CN1089742C - 制备1,6－己二醇和己内酯的方法 - Google Patents

制备1,6－己二醇和己内酯的方法 Download PDF

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Publication number
CN1089742C
CN1089742C CN97192521A CN97192521A CN1089742C CN 1089742 C CN1089742 C CN 1089742C CN 97192521 A CN97192521 A CN 97192521A CN 97192521 A CN97192521 A CN 97192521A CN 1089742 C CN1089742 C CN 1089742C
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CN
China
Prior art keywords
ester
esterification
cut
cyclohexanediol
caprolactone
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
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CN97192521A
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English (en)
Chinese (zh)
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CN1211969A (zh
Inventor
K·G·保尔
R·费舍尔
R·宾克斯
F·斯坦恩
B·布里特施德尔
H·鲁斯特
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BASF SE
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BASF SE
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Publication date
Priority claimed from DE1996107954 external-priority patent/DE19607954A1/de
Priority claimed from DE1996147349 external-priority patent/DE19647349A1/de
Application filed by BASF SE filed Critical BASF SE
Publication of CN1211969A publication Critical patent/CN1211969A/zh
Application granted granted Critical
Publication of CN1089742C publication Critical patent/CN1089742C/zh
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D315/00—Heterocyclic compounds containing rings having one oxygen atom as the only ring hetero atom according to more than one of groups C07D303/00 - C07D313/00
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
    • C07C29/147—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof
    • C07C29/149—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof with hydrogen or hydrogen-containing gases
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/74—Separation; Purification; Use of additives, e.g. for stabilisation
    • C07C29/76—Separation; Purification; Use of additives, e.g. for stabilisation by physical treatment
    • C07C29/80—Separation; Purification; Use of additives, e.g. for stabilisation by physical treatment by distillation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/74—Separation; Purification; Use of additives, e.g. for stabilisation
    • C07C29/88—Separation; Purification; Use of additives, e.g. for stabilisation by treatment giving rise to a chemical modification of at least one compound
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C31/00—Saturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
    • C07C31/18—Polyhydroxylic acyclic alcohols
    • C07C31/20—Dihydroxylic alcohols
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/31—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation of cyclic compounds with ring-splitting
    • C07C51/313—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation of cyclic compounds with ring-splitting with molecular oxygen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D313/00—Heterocyclic compounds containing rings of more than six members having one oxygen atom as the only ring hetero atom
    • C07D313/02—Seven-membered rings
    • C07D313/04—Seven-membered rings not condensed with other rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/14—The ring being saturated

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Polyesters Or Polycarbonates (AREA)
  • Pyrane Compounds (AREA)
CN97192521A 1996-03-01 1997-02-28 制备1,6－己二醇和己内酯的方法 Expired - Lifetime CN1089742C (zh)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
DE1996107954 DE19607954A1 (de) 1996-03-01 1996-03-01 Verfahren zur Herstellung von 1,6-Hexandiol und Caprolacton
DE19607954.3 1996-03-01
DE19647349.7 1996-11-15
DE1996147349 DE19647349A1 (de) 1996-11-15 1996-11-15 Verfahren zur Herstellung von 1,6-Hexandiol und Caprolacton

Publications (2)

Publication Number Publication Date
CN1211969A CN1211969A (zh) 1999-03-24
CN1089742C true CN1089742C (zh) 2002-08-28

Family

ID=26023397

Family Applications (1)

Application Number Title Priority Date Filing Date
CN97192521A Expired - Lifetime CN1089742C (zh) 1996-03-01 1997-02-28 制备1,6－己二醇和己内酯的方法

Country Status (13)

Country Link
US (1) US5981769A (enExample)
EP (1) EP0883591B1 (enExample)
JP (1) JP4107396B2 (enExample)
KR (1) KR100468182B1 (enExample)
CN (1) CN1089742C (enExample)
AT (1) ATE192730T1 (enExample)
CA (1) CA2248004C (enExample)
DE (1) DE59701646D1 (enExample)
ES (1) ES2147435T3 (enExample)
GR (1) GR3033955T3 (enExample)
MY (1) MY118128A (enExample)
PT (1) PT883591E (enExample)
WO (1) WO1997031883A1 (enExample)

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DE19757554A1 (de) 1997-12-23 1999-06-24 Basf Ag Verfahren zur Herstellung von 1,6-Hexandiol
DE19826614A1 (de) * 1998-05-29 1999-12-02 Basf Ag Verfahren zur Herstellung von Hexandiol-1,6
US6344586B1 (en) * 1998-07-30 2002-02-05 Sumitomo Chemical Company, Limited Process for producing adipic acid
AU2001253557A1 (en) * 2000-08-24 2002-03-04 Union Carbide Chemicals And Plastics Technology Corporation Processes for the manufacture of lactones
DE10100552A1 (de) * 2001-01-09 2002-07-11 Basf Ag Verfahren und Vorrichtung zur destillativen Aufarbeitung von 1,6-Hexandiol, 1,5-Pentandiol ung Caprolacton
DE10128249A1 (de) * 2001-06-11 2002-12-12 Basf Ag Verfahren zur Entfernung von Ameisensäure aus wässrigen Lösungen
DE10242882A1 (de) * 2002-09-16 2004-03-25 Basf Ag Verfahren zur Herstellung von 1,6-Hexandiol
CA2503967A1 (en) * 2002-11-01 2004-05-21 Cargill, Incorporated Process for preparation of 1,3-propanediol
US7794960B2 (en) * 2004-06-04 2010-09-14 Glaxosmithkline Llc Predictive biomarkers in cancer therapy
DE102004033557A1 (de) 2004-07-09 2006-02-16 Basf Ag Verfahren zur Herstellung von 1,6-Hexandiol in einer Reinheit von über 99,5%
DE102004054047A1 (de) 2004-11-05 2006-05-11 Basf Ag Verfahren zur Herstellung von 1,6-Hexandiol
DE602005019546D1 (de) * 2005-06-03 2010-04-08 Univ Twente Verzweigte Polymere, ein makromonomer, Verfahren zu deren Herstellungen und deren Verwendungen
KR101354953B1 (ko) * 2006-01-13 2014-01-22 우베 고산 가부시키가이샤 1,6-헥산디올의 제조 방법
KR20100020036A (ko) * 2007-06-14 2010-02-19 바스프 에스이 ε-카프로락톤의 제법
CN101848904B (zh) * 2007-11-05 2013-05-01 巴斯夫欧洲公司 生产ε-己内酯的方法
KR20100110830A (ko) * 2007-12-21 2010-10-13 바스프 에스이 ε-카프로락톤의 제조 방법
ES2393838T5 (es) 2008-02-15 2016-03-02 Basf Se Procedimiento para la obtención de ésteres de ácido 6-hidroxicaprónico
KR100922998B1 (ko) * 2008-03-06 2009-10-22 한국화학연구원 모노카르복실산 또는 그의 유도체로부터 일가 알콜의 제조방법
US8828903B2 (en) * 2008-11-10 2014-09-09 Basf Corporation Copper catalyst for dehydrogenation application
EP2373601B1 (de) * 2008-12-05 2012-11-21 Basf Se Verfahren zur herstellung von 1,6-hexandiol
CN102256927A (zh) * 2008-12-18 2011-11-23 因温斯特技术公司 环己烷氧化工艺副产物衍生物及其使用方法
BRPI1006870A2 (pt) 2009-01-12 2016-03-15 Basf Se processo para recuperar componentes de uma mistura de baixo ponto de ebulição
EP2417089B1 (de) * 2009-04-07 2013-06-05 Basf Se Verfahren zur herstellung von 1,6-hexandiol und caprolacton
EP2417088B1 (de) * 2009-04-07 2013-05-29 Basf Se Verfahren zur herstellung von 1,6-hexandiol
TWI490034B (zh) 2009-11-17 2015-07-01 Basf Se 製備具有增強氫化活性之經承載氫化觸媒之方法
CA2800733A1 (en) 2010-06-16 2011-12-22 Bioamber S.A.S. Processes for the production of hydrogenated products and derivatives thereof
KR20130044302A (ko) * 2010-06-16 2013-05-02 바이오엠버, 에스.아.에스. 수소화 생성물 및 이의 유도체를 제조하는 방법
EP2404889A1 (de) * 2010-07-06 2012-01-11 LANXESS Deutschland GmbH Verfahren zur Herstellung von Alpha, Omega-Diolen
CN103080098B (zh) * 2010-09-08 2014-11-05 巴斯夫欧洲公司 制备ε-己内酯和1,6-己二醇的方法
US20120059174A1 (en) * 2010-09-08 2012-03-08 Basf Se Process for preparing epsilon-caprolactone and 1,6-hexanediol
US8865940B2 (en) 2011-12-30 2014-10-21 E I Du Pont De Nemours And Company Process for preparing 1,6-hexanediol
US8889912B2 (en) 2011-12-30 2014-11-18 E I Du Pont De Nemours And Company Process for preparing 1,6-hexanediol
EP2797868A4 (en) 2011-12-30 2015-08-12 Du Pont PROCESS FOR PRODUCING HEXANEDIOLS
CN104011002A (zh) 2011-12-30 2014-08-27 纳幕尔杜邦公司 制备1，6-己二醇的方法
WO2013101970A1 (en) 2011-12-30 2013-07-04 E. I. Du Pont De Nemours And Company Production of 5-hydroxymethyl-2-furfural from levoglucosenone
JP2015508401A (ja) 2011-12-30 2015-03-19 イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニーＥ．Ｉ．Ｄｕ Ｐｏｎｔ Ｄｅ Ｎｅｍｏｕｒｓ Ａｎｄ Ｃｏｍｐａｎｙ イソソルビドからのテトラヒドロフラン−２，５−ジメタノールの生成
CN102603446B (zh) * 2012-02-13 2014-08-06 湖南大学 一种以碳材料催化氧化有机酮制备有机内酯的方法
CN102603447B (zh) * 2012-02-13 2014-09-03 湖南大学 一种制备有机内酯的方法
US9018423B2 (en) 2012-04-27 2015-04-28 E I Du Pont De Nemours And Company Production of alpha, omega-diols
US8846985B2 (en) 2012-04-27 2014-09-30 E I Du Pont De Nemours And Company Production of alpha, omega-diols
US8859826B2 (en) 2012-04-27 2014-10-14 E I Du Pont De Nemours And Company Production of alpha, omega-diols
US11208394B2 (en) 2018-09-17 2021-12-28 Regents Of The University Of Minnesota Chemical process to manufacture branched-caprolactone
GB202109710D0 (en) 2021-07-05 2021-08-18 Johnson Matthey Davy Technologies Ltd Separation process for the production of C5 or C6 alkanediol

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2819593A1 (de) * 1978-05-05 1979-11-08 Basf Ag Verfahren zur herstellung von diolen
EP0661255A1 (en) * 1993-12-28 1995-07-05 Ube Industries, Ltd. Process for producing diol compounds

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DE1618143C3 (de) * 1967-04-27 1975-08-21 Basf Ag, 6700 Ludwigshafen Verfahren zur Gewinnung von epsilon-Hydroxycapronsäurelacton und von Alkandicarbonsäuren
DE2060548C3 (de) * 1970-12-09 1979-10-11 Basf Ag, 6700 Ludwigshafen Verfahren zur Herstellung von sehr reinem 1,6-Hexandiol durch Kristallisation
DE2321101C2 (de) * 1973-04-26 1982-07-22 Basf Ag, 6700 Ludwigshafen Verfahren zur Herstellung im wesentlichen trägerfreier Kobaltkatalysatoren
US3933930A (en) * 1975-03-06 1976-01-20 Celanese Corporation Hexanediol from cyclohexane
DE3823213A1 (de) * 1988-07-08 1990-01-11 Basf Ag Verfahren zur herstellung von caprolacton
DE69417720T2 (de) * 1993-10-08 1999-07-29 Ube Industries, Ltd., Ube, Yamaguchi Verfahren zur herstellung von diolen

Patent Citations (2)

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Publication number Priority date Publication date Assignee Title
DE2819593A1 (de) * 1978-05-05 1979-11-08 Basf Ag Verfahren zur herstellung von diolen
EP0661255A1 (en) * 1993-12-28 1995-07-05 Ube Industries, Ltd. Process for producing diol compounds

Also Published As

Publication number Publication date
KR100468182B1 (ko) 2005-03-16
MY118128A (en) 2004-09-30
ATE192730T1 (de) 2000-05-15
WO1997031883A1 (de) 1997-09-04
EP0883591B1 (de) 2000-05-10
JP4107396B2 (ja) 2008-06-25
KR19990087422A (ko) 1999-12-27
JP2000506134A (ja) 2000-05-23
CA2248004C (en) 2006-04-11
CA2248004A1 (en) 1997-09-04
DE59701646D1 (de) 2000-06-15
GR3033955T3 (en) 2000-11-30
US5981769A (en) 1999-11-09
EP0883591A1 (de) 1998-12-16
PT883591E (pt) 2000-10-31
CN1211969A (zh) 1999-03-24
ES2147435T3 (es) 2000-09-01

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Granted publication date: 20020828