CN108893139A - 一种使用含钕两亲性催化剂燃油脱硫的方法 - Google Patents
一种使用含钕两亲性催化剂燃油脱硫的方法 Download PDFInfo
- Publication number
- CN108893139A CN108893139A CN201810864543.6A CN201810864543A CN108893139A CN 108893139 A CN108893139 A CN 108893139A CN 201810864543 A CN201810864543 A CN 201810864543A CN 108893139 A CN108893139 A CN 108893139A
- Authority
- CN
- China
- Prior art keywords
- parts
- desulfuration
- containing neodymium
- catalyst
- fuel
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000003054 catalyst Substances 0.000 title claims abstract description 66
- 238000006477 desulfuration reaction Methods 0.000 title claims abstract description 64
- 229910052779 Neodymium Inorganic materials 0.000 title claims abstract description 56
- QEFYFXOXNSNQGX-UHFFFAOYSA-N neodymium atom Chemical compound [Nd] QEFYFXOXNSNQGX-UHFFFAOYSA-N 0.000 title claims abstract description 56
- 239000000446 fuel Substances 0.000 title claims abstract description 40
- 238000000034 method Methods 0.000 title claims abstract description 37
- 238000006243 chemical reaction Methods 0.000 claims abstract description 47
- 239000003463 adsorbent Substances 0.000 claims abstract description 35
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims abstract description 24
- 239000000295 fuel oil Substances 0.000 claims abstract description 23
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 27
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 21
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 21
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 17
- QNXSIUBBGPHDDE-UHFFFAOYSA-N indan-1-one Chemical compound C1=CC=C2C(=O)CCC2=C1 QNXSIUBBGPHDDE-UHFFFAOYSA-N 0.000 claims description 16
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 16
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 14
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 claims description 14
- 238000002156 mixing Methods 0.000 claims description 12
- 235000012239 silicon dioxide Nutrition 0.000 claims description 12
- 238000003756 stirring Methods 0.000 claims description 12
- -1 1- (4- fluoro-phenyl) -5- oxo-pyrrolidine tricarboxylic acids Chemical class 0.000 claims description 8
- ZENKESXKWBIZCV-UHFFFAOYSA-N 2,2,4,4-tetrafluoro-1,3-benzodioxin-6-amine Chemical group O1C(F)(F)OC(F)(F)C2=CC(N)=CC=C21 ZENKESXKWBIZCV-UHFFFAOYSA-N 0.000 claims description 8
- 239000004327 boric acid Substances 0.000 claims description 8
- 238000001035 drying Methods 0.000 claims description 8
- 238000005516 engineering process Methods 0.000 claims description 8
- 150000002148 esters Chemical class 0.000 claims description 8
- 239000000463 material Substances 0.000 claims description 8
- 239000000377 silicon dioxide Substances 0.000 claims description 8
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 7
- 239000004202 carbamide Substances 0.000 claims description 7
- ORTQZVOHEJQUHG-UHFFFAOYSA-L copper(II) chloride Chemical compound Cl[Cu]Cl ORTQZVOHEJQUHG-UHFFFAOYSA-L 0.000 claims description 7
- 238000001125 extrusion Methods 0.000 claims description 7
- 238000005469 granulation Methods 0.000 claims description 7
- 230000003179 granulation Effects 0.000 claims description 7
- 238000004898 kneading Methods 0.000 claims description 7
- 239000007791 liquid phase Substances 0.000 claims description 7
- 239000002105 nanoparticle Substances 0.000 claims description 7
- KBJMLQFLOWQJNF-UHFFFAOYSA-N nickel(ii) nitrate Chemical compound [Ni+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O KBJMLQFLOWQJNF-UHFFFAOYSA-N 0.000 claims description 7
- DHRLEVQXOMLTIM-UHFFFAOYSA-N phosphoric acid;trioxomolybdenum Chemical compound O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.OP(O)(O)=O DHRLEVQXOMLTIM-UHFFFAOYSA-N 0.000 claims description 7
- 235000019832 sodium triphosphate Nutrition 0.000 claims description 7
- 239000007787 solid Substances 0.000 claims description 7
- 238000013517 stratification Methods 0.000 claims description 7
- 238000005406 washing Methods 0.000 claims description 7
- 235000005074 zinc chloride Nutrition 0.000 claims description 7
- 239000011592 zinc chloride Substances 0.000 claims description 7
- FMBHCBGNBUNBCM-UHFFFAOYSA-N CCCCCCCCCCCCCCCC[P+](CCCC)(CCCC)CCCC.N Chemical compound CCCCCCCCCCCCCCCC[P+](CCCC)(CCCC)CCCC.N FMBHCBGNBUNBCM-UHFFFAOYSA-N 0.000 claims description 6
- ACOLQZDYRBEHEV-UHFFFAOYSA-K decanoate;neodymium(3+) Chemical class [Nd+3].CCCCCCCCCC([O-])=O.CCCCCCCCCC([O-])=O.CCCCCCCCCC([O-])=O ACOLQZDYRBEHEV-UHFFFAOYSA-K 0.000 claims description 5
- 239000003502 gasoline Substances 0.000 claims description 4
- 239000003795 chemical substances by application Substances 0.000 claims description 3
- 239000010779 crude oil Substances 0.000 claims description 3
- 239000002283 diesel fuel Substances 0.000 claims description 3
- 239000003350 kerosene Substances 0.000 claims description 3
- 239000008213 purified water Substances 0.000 claims description 3
- 238000006555 catalytic reaction Methods 0.000 claims description 2
- 239000003610 charcoal Substances 0.000 claims description 2
- 230000000694 effects Effects 0.000 claims description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract description 17
- 230000023556 desulfurization Effects 0.000 abstract description 8
- 239000003921 oil Substances 0.000 abstract description 3
- 229910052717 sulfur Inorganic materials 0.000 abstract description 3
- 239000011593 sulfur Substances 0.000 abstract description 3
- 230000001681 protective effect Effects 0.000 abstract description 2
- 239000002608 ionic liquid Substances 0.000 abstract 1
- 239000005864 Sulphur Substances 0.000 description 14
- 238000011084 recovery Methods 0.000 description 11
- 230000000052 comparative effect Effects 0.000 description 7
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 5
- 229910052799 carbon Inorganic materials 0.000 description 5
- 229960004756 ethanol Drugs 0.000 description 5
- 235000019441 ethanol Nutrition 0.000 description 5
- FCEHBMOGCRZNNI-UHFFFAOYSA-N 1-benzothiophene Chemical compound C1=CC=C2SC=CC2=C1 FCEHBMOGCRZNNI-UHFFFAOYSA-N 0.000 description 4
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 239000003708 ampul Substances 0.000 description 4
- 239000007789 gas Substances 0.000 description 4
- 239000010453 quartz Substances 0.000 description 4
- 238000004064 recycling Methods 0.000 description 4
- 239000003643 water by type Substances 0.000 description 4
- 229910018557 Si O Inorganic materials 0.000 description 3
- 238000004090 dissolution Methods 0.000 description 3
- 239000012071 phase Substances 0.000 description 3
- 230000001699 photocatalysis Effects 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- LIVNPJMFVYWSIS-UHFFFAOYSA-N silicon monoxide Inorganic materials [Si-]#[O+] LIVNPJMFVYWSIS-UHFFFAOYSA-N 0.000 description 3
- YPIFGDQKSSMYHQ-UHFFFAOYSA-N 7,7-dimethyloctanoic acid Chemical compound CC(C)(C)CCCCCC(O)=O YPIFGDQKSSMYHQ-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 2
- YTPLMLYBLZKORZ-UHFFFAOYSA-N Thiophene Chemical compound C=1C=CSC=1 YTPLMLYBLZKORZ-UHFFFAOYSA-N 0.000 description 2
- UGACIEPFGXRWCH-UHFFFAOYSA-N [Si].[Ti] Chemical compound [Si].[Ti] UGACIEPFGXRWCH-UHFFFAOYSA-N 0.000 description 2
- WYTGDNHDOZPMIW-RCBQFDQVSA-N alstonine Natural products C1=CC2=C3C=CC=CC3=NC2=C2N1C[C@H]1[C@H](C)OC=C(C(=O)OC)[C@H]1C2 WYTGDNHDOZPMIW-RCBQFDQVSA-N 0.000 description 2
- 125000002843 carboxylic acid group Chemical group 0.000 description 2
- 229960000935 dehydrated alcohol Drugs 0.000 description 2
- 238000005265 energy consumption Methods 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 230000001590 oxidative effect Effects 0.000 description 2
- 239000012686 silicon precursor Substances 0.000 description 2
- OKBQUWUVZGPEQZ-UHFFFAOYSA-N tributyl(hexadecyl)phosphanium Chemical compound CCCCCCCCCCCCCCCC[P+](CCCC)(CCCC)CCCC OKBQUWUVZGPEQZ-UHFFFAOYSA-N 0.000 description 2
- LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical compound SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 238000003915 air pollution Methods 0.000 description 1
- 230000001476 alcoholic effect Effects 0.000 description 1
- 238000001354 calcination Methods 0.000 description 1
- 229910052681 coesite Inorganic materials 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 229910052906 cristobalite Inorganic materials 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- IYYZUPMFVPLQIF-UHFFFAOYSA-N dibenzothiophene Chemical class C1=CC=C2C3=CC=CC=C3SC2=C1 IYYZUPMFVPLQIF-UHFFFAOYSA-N 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 125000001207 fluorophenyl group Chemical group 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 238000005286 illumination Methods 0.000 description 1
- 125000000686 lactone group Chemical group 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 150000002898 organic sulfur compounds Chemical class 0.000 description 1
- 125000001741 organic sulfur group Chemical group 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000005504 petroleum refining Methods 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 238000007146 photocatalysis Methods 0.000 description 1
- 231100000572 poisoning Toxicity 0.000 description 1
- 230000000607 poisoning effect Effects 0.000 description 1
- 238000005070 sampling Methods 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 229910052682 stishovite Inorganic materials 0.000 description 1
- 150000003568 thioethers Chemical class 0.000 description 1
- 229930192474 thiophene Natural products 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titanium dioxide Inorganic materials O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- 229910052905 tridymite Inorganic materials 0.000 description 1
- 239000000052 vinegar Substances 0.000 description 1
- 235000021419 vinegar Nutrition 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G27/00—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation
- C10G27/04—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation with oxygen or compounds generating oxygen
- C10G27/12—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation with oxygen or compounds generating oxygen with oxygen-generating compounds, e.g. per-compounds, chromic acid, chromates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/0203—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of metals not provided for in B01J20/04
- B01J20/0225—Compounds of Fe, Ru, Os, Co, Rh, Ir, Ni, Pd, Pt
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/0203—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of metals not provided for in B01J20/04
- B01J20/0233—Compounds of Cu, Ag, Au
- B01J20/0237—Compounds of Cu
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/0203—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of metals not provided for in B01J20/04
- B01J20/024—Compounds of Zn, Cd, Hg
- B01J20/0244—Compounds of Zn
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/0203—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of metals not provided for in B01J20/04
- B01J20/0274—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of metals not provided for in B01J20/04 characterised by the type of anion
- B01J20/0288—Halides of compounds other than those provided for in B01J20/046
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/0203—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of metals not provided for in B01J20/04
- B01J20/0274—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of metals not provided for in B01J20/04 characterised by the type of anion
- B01J20/0296—Nitrates of compounds other than those provided for in B01J20/04
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/06—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04
- B01J20/08—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04 comprising aluminium oxide or hydroxide; comprising bauxite
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
- B01J20/14—Diatomaceous earth
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/20—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising free carbon; comprising carbon obtained by carbonising processes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/22—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2220/00—Aspects relating to sorbent materials
- B01J2220/40—Aspects relating to the composition of sorbent or filter aid materials
- B01J2220/48—Sorbents characterised by the starting material used for their preparation
- B01J2220/4806—Sorbents characterised by the starting material used for their preparation the starting material being of inorganic character
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2220/00—Aspects relating to sorbent materials
- B01J2220/40—Aspects relating to the composition of sorbent or filter aid materials
- B01J2220/48—Sorbents characterised by the starting material used for their preparation
- B01J2220/4812—Sorbents characterised by the starting material used for their preparation the starting material being of organic character
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/20—Characteristics of the feedstock or the products
- C10G2300/201—Impurities
- C10G2300/202—Heteroatoms content, i.e. S, N, O, P
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/70—Catalyst aspects
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Analytical Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- General Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Catalysts (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Abstract
本发明涉及环保领域，具体关于一种使用含钕两亲性催化剂燃油脱硫的方法；本发明方法公开的一种使用含钕两亲性催化剂燃油脱硫的方法，使用离子液体、脱硫吸附剂、含钕两亲性催化剂和双氧水对燃油进行脱硫，使用一种含钕含钕两亲性催化剂能够克服双氧水与油相不互溶的问题，提高反应速率；该方法反应速率快，硫脱除率高，催化剂有良好的再生性，本方法简单快捷，绿色环保，是一种高效燃油脱硫的方法。
Description
技术领域
本发明涉及环保领域，具体关于一种使用含钕两亲性催化剂燃油脱硫的方法。
背景技术
燃油中含有硫醇、硫醚、二硫化物、噻吩、苯并噻吩及二苯并噻吩等有机硫化物，硫化物的危害是多方面的，在石油炼制过程中会腐蚀设备，使催化剂中毒，在油品燃烧的过程中会造成空气污染，如何安全高效的脱除燃油中的硫，一直为人们所关注。
CN104001470A公开了一种Ti-Si-O双功能光催化吸附剂及其制备方法与其在燃油脱硫中的应用，其制备步骤为：将TiO2的前驱体和SiO2的前驱体混合，加入无水乙醇和冰醋酸，搅拌，得到钛硅前驱体溶液a；按将去离子水，无水乙醇和浓硝酸溶液混合均匀得到溶液b，逐滴将溶液b加入钛硅前驱体溶液a中，搅拌；将凝胶干燥，研磨；煅烧，制得Ti-Si-O双功能光催化吸附剂。其应用步骤为：将吸附剂和燃油混合；在光照下，通入空气反应，实现燃油中有机硫的脱除。该发明中的脱硫方法采用Ti-Si-O材料为吸附剂，空气为氧化剂，成本低，可回收和循环使用；该一步法光催化和吸附耦合脱硫技术，工艺简单，可在常温常压下操作，能耗低。
CN101041435A公开了一种用于燃油脱硫的改性脱硫吸附剂及其制备方法与装置。该方法是将装有已预处理的脱硫吸附剂U型管放入微波反应器中，往U型石英管内通入氮气，然后开启微波反应器，微波处理完毕后，再通入氮气，直至脱硫吸附剂冷却至室温。该装置中带有气体进口和出口的石英管置于微波反应器(4)中，石英管(5)气体进口端与气体流量控制器(3)连接，石英管(5)中放置吸附剂脱硫吸附剂(6)。制得的脱硫吸附剂表面主要含有酚羟基、羧酸基和内酯基；羧酸基浓度范围为0.0011mmol/g～0.0634mmol/g。该发明利用微波加热技术改性脱硫吸附剂，提高脱硫吸附剂对燃油中苯并噻吩的吸附容量，具有能耗低、时间短、效率高的特点。
CN201942646U公开了一种可磁分离回收磁载催化剂的燃油脱硫反应装置，包括水槽，反应容器，萃取分液阀，储罐，直流电动搅拌控制器和蛇形冷凝管，其中，反应容器上设有取样分析口和进料口，反应容器外套有恒温水浴管，水槽与恒温水浴管管路连接；储罐设在反应容器下方，通过萃取分液阀与反应容器管路连接；直流电动搅拌控制器位于反应容器上部，直流电动搅拌控制器的搅拌叶片位于反应容器中部，搅拌叶片为正、反双叶搅拌桨；蛇形冷凝管位于反应容器上方。该实用新型的装置具有双叶搅拌动力大、两相上下湍动撞击混合、高效无污染磁分离催化剂、循环利用等优点，在工业燃油非均相萃取-氧化耦合反应中应用前景广阔。
氧化脱硫技术是一种有效并且广为使用的一种方法，双氧水氧化法一直是人们常用的方法之一，但是由于水相与油相的不相溶的原因，导致反应速率无法提高。
发明内容
为了解决上述问题，本发明提供了一种使用含钕两亲性催化剂燃油脱硫的方法。
一种使用含钕两亲性催化剂燃油脱硫的方法，制备技术方案如下：
按照质量分数，将100-150份的燃油、5-10份的脱硫吸附剂、0.5-5份的含钕两亲性催化剂、10-50份的10%-30%双氧水入到反应釜中，控温50-90℃，剧烈搅拌下使物料混合均匀，反应60-150min；然后过滤出催化剂，液相静置分层，取上层，即可完成燃油脱硫操作。
所述的含钕两亲性催化剂按照以下方案制备：
按照质量份数，将20-30份的介孔二氧化硅纳米粒子、0.5-5份的三聚磷酸钠和350-400份的30%-50%乙醇溶液加入到反应釜中，搅拌均匀后超声分散30-60min，然后将13-18份的磷钼酸加入到反应釜搅拌溶解后，超声10-30min，静置10-20h；然后控温到50-70℃，加入12-20份的十六烷基三丁基溴化铵， 0.01-0.1份的6-氨基-2,3-二氢茚-1-酮、0.01-0.3份的1-(4-氟-苯基)-5-氧代吡咯烷三羧酸、0.02-0.6份新癸酸钕、0. 1-0.6份的2-(1H-苯并三偶氮L-1-基)-1,1,3,3-四甲基脲四氟硼酸酯、反应1-6h后降到常温，静置过夜，然后过滤，洗涤，在100-130℃下干燥5-15h，即可得到一种含钕含钕两亲性催化剂。
所述的燃油为汽油或柴油或煤油或原油。
所述的脱硫吸附剂按照以下方案制备：
按照质量份数，将50-70份的氯化锌、10-20份的硝酸镍、5-15份的氯化铜和200-300份的乙二醇加入到400-700份的纯化水中，加热到80-100℃，加入40-80份的尿素，搅拌反应12-18h；完成反应后，过滤，洗涤，干燥，将得到的固体与5-10份的氧化铝、20-35份的活性炭、6-18份的硅藻土、0.05-0.5份的盐酸和10-50份的水，混捏均匀，然后挤压造粒，在150-180℃下干燥即可得到所述的脱硫吸附剂。
本发明方法公开的一种使用含钕两亲性催化剂燃油脱硫的方法，使用脱硫吸附剂、含钕两亲性催化剂和双氧水对燃油进行脱硫，使用一种含钕含钕两亲性催化剂能够克服双氧水与油相不互溶的问题，提高反应速率；该方法反应速率快，硫脱除率高，催化剂有良好的再生性，本方法简单快捷，绿色环保，是一种高效燃油脱硫的方法。
具体实施方式
下面通过具体实施例对该发明作进一步说明：
实施例1
一种使用含钕两亲性催化剂燃油脱硫的方法，制备技术方案如下：
按照质量分数，将130份的燃油、8份的脱硫吸附剂、2.5份的含钕两亲性催化剂、30份的20%双氧水入到反应釜中，控温70℃，剧烈搅拌下使物料混合均匀，反应90min；然后过滤出催化剂，液相静置分层，取上层，即可完成燃油脱硫操作。
所述的含钕两亲性催化剂按照以下方案制备：
按照质量份数，将25份的介孔二氧化硅纳米粒子、2.5份的三聚磷酸钠和370份的40%乙醇溶液加入到反应釜中，搅拌均匀后超声分散40min，然后将15份的磷钼酸加入到反应釜搅拌溶解后，超声20min，静置15h；然后控温到60℃，加入17份的十六烷基三丁基溴化铵，0.03份的6-氨基-2,3-二氢茚-1-酮、0.1份的1-(4-氟-苯基)-5-氧代吡咯烷三羧酸、0.2份新癸酸钕、0.5份的2-(1H-苯并三偶氮L-1-基)-1,1,3,3-四甲基脲四氟硼酸酯、反应3h后降到常温，静置过夜，然后过滤，洗涤，在120℃下干燥10h，即可得到一种含钕含钕两亲性催化剂。
所述的燃油为汽油。
所述的脱硫吸附剂按照以下方案制备：
按照质量份数，将60份的氯化锌、15份的硝酸镍、10份的氯化铜和260份的乙二醇加入到600份的纯化水中，加热到90℃，加入60份的尿素，搅拌反应15h；完成反应后，过滤，洗涤，干燥，将得到的固体与8份的氧化铝、30份的活性炭、12份的硅藻土、0.25份的盐酸和30份的水，混捏均匀，然后挤压造粒，在160℃下干燥即可得到所述的脱硫吸附剂。
本实验燃油中硫的脱除率为96.3%，催化剂回收率为98.4%。
实施例2
一种使用含钕两亲性催化剂燃油脱硫的方法，制备技术方案如下：
按照质量分数，将100份的燃油、5份的脱硫吸附剂、0.5份的含钕两亲性催化剂、10份的10%双氧水入到反应釜中，控温50℃，剧烈搅拌下使物料混合均匀，反应60min；然后过滤出催化剂，液相静置分层，取上层，即可完成燃油脱硫操作。
所述的含钕两亲性催化剂按照以下方案制备：
按照质量份数，将20份的介孔二氧化硅纳米粒子、0.5份的三聚磷酸钠和350份的30%-50%乙醇溶液加入到反应釜中，搅拌均匀后超声分散30min，然后将13份的磷钼酸加入到反应釜搅拌溶解后，超声10min，静置10h；然后控温到50℃，加入12份的十六烷基三丁基溴化铵，0.01份的6-氨基-2,3-二氢茚-1-酮、0.01份的1-(4-氟-苯基)-5-氧代吡咯烷三羧酸、0.02份新癸酸钕、0. 1份的2-(1H-苯并三偶氮L-1-基)-1,1,3,3-四甲基脲四氟硼酸酯、反应1h后降到常温，静置过夜，然后过滤，洗涤，在100℃下干燥5h，即可得到一种含钕含钕两亲性催化剂。
所述的燃油为柴油。
所述的脱硫吸附剂按照以下方案制备：
按照质量份数，将50份的氯化锌、10份的硝酸镍、5份的氯化铜和200份的乙二醇加入到400份的纯化水中，加热到80℃，加入40份的尿素，搅拌反应12h；完成反应后，过滤，洗涤，干燥，将得到的固体与5份的氧化铝、20份的活性炭、6份的硅藻土、0.05份的盐酸和10份的水，混捏均匀，然后挤压造粒，在150℃下干燥即可得到所述的脱硫吸附剂。
本实验燃油中硫的脱除率为94.6%，催化剂回收率为98.1%。
实施例3
一种使用含钕两亲性催化剂燃油脱硫的方法，制备技术方案如下：
按照质量分数，将150份的燃油、10份的脱硫吸附剂、5份的含钕两亲性催化剂、50份的30%双氧水入到反应釜中，控温90℃，剧烈搅拌下使物料混合均匀，反应150min；然后过滤出催化剂，液相静置分层，取上层，即可完成燃油脱硫操作。
所述的含钕两亲性催化剂按照以下方案制备：
按照质量份数，将30份的介孔二氧化硅纳米粒子、5份的三聚磷酸钠和400份的50%乙醇溶液加入到反应釜中，搅拌均匀后超声分散60min，然后将18份的磷钼酸加入到反应釜搅拌溶解后，超声30min，静置20h；然后控温到70℃，加入20份的十六烷基三丁基溴化铵， 0.1份的6-氨基-2,3-二氢茚-1-酮、0.3份的1-(4-氟-苯基)-5-氧代吡咯烷三羧酸、0.6份新癸酸钕、0.6份的2-(1H-苯并三偶氮L-1-基)-1,1,3,3-四甲基脲四氟硼酸酯、反应6h后降到常温，静置过夜，然后过滤，洗涤，在130℃下干燥15h，即可得到一种含钕含钕两亲性催化剂。
所述的燃油为煤油。
所述的脱硫吸附剂按照以下方案制备：
按照质量份数，将70份的氯化锌、20份的硝酸镍、15份的氯化铜和300份的乙二醇加入到700份的纯化水中，加热到100℃，加入80份的尿素，搅拌反应18h；完成反应后，过滤，洗涤，干燥，将得到的固体与10份的氧化铝、35份的活性炭、18份的硅藻土、0.5份的盐酸和50份的水，混捏均匀，然后挤压造粒，在180℃下干燥即可得到所述的脱硫吸附剂。
本实验燃油中硫的脱除率为97.3%，催化剂回收率为99.2%。
实施例4
一种使用含钕两亲性催化剂燃油脱硫的方法，制备技术方案如下：
按照质量分数，将100份的燃油、5份的脱硫吸附剂、0.5份的含钕两亲性催化剂、10份的10%双氧水入到反应釜中，控温50℃，剧烈搅拌下使物料混合均匀，反应60min；然后过滤出催化剂，液相静置分层，取上层，即可完成燃油脱硫操作。
所述的含钕两亲性催化剂按照以下方案制备：
所述的含钕两亲性催化剂按照以下方案制备：
按照质量份数，将30份的介孔二氧化硅纳米粒子、5份的三聚磷酸钠和400份的50%乙醇溶液加入到反应釜中，搅拌均匀后超声分散60min，然后将18份的磷钼酸加入到反应釜搅拌溶解后，超声30min，静置20h；然后控温到70℃，加入20份的十六烷基三丁基溴化铵，0.05份的6-氨基-2,3-二氢茚-1-酮、0.01份的1-(4-氟-苯基)-5-氧代吡咯烷三羧酸、0.6份新癸酸钕、0. 1份的2-(1H-苯并三偶氮L-1-基)-1,1,3,3-四甲基脲四氟硼酸酯、反应6h后降到常温，静置过夜，然后过滤，洗涤，在130℃下干燥15h，即可得到一种含钕含钕两亲性催化剂。
所述的燃油为汽油。
所述的脱硫吸附剂按照以下方案制备：
按照质量份数，将60份的氯化锌、15份的硝酸镍、10份的氯化铜和260份的乙二醇加入到600份的纯化水中，加热到90℃，加入60份的尿素，搅拌反应15h；完成反应后，过滤，洗涤，干燥，将得到的固体与8份的氧化铝、30份的活性炭、12份的硅藻土、0.25份的盐酸和30份的水，混捏均匀，然后挤压造粒，在160℃下干燥即可得到所述的脱硫吸附剂。
本实验燃油中硫的脱除率为95.2%，催化剂回收率为98.7%。
实施例5
一种使用含钕两亲性催化剂燃油脱硫的方法，制备技术方案如下：
按照质量分数，将150份的燃油、10份的脱硫吸附剂、5份的含钕两亲性催化剂、50份的30%双氧水入到反应釜中，控温90℃，剧烈搅拌下使物料混合均匀，反应150min；然后过滤出催化剂，液相静置分层，取上层，即可完成燃油脱硫操作。
所述的含钕两亲性催化剂按照以下方案制备：
按照质量份数，将20份的介孔二氧化硅纳米粒子、0.5份的三聚磷酸钠和350份的30%-50%乙醇溶液加入到反应釜中，搅拌均匀后超声分散30min，然后将13份的磷钼酸加入到反应釜搅拌溶解后，超声10min，静置10h；然后控温到50℃，加入12份的十六烷基三丁基溴化铵，0.01份的6-氨基-2,3-二氢茚-1-酮、0.3份的1-(4-氟-苯基)-5-氧代吡咯烷三羧酸、0.02份新癸酸钕、0.6份的2-(1H-苯并三偶氮L-1-基)-1,1,3,3-四甲基脲四氟硼酸酯、反应1h后降到常温，静置过夜，然后过滤，洗涤，在100℃下干燥5h，即可得到一种含钕含钕两亲性催化剂。
所述的燃油为原油。
所述的脱硫吸附剂按照以下方案制备：
按照质量份数，将70份的氯化锌、20份的硝酸镍、15份的氯化铜和300份的乙二醇加入到700份的纯化水中，加热到100℃，加入80份的尿素，搅拌反应18h；完成反应后，过滤，洗涤，干燥，将得到的固体与10份的氧化铝、35份的活性炭、18份的硅藻土、0.5份的盐酸和50份的水，混捏均匀，然后挤压造粒，在180℃下干燥即可得到所述的脱硫吸附剂。
本实验燃油中硫的脱除率为96.7%，催化剂回收率为98.2%。
对比例1
不加脱硫吸附剂，其它同实施例1。
本实验燃油中硫的脱除率为84.3%，催化剂回收率为99.5%。
对比例2
不加含钕两亲性催化剂，其它同实施例1。
本实验燃油中硫的脱除率为56.1%，无催化剂回收。
对比例3
不加6-氨基-2,3-二氢茚-1-酮，其它同实施例1。
本实验燃油中硫的脱除率为93.1%，催化剂回收率为98.7%。
对比例4
不加十六烷基三丁基溴化铵，其它同实施例1。
本实验燃油中硫的脱除率为87.6%，催化剂回收率为98.1%。
对比例5
不加1-(4-氟-苯基)-5-氧代吡咯烷三羧酸，其它同实施例1。
本实验燃油中硫的脱除率为93.1%，催化剂回收率为98.7%。
对比例6
不加新癸酸钕，其它同实施例1。
本实验燃油中硫的脱除率为80.6%，催化剂回收率为98.1%。
对比例7
不加2-(1H-苯并三偶氮L-1-基)-1,1,3,3-四甲基脲四氟硼酸酯，其它同实施例1。
本实验燃油中硫的脱除率为89.6%，催化剂回收率为98.1%。
Claims (4)
1.一种使用含钕两亲性催化剂燃油脱硫的方法，制备技术方案如下：
按照质量分数，将100-150份的燃油、5-10份的脱硫吸附剂、0.5-5份的含钕两亲性催化剂、10-50份的10%-30%双氧水入到反应釜中，控温50-90℃，剧烈搅拌下使物料混合均匀，反应60-150min；然后过滤出催化剂，液相静置分层，取上层，即可完成燃油脱硫操作。
2.根据权利要求1所述的一种使用含钕两亲性催化剂燃油脱硫的方法，其特征在于：所述的含钕两亲性催化剂按照以下方案制备：
按照质量份数，将20-30份的介孔二氧化硅纳米粒子、0.5-5份的三聚磷酸钠和350-400份的30%-50%乙醇溶液加入到反应釜中，搅拌均匀后超声分散30-60min，然后将13-18份的磷钼酸加入到反应釜搅拌溶解后，超声10-30min，静置10-20h；然后控温到50-70℃，加入12-20份的十六烷基三丁基溴化铵，0.01-0.1份的6-氨基-2,3-二氢茚-1-酮、0.01-0.3份的1-(4-氟-苯基)-5-氧代吡咯烷三羧酸、0.02-0.6份新癸酸钕、0. 1-0.6份的2-(1H-苯并三偶氮L-1-基)-1,1,3,3-四甲基脲四氟硼酸酯、反应1-6h后降到常温，静置过夜，然后过滤，洗涤，在100-130℃下干燥5-15h，即可得到一种含钕含钕两亲性催化剂。
3.根据权利要求1所述的一种使用含钕两亲性催化剂燃油脱硫的方法，其特征在于：所述的燃油为汽油或柴油或煤油或原油。
4.根据权利要求1所述的一种使用含钕两亲性催化剂燃油脱硫的方法，其特征在于：所述的脱硫吸附剂按照以下方案制备：
按照质量份数，将50-70份的氯化锌、10-20份的硝酸镍、5-15份的氯化铜和200-300份的乙二醇加入到400-700份的纯化水中，加热到80-100℃，加入40-80份的尿素，搅拌反应12-18h；完成反应后，过滤，洗涤，干燥，将得到的固体与5-10份的氧化铝、20-35份的活性炭、6-18份的硅藻土、0.05-0.5份的盐酸和10-50份的水，混捏均匀，然后挤压造粒，在150-180℃下干燥即可得到所述的脱硫吸附剂。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810864543.6A CN108893139B (zh) | 2018-08-01 | 2018-08-01 | 一种使用含钕两亲性催化剂燃油脱硫的方法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810864543.6A CN108893139B (zh) | 2018-08-01 | 2018-08-01 | 一种使用含钕两亲性催化剂燃油脱硫的方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN108893139A true CN108893139A (zh) | 2018-11-27 |
| CN108893139B CN108893139B (zh) | 2020-12-04 |
Family
ID=64352810
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810864543.6A Active CN108893139B (zh) | 2018-08-01 | 2018-08-01 | 一种使用含钕两亲性催化剂燃油脱硫的方法 |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108893139B (zh) |
Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20060108263A1 (en) * | 2004-11-23 | 2006-05-25 | Chinese Petroleum Corporation | Oxidative desulfurization and denitrogenation of petroleum oils |
| CN101205478A (zh) * | 2006-12-22 | 2008-06-25 | 中国科学院大连化学物理研究所 | 一种用于溶剂油脱硫脱臭的吸附剂及其制备方法 |
| CN101255353A (zh) * | 2008-04-21 | 2008-09-03 | 大连理工大学 | 一种氧化吸附脱除柴油中硫化物的方法 |
| CN101255352A (zh) * | 2008-04-21 | 2008-09-03 | 大连理工大学 | 一种温和条件下氧化-吸附脱除汽油中硫化物的方法 |
| CN101375027A (zh) * | 2006-01-30 | 2009-02-25 | 罗地亚管理公司 | 使用包含稀土元素胶态分散体的润滑组合物催化烟炱燃烧的发动机的运行方法 |
| CN101450302A (zh) * | 2008-12-17 | 2009-06-10 | 中国科学院大连化学物理研究所 | 一种碳四烯烃脱硫吸附剂及制法和应用 |
| CN101538480A (zh) * | 2009-05-12 | 2009-09-23 | 大连理工大学 | 一种氧化脱除二甲基二硫醚的方法 |
| CN102935381A (zh) * | 2012-11-19 | 2013-02-20 | 北京化工大学 | 一种两亲型稀土多酸催化材料、制备方法及应用 |
| CN104817664A (zh) * | 2015-04-02 | 2015-08-05 | 浙江大学 | 两亲性嵌段共聚物及包含该共聚物的纳米粒子、其制备方法和应用 |
| CN107803192A (zh) * | 2017-07-18 | 2018-03-16 | 华南理工大学 | 一种燃料氧化脱硫双功能催化吸附剂清洁再生工艺 |
-
2018
- 2018-08-01 CN CN201810864543.6A patent/CN108893139B/zh active Active
Patent Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20060108263A1 (en) * | 2004-11-23 | 2006-05-25 | Chinese Petroleum Corporation | Oxidative desulfurization and denitrogenation of petroleum oils |
| CN101375027A (zh) * | 2006-01-30 | 2009-02-25 | 罗地亚管理公司 | 使用包含稀土元素胶态分散体的润滑组合物催化烟炱燃烧的发动机的运行方法 |
| CN101205478A (zh) * | 2006-12-22 | 2008-06-25 | 中国科学院大连化学物理研究所 | 一种用于溶剂油脱硫脱臭的吸附剂及其制备方法 |
| CN101255353A (zh) * | 2008-04-21 | 2008-09-03 | 大连理工大学 | 一种氧化吸附脱除柴油中硫化物的方法 |
| CN101255352A (zh) * | 2008-04-21 | 2008-09-03 | 大连理工大学 | 一种温和条件下氧化-吸附脱除汽油中硫化物的方法 |
| CN101450302A (zh) * | 2008-12-17 | 2009-06-10 | 中国科学院大连化学物理研究所 | 一种碳四烯烃脱硫吸附剂及制法和应用 |
| CN101538480A (zh) * | 2009-05-12 | 2009-09-23 | 大连理工大学 | 一种氧化脱除二甲基二硫醚的方法 |
| CN102935381A (zh) * | 2012-11-19 | 2013-02-20 | 北京化工大学 | 一种两亲型稀土多酸催化材料、制备方法及应用 |
| CN104817664A (zh) * | 2015-04-02 | 2015-08-05 | 浙江大学 | 两亲性嵌段共聚物及包含该共聚物的纳米粒子、其制备方法和应用 |
| CN107803192A (zh) * | 2017-07-18 | 2018-03-16 | 华南理工大学 | 一种燃料氧化脱硫双功能催化吸附剂清洁再生工艺 |
Also Published As
| Publication number | Publication date |
|---|---|
| CN108893139B (zh) | 2020-12-04 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103752268B (zh) | 吸附饮用水中重金属和砷、氟的滤芯制备方法和应用 | |
| CN101337707B (zh) | 一种离子交换法处理二甲胺废水的方法 | |
| CN106799246A (zh) | 一种磁性MoS2@Fe3O4复合可见光催化剂及其制备方法和应用 | |
| CN101338221B (zh) | 离子液体萃取-光催化氧化燃料油脱硫方法 | |
| CN104475165B (zh) | 一种氧化脱硫催化剂的制备方法 | |
| CN100569916C (zh) | 一种燃料油光催化氧化脱硫方法 | |
| CN105457681B (zh) | 一种ZnO/氧化石墨烯复合光催化材料的制备方法 | |
| CN104312621B (zh) | 一种基于磷钨酸离子液体的催化氧化油品脱硫方法 | |
| WO2012136063A1 (zh) | 脱除燃油中含硫化合物的可见光催化剂及其制备和应用 | |
| CN103831137A (zh) | 金属酞菁敏化二氧化钛光催化剂及其制备方法 | |
| CN105597775A (zh) | 一种石墨烯/Cu-Mn-Ce复合催化剂以及制备方法和应用 | |
| CN103386312B (zh) | 制备用于VOCs催化燃烧的球壳型催化剂的方法 | |
| CN104724786B (zh) | 一种含汞废水处理方法 | |
| Ghahramaninezhad et al. | A new simple protocol for the synthesis of nanohybrid catalyst for oxidative desulfurization of dibenzothiophene | |
| CN102218309A (zh) | 一种催化臭氧化稀土氧化铈复合氧化物催化剂的制备方法 | |
| CN104307469B (zh) | 一种用于精制柴油深度脱硫的脱硫吸附剂及其制备方法 | |
| CN104801347A (zh) | 羧基取代金属酞菁敏化Zn2SnO4粉末的催化脱硫剂及其制备方法 | |
| CN112044425B (zh) | 盐酸酸化高岭土负载钒氧化脱硫催化剂及其制备和应用 | |
| CN101696359A (zh) | 一种利用吸收法深度脱苯制备正己烷溶剂油的方法 | |
| CN108893139A (zh) | 一种使用含钕两亲性催化剂燃油脱硫的方法 | |
| CN205953515U (zh) | 一种乙炔清净废酸的再生系统 | |
| CN108970644A (zh) | 一种使用含胍基催化剂燃油脱硫的方法 | |
| CN105233857A (zh) | 一种催化分解甲硫醇气体的催化剂及其制备方法和应用 | |
| CN114130428B (zh) | 一种新型多酸基离子液体氧化脱硫催化剂的制备方法及其应用 | |
| CN105820832B (zh) | 电化学催化常温常压柴油脱硫方法 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| TA01 | Transfer of patent application right | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20201118 Address after: 314500 No. xd701-6, No. 1, Gongnong Road, Nanmen, Chongfu Town, Tongxiang City, Jiaxing City, Zhejiang Province Applicant after: JIAXING LONGLIE ELECTRONIC COMMERCE Co.,Ltd. Address before: 152500 Manjiang Hongcun, Tieli Town, Yichun City, Heilongjiang Province Applicant before: Li Chengxia |
|
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20240328 Address after: No. 31 Changshan Road, Nanchangshan Town, Changdao County, Yantai City, Shandong Province, 265600 Patentee after: Changdao Weiya Environmental Protection Technology Center Country or region after: China Address before: No. xd701-6, Nanmen Gongnong Road, Chongfu Town, Tongxiang City, Jiaxing City, Zhejiang Province Patentee before: JIAXING LONGLIE ELECTRONIC COMMERCE Co.,Ltd. Country or region before: China |