CN109950524A - 多晶型钼酸锌材料的合成方法及其在锂离子电池中的应用 - Google Patents
多晶型钼酸锌材料的合成方法及其在锂离子电池中的应用 Download PDFInfo
- Publication number
- CN109950524A CN109950524A CN201910238647.0A CN201910238647A CN109950524A CN 109950524 A CN109950524 A CN 109950524A CN 201910238647 A CN201910238647 A CN 201910238647A CN 109950524 A CN109950524 A CN 109950524A
- Authority
- CN
- China
- Prior art keywords
- polymorphic
- zmo
- molybdic acid
- acid zinc
- lithium ion
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000463 material Substances 0.000 title claims abstract description 61
- 239000011701 zinc Substances 0.000 title claims abstract description 43
- 229910001416 lithium ion Inorganic materials 0.000 title claims abstract description 42
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 title claims abstract description 41
- 229910052725 zinc Inorganic materials 0.000 title claims abstract description 29
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 title claims abstract description 26
- VLAPMBHFAWRUQP-UHFFFAOYSA-L molybdic acid Chemical compound O[Mo](O)(=O)=O VLAPMBHFAWRUQP-UHFFFAOYSA-L 0.000 title claims abstract description 25
- 238000010189 synthetic method Methods 0.000 title claims abstract description 14
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims abstract description 13
- XIOUDVJTOYVRTB-UHFFFAOYSA-N 1-(1-adamantyl)-3-aminothiourea Chemical compound C1C(C2)CC3CC2CC1(NC(=S)NN)C3 XIOUDVJTOYVRTB-UHFFFAOYSA-N 0.000 claims abstract description 11
- 238000006243 chemical reaction Methods 0.000 claims description 18
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 16
- 238000000034 method Methods 0.000 claims description 15
- 239000007773 negative electrode material Substances 0.000 claims description 14
- 239000008367 deionised water Substances 0.000 claims description 11
- 229910021641 deionized water Inorganic materials 0.000 claims description 11
- 239000001509 sodium citrate Substances 0.000 claims description 10
- 238000003756 stirring Methods 0.000 claims description 10
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 claims description 9
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 8
- 238000001291 vacuum drying Methods 0.000 claims description 7
- 239000003792 electrolyte Substances 0.000 claims description 6
- 239000006258 conductive agent Substances 0.000 claims description 5
- 238000010438 heat treatment Methods 0.000 claims description 5
- 238000004080 punching Methods 0.000 claims description 5
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 4
- 239000011230 binding agent Substances 0.000 claims description 4
- 229910052802 copper Inorganic materials 0.000 claims description 4
- 239000010949 copper Substances 0.000 claims description 4
- 229910052744 lithium Inorganic materials 0.000 claims description 4
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 claims description 3
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims description 3
- 239000006230 acetylene black Substances 0.000 claims description 3
- 239000000908 ammonium hydroxide Substances 0.000 claims description 3
- 238000000137 annealing Methods 0.000 claims description 3
- 239000001768 carboxy methyl cellulose Substances 0.000 claims description 3
- 239000011248 coating agent Substances 0.000 claims description 3
- 238000000576 coating method Methods 0.000 claims description 3
- 239000012456 homogeneous solution Substances 0.000 claims description 3
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 claims description 3
- 239000002033 PVDF binder Substances 0.000 claims description 2
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical group [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 claims description 2
- 238000005119 centrifugation Methods 0.000 claims description 2
- 238000001035 drying Methods 0.000 claims description 2
- 229920002981 polyvinylidene fluoride Polymers 0.000 claims description 2
- 239000002002 slurry Substances 0.000 claims description 2
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 claims description 2
- 238000005406 washing Methods 0.000 claims description 2
- APUPEJJSWDHEBO-UHFFFAOYSA-P ammonium molybdate Chemical compound [NH4+].[NH4+].[O-][Mo]([O-])(=O)=O APUPEJJSWDHEBO-UHFFFAOYSA-P 0.000 claims 1
- 239000011609 ammonium molybdate Substances 0.000 claims 1
- 229940010552 ammonium molybdate Drugs 0.000 claims 1
- 235000018660 ammonium molybdate Nutrition 0.000 claims 1
- 239000002243 precursor Substances 0.000 claims 1
- 239000000126 substance Substances 0.000 abstract description 20
- 238000009792 diffusion process Methods 0.000 abstract description 7
- 238000012546 transfer Methods 0.000 abstract description 4
- 230000014759 maintenance of location Effects 0.000 abstract description 2
- 239000002994 raw material Substances 0.000 abstract description 2
- 239000000243 solution Substances 0.000 description 19
- 230000004087 circulation Effects 0.000 description 14
- 239000000047 product Substances 0.000 description 10
- 238000001228 spectrum Methods 0.000 description 9
- 230000008569 process Effects 0.000 description 8
- 238000002441 X-ray diffraction Methods 0.000 description 7
- 239000013078 crystal Substances 0.000 description 7
- 238000004833 X-ray photoelectron spectroscopy Methods 0.000 description 6
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- JKQOBWVOAYFWKG-UHFFFAOYSA-N molybdenum trioxide Chemical compound O=[Mo](=O)=O JKQOBWVOAYFWKG-UHFFFAOYSA-N 0.000 description 5
- 238000001878 scanning electron micrograph Methods 0.000 description 5
- 229910001868 water Inorganic materials 0.000 description 5
- 238000005275 alloying Methods 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- 238000001027 hydrothermal synthesis Methods 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 238000001354 calcination Methods 0.000 description 3
- 238000010586 diagram Methods 0.000 description 3
- 238000003487 electrochemical reaction Methods 0.000 description 3
- 238000000157 electrochemical-induced impedance spectroscopy Methods 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 229910052750 molybdenum Inorganic materials 0.000 description 3
- 230000009467 reduction Effects 0.000 description 3
- 238000003786 synthesis reaction Methods 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- 229910052723 transition metal Inorganic materials 0.000 description 3
- 229910000314 transition metal oxide Inorganic materials 0.000 description 3
- 150000003624 transition metals Chemical group 0.000 description 3
- XAEWLETZEZXLHR-UHFFFAOYSA-N zinc;dioxido(dioxo)molybdenum Chemical compound [Zn+2].[O-][Mo]([O-])(=O)=O XAEWLETZEZXLHR-UHFFFAOYSA-N 0.000 description 3
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- 229910002651 NO3 Inorganic materials 0.000 description 2
- QGAVSDVURUSLQK-UHFFFAOYSA-N ammonium heptamolybdate Chemical compound N.N.N.N.N.N.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.[Mo].[Mo].[Mo].[Mo].[Mo].[Mo].[Mo] QGAVSDVURUSLQK-UHFFFAOYSA-N 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 238000012512 characterization method Methods 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 125000004122 cyclic group Chemical group 0.000 description 2
- 238000002484 cyclic voltammetry Methods 0.000 description 2
- 238000007599 discharging Methods 0.000 description 2
- GNTDGMZSJNCJKK-UHFFFAOYSA-N divanadium pentaoxide Chemical compound O=[V](=O)O[V](=O)=O GNTDGMZSJNCJKK-UHFFFAOYSA-N 0.000 description 2
- 238000011049 filling Methods 0.000 description 2
- 229910021389 graphene Inorganic materials 0.000 description 2
- 229910002804 graphite Inorganic materials 0.000 description 2
- 239000010439 graphite Substances 0.000 description 2
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 2
- 239000010410 layer Substances 0.000 description 2
- MEFBJEMVZONFCJ-UHFFFAOYSA-N molybdate Chemical compound [O-][Mo]([O-])(=O)=O MEFBJEMVZONFCJ-UHFFFAOYSA-N 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 230000002195 synergetic effect Effects 0.000 description 2
- ONDPHDOFVYQSGI-UHFFFAOYSA-N zinc nitrate Chemical compound [Zn+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ONDPHDOFVYQSGI-UHFFFAOYSA-N 0.000 description 2
- 229910002703 Al K Inorganic materials 0.000 description 1
- 229910004647 CaMoO4 Inorganic materials 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- 229910018864 CoMoO4 Inorganic materials 0.000 description 1
- 206010013786 Dry skin Diseases 0.000 description 1
- 229910015142 FeMoO4 Inorganic materials 0.000 description 1
- 229910008405 Li-Zn Inorganic materials 0.000 description 1
- FUJCRWPEOMXPAD-UHFFFAOYSA-N Li2O Inorganic materials [Li+].[Li+].[O-2] FUJCRWPEOMXPAD-UHFFFAOYSA-N 0.000 description 1
- 229910007049 Li—Zn Inorganic materials 0.000 description 1
- 229910005809 NiMoO4 Inorganic materials 0.000 description 1
- XOLBLPGZBRYERU-UHFFFAOYSA-N SnO2 Inorganic materials O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 239000011149 active material Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 230000003321 amplification Effects 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 239000011258 core-shell material Substances 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 229960000935 dehydrated alcohol Drugs 0.000 description 1
- 238000002242 deionisation method Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 229910003460 diamond Inorganic materials 0.000 description 1
- 239000010432 diamond Substances 0.000 description 1
- XUCJHNOBJLKZNU-UHFFFAOYSA-M dilithium;hydroxide Chemical compound [Li+].[Li+].[OH-] XUCJHNOBJLKZNU-UHFFFAOYSA-M 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 230000005518 electrochemistry Effects 0.000 description 1
- 239000007772 electrode material Substances 0.000 description 1
- 229960004756 ethanol Drugs 0.000 description 1
- 235000019441 ethanol Nutrition 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- XLYOFNOQVPJJNP-ZSJDYOACSA-N heavy water Substances [2H]O[2H] XLYOFNOQVPJJNP-ZSJDYOACSA-N 0.000 description 1
- 230000036571 hydration Effects 0.000 description 1
- 238000006703 hydration reaction Methods 0.000 description 1
- 238000003780 insertion Methods 0.000 description 1
- 230000037431 insertion Effects 0.000 description 1
- 239000011229 interlayer Substances 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 238000003760 magnetic stirring Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000013528 metallic particle Substances 0.000 description 1
- 239000011259 mixed solution Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- 239000002086 nanomaterial Substances 0.000 description 1
- 239000002073 nanorod Substances 0.000 description 1
- 239000002070 nanowire Substances 0.000 description 1
- 238000003199 nucleic acid amplification method Methods 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 230000002441 reversible effect Effects 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 238000004088 simulation Methods 0.000 description 1
- 229910000679 solder Inorganic materials 0.000 description 1
- 239000007784 solid electrolyte Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000010408 sweeping Methods 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Landscapes
- Battery Electrode And Active Subsutance (AREA)
Abstract
Description
Claims (10)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201910238647.0A CN109950524B (zh) | 2019-03-27 | 2019-03-27 | 多晶型钼酸锌材料的合成方法及其在锂离子电池中的应用 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201910238647.0A CN109950524B (zh) | 2019-03-27 | 2019-03-27 | 多晶型钼酸锌材料的合成方法及其在锂离子电池中的应用 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN109950524A true CN109950524A (zh) | 2019-06-28 |
CN109950524B CN109950524B (zh) | 2021-02-23 |
Family
ID=67011960
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201910238647.0A Active CN109950524B (zh) | 2019-03-27 | 2019-03-27 | 多晶型钼酸锌材料的合成方法及其在锂离子电池中的应用 |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN109950524B (zh) |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110474017A (zh) * | 2019-08-29 | 2019-11-19 | 瑞海泊有限公司 | 锰酸锌电极的制备方法及其应用 |
CN112573573A (zh) * | 2020-12-04 | 2021-03-30 | 青岛科技大学 | 一种ZnMoO4电活性材料、制备方法及应用 |
CN114162869A (zh) * | 2022-01-05 | 2022-03-11 | 大连理工大学 | 一种具有微纳米棒状结构Li2Zn2Mo3O12材料及制备方法 |
CN115036491A (zh) * | 2022-07-11 | 2022-09-09 | 费县威尚新能源技术中心 | 一种锂离子电池 |
CN115465894A (zh) * | 2022-09-20 | 2022-12-13 | 河北地质大学 | 特殊形貌的钼酸锌-氧化锌复合材料的制备方法 |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105540669A (zh) * | 2015-12-07 | 2016-05-04 | 陕西科技大学 | 一种钼酸锌的制备方法及钼酸锌在锂离子电池负极材料中的应用 |
CN105742630A (zh) * | 2016-02-29 | 2016-07-06 | 陕西科技大学 | 一种α-ZnMoO4锂离子电池负极材料及其制备方法 |
CN106010526A (zh) * | 2016-05-25 | 2016-10-12 | 暨南大学 | 一种不同表面活性剂的钼酸盐纳米微颗粒制备方法 |
US9579636B1 (en) * | 2014-02-26 | 2017-02-28 | Stc.Unm | Method for synthesis of functional ceramic materials |
-
2019
- 2019-03-27 CN CN201910238647.0A patent/CN109950524B/zh active Active
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US9579636B1 (en) * | 2014-02-26 | 2017-02-28 | Stc.Unm | Method for synthesis of functional ceramic materials |
CN105540669A (zh) * | 2015-12-07 | 2016-05-04 | 陕西科技大学 | 一种钼酸锌的制备方法及钼酸锌在锂离子电池负极材料中的应用 |
CN105742630A (zh) * | 2016-02-29 | 2016-07-06 | 陕西科技大学 | 一种α-ZnMoO4锂离子电池负极材料及其制备方法 |
CN106010526A (zh) * | 2016-05-25 | 2016-10-12 | 暨南大学 | 一种不同表面活性剂的钼酸盐纳米微颗粒制备方法 |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110474017A (zh) * | 2019-08-29 | 2019-11-19 | 瑞海泊有限公司 | 锰酸锌电极的制备方法及其应用 |
CN112573573A (zh) * | 2020-12-04 | 2021-03-30 | 青岛科技大学 | 一种ZnMoO4电活性材料、制备方法及应用 |
CN114162869A (zh) * | 2022-01-05 | 2022-03-11 | 大连理工大学 | 一种具有微纳米棒状结构Li2Zn2Mo3O12材料及制备方法 |
CN114162869B (zh) * | 2022-01-05 | 2023-02-14 | 大连理工大学 | 一种具有微纳米棒状结构Li2Zn2Mo3O12材料及制备方法 |
CN115036491A (zh) * | 2022-07-11 | 2022-09-09 | 费县威尚新能源技术中心 | 一种锂离子电池 |
CN115465894A (zh) * | 2022-09-20 | 2022-12-13 | 河北地质大学 | 特殊形貌的钼酸锌-氧化锌复合材料的制备方法 |
CN115465894B (zh) * | 2022-09-20 | 2023-07-28 | 河北地质大学 | 特殊形貌的钼酸锌-氧化锌复合材料的制备方法 |
Also Published As
Publication number | Publication date |
---|---|
CN109950524B (zh) | 2021-02-23 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN109950524A (zh) | 多晶型钼酸锌材料的合成方法及其在锂离子电池中的应用 | |
CN103456936B (zh) | 钠离子二次电池及其用的层状钛酸盐活性物质、电极材料、正负极和活性物质的制备方法 | |
Liu et al. | Improvement of electrochemical properties of LiNi1/3Co1/3Mn1/3O2 by coating with V2O5 layer | |
Xu et al. | The preparation and role of Li2ZrO3 surface coating LiNi0. 5Co0. 2Mn0. 3O2 as cathode for lithium-ion batteries | |
CN106684369A (zh) | 一种钠快离子导体镶嵌包覆的钠离子电池正极材料及其合成方法 | |
CN108448057B (zh) | CoO/CoMoO4复合材料的制备及其在锂离子电池中的应用 | |
CN105932251B (zh) | 一种金属氧化物包覆锂离子电池正极材料的制备方法及其应用 | |
CN107681147B (zh) | 一种固态电解质包覆改性锂离子电池正极材料的制备方法与应用 | |
CN103094550A (zh) | 一种富锂正极材料的制备方法 | |
CN107112533A (zh) | 用于锂二次电池的阴极活性材料、其制备方法以及包含其的锂二次电池 | |
CN106450211A (zh) | 一种表面包覆复合的富锂锰基正极材料及其制备方法 | |
CN105938899A (zh) | 一种快离子导体包覆改性锂离子电池正极材料的制备方法及应用 | |
CN107634189A (zh) | 一种改性镍钴铝三元正极材料及其制备方法和应用 | |
CN104157866A (zh) | 用于高倍率锂离子电池的、具有分级微/纳米结构的金属/非金属共掺杂的钛酸锂球体 | |
WO2017063233A1 (zh) | 离子基团诱导复合相修饰的富锂层状正极材料及制备方法 | |
Liu et al. | Electrochemical properties of four novel high-entropy spinel oxides used as lithium-ion battery anodes synthesized by the glycine-nitrate SCS method | |
CN107204424B (zh) | 一种富锂锰基层状锂电池正极材料的制备方法 | |
CN111554914B (zh) | 一种磷酸铁锂-磷酸钒钠-碳复合材料及其制备方法和应用 | |
CN107170969B (zh) | 一种改性的锂离子电池富锂锰基正极材料及其制备方法 | |
CN111211302B (zh) | 锂离子电池正极材料及其制备方法、锂离子电池正极、锂离子电池和用电设备 | |
CN107256963A (zh) | 负极材料及制作方法、负极及锂离子全电池及制作方法 | |
CN105185969B (zh) | 一种正极材料及其制备方法 | |
CN115939360A (zh) | 磷酸锰铁锂-富锂锰基复合正极材料、制备方法及应用 | |
CN110176587A (zh) | 一种钒离子表面掺杂镍钴铝三元正极材料、制备方法及其应用 | |
Zhu et al. | Enabling improved lithium storage properties of novel LiNbMoO6 anode through co-modification by uniform Li2SiO3 thin film and oxygen vacancies |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PB01 | Publication | ||
PB01 | Publication | ||
SE01 | Entry into force of request for substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
CB03 | Change of inventor or designer information | ||
CB03 | Change of inventor or designer information |
Inventor after: Feng Chuanqi Inventor after: Zhang Zhen Inventor after: Chen Xiao Inventor before: Feng Chuanqi Inventor before: Zhang Zhen Inventor before: Chen Xiao Inventor before: Guo Zaiping |
|
GR01 | Patent grant | ||
GR01 | Patent grant | ||
TR01 | Transfer of patent right | ||
TR01 | Transfer of patent right |
Effective date of registration: 20240424 Address after: 230000 floor 1, building 2, phase I, e-commerce Park, Jinggang Road, Shushan Economic Development Zone, Hefei City, Anhui Province Patentee after: Dragon totem Technology (Hefei) Co.,Ltd. Country or region after: China Address before: 430062 368 Friendship Avenue, Wuchang District, Wuhan, Hubei. Patentee before: Hubei University Country or region before: China |