CN1090534C - 用于制备乙酸乙烯酯的方法和催化剂 - Google Patents

用于制备乙酸乙烯酯的方法和催化剂 Download PDF

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Publication number
CN1090534C
CN1090534C CN97193584A CN97193584A CN1090534C CN 1090534 C CN1090534 C CN 1090534C CN 97193584 A CN97193584 A CN 97193584A CN 97193584 A CN97193584 A CN 97193584A CN 1090534 C CN1090534 C CN 1090534C
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CN
China
Prior art keywords
catalyst
compounds
boron
support
oxygen
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CN97193584A
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English (en)
Chinese (zh)
Other versions
CN1215355A (zh
Inventor
R·埃贝尔
I·尼克劳
E·霍弗
R·柯迈尔
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Celanese GmbH
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Celanese GmbH
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Publication of CN1215355A publication Critical patent/CN1215355A/zh
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Publication of CN1090534C publication Critical patent/CN1090534C/zh
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/58—Platinum group metals with alkali- or alkaline earth metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/66—Silver or gold
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/48—Silver or gold
    • B01J23/52—Gold
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/04—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds
    • C07C67/05—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds with oxidation
    • C07C67/055—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds with oxidation in the presence of platinum group metals or their compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/007—Esters of unsaturated alcohols having the esterified hydroxy group bound to an acyclic carbon atom
    • C07C69/01—Vinyl esters

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CN97193584A 1996-04-04 1997-03-17 用于制备乙酸乙烯酯的方法和催化剂 Expired - Fee Related CN1090534C (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE19613791A DE19613791C2 (de) 1996-04-04 1996-04-04 Katalysator, Verfahren zu seiner Herstellung und Verfahren zur Herstellung von Vinylacetat
DE19613791.8 1996-04-04

Publications (2)

Publication Number Publication Date
CN1215355A CN1215355A (zh) 1999-04-28
CN1090534C true CN1090534C (zh) 2002-09-11

Family

ID=7790648

Family Applications (1)

Application Number Title Priority Date Filing Date
CN97193584A Expired - Fee Related CN1090534C (zh) 1996-04-04 1997-03-17 用于制备乙酸乙烯酯的方法和催化剂

Country Status (18)

Country Link
US (1) US6114571A (enExample)
EP (1) EP0891226B1 (enExample)
JP (1) JP3999269B2 (enExample)
KR (1) KR100439454B1 (enExample)
CN (1) CN1090534C (enExample)
AT (1) ATE186476T1 (enExample)
AU (1) AU711272B2 (enExample)
BR (1) BR9708504A (enExample)
CZ (1) CZ291509B6 (enExample)
DE (2) DE19613791C2 (enExample)
ES (1) ES2141604T3 (enExample)
HU (1) HUP9901871A3 (enExample)
NO (1) NO984550L (enExample)
NZ (1) NZ331900A (enExample)
PL (1) PL329215A1 (enExample)
TR (1) TR199801982T2 (enExample)
WO (1) WO1997037759A1 (enExample)
YU (1) YU42798A (enExample)

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* Cited by examiner, † Cited by third party
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DE19755023C2 (de) * 1997-12-11 2000-03-09 Celanese Chem Europe Gmbh Katalysator und Verfahren zur Herstellung von Vinylacetat
DE19754991C2 (de) * 1997-12-11 2000-03-23 Celanese Chem Europe Gmbh Katalysator, Verfahren zur Herstellung des Katalysators und Verfahren zur Herstellung von Vinylacetat unter Einsatz des Katalysators
DE19754992C2 (de) * 1997-12-11 2000-03-23 Celanese Chem Europe Gmbh Katalysator, Verfahren zur Herstellung des Katalysators und Verfahren zur Herstellung von Vinylacetat unter Einsatz des Katalysators
DE19914066A1 (de) * 1999-03-27 2000-10-05 Celanese Chem Europe Gmbh Katalysatoren für die Gasphasenoxidation von Ethylen und Essigsäure zu Vinylacetat, Verfahren zu ihrer Herstellung und ihre Verwendung
DE19920390C2 (de) * 1999-05-04 2002-08-01 Celanese Chem Europe Gmbh Katalysator und Verfahren zur Herstellung von Vinylacetat
CA2448322A1 (en) * 2001-03-30 2002-10-10 Shell Internationale Research Maatschappij B.V. Process for preparing a group viii-metal containing catalyst, use thereof for preparing an alkenyl carboxylate
JP4421201B2 (ja) * 2002-03-27 2010-02-24 シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー 触媒を調製する方法、触媒、および触媒の使用
TW201240725A (en) * 2003-12-19 2012-10-16 Celanese Int Corp Layered support material for catalysts
JP4772694B2 (ja) * 2003-12-19 2011-09-14 セラニーズ・インターナショナル・コーポレーション 触媒のための層状担持材
JP4551109B2 (ja) * 2004-04-14 2010-09-22 エヌ・イーケムキャット株式会社 触媒の製造方法
ZA200704864B (en) 2004-12-20 2008-08-27 Celanese Int Corp Modified support materials for catalysts
US8227369B2 (en) 2005-05-25 2012-07-24 Celanese International Corp. Layered composition and processes for preparing and using the composition
US8471075B2 (en) * 2008-07-31 2013-06-25 Celanese International Corporation Processes for making ethanol from acetic acid
US8304586B2 (en) 2010-02-02 2012-11-06 Celanese International Corporation Process for purifying ethanol
US8309772B2 (en) 2008-07-31 2012-11-13 Celanese International Corporation Tunable catalyst gas phase hydrogenation of carboxylic acids
US8680317B2 (en) 2008-07-31 2014-03-25 Celanese International Corporation Processes for making ethyl acetate from acetic acid
US8501652B2 (en) 2008-07-31 2013-08-06 Celanese International Corporation Catalysts for making ethanol from acetic acid
US8546622B2 (en) 2008-07-31 2013-10-01 Celanese International Corporation Process for making ethanol from acetic acid using acidic catalysts
US8637714B2 (en) 2008-07-31 2014-01-28 Celanese International Corporation Process for producing ethanol over catalysts containing platinum and palladium
US8309773B2 (en) 2010-02-02 2012-11-13 Calanese International Corporation Process for recovering ethanol
US8338650B2 (en) 2008-07-31 2012-12-25 Celanese International Corporation Palladium catalysts for making ethanol from acetic acid
US7855303B2 (en) * 2008-11-14 2010-12-21 Celanese International Corporation Integrated process for the production of vinyl acetate from acetic acid via ethylene
US7820853B2 (en) * 2008-12-31 2010-10-26 Celanese International Corporation Integrated process for the production of vinyl acetate from acetic acid via ethyl acetate
US8178715B2 (en) * 2008-12-31 2012-05-15 Celanese International Corporation Integrated process for the production of vinyl acetate from acetic acid via acetaldehyde
US8450535B2 (en) 2009-07-20 2013-05-28 Celanese International Corporation Ethanol production from acetic acid utilizing a cobalt catalyst
US8710277B2 (en) * 2009-10-26 2014-04-29 Celanese International Corporation Process for making diethyl ether from acetic acid
US8680321B2 (en) 2009-10-26 2014-03-25 Celanese International Corporation Processes for making ethanol from acetic acid using bimetallic catalysts
US8211821B2 (en) 2010-02-01 2012-07-03 Celanese International Corporation Processes for making tin-containing catalysts
US8932372B2 (en) 2010-02-02 2015-01-13 Celanese International Corporation Integrated process for producing alcohols from a mixed acid feed
US8747492B2 (en) 2010-02-02 2014-06-10 Celanese International Corporation Ethanol/fuel blends for use as motor fuels
US8541633B2 (en) 2010-02-02 2013-09-24 Celanese International Corporation Processes for producing anhydrous ethanol compositions
US8728179B2 (en) 2010-02-02 2014-05-20 Celanese International Corporation Ethanol compositions
US8858659B2 (en) 2010-02-02 2014-10-14 Celanese International Corporation Processes for producing denatured ethanol
US8344186B2 (en) 2010-02-02 2013-01-01 Celanese International Corporation Processes for producing ethanol from acetaldehyde
US8222466B2 (en) 2010-02-02 2012-07-17 Celanese International Corporation Process for producing a water stream from ethanol production
US8680343B2 (en) 2010-02-02 2014-03-25 Celanese International Corporation Process for purifying ethanol
US8460405B2 (en) 2010-02-02 2013-06-11 Celanese International Corporation Ethanol compositions
CN102413921B (zh) 2010-02-02 2016-05-18 国际人造丝公司 由乙醛生产乙醇的方法
US8668750B2 (en) 2010-02-02 2014-03-11 Celanese International Corporation Denatured fuel ethanol compositions for blending with gasoline or diesel fuel for use as motor fuels
MX2012008940A (es) 2010-02-02 2012-08-15 Celanese Int Corp Preparacion y uso de un catalizador para producir etanol que comprende un modificador de soporte.
US8314272B2 (en) 2010-02-02 2012-11-20 Celanese International Corporation Process for recovering ethanol with vapor separation
US8569551B2 (en) 2010-05-07 2013-10-29 Celanese International Corporation Alcohol production process integrating acetic acid feed stream comprising water from carbonylation process
US8680342B2 (en) 2010-05-07 2014-03-25 Celanese International Corporation Process for recovering alcohol produced by hydrogenating an acetic acid feed stream comprising water
US8754267B2 (en) 2010-05-07 2014-06-17 Celanese International Corporation Process for separating acetaldehyde from ethanol-containing mixtures
ES2803473T3 (es) 2010-10-28 2021-01-26 Celanese Int Corp Procedimientos para producir una composición de acetato de vinilo que tiene un contenido de impurezas bajo
US8350098B2 (en) 2011-04-04 2013-01-08 Celanese International Corporation Ethanol production from acetic acid utilizing a molybdenum carbide catalyst
US8536382B2 (en) 2011-10-06 2013-09-17 Celanese International Corporation Processes for hydrogenating alkanoic acids using catalyst comprising tungsten
US8658843B2 (en) 2011-10-06 2014-02-25 Celanese International Corporation Hydrogenation catalysts prepared from polyoxometalate precursors and process for using same to produce ethanol while minimizing diethyl ether formation
US8648220B2 (en) 2011-10-11 2014-02-11 Celanese International Corporation Process for producing ethanol using a crude vinyl acetate feed
US8703868B2 (en) 2011-11-28 2014-04-22 Celanese International Corporation Integrated process for producing polyvinyl alcohol or a copolymer thereof and ethanol
US8697802B2 (en) 2011-11-28 2014-04-15 Celanese International Corporation Process for producing polyvinyl alcohol or a copolymer thereof
US8884052B2 (en) 2011-12-15 2014-11-11 Celanese International Corporation Production of diacetoxyethylene by direct acetoxylation
US9000234B2 (en) 2011-12-22 2015-04-07 Celanese International Corporation Calcination of modified support to prepare hydrogenation catalysts
US9233899B2 (en) 2011-12-22 2016-01-12 Celanese International Corporation Hydrogenation catalysts having an amorphous support
US8907142B2 (en) 2011-12-29 2014-12-09 Celanese International Corporation Process for promoting catalyst activity for ethyl acetate conversion
SG11201501463QA (en) 2012-09-06 2015-03-30 Celanese Int Corp Processes for producing vinyl acetate
US8772553B2 (en) 2012-10-26 2014-07-08 Celanese International Corporation Hydrogenation reaction conditions for producing ethanol
US8853469B2 (en) 2012-11-20 2014-10-07 Celanese International Corporation Combined column for separating products of different hydrogenation reactors
JP6193723B2 (ja) * 2013-10-25 2017-09-06 日本酢ビ・ポバール株式会社 主鎖に１，２，３−トリオール基を有するポリビニルアルコール系樹脂およびその製造方法
DE102015224422B4 (de) * 2015-12-07 2026-06-25 Robert Bosch Gmbh Elektronische Schaltungseinheit
US20240059848A1 (en) * 2021-01-12 2024-02-22 Bridgestone Corporation Rubber vulcanization processes employing a eutectic mixture

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3939199A (en) * 1971-01-06 1976-02-17 Hoechst Aktiengesellschaft Oxacylation of olefins in the gaseous phase
US4048096A (en) * 1976-04-12 1977-09-13 E. I. Du Pont De Nemours And Company Surface impregnated catalyst
CN1068104A (zh) * 1991-06-21 1993-01-20 赫彻斯特股份公司 制备乙酸乙烯酯的催化剂和方法
CN1068051A (zh) * 1991-06-21 1993-01-20 赫彻斯特股份公司 制备乙酸乙烯酯的载体催化剂、方法和用途
US5332710A (en) * 1992-10-14 1994-07-26 Hoechst Celanese Corporation Vinyl acetate catalyst preparation method

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DE1252662B (enExample) * 1965-06-25
EP0672453B1 (en) * 1994-02-22 2005-11-02 The Standard Oil Company Process for the preparation of fluid bed vinyl acetate catalyst
US5665667A (en) * 1994-06-02 1997-09-09 The Standard Oil Company Process for the preparation of vinyl acetate catalyst
US5688993A (en) * 1995-12-22 1997-11-18 E. I. Du Pont De Nemours And Company Method for modifying catalyst performance during the gas phase synthesis of vinyl acetate

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3939199A (en) * 1971-01-06 1976-02-17 Hoechst Aktiengesellschaft Oxacylation of olefins in the gaseous phase
US4048096A (en) * 1976-04-12 1977-09-13 E. I. Du Pont De Nemours And Company Surface impregnated catalyst
CN1068104A (zh) * 1991-06-21 1993-01-20 赫彻斯特股份公司 制备乙酸乙烯酯的催化剂和方法
CN1068051A (zh) * 1991-06-21 1993-01-20 赫彻斯特股份公司 制备乙酸乙烯酯的载体催化剂、方法和用途
US5332710A (en) * 1992-10-14 1994-07-26 Hoechst Celanese Corporation Vinyl acetate catalyst preparation method

Also Published As

Publication number Publication date
DE59700698D1 (de) 1999-12-16
DE19613791A1 (de) 1997-10-09
EP0891226B1 (de) 1999-11-10
CZ314898A3 (cs) 1999-03-17
CZ291509B6 (cs) 2003-03-12
WO1997037759A1 (de) 1997-10-16
KR20000005212A (ko) 2000-01-25
JP3999269B2 (ja) 2007-10-31
EP0891226A1 (de) 1999-01-20
HUP9901871A3 (en) 2000-05-29
CN1215355A (zh) 1999-04-28
US6114571A (en) 2000-09-05
NO984550D0 (no) 1998-09-29
YU42798A (sh) 1999-07-28
HUP9901871A2 (hu) 1999-09-28
KR100439454B1 (ko) 2004-10-15
AU711272B2 (en) 1999-10-07
JP2000508575A (ja) 2000-07-11
TR199801982T2 (xx) 1999-02-22
DE19613791C2 (de) 2002-01-31
PL329215A1 (en) 1999-03-15
NZ331900A (en) 2000-05-26
ES2141604T3 (es) 2000-03-16
ATE186476T1 (de) 1999-11-15
NO984550L (no) 1998-09-29
AU2157097A (en) 1997-10-29
BR9708504A (pt) 2000-01-04

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Granted publication date: 20020911

Termination date: 20140317