CN106190472A - 一种用于车身冲压成型的可乳化型冲压油 - Google Patents

一种用于车身冲压成型的可乳化型冲压油 Download PDF

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CN106190472A
CN106190472A CN201610546205.9A CN201610546205A CN106190472A CN 106190472 A CN106190472 A CN 106190472A CN 201610546205 A CN201610546205 A CN 201610546205A CN 106190472 A CN106190472 A CN 106190472A
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oil
type punching
emulsifiable type
punching oil
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赵中原
孙立华
周宪民
王维
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SHENYANG PARKERIZING CO Ltd
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Abstract

本发明公开了一种用于车身冲压成型的可乳化型冲压油，按重量计百分比：防锈剂3‑15％；润滑剂10‑40％；表面活性剂6‑12％；铺展剂0.5‑2.0％，杀菌剂0.1‑5％，基础油50‑70％。现场使用时可按照油与水的比例为1比9稀释使用，稀释液是水，减少废油排放，经济环保；配方加入铺展剂，即使含油钢板表面也可以均匀涂覆，不会造成局部涂油不均导致冲压缺陷的现象发生；可以很大程度上降低现场油气，改善工作环境质量，降低现场消防隐患；润滑性好，可满足汽车制造过程外板，内板冲压成型加工；用水乳化后冷却性好，可延长模具使用寿命；防锈性好，室内储存防锈一个月以上；冲压成型件表面油膜小，易脱脂，不影响后续焊装，涂装工艺。

Description

一种用于车身冲压成型的可乳化型冲压油
技术领域
本发明属于金属加工的冲压成型领域，具体说是一种用于车身冲压成型的可乳化型冲压油，主要用于车身(冷轧板，镀锌板)或其他零部件的冲压成型加工。
技术背景
自2009年以来，我国汽车年产量已超过1379.1万辆，随后更是产量逐年递增，至2014年，汽车年产量达到2389.5万辆，比对09年产量将近增加一倍。这么大的产量，在车身的冲压成型过程中会消耗大量的冲压成型油，随着社会环保意识的增强，对废油，废物废水的三废处理要去也越来越严格，无疑在处理这些废油的同时也会消耗大量人力，物力等资源。
目前国内所有汽车厂使用的冲压成型油产品都是纯油产品，除了处理废油的高成本，高消耗外，现场的温度较高，石油产品挥发出来的油气味道很重，对现场操作人员的健康也带来了隐患；另外纯油产品属于危险品，给现场也带来了很大的消防隐患，这款可乳化型冲压油用过的废液可直接进行破乳处理，降低了汽车厂后期的处理成本，生产相同台数的车，费油处理量减小了十分之一，很大程度上避免了人力物力资源的浪费；由于现场使用时用水稀释，属于不可燃物，降低了现场的消防隐患。除以上优势外，该发明还具备以下特点：①铺展性好，在含油钢板表面也可以均匀涂覆，避免局部加工缺陷；②润滑性好，完全能够满足车身内板，外板及零部件的冲压成型；③脱脂性好，用一般的脱脂剂即可完全脱脂；④防锈性好，可满足室内储存防锈一个月以上。
目前市场上可乳化型冲压油都是应用在小的零部件上，且防锈性也不是很理想，在含油钢板表面铺展性也不是很理想，经常造成表面质量缺陷。本发明除可应用在小的零部件冲压成型外，还可以用在面积较大的车身的冲压成型加工，防锈性能优越，铺展性好，润滑性好，对此也是乳化型冲压产品在行业上的突破。
发明内容
本发明提供的技术方案如下：(定稿后权利要求复制过来)
本发明的优点：
现场使用时可按照油与水的比例为1比9稀释使用，稀释液是水，减少废油排放，经济环保；配方加入铺展剂，即使含油钢板表面也可以均匀涂覆，不会造成局部涂油不均导致冲压缺陷的现象发生；可以很大程度上降低现场油气，改善工作环境质量，降低现场消防隐患；润滑性好，可满足汽车制造过程外板，内板冲压成型加工；用水乳化后冷却性好，可延长模具使用寿命；防锈性好，室内储存防锈一个月以上；冲压成型件表面油膜小，易脱脂，不影响后续焊装，涂装工艺。
本发明是可乳化型冲压油产品在行业上的突破，避免了乳化液在含油钢板表面铺展不均，在冲压过程出现局部划伤，冲裂等质量缺陷等问题。同时该发明具有经济环保，降低现场火灾隐患，安全性高，润滑性好，防锈性好，且不影响冲压后续工艺等特点。同时由于用水乳化后使用，冷却性非常好，可延长模具的使用寿命。
具体实施方式
下面用具体实施例对本发明做进一步说明，但以下实施例并不限制本发明。实施例中个组分含量以重量的百分含量表示，合计100％
实施例1
向反应釜中打入58％的25#变压器油，开启搅拌升温至60℃，然后分别投入3％的羊毛脂季戊四醇酯，4％的十六碳二元酸铵盐，2％的硫化脂肪酸酯，20％硫化猪油，搅拌30min；降温至50℃投入3％的SP80，6％的tween80,1％的醚羧酸，1.0％的脂肪醇聚氧乙烯醚季戊四醇酯，搅拌30min；降温至40℃以下投入2％甲基噻唑啉酮，继续搅拌30min即可包装检验。其组合物特性如下：
项目 实测值
运动粘度(40℃)，mm2/s 23.0
密度(15℃)，g/cm3 0.891
闪点，℃ 184
实施例2
向反应釜中打入62.2％的环烷基基础油(粘度68.5)，开启搅拌升温至60℃，然后分别投入6％的羊毛脂季戊四醇酯，2％的环烷酸锌，15％硫化猪油，搅拌30min；降温至50℃投入3％的脂肪醇聚氧乙烯醚，5％的石油磺酸胺,3.5％的醚羧酸，0.8％的脂肪醇聚氧乙烯醚甘油酯，搅拌30min；降温至40℃以下投入2.5％吗啉衍生物，继续搅拌30min即可包装检验。
项目 实测值
运动粘度(40℃)，mm2/s 84.3
密度(15℃)，g/cm3 0.898
闪点，℃ 192
实施例3
向反应釜中打入60.0％的环烷基基础油(粘度112)，1％的25#的变压器油，开启搅拌升温至60℃，然后分别投入6％十二碳二元酸铵盐，2％的十六碳二元酸铵盐，10％硫化猪油，10％季戊四醇酯，搅拌30min；降温至50℃投入3％的脂肪胺改性聚氧乙烯醚，4％的SP80,2％的醚羧酸，1.0％的脂肪醇聚氧乙烯醚季戊四醇酯，搅拌30min；降温至40℃以下投入1.0％的甲基噻唑啉酮，继续搅拌30min即可包装检验。
项目 实测值
运动粘度(40℃)，mm2/s 112.7
密度(15℃)，g/cm3 0.901
闪点，℃ 204
实施例4
向反应釜中打入64.5％的环烷基基础油(粘度112)，开启搅拌升温至60℃，然后分别投入3％十二碳二元酸铵盐，4％的十六碳二元酸铵盐，3％中和处理的磷酸二丁脂，10％硫化猪油，2％的聚酯(4500分子量)，搅拌30min；降温至50℃投入3％的十六碳二元酸铵盐，5％的十四碳二元酸钠盐,2％醚羧酸，0.5％的脂肪醇聚氧乙烯醚甘油酯，搅拌30min；降温至40℃以下投入3％的乙二醇二羟甲醚，继续搅拌30min即可包装检验。
项目 实测值
运动粘度(40℃)，mm2/s 132.1
密度(15℃)，g/cm3 0.921
闪点，℃ 218
实施例5
向反应釜中打入64.3％的环烷基基础油(粘度145)，开启搅拌升温至60℃，然后分别投入4％十二碳二元酸铵盐，2％的十六碳二元酸铵盐，3％的聚醚(5000分子量)，10％合成脂，3％的中和处理的磷酸二丁脂，搅拌30min；降温至50℃投入3％的C14羧酸铵，4％的石油磺酸铵,3％辛醇，0.7％的脂肪醇聚氧乙烯醚甘油酯，搅拌30min；降温至40℃以下投入3％的乙二醇二羟甲醚，继续搅拌30min即可包装检验。
项目 实测值
运动粘度(40℃)，mm2/s 202.4
密度(15℃)，g/cm3 0.945
闪点，℃ 248

Claims (8)

1.一种用于车身冲压成型的可乳化型冲压油，其特征在于：可乳化型冲压油按重量百分比计：
A.防锈剂：3-15％
B.润滑剂：10-40％
C.表面活性剂：6-14％
D.铺展剂：0.5-2.0
E.杀菌剂：0.1-5％
F.基础油：50-70％。
2.根据权利要求1所述的可乳化型冲压油，其特征在于：组分A选自羊毛脂、羊毛酸季戊四醇酯、十二碳二元酸铵盐、十六碳二元酸铵盐、十四碳二元酸钠盐、环烷酸皂、油酸咪唑啉中的一种或几种。
3.根据权利要求1所述的可乳化型冲压油，其特征在于：组分B选自硫化烯烃、硫化猪油、硫化脂肪酸酯、中和处理的磷酸二丁脂、3000-5000分子量的聚酯、3000-5000分子量聚醚、油酸甘油酯、合成酯中的一种或几种。
4.根据权利要求1所述的可乳化型冲压油，其特征在于：组分C选自：聚氧乙烯醚、脂肪胺改性聚氧乙烯醚、司盘80、司盘60、吐温80、吐温60、石油磺酸铵、十二烷基苯磺酸钠、C8-C18羧酸铵、醚羧酸、C6-C14醇、脂肪醇聚氧乙烯醚、壬基酚聚氧乙烯醚、多元醇酯中的一种或几种。
5.根据权利要求1所述的可乳化型冲压油，其特征在于：组分D选自：脂肪醇聚氧乙烯醚季戊四醇酯、脂肪醇聚氧乙烯醚甘油酯中的一种或几种。
6.根据权利要求1所述的可乳化型冲压油，其特征在于：组分E选自：吡啶钠-硫醇氧化物六氢三嗪衍生物、三甲基三嗪三乙醇、甲基噁唑烷、六氢三嗪衍生物、甲基噻唑啉酮、乙二醇二羟甲醚、吗啉衍生物中的一种或几种。
7.根据权利要求1所述的可乳化型冲压油，其特征在于：组分F选自：25#变压器油、环烷基基础油、石蜡基基础油中的一种或几种。
8.根据权利要求7所述的可乳化型冲压油，其特征在于：环烷基基础油的粘度为60-180，石蜡基基础油的粘度为8-10。
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Application publication date: 20161207