CN114106922A - 不锈钢轧制组合物 - Google Patents
不锈钢轧制组合物 Download PDFInfo
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- CN114106922A CN114106922A CN202111515576.8A CN202111515576A CN114106922A CN 114106922 A CN114106922 A CN 114106922A CN 202111515576 A CN202111515576 A CN 202111515576A CN 114106922 A CN114106922 A CN 114106922A
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- composition
- stainless steel
- steel rolling
- oil
- agent
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- 239000000203 mixture Substances 0.000 title claims abstract description 64
- 238000005096 rolling process Methods 0.000 title claims abstract description 21
- 229910001220 stainless steel Inorganic materials 0.000 title claims abstract description 21
- 239000010935 stainless steel Substances 0.000 title claims abstract description 21
- 239000003921 oil Substances 0.000 claims abstract description 32
- 239000002518 antifoaming agent Substances 0.000 claims abstract description 21
- 239000002131 composite material Substances 0.000 claims abstract description 20
- 239000013556 antirust agent Substances 0.000 claims abstract description 19
- 239000000654 additive Substances 0.000 claims abstract description 17
- 230000000996 additive effect Effects 0.000 claims abstract description 17
- 239000006078 metal deactivator Substances 0.000 claims abstract description 17
- 239000003595 mist Substances 0.000 claims abstract description 12
- 239000002199 base oil Substances 0.000 claims abstract description 11
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 10
- 230000003078 antioxidant effect Effects 0.000 claims abstract description 10
- 230000001050 lubricating effect Effects 0.000 claims abstract description 9
- 238000002360 preparation method Methods 0.000 claims abstract description 9
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 5
- 235000019198 oils Nutrition 0.000 claims description 27
- 238000013329 compounding Methods 0.000 claims description 19
- 239000007866 anti-wear additive Substances 0.000 claims description 11
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 claims description 10
- -1 fatty acid ester Chemical class 0.000 claims description 10
- 239000000126 substance Substances 0.000 claims description 8
- 150000004996 alkyl benzenes Chemical class 0.000 claims description 7
- QMMJWQMCMRUYTG-UHFFFAOYSA-N 1,2,4,5-tetrachloro-3-(trifluoromethyl)benzene Chemical compound FC(F)(F)C1=C(Cl)C(Cl)=CC(Cl)=C1Cl QMMJWQMCMRUYTG-UHFFFAOYSA-N 0.000 claims description 5
- QDCPNGVVOWVKJG-VAWYXSNFSA-N 2-[(e)-dodec-1-enyl]butanedioic acid Chemical compound CCCCCCCCCC\C=C\C(C(O)=O)CC(O)=O QDCPNGVVOWVKJG-VAWYXSNFSA-N 0.000 claims description 5
- FMNZBNCPTJEVDS-KVVVOXFISA-N 2-ethyl-2-(hydroxymethyl)propane-1,3-diol;(z)-octadec-9-enoic acid Chemical compound CCC(CO)(CO)CO.CCCCCCCC\C=C/CCCCCCCC(O)=O FMNZBNCPTJEVDS-KVVVOXFISA-N 0.000 claims description 5
- SAUIGQBKPDQYHL-QXMHVHEDSA-N 6-methylheptyl (z)-octadec-9-enoate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCCCCCC(C)C SAUIGQBKPDQYHL-QXMHVHEDSA-N 0.000 claims description 5
- SJIDAAGFCNIAJP-UHFFFAOYSA-N 6-methylheptyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCCCCC(C)C SJIDAAGFCNIAJP-UHFFFAOYSA-N 0.000 claims description 5
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 claims description 5
- 229910019142 PO4 Inorganic materials 0.000 claims description 5
- 229920002367 Polyisobutene Polymers 0.000 claims description 5
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 5
- YSMRWXYRXBRSND-UHFFFAOYSA-N TOTP Chemical compound CC1=CC=CC=C1OP(=O)(OC=1C(=CC=CC=1)C)OC1=CC=CC=C1C YSMRWXYRXBRSND-UHFFFAOYSA-N 0.000 claims description 5
- QCJQWJKKTGJDCM-UHFFFAOYSA-N [P].[S] Chemical compound [P].[S] QCJQWJKKTGJDCM-UHFFFAOYSA-N 0.000 claims description 5
- 150000001336 alkenes Chemical class 0.000 claims description 5
- 150000001412 amines Chemical class 0.000 claims description 5
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 claims description 5
- 239000012964 benzotriazole Substances 0.000 claims description 5
- 125000003354 benzotriazolyl group Chemical class N1N=NC2=C1C=CC=C2* 0.000 claims description 5
- ZWYAVGUHWPLBGT-UHFFFAOYSA-N bis(6-methylheptyl) decanedioate Chemical compound CC(C)CCCCCOC(=O)CCCCCCCCC(=O)OCCCCCC(C)C ZWYAVGUHWPLBGT-UHFFFAOYSA-N 0.000 claims description 5
- CJFLBOQMPJCWLR-UHFFFAOYSA-N bis(6-methylheptyl) hexanedioate Chemical compound CC(C)CCCCCOC(=O)CCCCC(=O)OCCCCCC(C)C CJFLBOQMPJCWLR-UHFFFAOYSA-N 0.000 claims description 5
- OOSPDKSZPPFOBR-UHFFFAOYSA-N butyl dihydrogen phosphite Chemical compound CCCCOP(O)O OOSPDKSZPPFOBR-UHFFFAOYSA-N 0.000 claims description 5
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 claims description 5
- 239000000292 calcium oxide Substances 0.000 claims description 5
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 claims description 5
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 5
- 239000004205 dimethyl polysiloxane Substances 0.000 claims description 5
- 150000002148 esters Chemical class 0.000 claims description 5
- 239000000194 fatty acid Substances 0.000 claims description 5
- 229930195729 fatty acid Natural products 0.000 claims description 5
- 239000003879 lubricant additive Substances 0.000 claims description 5
- WIBFFTLQMKKBLZ-SEYXRHQNSA-N n-butyl oleate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCCCC WIBFFTLQMKKBLZ-SEYXRHQNSA-N 0.000 claims description 5
- 229940049964 oleate Drugs 0.000 claims description 5
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 5
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 claims description 5
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 claims description 5
- 239000002530 phenolic antioxidant Substances 0.000 claims description 5
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 5
- 239000010452 phosphate Substances 0.000 claims description 5
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 claims description 5
- 229920000058 polyacrylate Polymers 0.000 claims description 5
- 229920013639 polyalphaolefin Polymers 0.000 claims description 5
- 229920000570 polyether Polymers 0.000 claims description 5
- 238000005245 sintering Methods 0.000 claims description 5
- VLLMWSRANPNYQX-UHFFFAOYSA-N thiadiazole Chemical compound C1=CSN=N1.C1=CSN=N1 VLLMWSRANPNYQX-UHFFFAOYSA-N 0.000 claims description 5
- DECPGQLXYYCNEZ-UHFFFAOYSA-N tris(6-methylheptyl) phosphite Chemical compound CC(C)CCCCCOP(OCCCCCC(C)C)OCCCCCC(C)C DECPGQLXYYCNEZ-UHFFFAOYSA-N 0.000 claims description 5
- 235000015112 vegetable and seed oil Nutrition 0.000 claims description 5
- 239000008158 vegetable oil Substances 0.000 claims description 5
- NAGJZTKCGNOGPW-UHFFFAOYSA-K dioxido-sulfanylidene-sulfido-$l^{5}-phosphane Chemical compound [O-]P([O-])([S-])=S NAGJZTKCGNOGPW-UHFFFAOYSA-K 0.000 claims description 4
- 229910052788 barium Inorganic materials 0.000 claims description 2
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 claims description 2
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 2
- 230000007797 corrosion Effects 0.000 abstract description 11
- 238000005260 corrosion Methods 0.000 abstract description 11
- 229910052751 metal Inorganic materials 0.000 abstract description 8
- 239000002184 metal Substances 0.000 abstract description 8
- 239000003518 caustics Substances 0.000 abstract description 6
- 230000006378 damage Effects 0.000 abstract description 3
- 239000000314 lubricant Substances 0.000 abstract description 2
- 229940071160 cocoate Drugs 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- SECPZKHBENQXJG-FPLPWBNLSA-N palmitoleic acid Chemical compound CCCCCC\C=C/CCCCCCCC(O)=O SECPZKHBENQXJG-FPLPWBNLSA-N 0.000 description 3
- 238000000034 method Methods 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 239000010731 rolling oil Substances 0.000 description 2
- 238000005299 abrasion Methods 0.000 description 1
- 230000003064 anti-oxidating effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000003490 calendering Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000010297 mechanical methods and process Methods 0.000 description 1
- 230000005226 mechanical processes and functions Effects 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
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- C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
- C10M169/04—Mixtures of base-materials and additives
- C10M169/048—Mixtures of base-materials and additives the additives being a mixture of compounds of unknown or incompletely defined constitution, non-macromolecular and macromolecular compounds
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Abstract
本发明提供不锈钢轧制组合物，涉及润滑剂技术领域，所述组合物按重量百分比包括下列组分：油性润滑添加剂组合物8‑20％，油雾拟制剂0.1‑1％，极压抗磨剂组合物0.5‑5.0％，其他添加剂组合物0.5‑1.0％，基础油50‑80％，消泡剂0.1‑0.3％，金属减活剂0.5‑0.7％。本发明中的组合物具有优良的极压抗磨润滑性能和油雾拟制性能，不仅降低了油品挥发而造成的损耗，避免了白线条和色差，以及烧辊现象的发生，提升板面光泽度，更重要是避免了油雾对环境和人体造成的伤害，同时本发明中还加入了金属减活剂、复合防锈剂，其中金属减活剂能够有效抑制油品中腐蚀性物质对金属表面的腐蚀，而且兼有抗氧化功能，而复合防锈剂则可以降低锈蚀的速度，综上，本发明实用性较高，具有突出的创造性。
Description
技术领域
本发明涉及润滑剂技术领域，尤其涉及不锈钢轧制组合物。
背景技术
在金属板材轧制过程中，一般是采用复合多组辊连续轧制工艺属于当今较为先进的生产工艺，而为了保证组合式轧机的正常工作，适应精密机械工艺过程对润滑性，冷却性等的严格要求，不锈钢压延油便应运而生。
但是面对愈来愈苛刻的加工条件和工艺质量要求，不锈钢压延油的耐高温性和极压抗磨性要求愈来愈高，而目前所有油品普遍存在挥发性高，油烟大，板面光泽度不佳，容易出现白线条和色差，以及烧辊现象，不能很好地满足现在加工要求，因此，需要进行改进。
发明内容
本发明的目的是为了解决现有技术中存在的缺点，而提出的不锈钢轧制组合物。
为了实现上述目的，本发明采用了如下技术方案：不锈钢轧制组合物，所述组合物按重量百分比包括下列组分：
油性润滑添加剂组合物8-20％，油雾拟制剂0.1-1％，极压抗磨剂组合物0.5-5.0％，其他添加剂组合物0.5-1.0％，基础油50-80％，消泡剂0.1-0.3％，金属减活剂0.5-0.7％，复合防锈剂0.1-0.2％。
为了提高实用性，本发明改进有，所述油性润滑添加剂组合物含有三羟甲基丙烷油酸酯、三羟甲基丙烷椰子油酸酯、三羟甲基丙烷棕榈油酸酯、季戊四醇油酸酯、油酸丁酯、油酸异辛酯、硬脂酸丁酯、硬脂酸异辛酯、己二酸二异辛酯和葵二酸二异辛酯的一种或多种组合。
为了提高耐磨性能，本发明改进有，所述极压抗磨剂组合物包括亚磷酸正丁酯、亚磷酸异辛酯、磷酸三甲酚酯、C12-16磷酸酯、硫化脂肪酸酯、硫化植物油、硫化猪油、硫化烯烃和硫磷极压抗磨剂的任意一种。
为了提高抗氧化效果，本发明改进有，所述其他添加剂组合物包括酚型抗氧剂、胺类抗氧剂、聚α－烯烃和聚异丁烯的一种或多种，所述基础油包括60N、100N、100SN、150N、150SN、500N、500SN和150BS中的一种或多种。
为了提高产品质量，本发明改进有，所述组合物为无色或者浅黄色透明油状物质，所述组合物的40℃运动粘度为5-20mm2/s，闪点(开口)≥160℃，油膜强度Pb值≥52斤，烧结负荷Pd值≥126公斤。
为了避免防止泡沫形成，本发明改进有，所述消泡剂为聚二甲基硅氧烷、聚丙烯酸酯、聚醚型消泡剂和PESO消泡剂的任意一种或两种。
为了保护金属不被腐蚀，本发明改进有，所述金属减活剂为苯三唑衍生物、二硫代磷酸酯和噻二唑复配而成，其复配比例为2:0.5:1。
为了防锈蚀，本发明改进有，所述复合防锈剂为十二烯基丁二酸及其半酯、苯并三氮唑及其酯化物、烷基苯磺酸钡、烷基苯磺酸和氧化钙复配而成，其复配比例为10:1:2:1:0.5。
相比于现有技术，本发明中的组合物具有优良的极压抗磨润滑性能和油雾拟制性能，不仅降低了油品挥发而造成的损耗，避免了白线条和色差，以及烧辊现象的发生，提升板面光泽度，更重要是避免了油雾对环境和人体造成的伤害，同时本发明中还加入了金属减活剂、复合防锈剂，其中金属减活剂能够有效抑制油品中腐蚀性物质对金属表面的腐蚀，而且兼有抗氧化功能，而复合防锈剂则可以降低锈蚀的速度，综上，本发明实用性较高，具有突出的创造性。
本发明的其它特征和优点将在随后的说明书中阐述，并且，部分地从说明书中变得显而易见，或者通过实施本发明而了解。本发明的目的和其他优点可通过在所写的说明书、权利要求书、以及附图中所特别指出的结构来实现和获得。
下面通过附图和实施例，对本发明的技术方案做进一步的详细描述。
附图说明
为了更清楚地说明本发明实施例或现有技术中的技术方案，下面将对实施例或现有技术描述中所需要使用的附图作简单地介绍，显而易见地，下面描述中的附图仅仅是本发明的一些实施例，对于本领域普通技术人员来讲，在不付出创造性劳动的前提下，还可以根据这些附图获得其他的附图。
图1为本发明提出不锈钢轧制组合物的性能表格图。
具体实施方式
下面将结合本发明实施例中的附图，对本发明实施例中的技术方案进行清楚、完整地描述，显然，所描述的实施例仅仅是本发明一部分实施例，而不是全部的实施例。基于本发明中的实施例，本领域普通技术人员在没有作出创造性劳动前提下所获得的所有其他实施例，都属于本发明保护的范围。
实施例一，参阅图1，不锈钢轧制组合物，所述组合物按重量百分比包括下列组分：
油性润滑添加剂组合物20％，油雾拟制剂1％，极压抗磨剂组合物0.5-5.0％，其他添加剂组合物0.7％，基础油77％，消泡剂0.2％，金属减活剂0.6％，复合防锈剂0.2％。
本实施例中，所述油性润滑添加剂组合物含有三羟甲基丙烷油酸酯、三羟甲基丙烷椰子油酸酯、三羟甲基丙烷棕榈油酸酯、季戊四醇油酸酯、油酸丁酯、油酸异辛酯、硬脂酸丁酯、硬脂酸异辛酯、己二酸二异辛酯和葵二酸二异辛酯的一种或多种组合。
本实施例中，所述极压抗磨剂组合物包括亚磷酸正丁酯、亚磷酸异辛酯、磷酸三甲酚酯、C12-16磷酸酯、硫化脂肪酸酯、硫化植物油、硫化猪油、硫化烯烃和硫磷极压抗磨剂的任意一种。
本实施例中，所述其他添加剂组合物包括酚型抗氧剂、胺类抗氧剂、聚α－烯烃和聚异丁烯的一种或多种，所述基础油包括60N、100N、100SN、150N、150SN、500N、500SN和150BS中的一种或多种。
本实施例中，所述组合物为无色透明油状物质，所述组合物的40℃运动粘度为5-20mm2/s，闪点(开口)≥160℃，油膜强度Pb值≥56公斤，烧结负荷Pd值≥160公斤。
本实施例中，所述消泡剂为聚二甲基硅氧烷、聚丙烯酸酯、聚醚型消泡剂和PESO消泡剂的任意一种或两种。
本实施例中，所述金属减活剂为苯三唑衍生物、二硫代磷酸酯和噻二唑复配而成，其复配比例为2:0.5:1，金属减活剂能够有效抑制油品中腐蚀性物质对金属表面的腐蚀，而且兼有抗氧化功能。
本实施例中，所述复合防锈剂为十二烯基丁二酸及其半酯、苯并三氮唑及其酯化物、烷基苯磺酸和氧化钙复配而成，其复配比例为10:1:2:1:0.5，复合防锈剂可以有效抑制锈蚀速度。
实施例二，参阅图1，不锈钢轧制组合物，所述组合物按重量百分比包括下列组分：
油性润滑添加剂组合物15％，油雾拟制剂0.5％，极压抗磨剂组合物3％，其他添加剂组合物0.7％，基础油75％，消泡剂0.2％，金属减活剂0.6％，复合防锈剂0.2％。
本实施例中，所述油性润滑添加剂组合物含有三羟甲基丙烷油酸酯、三羟甲基丙烷椰子油酸酯、三羟甲基丙烷棕榈油酸酯、季戊四醇油酸酯、油酸丁酯、油酸异辛酯、硬脂酸丁酯、硬脂酸异辛酯、己二酸二异辛酯和葵二酸二异辛酯的一种或多种组合。
本实施例中，所述极压抗磨剂组合物包括亚磷酸正丁酯、亚磷酸异辛酯、磷酸三甲酚酯、C12-16磷酸酯、硫化脂肪酸酯、硫化植物油、硫化猪油、硫化烯烃和硫磷极压抗磨剂的任意一种。
本实施例中，所述其他添加剂组合物包括酚型抗氧剂、胺类抗氧剂、聚α－烯烃和聚异丁烯的一种或多种，所述基础油包括60N、100N、100SN、150N、150SN、500N、500SN和150BS中的一种或多种。
本实施例中，所述组合物为无色透明油状物质，所述组合物的40℃运动粘度为5-20mm2/s，闪点(开口)≥160℃，油膜强度Pb值≥66公斤，烧结负荷Pd值≥160公斤。
本实施例中，所述消泡剂为聚二甲基硅氧烷、聚丙烯酸酯、聚醚型消泡剂和PESO消泡剂的任意一种或两种。
本实施例中，所述金属减活剂为苯三唑衍生物、二硫代磷酸酯和噻二唑复配而成，其复配比例为2:0.5:1，金属减活剂能够有效抑制油品中腐蚀性物质对金属表面的腐蚀，而且兼有抗氧化功能。
本实施例中，所述复合防锈剂为十二烯基丁二酸及其半酯、苯并三氮唑及其酯化物、烷基苯磺酸和氧化钙复配而成，其复配比例为10:1:2:1:0.5，复合防锈剂可以有效抑制锈蚀速度。
实施例三，参阅图1，不锈钢轧制组合物，所述组合物按重量百分比包括下列组分：
油性润滑添加剂组合物19％，油雾拟制剂0.5％，极压抗磨剂组合物5.0％，其他添加剂组合物1.0％，基础油80％，消泡剂0.3％，金属减活剂0.7％，复合防锈剂0.2％。
本实施例中，所述油性润滑添加剂组合物含有三羟甲基丙烷油酸酯、三羟甲基丙烷椰子油酸酯、三羟甲基丙烷棕榈油酸酯、季戊四醇油酸酯、油酸丁酯、油酸异辛酯、硬脂酸丁酯、硬脂酸异辛酯、己二酸二异辛酯和葵二酸二异辛酯的一种或多种组合。
本实施例中，所述极压抗磨剂组合物包括亚磷酸正丁酯、亚磷酸异辛酯、磷酸三甲酚酯、C12-16磷酸酯、硫化脂肪酸酯、硫化植物油、硫化猪油、硫化烯烃和硫磷极压抗磨剂的任意一种。
本实施例中，所述其他添加剂组合物包括酚型抗氧剂、胺类抗氧剂、聚α－烯烃和聚异丁烯的一种或多种，所述基础油包括60N、100N、100SN、150N、150SN、500N、500SN和150BS中的一种或多种。
本实施例中，所述组合物为琥珀色透明油状物质，所述组合物的40℃运动粘度为5-20mm2/s，闪点(开口)≥160℃，油膜强度Pb值≥52斤，烧结负荷Pd值≥126公斤。
本实施例中，所述消泡剂为聚二甲基硅氧烷、聚丙烯酸酯、聚醚型消泡剂和PESO消泡剂的任意一种或两种。
本实施例中，所述金属减活剂为苯三唑衍生物、二硫代磷酸酯和噻二唑复配而成，其复配比例为2:0.5:1，金属减活剂能够有效抑制油品中腐蚀性物质对金属表面的腐蚀，而且兼有抗氧化功能。
本实施例中，所述复合防锈剂为十二烯基丁二酸及其半酯、苯并三氮唑及其酯化物、烷基苯磺酸和氧化钙复配而成，其复配比例为10:1:2:1:0.5，复合防锈剂可以有效抑制锈蚀速度。
将上述实施例一中的原料在40-50℃温度下，混合均匀，制成样品1，将上述实施例二中的原料在40-50℃温度下，混合均匀，制成样品2，再取市面销售使用的不锈钢轧制油为样品3，最后进行性能测试，结果如图1所示。
从上述实施例可以看出，本发明中的组合物具有优良的极压抗磨润滑性能和油雾拟制性能，不仅降低了油品挥发而造成的损耗，避免了白线条和色差，以及烧辊现象的发生，提升板面光泽度，更重要是避免了油雾对环境和人体造成的伤害，同时本发明中还加入了金属减活剂、复合防锈剂，其中金属减活剂能够有效抑制油品中腐蚀性物质对金属表面的腐蚀，而且兼有抗氧化功能，而复合防锈剂则可以降低锈蚀的速度，综上，本发明实用性较高，具有突出的创造性。
显然，本领域的技术人员可以对本发明进行各种改动和变型而不脱离本发明的精神和范围。这样，倘若本发明的这些修改和变型属于本发明权利要求及其等同技术的范围之内，则本发明也意图包含这些改动和变型在内。
Claims (8)
1.不锈钢轧制组合物，其特征在于，所述组合物按重量百分比包括下列组分：
油性润滑添加剂组合物8-20％，油雾拟制剂0.1-1％，极压抗磨剂组合物0.5-5.0％，其他添加剂组合物0.5-1.0％，基础油50-80％，消泡剂0.1-0.3％，金属减活剂0.5-0.7％，复合防锈剂0.1-0.2％。
2.根据权利要求1所述的不锈钢轧制组合物，其特征在于：所述油性润滑添加剂组合物含有三羟甲基丙烷油酸酯、三羟甲基丙烷椰子油酸酯、三羟甲基丙烷棕榈油酸酯、季戊四醇油酸酯、油酸丁酯、油酸异辛酯、硬脂酸丁酯、硬脂酸异辛酯、己二酸二异辛酯和葵二酸二异辛酯的一种或多种组合。
3.根据权利要求1所述的不锈钢轧制组合物，其特征在于：所述极压抗磨剂组合物包括亚磷酸正丁酯、亚磷酸异辛酯、磷酸三甲酚酯、C12-16磷酸酯、硫化脂肪酸酯、硫化植物油、硫化猪油、硫化烯烃和硫磷极压抗磨剂的任意一种。
4.根据权利要求1所述的不锈钢轧制组合物，其特征在于：所述其他添加剂组合物包括酚型抗氧剂、胺类抗氧剂、聚α－烯烃和聚异丁烯的一种或多种，所述基础油包括60N、100N、100SN、150N、150SN、500N、500SN和150BS中的一种或多种。
5.根据权利要求1所述的不锈钢轧制组合物，其特征在于：所述组合物为无色或者浅黄色透明油状物质，所述组合物的40℃运动粘度为5-20mm2/s，闪点(开口)≥160℃，油膜强度Pb值≥52斤，烧结负荷Pd值≥126公斤。
6.根据权利要求1所述的不锈钢轧制组合物，其特征在于：所述消泡剂为聚二甲基硅氧烷、聚丙烯酸酯、聚醚型消泡剂和PESO消泡剂的任意一种或两种。
7.根据权利要求1所述的不锈钢轧制组合物，其特征在于：所述金属减活剂为苯三唑衍生物、二硫代磷酸酯和噻二唑复配而成，其复配比例为2:0.5:1。
8.根据权利要求1所述的不锈钢轧制组合物，其特征在于：所述复合防锈剂为十二烯基丁二酸及其半酯、苯并三氮唑及其酯化物、烷基苯磺酸钡、烷基苯磺酸和氧化钙复配而成，其复配比例为10:1:2:1:0.5。
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