CN116200221A - 一种无氯冲压油 - Google Patents

一种无氯冲压油 Download PDF

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CN116200221A
CN116200221A CN202211741899.3A CN202211741899A CN116200221A CN 116200221 A CN116200221 A CN 116200221A CN 202211741899 A CN202211741899 A CN 202211741899A CN 116200221 A CN116200221 A CN 116200221A
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chlorine
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杜超
李琦
黄旻晔
谷云
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Wuxi Gorunjie Chemical Co ltd
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Abstract

本发明公开一种环保型无氯冲压油,该无氯冲压油包括以下重量百分比的组分:基础油42~55%,油性剂20~30%,极压剂5~11%,铺展剂1~5%,防锈剂3~6%,增粘剂3~6%,抗氧剂0.1~0.6%,减活剂0.2~0.5%。与现有含氯化石蜡的冲压油相比,本发明的冲压油不含氯化石蜡,更为环保,该冲压油具很高的闪点和优异的极压抗磨性能,可应用于厚度最大达15mm黑色金属工件的冲压成形;该冲压油具有极佳的防锈性能,工件经冲压后,完全满足工序间的防锈要求。

Description

一种无氯冲压油
技术领域
本发明属于冲压成形加工介质领域,具体涉及一种环保型无氯冲压油。
背景技术
随着我国汽车、家电等制造业的快速发展,各类冲压件的需求正日益增长。冲压加工属于塑性加工,在外力作用下,使板材、带材、管材和型材等,产生塑性变形或分离,从而获得所需形状和尺寸的工件(冲压件)的成形加工方法。
在冲压加工过程中,加工介质性能的好坏直接关系到冲压工件质量的成败,也对模具寿命、生产效率及后道工序能否顺利进行产生重大影响。因此,很多用户对冲压油提出更高的适用性要求,其中润滑和防锈是最为关注的方面;同时,随着国家政策对环境和职业健康的日益重视,油品的环保性能也成为是用户关注的重点。
截至21世纪20年代初,市场上普遍使用的冲压油多为氯化石蜡体系,以氯化石蜡为主要成分的油品不仅价格相对便宜,还具有优良的极压抗磨性能,所以在冲压油配方中,氯化石蜡通常作为首选润滑添加剂。通常在配方中氯化石蜡的添加量在10%-70%,有些油品甚至添加到90%。用户在使用氯化石蜡体系的冲压油时,虽然性价比较高,但是防锈和环保问题是无法逾越的障碍。氯化石蜡体系的冲压油,由于使用中氯离子的析出,防锈周期非常短,工件最多放置3天就出现锈蚀情况,而在湿度较大的天气情况下甚至数小时内就会布满锈点。由于氯化石蜡对人的生殖系统及遗产基因有负面影响,欧洲已经将短链氯化石蜡列为禁用工业品。在某些行业中,例如核工业或手机制造业,对工业介质中卤素含量有严格控制,因此含氯成分被禁止使用。综上,出于防锈和环保方面的要求,市场上迫切需要一款无氯且润滑性能好的冲压油。
发明内容
基于上述现有技术,本发明的目的在于提供一种环保型的无氯冲压油。
为实现上述目的,本发明采用的技术方案如下:
一种无氯冲压油,其特点在于,所述无氯冲压油包括以下重量百分比的组分:
基础油42~55%,
油性剂20~30%,
极压剂5~11%,
铺展剂1~5%,
防锈剂3~6%,
增粘剂3~6%,
抗氧剂0.1~0.6%,
减活剂0.2~0.5%。
优选地,所述基础油为150BS基础油和/或500SN基础油。
优选地,所述油性剂为大豆油和/或棕榈油。
更优选地,所述油性剂由重量比为2:3的大豆油和棕榈油组成。
优选地,所述极压剂为磷酸三甲酚酯、磷酸酯铵盐、硫化脂肪酸酯、硫磷丁辛伯烷基锌盐、二烷基五硫化物中的至少一种。
优选地,所述极压剂为磷酸三甲酚酯、磷酸酯铵盐、硫化脂肪酸酯和二烷基五硫化物质量比为1~4:1~4:1~4:1~4的组合物。
更优选地,所述极压剂为磷酸三甲酚酯、磷酸酯铵盐、硫化脂肪酸酯和二烷基五硫化物质量比为1~3:1~3:1.5~3:1.5~4的组合物。
优选地,所述铺展剂为丙三醇、乙二醇、十四醇中的至少一种。
优选地,所述防锈剂为石油磺酸钡、二壬基萘磺酸钡,环烷酸锌、十二烯基丁二酸中的至少一种。
优选地,所述增粘剂为聚异丁烯。
优选地,所述抗氧剂为2,6二叔丁基对甲酚、2,2-硫代双(4-甲基-6-叔丁基苯酚)、辛/丁基二苯胺中的至少一种。
优选地,所述减活剂为苯并三氮唑。
本发明以精炼矿物基础油为主要原料,辅以多种添加剂,各添加剂之间协同搭配,因其选用适当比例的油性剂、铺展剂、极压剂、防锈剂和增粘剂以及这些添加剂互配得当,从而开发出不含氯化石蜡的环保型冲压油,该冲压油具很高的闪点、同时在不含氯化石蜡的情况下,仍具有优异的抗磨极压性能,完全适用于14mm厚度工件的冲压;另外,该冲压油还具有极佳的防锈性能;在工件冲压后,后期防锈周期能高达到3个月,远远优于目前市面在售冲压油(例如,福斯51H精密冲压油)。
附图说明书
图1为以本发明实施例1的环保型无氯冲压油进行冲压工件的一个侧面的示意图。
图2为以本发明实施例1的环保型无氯冲压油进行冲压工件的另一个侧面的示意图。
图3为以本发明实施例1的环保型无氯冲压油进行冲压工件的另一个侧面的示意图。
具体实施方式
以下结合实施例对本发明技术方案做进一步详细说明。
实施例1
一种环保型无氯冲压油,是由以下质量分数的原料制备得到的:150BS为52.4wt%、大豆油为10wt%、棕榈油为15wt%、磷酸三甲酚酯为1wt%、磷酸酯铵盐(范德比尔特,型号Vanlube 672)为2wt%、硫化脂肪酸酯(DOG,型号MD18)为2wt%、二烷基五硫化物(路博润,型号:5340)为4wt%、丙三醇为2wt%、乙二醇为2wt%、石油磺酸钡(King,型号:NA-SUL611)为1wt%、二壬基萘磺酸钡(King,型号:NA-SUL BSN)为1wt%、环烷酸锌为3wt%、聚异丁烯为4wt%、2,6二叔丁基对甲酚为0.3wt%、苯并三氮唑为0.3wt%。
制备过程:先在反应釜中加入150BS、大豆油、棕榈油,在向其中加入2,6二叔丁基对甲酚,升温到70-80℃,保持该温度,不断搅拌半小时,至固体物质全部溶解,然后降温到50-60℃,依次加入磷酸三甲酚酯、磷酸酯铵盐、硫化脂肪酸酯、二烷基五硫化物、丙三醇、乙二醇、石油磺酸钡、二壬基萘磺酸钡、环烷酸锌、聚异丁烯、苯并三氮唑后,再继续搅拌1h,即得到所述的环保型无氯冲压油。
实施例2
一种环保型无氯冲压油,是由以下质量分数的原料制备得到的:150BS为33wt%、500SN为22wt%、大豆油为8wt%、棕榈油为12.6wt%、磷酸三甲酚酯为1wt%、磷酸酯铵盐(范德比尔特,型号Vanlube 672)为1.8wt%、硫化脂肪酸酯(DOG,型号MD18)为1.8wt%、二烷基五硫化物(路博润,型号:5340)为1.8wt%、丙三醇为3wt%、十四醇为2wt%、石油磺酸钡(King,型号:NA-SUL611)为2wt%、二壬基萘磺酸钡(King,型号:NA-SUL BSN)为2wt%、十二烯基丁二酸为2wt%、聚异丁烯为5.9wt%、2,6二叔丁基对甲酚为0.6wt%、苯并三氮唑为0.5wt%。
制备过程:先在反应釜中加入150BS、500SN、大豆油、棕榈油,在向其中加入2,6二叔丁基对甲酚,升温到70-80℃,保持该温度,不断搅拌半小时,至固体物质全部溶解,然后降温到50-60℃,依次加入磷酸三甲酚酯、磷酸酯铵盐、硫化脂肪酸酯、二烷基五硫化物、丙三醇、十四醇、石油磺酸钡、二壬基萘磺酸钡、十二烯基丁二酸、聚异丁烯、苯并三氮唑后,再继续搅拌1h,即得到所述的环保型无氯冲压油。
实施例3
一种环保型无氯冲压油,是由以下质量分数的原料制备得到的:500SN为42wt%、大豆油为12wt%、棕榈油为18wt%、磷酸三甲酚酯为3wt%、磷酸酯铵盐(范德比尔特,型号Vanlube 672)为2wt%、硫化脂肪酸酯(DOG,型号MD18)为2.5wt%、二烷基五硫化物(路博润,型号:5340)为3.5wt%、乙二醇为3wt%、十四醇为2wt%、石油磺酸钡(King,型号:NA-SUL611)为3wt%、十二烯基丁二酸为2.5wt%、聚异丁烯为6wt%、2,6二叔丁基对甲酚为0.3wt%、苯并三氮唑为0.2wt%。
制备过程:先在反应釜中加入500SN、大豆油、棕榈油,在向其中加入2,6二叔丁基对甲酚,升温到70-80℃,保持该温度,不断搅拌半小时,至固体物质全部溶解,然后降温到50-60℃,依次加入磷酸三甲酚酯、磷酸酯铵盐、硫化脂肪酸酯、二烷基五硫化物、乙二醇、十四醇、石油磺酸钡、十二烯基丁二酸、聚异丁烯、苯并三氮唑后,再继续搅拌1h,即得到所述的环保型无氯冲压油。
以市售福斯51H精密冲压油(RENOFORM MZAN 51H)作为对比,本发明的无氯冲压油及福斯51H冲压油的性能如下:
Figure BDA0004033007830000051
以市售福斯51H精密冲压油(RENOFORM MZAN 51H)作为对比,本发明的无氯冲压油及福斯51H冲压油的现场试用数据如下:
项目 实施例1 实施例2 实施例3 福斯51H
冲压频率,次/分 20 20 20 20
材质,厚度mm 16CrMo,14 16CrMo,14 16CrMo,14 16CrMo,14
冲压断面Ra,μm 0.584 0.658 0.635 0.575
光亮带占比,% 94 92 93 95
工件生锈情况 1个月未生锈 1个月未生锈 1个月未生锈 2-4h出现生锈
另外,以本发明实施例1的无氯冲压油进行工件冲压,如图1~图3所示,本发明的无氯冲压油完全适用于14mm厚度工件的冲压。
最后应说明的是:以上所述仅为本发明的优选实施例而已,并不用于限制本发明,尽管参照前述实施例对本发明进行了详细的说明,对于本领域的技术人员来说,其依然可以对前述各实施例所记载的技术方案进行修改,或者对其中部分技术特征进行等同替换。凡在本发明的精神和原则之内,所作的任何修改、等同替换、改进等,均应包含在本发明的保护范围之内。

Claims (10)

1.一种无氯冲压油,其特征在于,所述无氯冲压油包括以下重量百分比的组分:
基础油42~55%,
油性剂20~30%,
极压剂5~11%,
铺展剂1~5%,
防锈剂3~6%,
增粘剂3~6%,
抗氧剂0.1~0.6%,
减活剂0.2~0.5%。
2.根据权利要求1所述的无氯冲压油,其特征在于:所述基础油为150BS基础油和/或500SN基础油。
3.根据权利要求1所述的无氯冲压油,其特征在于:所述油性剂为大豆油和/或棕榈油。
4.根据权利要求3所述的无氯冲压油,其特征在于:所述油性剂由重量比为2:3的大豆油和棕榈油组成。
5.根据权利要求1所述的无氯冲压油,其特征在于:所述极压剂为磷酸三甲酚酯、磷酸酯铵盐、硫化脂肪酸酯、硫磷丁辛伯烷基锌盐、二烷基五硫化物中的至少一种。
6.根据权利要求1所述的无氯冲压油,其特征在于:所述铺展剂为丙三醇、乙二醇、十四醇中的至少一种。
7.根据权利要求1所述的无氯冲压油,其特征在于:所述防锈剂为石油磺酸钡、二壬基萘磺酸钡,环烷酸锌、十二烯基丁二酸中的至少一种。
8.根据权利要求1所述的无氯冲压油,其特征在于:所述增粘剂为聚异丁烯。
9.根据权利要求1所述的无氯冲压油,其特征在于:所述抗氧剂为2,6二叔丁基对甲酚、2,2-硫代双(4-甲基-6-叔丁基苯酚)、辛/丁基二苯胺中的至少一种。
10.根据权利要求1所述的无氯冲压油,其特征在于:所述减活剂为苯并三氮唑。
CN202211741899.3A 2022-12-31 2022-12-31 一种无氯冲压油 Pending CN116200221A (zh)

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Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB586679A (en) * 1943-12-08 1947-03-27 Dudley Herbert Japes Improvements in or relating to anti-corrosion oils
JPH0718281A (ja) * 1993-06-30 1995-01-20 Honda Motor Co Ltd 金属加工用洗浄油
JP2010195912A (ja) * 2009-02-25 2010-09-09 Sumitomo Light Metal Ind Ltd ステンレス合金板あるいは鋼板のプレス加工用潤滑油、及びそれを用いたステンレス合金板あるいは鋼板のプレス加工方法
CN103666660A (zh) * 2012-09-20 2014-03-26 中国石油化工股份有限公司 汽车零部件拉延油组合物及其用途
CN106190472A (zh) * 2016-07-11 2016-12-07 沈阳帕卡濑精有限总公司 一种用于车身冲压成型的可乳化型冲压油
CN109135895A (zh) * 2018-10-09 2019-01-04 中国石油化工股份有限公司 高润滑热轧油组合物及其用途
CN111205913A (zh) * 2020-02-21 2020-05-29 上海中孚特种油品有限公司 一种环保型多工位冷镦油及其制备方法
CN112239696A (zh) * 2019-07-17 2021-01-19 中国石油化工股份有限公司 冲压油组合物及其用途

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB586679A (en) * 1943-12-08 1947-03-27 Dudley Herbert Japes Improvements in or relating to anti-corrosion oils
JPH0718281A (ja) * 1993-06-30 1995-01-20 Honda Motor Co Ltd 金属加工用洗浄油
JP2010195912A (ja) * 2009-02-25 2010-09-09 Sumitomo Light Metal Ind Ltd ステンレス合金板あるいは鋼板のプレス加工用潤滑油、及びそれを用いたステンレス合金板あるいは鋼板のプレス加工方法
CN103666660A (zh) * 2012-09-20 2014-03-26 中国石油化工股份有限公司 汽车零部件拉延油组合物及其用途
CN106190472A (zh) * 2016-07-11 2016-12-07 沈阳帕卡濑精有限总公司 一种用于车身冲压成型的可乳化型冲压油
CN109135895A (zh) * 2018-10-09 2019-01-04 中国石油化工股份有限公司 高润滑热轧油组合物及其用途
CN112239696A (zh) * 2019-07-17 2021-01-19 中国石油化工股份有限公司 冲压油组合物及其用途
CN111205913A (zh) * 2020-02-21 2020-05-29 上海中孚特种油品有限公司 一种环保型多工位冷镦油及其制备方法

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