CN109023932B - 一种织物柔顺剂 - Google Patents

一种织物柔顺剂 Download PDF

Info

Publication number
CN109023932B
CN109023932B CN201810640654.9A CN201810640654A CN109023932B CN 109023932 B CN109023932 B CN 109023932B CN 201810640654 A CN201810640654 A CN 201810640654A CN 109023932 B CN109023932 B CN 109023932B
Authority
CN
China
Prior art keywords
parts
silicone oil
fabric softener
fabric
amino silicone
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN201810640654.9A
Other languages
English (en)
Other versions
CN109023932A (zh
Inventor
龚亚丽
徐涛
余守洪
高京华
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hubei Jianke Daily Chemical Co ltd
Original Assignee
Hubei Jianke Daily Chemical Co ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hubei Jianke Daily Chemical Co ltd filed Critical Hubei Jianke Daily Chemical Co ltd
Priority to CN201810640654.9A priority Critical patent/CN109023932B/zh
Publication of CN109023932A publication Critical patent/CN109023932A/zh
Application granted granted Critical
Publication of CN109023932B publication Critical patent/CN109023932B/zh
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/46—Compounds containing quaternary nitrogen atoms
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/144—Alcohols; Metal alcoholates
    • D06M13/148—Polyalcohols, e.g. glycerol or glucose
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/325—Amines
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/402—Amides imides, sulfamic acids
    • D06M13/419—Amides having nitrogen atoms of amide groups substituted by hydroxyalkyl or by etherified or esterified hydroxyalkyl groups
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
    • D06M15/03—Polysaccharides or derivatives thereof
    • D06M15/05—Cellulose or derivatives thereof
    • D06M15/09—Cellulose ethers
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
    • D06M15/6436—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain containing amino groups
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
    • D06M15/647—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain containing polyether sequences
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/50—Modified hand or grip properties; Softening compositions

Abstract

本发明公开了一种织物柔顺剂，包括以下质量份的组分：酯基季铵盐3～15份、水溶性聚醚硅油1～5份、氨基硅油2～10份、EDC 0.2～0.8份、N‑羟基硫代琥珀酰亚胺0.06～0.18份，去离子水70～80份。本发明的织物柔顺剂在发挥高氨值的氨基硅油良好的柔软性和滑度的优点时，可有效减少色变，使用后对织物无伤害，可增加织物的柔软性、透气性，洗涤后，织物再润湿性好，抗静电，不泛黄，香味淡雅清闲，留香持久。

Description

一种织物柔顺剂
技术领域
本发明属于日化用品技术领域，特别涉及一种织物柔顺剂技术领域。
背景技术
织物柔顺剂，也叫织物护理剂，是一种洗涤护理用品，其可在织物纤维的表面上均匀地附着一层保护膜，纤维表面由于吸附了柔软剂，纤维间的摩擦系数降低，从而可增强移动性，同时纤维固有的平滑、延伸、压缩性能也均得到了恢复，所以织物变得更加柔软、蓬松、有弹性。
市场现有的织物柔顺剂的基本活性成份之一为氨基硅油，氨基硅油中由于氨基的极性，能与纤维表面的羟基、羧基等通过化学键合，使硅氧烷主链定向吸附在纤维表面，从而降低了纤维之间的摩擦系数，以很小的力就能使纤维之间产生滑动，表现出柔软、平滑特性，所以氨基硅油用于织物整理后可以赋予优良的柔软性、滑爽性、弹性、抗皱、耐洗、抗撕裂和穿着舒适等性能，硅油分子在织物表面成膜，使织物具有良好的弹性，大大提高了对织物的整理效果，氨基硅油由其上述优点而广泛应用于织物柔顺剂中。
但氨基硅油因其侧键上氨基及活泼氢原子，在光照、温热和紫外线的影响下易生成偶氮基发色团，导致整理浅色或白色织物在经过高温烘焙或长时间穿着后会出现不同程度的黄变现象，使得现有的织物柔顺剂难以应用于浅色或白色，及高端织物。一般认为，氨基硅油的氨值越高，织物的柔软性和滑度越好，但是黄变也会越大。
发明内容
本发明为克服现有技术中存在的问题，提供一种织物柔顺剂，在发挥高氨值的氨基硅油良好的柔软性和滑度的优点时，可有效减少色变。
本发明为解决上述现有技术中存在的问题，采用如下的技术方案。
一种织物柔顺剂，其特征在于，所述织物柔顺剂包括以下质量份的组分：酯基季铵盐3～15份、水溶性聚醚硅油1～5份、氨基硅油2～10份、EDC 0.2～0.8份、N-羟基硫代琥珀酰亚胺0.06～0.18份，去离子水70～80份。
进一步的，所述氨基硅油的氨值为0.5～1.0。
进一步的，所述织物柔顺剂，还包括3～8份质量份的粘度稳定剂。
进一步的，所述粘度稳定剂为羧甲基纤维素、羟乙基纤维素的一种或两种。
进一步的，所述织物柔顺剂，还包括香芬微胶囊0.5～3份。
进一步的，所述香芬微胶囊为玫瑰香芬微胶囊、迪奥香芬微胶囊、宝莉香芬微胶囊中的一种或几种。
相对于现有技术，本发明取得了以下有益效果：
1、本发明的织物柔顺剂，使用后对织物无伤害，可增加织物的柔软性、透气性，洗涤后，织物再润湿性好，抗静电，不泛黄，香味淡雅清闲，留香持久。
2、本发明的织物柔顺剂，EDC(1-(3-二甲氨基丙基)-3-乙基碳二亚胺盐酸盐)中具有的活性基团可在在纤维分子与氨基硅油分子之间形成联结发生架桥反应，形成的网状结构更连续及稳定，织物染料只能在纤维分子间隙内移动，尚不能脱离纤维，所以织物色变低；另外，N-羟基硫代琥珀酰亚胺与EDC联用，可进一步提高EDC架桥反应的联结效率，少量添加即可大大降低织物色变。
3、现有技术中，应用于织物柔顺剂中的氨基硅油的氨值一般较低仅为0.1～0.3，而本发有的织物柔顺剂的氨基硅油的氨值可高达0.5～1.0，EDC组份使氨基硅油分子在织物及纤维内外的交联更充分，结构更稳定，在发挥高氨值的氨基硅油良好的柔软性和滑度的优点时，可有效减少色变。
4、本发明的织物柔顺剂，采用羧甲基纤维素、羟乙基纤维素的一种或两种作为粘度稳定剂，羧甲基纤维素或羟乙基纤维素用于调节织物柔顺剂的粘度时，也可在EDC中的活性基团作用下与氨基硅油分子之间发生架桥反应，进一步提高氨基硅油分子在织物及纤维内外的交联度，结构更稳定。
具体实施方式
下面将对实施例中的技术方案进行清楚、完整地描述。显然，所描述的实施例仅仅是本发明的一部分实施例，而不是全部的实施例。基于本发明的实施例，本领域普通技术人员在没有作出创造性劳动前提下所获得的所有其他实施例，都属于本发明保护的范围。
一、实施例
实施例1
织物柔顺剂包括以下质量份的组分：
酯基季铵盐3份、水溶性聚醚硅油5份、氨基硅油6份、EDC 0.8份、N-羟基硫代琥珀酰亚胺0.12份、香芬2份，去离子水80份。
其中，氨基硅油的氨值为1.0。
实施例2
织物柔顺剂包括以下质量份的组分：
酯基季铵盐9份、水溶性聚醚硅油1份、氨基硅油10份、EDC 0.2份、N-羟基硫代琥珀酰亚胺0.18份、香芬2份，去离子水75份。
其中，氨基硅油的氨值为0.5。
实施例3
织物柔顺剂包括以下质量份的组分：
酯基季铵盐15份、水溶性聚醚硅油1份、氨基硅油10份、EDC 0.2份、N-羟基硫代琥珀酰亚胺0.12份、粘度稳定剂8份、香芬0.5份，去离子水70份。
其中，氨基硅油的氨值为1.0，粘度稳定剂为羧甲基纤维素。
实施例4
织物柔顺剂包括以下质量份的组分：
酯基季铵盐9份、水溶性聚醚硅油3份、氨基硅油6份、EDC 0.5份、N-羟基硫代琥珀酰亚胺0.06份、粘度稳定剂3份、香芬3份，去离子水75份。
其中，氨基硅油的氨值为0.7，粘度稳定剂为羧甲基纤维素。
实施例5
织物柔顺剂包括以下质量份的组分：
酯基季铵盐3份、水溶性聚醚硅油5份、氨基硅油2份、EDC 0.8份、N-羟基硫代琥珀酰亚胺0.18份、粘度稳定剂5.5份、香芬3份，去离子水80份。
其中，氨基硅油的氨值为0.5，粘度稳定剂为羧甲基纤维素及羟乙基纤维素的组合物，羧甲基纤维素与羟乙基纤维素的组合物的质量比为5：5。
实施例6
织物柔顺剂包括以下质量份的组分：
酯基季铵盐15份、水溶性聚醚硅油3份、氨基硅油2份、EDC 0.5份、N-羟基硫代琥珀酰亚胺0.06份、粘度稳定剂5.5份、香芬0.5份，去离子水70份。
其中，氨基硅油的氨值为0.7，粘度稳定剂为羧甲基纤维素及羟乙基纤维素的组合物，羧甲基纤维素与羟乙基纤维素的组合物的质量比为8：2。
二、试验例
分别取本实施例1～6配比制备的织物柔顺剂，及2款市售畅销氨基硅油柔顺剂(对比例1的氨值为0.2；对比例2的氨值为0.3)作为对比例处理同一批白色织物，评估其黄变度及柔软度。
1、黄变试验
分别取本实施例1～6配比制备的织物柔顺剂及对比例1和2的柔顺剂，分别处理同款白色棉质毛巾，晒干6小时，用Datacolor测色仪测试增白织物与基准样布的黄度变化情况，正值越大表明黄变越大。
2、柔软度试验
分别取本实施例1～6配比制备的织物柔顺剂及对比例1和2的柔顺剂，分别处理同款白色棉质毛巾，选择10名专业人员进行触摸测试，1分为柔软度最差，10分为柔软度最好，根据打分结果取平均值。
相关试验结果如下：
样品 黄变值 柔软度评分
实施例1 0.09 8.5
实施例2 0.05 8.1
实施例3 0.07 9
实施例4 0.06 8.6
实施例5 0.02 7.4
实施例6 0.03 8.2
对比例1(氨值为0.2) 0.12 5.6
对比例2(氨值为0.3) 0.15 6.2
从上表中可以看出，(1)本发明的织物柔顺剂的氨值虽高达0.5～1.0，但经其处理的织物较市售的柔顺剂而言，黄变值均明显小于对比例，而且所有实施例处理的织物的柔软度明显优于对比例，说明本发明的织物柔顺剂在发挥高氨值的氨基硅油良好的柔软性和滑度的优点时，可有效减少色变。

Claims (3)

1.一种织物柔顺剂，其特征在于，所述织物柔顺剂包括以下质量份的组分：酯基季铵盐3～15份、水溶性聚醚硅油1～5份、氨基硅油2～10份、EDC 0.2～0.8份、N-羟基硫代琥珀酰亚胺0.06～0.18份，去离子水70～80份，EDC为1-(3-二甲氨基丙基)-3-乙基碳二亚胺盐酸盐，所述氨基硅油的氨值为0.5～1.0，所述织物柔顺剂，还包括3～8份质量份的粘度稳定剂，所述粘度稳定剂为羧甲基纤维素、羟乙基纤维素的一种或两种。
2.根据权利要求1所述的织物柔顺剂，其特征在于，所述织物柔顺剂，还包括香芬微胶囊0.5～3份。
3.根据权利要求2所述的织物柔顺剂，其特征在于，所述香芬微胶囊为玫瑰香芬微胶囊、迪奥香芬微胶囊、宝莉香芬微胶囊中的一种或几种。
CN201810640654.9A 2018-06-21 2018-06-21 一种织物柔顺剂 Active CN109023932B (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810640654.9A CN109023932B (zh) 2018-06-21 2018-06-21 一种织物柔顺剂

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201810640654.9A CN109023932B (zh) 2018-06-21 2018-06-21 一种织物柔顺剂

Publications (2)

Publication Number Publication Date
CN109023932A CN109023932A (zh) 2018-12-18
CN109023932B true CN109023932B (zh) 2021-08-13

Family

ID=64610345

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201810640654.9A Active CN109023932B (zh) 2018-06-21 2018-06-21 一种织物柔顺剂

Country Status (1)

Country Link
CN (1) CN109023932B (zh)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111234947A (zh) * 2020-02-28 2020-06-05 深圳市科玺化工有限公司 一种抗菌防臭洗衣液组合物及其制备方法
CN112553886A (zh) * 2020-12-01 2021-03-26 江苏合源纺织科技有限公司 一种高弹吸湿功能面料
CN114808460A (zh) * 2021-06-28 2022-07-29 染格材料科技(上海)有限公司 一种柔软剂及其制备方法、应用

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102505498A (zh) * 2011-11-01 2012-06-20 吴江市北厍盛源纺织品助剂厂 耐黄变有机硅改性聚氨酯柔软剂的制备方法
CN103642044A (zh) * 2013-12-05 2014-03-19 宁波润禾化学工业有限公司 一种高活性抗黄变改性氨基硅油的制备方法

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103031714B (zh) * 2012-12-30 2015-09-30 浙江喜得宝丝绸科技有限公司 丝绸后整理复配柔软剂及制备方法
CN105648757B (zh) * 2015-12-30 2018-01-30 江阴市长泾花园毛纺织有限公司 一种棉织物层的拒水整理方法
CN106868872A (zh) * 2017-03-13 2017-06-20 广东得到宝贝科技有限公司 一种衣物柔顺剂

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102505498A (zh) * 2011-11-01 2012-06-20 吴江市北厍盛源纺织品助剂厂 耐黄变有机硅改性聚氨酯柔软剂的制备方法
CN103642044A (zh) * 2013-12-05 2014-03-19 宁波润禾化学工业有限公司 一种高活性抗黄变改性氨基硅油的制备方法

Also Published As

Publication number Publication date
CN109023932A (zh) 2018-12-18

Similar Documents

Publication Publication Date Title
CN109023932B (zh) 一种织物柔顺剂
CN102605619B (zh) 一种棉织物的丝胶后整理方法
CN110820352B (zh) 一种高安全性无黄变滑弹柔软整理剂及其制备方法
CN109023933B (zh) 一种低温抗冻型织物柔顺剂
CN105040445A (zh) 一种印染用抗静电剂及其制备方法
JP4302523B2 (ja) 織物加工組成物及びこの組成物の使用方法
CN109082887B (zh) 一种织物柔顺剂
CN108797129B (zh) 一种织物柔顺剂
CN108486899B (zh) 一种织物柔软整理剂及其制备方法
CN112680968B (zh) 一种抗皱服饰生产工艺
CN110656500A (zh) 一种非硅型亲水性柔软剂及其制备方法与应用
Choudhury Advances in the finishing of silk fabrics
CN108395946A (zh) 防蛀型不缩水不变形羊毛羊绒丝毛专用洗涤剂及制备方法
CN111962312A (zh) 一种超柔顺不扎人排汗保暖羊毛睡衣/内衣面料的制备方法
WO2005079439B1 (en) Compositions useful as fabric softeners
CN110924174A (zh) 一种织物柔软剂及其制备方法
CN111499872A (zh) 一种棉用侧链亲水改性嵌段硅油的制备方法
CN110791965A (zh) 一种面料柔软剂及其制备方法
CN115652613A (zh) 一种银离子抗菌面料及其生产方法
CN105088829A (zh) 一种织物印染用高效抗静电剂及其制备方法
CN112981964B (zh) 一种抗皱面料加工工艺及抗皱面料
CN108484918B (zh) 一种新型硅聚合物体系及其制备方法
CN108951169B (zh) 一种天然醇醚改性有机硅亲水柔软剂的制备方法
JP2014101598A (ja) 布帛
CN109610167B (zh) 一种柔软爽滑的梭织面料及其在高端女装中的应用

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant