CN108659925B - 一种钽板专用合成加工液及其制备方法 - Google Patents

一种钽板专用合成加工液及其制备方法 Download PDF

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CN108659925B
CN108659925B CN201810365231.0A CN201810365231A CN108659925B CN 108659925 B CN108659925 B CN 108659925B CN 201810365231 A CN201810365231 A CN 201810365231A CN 108659925 B CN108659925 B CN 108659925B
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熊桑
吴梦陵
郝洪艳
柯旭贵
李玉平
赵伟
张振
司佳
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Nanjing Institute of Technology
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Abstract

本发明涉及一种钽板专用合成加工液及其制备方法；其中，该方法包括以下步骤：先将矿物油和机械油N32放入转速为50‑120转/分钟反应釜中进行加热搅拌，当温度达到60‑80℃，再依次将油溶性纳米Cu(10‑60nm)、硼酸酯、噻二唑衍生物THX726、硬脂酸丁酯、C10‑C12混合醇、十二烷基苯磺酸钠和椰子油基咪唑啉加入到反应釜中，保温并持续搅拌60‑100分钟，随后温度降为70℃作用时，加入失水山梨醇单油酸酯聚氧乙烯醚Tween 80、TX‑7、三乙醇胺、PX‑122有机硅消泡剂、辛基异噻唑啉酮和吡啶钠‑硫醇氧化物，将搅拌机转速调到30转/分钟并保持搅拌30‑60分钟，随后停止加热继续搅拌至室温，即得到棕黄色透明均匀的钽板加工液。

Description

一种钽板专用合成加工液及其制备方法
技术领域
本发明涉及润滑剂技术领域，用于钽板加工中的润滑，其具体的是一种具有环保超高润滑性能、可防止钽板加工过程中与模具黏着并可保证成品表面光洁度的钽板加工液及其制备方法。
背景技术
金属钽主要应用于电子工业，钽电容器体积小，容量大，可靠性高，寿命长，耐压性能好，功能稳定，在通讯、计算机集成电路、汽车电子控制系统、数码电器等方面得到了极为广泛的应用。工艺润滑对钽板金属加工过程具有重要的作用，使用不同的加工液，润滑状态不同，对钽板加工精度、板形控制都有一定影响，尤其影响加工后续工序如退火后表面清净性，因此，加工液的研究成为提高工艺润滑技术的关键。目前，生产的钽板在深冲引伸钽外壳时容易产生开裂、起皱、桔皮、制耳等现象，成品率低，难以达到高性能、高可靠性的要求。钽板加工使用常规的金属加工液，能降低金属与模具的磨损，稍稍改善钽板加工后表面形貌，但是使用一段时间后钽板易与模具黏着，因此急需开发专用的钽板加工液，为钽板的加工生产提供参考依据。
发明内容
本发明的目的是提供一种环保型、稳定性、防锈和润滑性优良的钽板加工液，可防止钽板加工过程中与模具黏着并可保证成品表面光洁度的钽板润滑技术及其制备方法。
本发明选择具有摩擦学性能优良及一定的表面修复功能的油溶性纳米Cu、硼酸酯和噻二唑衍生物THX726作为极压剂，选用硬脂酸丁酯和C10-C12混合醇作为油性剂，失水山梨醇单油酸酯聚氧乙烯醚Tween 80、TX-7和三乙醇胺作为乳化剂，十二烷基苯磺酸钠和椰子油基咪唑啉作为防锈剂，PX-122有机硅消泡剂作为消泡剂，辛基异噻唑啉酮和吡啶钠-硫醇氧化物作为杀菌剂，矿物油和机械油N32作为基础油，其中油溶性纳米Cu：硼酸酯：噻二唑衍生物THX726重量百分比为1:2:3～3:4:1，硬脂酸丁酯：C10-C12混合醇重量百分比为1:3～3:1，失水山梨醇单油酸酯聚氧乙烯醚Tween 80：TX-7：三乙醇胺重量百分比为1:3:1～3:1:3，十二烷基苯磺酸钠：椰子油基咪唑啉重量百分比为1:3～3:1，辛基异噻唑啉酮：吡啶钠-硫醇氧化物重量百分比为1:3～3:1，矿物油：机械油N32重量百分比为2:1～1:3，配制成具有良好的冷却、润滑、防锈性能的钽板加工液。
一种钽板专用合成加工液，其主要组分及所占重量百分比如下。
Figure BDA0001637004720000021
另一方面，本发明提供了一种钽板专用合成加工液及其制备方法，该钽板加工液的制作方法，其特征在于按如下步骤进行：先将计算量的矿物油和机械油N32放入转速为50-120转/分钟反应釜中进行加热搅拌，当温度达到60-80℃，再依次将计算量的油溶性纳米Cu(10-60nm)、硼酸酯、噻二唑衍生物THX726、硬脂酸丁酯、C10-C12混合醇、十二烷基苯磺酸钠和椰子油基咪唑啉加入到反应釜中，保温并持续搅拌60-100分钟，随后温度降为70℃作用时，加入计算量的失水山梨醇单油酸酯聚氧乙烯醚Tween 80、TX-7、三乙醇胺、PX-122有机硅消泡剂、辛基异噻唑啉酮和吡啶钠-硫醇氧化物，将搅拌机转速调到30转/分钟并保持搅拌30-60分钟，随后停止加热继续搅拌至室温，即得到棕黄色透明均匀的钽板加工液。
本发明制备的钽板加工液可以直接用于钽板加工的制造与生产过程。该钽板加工液使用简单，操作方便，在钽板加工的制造与生产过程中无毒无刺激性气味，提供了一种安全、环境友好的工作环境。
具体实施方式
以下结合实施例对本发明进一步描述：
一、配方及生产方法
1、实施例1
实施例1配方见下表：
序号 组分名称 重量百分比(100％)
1 油溶性纳米Cu(10-60nm) 2
2 硼酸酯 4
3 噻二唑衍生物THX726 2
4 硬脂酸丁酯 30
5 C10-C12混合醇 30
6 失水山梨醇单油酸酯聚氧乙烯醚Tween 80 20
7 TX-7 20
8 三乙醇胺 20
9 十二烷基苯磺酸钠 3
10 椰子油基咪唑啉 3
11 辛基异噻唑啉酮 3
12 吡啶钠-硫醇氧化物 3
13 PX-122有机硅消泡剂 3
14 矿物油 120
15 机械油N32 738
生产方法：按上表的各组分重量配方，先将120kg矿物油和738kg机械油N32放入转速为50-120转/分钟反应釜中进行加热搅拌，当温度达到60-80℃，再依次将2kg油溶性纳米Cu(10-60nm)、4kg硼酸酯、2kg噻二唑衍生物THX726、30kg硬脂酸丁酯、30kgC10-C12混合醇、3kg十二烷基苯磺酸钠和3kg椰子油基咪唑啉加入到反应釜中，保温并持续搅拌60-100分钟，随后温度降为70℃作用时，加入20kg失水山梨醇单油酸酯聚氧乙烯醚Tween 80、20kgTX-7、20kg三乙醇胺、3kgPX-122有机硅消泡剂和3kg辛基异噻唑啉酮和3kg吡啶钠-硫醇氧化物，将搅拌机转速调到30转/分钟并保持搅拌30-60分钟，随后停止加热继续搅拌至室温，即得到棕黄色透明均匀的钽板加工液。
2、实施例2
生产方法同实施例1，组分名称及其重量百分比见下表：
序号 组分名称 重量百分比(100％)
1 油溶性纳米Cu(10-60nm) 10
2 硼酸酯 20
3 噻二唑衍生物THX726 30
4 硬脂酸丁酯 60
5 C10-C12混合醇 80
6 失水山梨醇单油酸酯聚氧乙烯醚Tween 80 50
7 TX-7 40
8 三乙醇胺 80
9 十二烷基苯磺酸钠 20
10 椰子油基咪唑啉 15
11 辛基异噻唑啉酮 30
12 吡啶钠-硫醇氧化物 30
13 PX-122有机硅消泡剂 25
14 矿物油 150
15 机械油N32 360
生产方法：按上表的各组分重量配方，先将150kg矿物油和360kg机械油N32放入转速为50-120转/分钟反应釜中进行加热搅拌，当温度达到60-80℃，再依次将10kg油溶性纳米Cu(10-60nm)、20kg硼酸酯、30kg噻二唑衍生物THX726、60kg硬脂酸丁酯、80kgC10-C12混合醇、20kg十二烷基苯磺酸钠和15kg椰子油基咪唑啉加入到反应釜中，保温并持续搅拌60-100分钟，随后温度降为70℃作用时，加入50kg失水山梨醇单油酸酯聚氧乙烯醚Tween 80、40kgTX-7、80kg三乙醇胺、25kgPX-122有机硅消泡剂和30kg辛基异噻唑啉酮和30kg吡啶钠-硫醇氧化物，将搅拌机转速调到30转/分钟并保持搅拌30-60分钟，随后停止加热继续搅拌至室温，即得到棕黄色透明均匀的钽板加工液。
3、实施例3
实施例3配方见下表：
序号 组分名称 重量百分比(100％)
1 油溶性纳米Cu(10-60nm) 15
2 硼酸酯 30
3 噻二唑衍生物THX726 45
4 硬脂酸丁酯 100
5 C10-C12混合醇 80
6 失水山梨醇单油酸酯聚氧乙烯醚Tween 80 60
7 TX-7 60
8 三乙醇胺 100
9 十二烷基苯磺酸钠 30
10 椰子油基咪唑啉 20
11 辛基异噻唑啉酮 30
12 吡啶钠-硫醇氧化物 30
13 PX-122有机硅消泡剂 40
14 矿物油 180
15 机械油N32 170
生产方法：按上表的各组分重量配方，先将180kg矿物油和170kg机械油N32放入转速为50-120转/分钟反应釜中进行加热搅拌，当温度达到60-80℃，再依次将15kg油溶性纳米Cu(10-60nm)、30kg硼酸酯、45kg噻二唑衍生物THX726、100kg硬脂酸丁酯、80kgC10-C12混合醇、30kg十二烷基苯磺酸钠和20kg椰子油基咪唑啉加入到反应釜中，保温并持续搅拌60-100分钟，随后温度降为70℃作用时，加入60kg失水山梨醇单油酸酯聚氧乙烯醚Tween 80、60kgTX-7、100kg三乙醇胺、40kgPX-122有机硅消泡剂和50kg辛基异噻唑啉酮和吡啶钠-硫醇氧化物，将搅拌机转速调到30转/分钟并保持搅拌30-60分钟，随后停止加热继续搅拌至室温，即得到棕黄色透明均匀的钽板加工液。
二、制得的产品性能指标如下：
Figure BDA0001637004720000061
以上所述之实施例只为本发明的较佳施例，并非以此限制本发明的实施范围，故凡依本发明之组分重量百分比，方法及原理所作的等效变化，均应含盖于本发明的保护范围。

Claims (4)

1.一种钽板专用合成加工液，其特征在于选择具有摩擦学性能优良及一定的表面修复功能的10-60nm油溶性纳米Cu、硼酸酯和噻二唑衍生物THX726作为极压剂，选用硬脂酸丁酯和C10-C12混合醇作为油性剂，失水山梨醇单油酸酯聚氧乙烯醚Tween 80、TX-7和三乙醇胺作为乳化剂，十二烷基苯磺酸钠和椰子油基咪唑啉作为防锈剂，PX-122有机硅消泡剂作为消泡剂，辛基异噻唑啉酮和吡啶钠-硫醇氧化物作为杀菌剂，矿物油和机械油N32作为基础油，配制成具有良好的冷却、润滑、防锈性能的钽板加工液。
2.根据权利要求书1所述的一种钽板专用合成加工液，其特征在于具体主要组分的比例，油溶性纳米Cu：硼酸酯：噻二唑衍生物THX726重量比为1:2:3～3:4:1，硬脂酸丁酯：C10-C12混合醇重量比为1:3～3:1，失水山梨醇单油酸酯聚氧乙烯醚Tween 80：TX-7：三乙醇胺重量比为1:3:1～3:1:3，十二烷基苯磺酸钠：椰子油基咪唑啉重量比为1:3～3:1，辛基异噻唑啉酮：吡啶钠-硫醇氧化物重量比为1:3～3:1，矿物油：机械油N32重量比为2:1～1:3。
3.根据权利要求书1所述的一种钽板专用合成加工液，其特征在于具体主要组分及所占重量百分比如下：油溶性纳米Cu：0.2-2.5％，硼酸酯：0.4-5.0％，噻二唑衍生物THX726：0.2-5.5％，硬脂酸丁酯：3.0-12.0％，C10-C12混合醇：2.0-10.0％，失水山梨醇单油酸酯聚氧乙烯醚Tween 80：2.0-8.0％，TX-7：2.0-8.0％，三乙醇胺：2.0-12.0％，十二烷基苯磺酸钠：0.1-3.0％，椰子油基咪唑啉：0.1-2.0％，辛基异噻唑啉酮：0.1-3.0％，吡啶钠-硫醇氧化物：0.1-3.0％，PX-122有机硅消泡剂：0.1-4.0％，矿物油：10.0-20.0％，余量为机械油N32。
4.根据权利要求1所述的一种钽板专用合成加工液制作方法，其特征在于：先将计算量的矿物油和机械油N32放入转速为50-120转/分钟反应釜中进行加热搅拌，当温度达到60-80℃，再依次将计算量的10-60nm油溶性纳米Cu、硼酸酯、噻二唑衍生物THX726、硬脂酸丁酯、C10-C12混合醇、十二烷基苯磺酸钠和椰子油基咪唑啉加入到反应釜中，保温并持续搅拌60-100分钟，随后温度70℃时，依次加入计算量的失水山梨醇单油酸酯聚氧乙烯醚Tween80、TX-7、三乙醇胺、PX-122有机硅消泡剂、辛基异噻唑啉酮和吡啶钠-硫醇氧化物，将搅拌机转速调到30转/分钟并保持搅拌30-60分钟，随后停止加热继续搅拌至室温，即得到棕黄色透明均匀的钽板加工液。
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