CN109526217A - 包含环三藜芦烃及其衍生物的烯烃聚合催化剂 - Google Patents
包含环三藜芦烃及其衍生物的烯烃聚合催化剂 Download PDFInfo
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- CN109526217A CN109526217A CN201880002860.5A CN201880002860A CN109526217A CN 109526217 A CN109526217 A CN 109526217A CN 201880002860 A CN201880002860 A CN 201880002860A CN 109526217 A CN109526217 A CN 109526217A
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- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
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- C07C43/20—Ethers having an ether-oxygen atom bound to a carbon atom of a six-membered aromatic ring
- C07C43/21—Ethers having an ether-oxygen atom bound to a carbon atom of a six-membered aromatic ring containing rings other than six-membered aromatic rings
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- C07C43/02—Ethers
- C07C43/20—Ethers having an ether-oxygen atom bound to a carbon atom of a six-membered aromatic ring
- C07C43/225—Ethers having an ether-oxygen atom bound to a carbon atom of a six-membered aromatic ring containing halogen
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- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/02—Ethene
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- C—CHEMISTRY; METALLURGY
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- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/04—Monomers containing three or four carbon atoms
- C08F10/06—Propene
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- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/02—Carriers therefor
- C08F4/022—Magnesium halide as support anhydrous or hydrated or complexed by means of a Lewis base for Ziegler-type catalysts
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- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/642—Component covered by group C08F4/64 with an organo-aluminium compound
- C08F4/6421—Titanium tetrahalides with organo-aluminium compounds
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- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/643—Component covered by group C08F4/64 with a metal or compound covered by group C08F4/44 other than an organo-aluminium compound
- C08F4/6432—Component of C08F4/64 containing at least two different metals
- C08F4/6435—Component of C08F4/64 containing at least two different metals containing magnesium
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- C—CHEMISTRY; METALLURGY
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- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
- C08F4/652—Pretreating with metals or metal-containing compounds
- C08F4/654—Pretreating with metals or metal-containing compounds with magnesium or compounds thereof
- C08F4/6541—Pretreating with metals or metal-containing compounds with magnesium or compounds thereof and metals of C08F4/64 or compounds thereof
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
- C08F4/652—Pretreating with metals or metal-containing compounds
- C08F4/654—Pretreating with metals or metal-containing compounds with magnesium or compounds thereof
- C08F4/6546—Pretreating with metals or metal-containing compounds with magnesium or compounds thereof organo-magnesium compounds
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2603/00—Systems containing at least three condensed rings
- C07C2603/02—Ortho- or ortho- and peri-condensed systems
- C07C2603/40—Ortho- or ortho- and peri-condensed systems containing four condensed rings
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- C—CHEMISTRY; METALLURGY
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- C08F2410/00—Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
- C08F2410/01—Additive used together with the catalyst, excluding compounds containing Al or B
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Abstract
本发明公开了一种用于烯烃聚合的齐格勒‑纳塔型催化剂体系,其包含至少一种式(Ⅰ)所示的化合物作为(i)内给电子体,(ii)外给电子体,或者(iii)二者,其中M1、M2、M3、M4、M5、M6、M1’、M2’、M3’、M4’、M5’、M6’各自独立地选自氢、羟基、氨基、醛基、羧基、酰基、卤原子、‑R1或‑OR2,其中R1和R2各自独立地为未取代的C1‑C10烃基或被选自羟基、氨基、醛基、羧基、酰基、卤原子、C1‑C10烷氧基和杂原子的取代基取代的C1‑C10烃基;其中当M1‑M6和M1’‑M6’中的在同一苯环上的任何两个相邻的基团各自独立地选自R1和‑OR2时,所述两个相邻的基团可任选地连接成环,前提是M1、M2、M3、M4、M5、M6、M1’、M2’、M3’、M4’、M5’、M6’不同时为氢。
Description
PCT国内申请,说明书已公开。
Claims (31)
- PCT国内申请,权利要求书已公开。
Applications Claiming Priority (23)
Application Number | Priority Date | Filing Date | Title |
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CN2017105923810 | 2017-07-19 | ||
CN2017105923863 | 2017-07-19 | ||
CN201710592381.0A CN109280106B (zh) | 2017-07-19 | 2017-07-19 | 用于烯烃聚合的固体催化剂组分和催化剂体系以及烯烃聚合方法 |
CN201710591148.0A CN109280101B (zh) | 2017-07-19 | 2017-07-19 | 用于烯烃聚合的固体催化剂组分和催化剂体系以及烯烃聚合方法 |
CN2017105923986 | 2017-07-19 | ||
CN201710591859.8A CN109280105B (zh) | 2017-07-19 | 2017-07-19 | 一种用于烯烃聚合的催化剂体系及其应用 |
CN2017105923844 | 2017-07-19 | ||
CN2017105923859 | 2017-07-19 | ||
CN201710592386.3A CN109280110B (zh) | 2017-07-19 | 2017-07-19 | 用于烯烃聚合的固体催化剂组分和烯烃聚合催化剂及其应用和乙烯共聚物 |
CN201710591181.3A CN109280103B (zh) | 2017-07-19 | 2017-07-19 | 一种用于烯烃聚合的催化剂体系及其应用 |
CN201710592398.6A CN109280111B (zh) | 2017-07-19 | 2017-07-19 | 一种用于烯烃聚合的催化剂体系及其应用 |
CN2017105911739 | 2017-07-19 | ||
CN201710591173.9A CN109280102B (zh) | 2017-07-19 | 2017-07-19 | 用于烯烃聚合的固体催化剂组分和催化剂体系以及烯烃聚合方法 |
CN2017105918598 | 2017-07-19 | ||
CN201710592384.4A CN109280108B (zh) | 2017-07-19 | 2017-07-19 | 用于烯烃聚合的固体催化剂组分和催化剂体系以及烯烃聚合方法 |
CN201710591855X | 2017-07-19 | ||
CN2017105911480 | 2017-07-19 | ||
CN201710591855.XA CN109280104B (zh) | 2017-07-19 | 2017-07-19 | 环三藜芦烃及其衍生物在烯烃聚合催化剂中的应用 |
CN201710592385.9A CN109280109B (zh) | 2017-07-19 | 2017-07-19 | 一种用于烯烃聚合的催化剂体系及其应用 |
CN2017105911813 | 2017-07-19 | ||
CN201710592383.XA CN109280107B (zh) | 2017-07-19 | 2017-07-19 | 一种用于烯烃聚合的催化剂体系及其应用 |
CN201710592383X | 2017-07-19 | ||
PCT/CN2018/096248 WO2019015638A1 (zh) | 2017-07-19 | 2018-07-19 | 包含环三藜芦烃及其衍生物的烯烃聚合催化剂 |
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CN109526217A true CN109526217A (zh) | 2019-03-26 |
CN109526217B CN109526217B (zh) | 2022-05-24 |
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CN201880002860.5A Active CN109526217B (zh) | 2017-07-19 | 2018-07-19 | 包含环三藜芦烃及其衍生物的烯烃聚合催化剂 |
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US (1) | US11401356B2 (zh) |
EP (1) | EP3656754B1 (zh) |
JP (1) | JP7038797B2 (zh) |
KR (1) | KR102336976B1 (zh) |
CN (1) | CN109526217B (zh) |
BR (1) | BR112020001201B1 (zh) |
FI (1) | FI3656754T3 (zh) |
RU (1) | RU2740916C1 (zh) |
WO (1) | WO2019015638A1 (zh) |
Families Citing this family (5)
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JP2022542156A (ja) * | 2019-07-26 | 2022-09-29 | 中国石油化工股▲ふん▼有限公司 | オレフィン重合に用いられる触媒系、及びその適用 |
CN114478861B (zh) * | 2020-10-26 | 2024-03-26 | 中国石油化工股份有限公司 | 用于烯烃聚合的催化剂组分及其制备方法、催化剂和制备超高分子量聚烯烃的方法及应用 |
CN114478854A (zh) * | 2020-10-26 | 2022-05-13 | 中国石油化工股份有限公司 | 用于烯烃聚合的催化剂组分及其制备方法、催化剂和制备超高分子量聚烯烃的方法及应用 |
CN115975083A (zh) * | 2021-10-14 | 2023-04-18 | 中国石油化工股份有限公司 | 一种用于乙烯聚合的催化剂组分及催化剂和乙烯聚合反应方法 |
WO2024120970A1 (en) * | 2022-12-09 | 2024-06-13 | Ineos Europe Ag | Catalyst component |
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2018
- 2018-07-19 FI FIEP18835679.4T patent/FI3656754T3/fi active
- 2018-07-19 US US16/631,482 patent/US11401356B2/en active Active
- 2018-07-19 KR KR1020207002897A patent/KR102336976B1/ko active IP Right Grant
- 2018-07-19 CN CN201880002860.5A patent/CN109526217B/zh active Active
- 2018-07-19 JP JP2020502696A patent/JP7038797B2/ja active Active
- 2018-07-19 RU RU2020103744A patent/RU2740916C1/ru active
- 2018-07-19 WO PCT/CN2018/096248 patent/WO2019015638A1/zh unknown
- 2018-07-19 BR BR112020001201-7A patent/BR112020001201B1/pt active IP Right Grant
- 2018-07-19 EP EP18835679.4A patent/EP3656754B1/en active Active
Patent Citations (3)
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CN1220672A (zh) * | 1997-02-07 | 1999-06-23 | 三井化学株式会社 | 烯烃聚合催化剂以及生产烯烃聚合物的方法 |
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Publication number | Publication date |
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BR112020001201A2 (pt) | 2020-07-21 |
KR20200033267A (ko) | 2020-03-27 |
JP7038797B2 (ja) | 2022-03-18 |
FI3656754T3 (fi) | 2024-06-20 |
BR112020001201B1 (pt) | 2023-03-21 |
JP2020526655A (ja) | 2020-08-31 |
WO2019015638A1 (zh) | 2019-01-24 |
US20200181296A1 (en) | 2020-06-11 |
EP3656754B1 (en) | 2024-05-29 |
US11401356B2 (en) | 2022-08-02 |
EP3656754A1 (en) | 2020-05-27 |
RU2740916C1 (ru) | 2021-01-21 |
KR102336976B1 (ko) | 2021-12-07 |
CN109526217B (zh) | 2022-05-24 |
EP3656754A4 (en) | 2021-05-05 |
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