂TAIC、与0.02g的自由基起始剂101，再加入10g的DMSO后混合均匀，以形成树脂组合物。将上述树脂组合物涂布于铜箔上，待烘烤至210℃后的涂层性质如表1所示。
实施例7
取12g的合成例2的产物与6g的合成例3的产物作为导热树脂、2g的交联剂TAIC、与0.02g的自由基起始剂101，再加入10g的DMSO后混合均匀，以形成树脂组合物。将上述树脂组合物涂布于铜箔上，待烘烤至210℃后的涂层性质如表1所示。
实施例8
取9g的合成例2的产物与9g的合成例3的产物作为导热树脂、2g的交联剂TAIC、与0.02g的自由基起始剂101，再加入10g的DMSO后混合均匀，以形成树脂组合物。将上述树脂组合物涂布于铜箔上，待烘烤至210℃后的涂层性质如表1所示。
实施例9
取6g的合成例2的产物与12g的合成例3的产物作为导热树脂、2g的交联剂TAIC、与0.02g的自由基起始剂101，再加入10g的DMSO后混合均匀，以形成树脂组合物。将上述树脂组合物涂布于铜箔上，待烘烤至210℃后的涂层性质如表1所示。
表1
由表1可知，合成例的导热树脂搭配交联剂与自由基起始剂，在加热硬化后所形成的膜层可具有高导热性(K)、低介电常数(Dk)、与低介电损失(Df)。上述膜层的导热系数(K)的测量标准为ASTM-D5470，介电常数(Dk)的测量标准为JIS C2565，而介电损失(Df)的测量标准为JIS C2565。
虽然本公开已以数个实施例披露如上，然其并非用以限定本公开，任何本技术领域的技术人员在不脱离本公开的精神和范围内，应可作任意的更动与润饰，因此本公开的保护范围应以所附权利要求书所界定的范围为准。

Claims (9)

1.一种导热树脂，其结构为：
其中R1为-CH2-、-C(＝O)-或-(CH2)-(C6H5)-；以及
R2为H或CH3。
2.一种树脂组合物，包括：
1重量份的导热树脂；
0.001至0.05重量份的自由基起始剂；以及
0.05至0.30重量份的交联剂，
其中该导热树脂的结构为：
其中R1为-CH2-、-C(＝O)-、或-(CH2)-(C6H5)-；以及
R2为H或CH3。
3.如权利要求2所述的树脂组合物，其中该导热树脂为
的组合，且两者的重量比例为1:3至3:1。
4.如权利要求2所述的树脂组合物，其中该交联剂包括三烯丙基异氰尿酸酯、三烯丙基氰尿酸酯、八乙烯基八硅倍半氧烷、三乙烯基胺、或上述的组合。
5.如权利要求2所述的树脂组合物，其中该自由基起始剂包括偶氮二异丁腈、2,5-双(叔丁基过氧基)-2,5-二甲基己烷、过氧化二异丙苯、过氧化苯甲酰、2,2-双(叔丁基过氧)丁烷、2,5-二甲基-2,5-二(叔丁基过氧)己-3-炔、1,1-双(叔丁基过氧)环己烷、1,1-双(叔丁基过氧)-3,3,5-三甲基环己烷、叔丁基氢过氧化物、二叔丁基过氧化物、过氧化苯甲酸叔丁基酯、或上述的组合。
6.一种预浸料，包括：
补强材料；
其中该预浸料是将该补强材料含浸于权利要求2所述的树脂组合物后硬化而成。
7.如权利要求6所述的预浸料，其中该补强材料包括玻璃、陶瓷、碳材、树脂、或上述的组合。
8.如权利要求6所述的预浸料，其中该补强材料的形态为纤维、粉体、片状物、编织物、或上述的组合。
9.一种铜箔基板，包括：
权利要求6所述的预浸料；
其中该铜箔基板是将该预浸料与铜箔压合而成。
CN201810178681.9A 2017-12-25 2018-03-05 导热树脂、树脂组合物、预浸料及铜箔基板 Active CN109957059B (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
TW106145518A TWI631167B (zh) 2017-12-25 2017-12-25 單體、樹脂組合物、膠片、與銅箔基板
TW106145518 2017-12-25

Publications (2)

Publication Number Publication Date
CN109957059A true CN109957059A (zh) 2019-07-02
CN109957059B CN109957059B (zh) 2021-10-08

Family

ID=63959760

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201810178681.9A Active CN109957059B (zh) 2017-12-25 2018-03-05 导热树脂、树脂组合物、预浸料及铜箔基板

Country Status (3)

Country Link
US (1) US10752744B2 (zh)
CN (1) CN109957059B (zh)
TW (1) TWI631167B (zh)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2020256045A1 (ja) * 2019-06-20 2020-12-24 本州化学工業株式会社 ヘキサメチル置換／ジメチル置換４，４'－ビス（２－プロペン－１－イルオキシ）－１，１'－ビフェニルの結晶体
TWI775423B (zh) * 2021-05-06 2022-08-21 財團法人工業技術研究院 共聚物與複合材料
TWI782688B (zh) * 2021-09-02 2022-11-01 財團法人工業技術研究院 聚合物、聚合物組成物、與太陽能電池模組
JP2023085845A (ja) 2021-12-09 2023-06-21 住友化学株式会社 ビニル化合物、ビニル化合物の製造方法、ビニル組成物、ビニル樹脂硬化物、プリプレグ、樹脂付きフィルム、樹脂付き金属箔、金属張積層板およびプリント配線板

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH05224187A (ja) * 1992-02-13 1993-09-03 Dainippon Ink & Chem Inc 液晶デバイス
CN102304264A (zh) * 2011-08-23 2012-01-04 南亚塑胶工业股份有限公司 一种高频铜箔基板及其所使用的复合材料
CN102807658A (zh) * 2012-08-09 2012-12-05 广东生益科技股份有限公司 聚苯醚树脂组合物及使用其制作的半固化片与覆铜箔层压板
JP2014034580A (ja) * 2012-08-07 2014-02-24 Ajinomoto Co Inc 樹脂組成物
CN104725828A (zh) * 2015-03-04 2015-06-24 广东生益科技股份有限公司 一种树脂组合物以及使用它的预浸料和层压板
TWI582136B (zh) * 2016-07-25 2017-05-11 Chin Yee Chemical Industres Co Ltd Thermosetting resin and its composition, use

Family Cites Families (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2002094905A1 (fr) 2001-05-18 2002-11-28 Hitachi, Ltd. Produit durci de resine thermodurcissable
US6646102B2 (en) 2001-07-05 2003-11-11 Dow Global Technologies Inc. Process for manufacturing an alpha-dihydroxy derivative and epoxy resins prepared therefrom
US6835785B2 (en) 2002-01-28 2004-12-28 Mitsubishi Gas Chemical Company, Inc. Polyphenylene ether oligomer compound, derivatives thereof and use thereof
JP4414674B2 (ja) 2003-05-07 2010-02-10 ポリマテック株式会社 熱伝導性エポキシ樹脂成形体及びその製造方法
US20060074149A1 (en) 2003-09-09 2006-04-06 Boriack Clinton J Process for manufacturing an alpha-dihydroxy derivative and epoxy resins prepared therefrom
US7329708B2 (en) 2004-08-18 2008-02-12 General Electric Company Functionalized poly(arylene ether) composition and method
TWI291480B (en) 2005-12-20 2007-12-21 Ind Tech Res Inst Composition for thermal interface materials
TWI290565B (en) 2005-12-20 2007-12-01 Ind Tech Res Inst Composition for thermal interface materials
US20110073798A1 (en) 2009-09-25 2011-03-31 Yeh Yun-Chao High thermal conductivity and low dissipation factor adhesive varnish for build-up additional insulation layers
TWI475103B (zh) 2009-12-15 2015-03-01 Ind Tech Res Inst 散熱結構
TWI457387B (zh) 2011-03-09 2014-10-21 Ind Tech Res Inst 絕緣導熱組成物與電子裝置
US10028377B2 (en) 2011-09-30 2018-07-17 Mitsubishi Gas Chemical Company, Inc. Resin composition, prepreg and metal foil-clad laminate
TWI475387B (zh) 2012-07-19 2015-03-01 Jmicron Technology Corp 記憶體控制方法及記憶體控制電路
TWI598294B (zh) 2013-12-17 2017-09-11 財團法人工業技術研究院 聚醯胺亞醯胺高分子、石墨膜及其製備方法
EP3172188B1 (en) * 2014-07-22 2019-09-04 SABIC Global Technologies B.V. High heat monomers and methods of use thereof
TWI518136B (zh) 2014-12-23 2016-01-21 Nanya Plastics Corp A thermosetting resin composition, and a prepreg and a hardened product using the composition
TWI576414B (zh) 2015-11-20 2017-04-01 財團法人工業技術研究院 封裝組合物及包含其之封裝結構
TWI575016B (zh) 2015-12-03 2017-03-21 財團法人工業技術研究院 環氧樹脂組成物及包含該組成物之熱介面材料

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH05224187A (ja) * 1992-02-13 1993-09-03 Dainippon Ink & Chem Inc 液晶デバイス
CN102304264A (zh) * 2011-08-23 2012-01-04 南亚塑胶工业股份有限公司 一种高频铜箔基板及其所使用的复合材料
JP2014034580A (ja) * 2012-08-07 2014-02-24 Ajinomoto Co Inc 樹脂組成物
CN102807658A (zh) * 2012-08-09 2012-12-05 广东生益科技股份有限公司 聚苯醚树脂组合物及使用其制作的半固化片与覆铜箔层压板
CN104725828A (zh) * 2015-03-04 2015-06-24 广东生益科技股份有限公司 一种树脂组合物以及使用它的预浸料和层压板
TWI582136B (zh) * 2016-07-25 2017-05-11 Chin Yee Chemical Industres Co Ltd Thermosetting resin and its composition, use

Also Published As

Publication number Publication date
US20190194408A1 (en) 2019-06-27
TWI631167B (zh) 2018-08-01
US10752744B2 (en) 2020-08-25
TW201927890A (zh) 2019-07-16
CN109957059B (zh) 2021-10-08

Similar Documents

Publication Publication Date Title
CN109957059A (zh) 导热树脂、树脂组合物、预浸料及铜箔基板
JP6514335B2 (ja) シリコーン樹脂組成物、並びにそれを用いたプリプレグ、積層板、銅張積層板、及びアルミ基板
JP2018523592A (ja) オルガノシリコーン樹脂アルミベース銅張積層板及びその調製方法
TWI656158B (zh) 樹脂組合物、膠片、與銅箔基板
JP6510650B2 (ja) シリコーン樹脂組成物、および、それを用いた白色プリプレグと白色積層板
WO2022244728A1 (ja) 樹脂組成物、並びに、それを用いたプリプレグ、樹脂付きフィルム、樹脂付き金属箔、金属張積層板及び配線基板
KR20160106673A (ko) 페녹시 사이클로트리포스파젠 활성 에스테르, 무할로겐 수지 조성물 및 그 용도
WO2014190526A1 (zh) 氰酸酯树脂组合物及其用途
TW201823411A (zh) 接著組成物及包含其之複合基材
TW202045606A (zh) 樹脂組合物及其應用
JP2016538363A (ja) 相互進入高分子網目を形成する硬化性組成物
TWI432487B (zh) Flammable polyimide silicone resin composition
JP7434727B2 (ja) 接着剤組成物、積層体及び接着シート
US20240279457A1 (en) Resin composition, prepreg using same, film provided with resin, metal foil provided with resin, metal-clad layered board, and wiring board
WO2022244723A1 (ja) 樹脂組成物、並びに、それを用いたプリプレグ、樹脂付きフィルム、樹脂付き金属箔、金属張積層板及び配線基板
EP4423171A1 (en) Fluororesin
WO2023042780A1 (ja) 熱硬化性組成物、樹脂フィルム、プリプレグ、金属張積層板、及びプリント配線板
CN109957229A (zh) 树脂组合物、预浸料、与铜箔基板
JP2024002605A (ja) 硬化性樹脂組成物、半導体封止材、接着剤、接着フィルム、プリプレグ、層間絶縁材料及びプリント配線板
JP7387235B2 (ja) 熱硬化性マレイミド樹脂組成物、並びにその樹脂組成物からなる未硬化樹脂フィルム及び硬化樹脂フィルム
JP2020147689A (ja) 樹脂組成物
JP7582303B2 (ja) ビスマレイミド系接着剤組成物、硬化物、接着シート及びフレキシブルプリント配線板
WO2024004618A1 (ja) 多官能ビニル樹脂及びその製造方法
JP2022077908A (ja) 樹脂組成物
US20190390061A1 (en) Multi-layered structure and substrate

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant