CN114106919A - 清洁润滑油 - Google Patents
清洁润滑油 Download PDFInfo
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- CN114106919A CN114106919A CN202111490086.7A CN202111490086A CN114106919A CN 114106919 A CN114106919 A CN 114106919A CN 202111490086 A CN202111490086 A CN 202111490086A CN 114106919 A CN114106919 A CN 114106919A
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- 238000004140 cleaning Methods 0.000 title claims description 12
- 239000010687 lubricating oil Substances 0.000 title abstract description 22
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims abstract description 17
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 17
- 230000003078 antioxidant effect Effects 0.000 claims abstract description 17
- 229910052750 molybdenum Inorganic materials 0.000 claims abstract description 17
- 239000011733 molybdenum Substances 0.000 claims abstract description 17
- 239000002270 dispersing agent Substances 0.000 claims abstract description 16
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000002199 base oil Substances 0.000 claims abstract description 14
- 239000003599 detergent Substances 0.000 claims abstract description 11
- 229910052751 metal Inorganic materials 0.000 claims abstract description 11
- 239000002184 metal Substances 0.000 claims abstract description 11
- 239000002518 antifoaming agent Substances 0.000 claims abstract description 10
- 150000001875 compounds Chemical class 0.000 claims abstract description 9
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000013556 antirust agent Substances 0.000 claims abstract description 7
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000011787 zinc oxide Substances 0.000 claims abstract description 7
- 239000000654 additive Substances 0.000 claims abstract description 5
- 230000000996 additive effect Effects 0.000 claims abstract description 5
- 239000002131 composite material Substances 0.000 claims description 15
- KZNICNPSHKQLFF-UHFFFAOYSA-N succinimide Chemical compound O=C1CCC(=O)N1 KZNICNPSHKQLFF-UHFFFAOYSA-N 0.000 claims description 10
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 8
- 229960003742 phenol Drugs 0.000 claims description 7
- -1 3, 5-di-tert-butyl-4-hydroxy-benzene propionic acid isooctyl ester Chemical class 0.000 claims description 6
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 6
- 229910052749 magnesium Inorganic materials 0.000 claims description 6
- 239000011777 magnesium Substances 0.000 claims description 6
- HXRAIVCWVIJIKB-UHFFFAOYSA-N 2-butyl-n-octyl-n-phenylaniline Chemical compound C=1C=CC=C(CCCC)C=1N(CCCCCCCC)C1=CC=CC=C1 HXRAIVCWVIJIKB-UHFFFAOYSA-N 0.000 claims description 5
- 229960002317 succinimide Drugs 0.000 claims description 5
- 229920002367 Polyisobutene Polymers 0.000 claims description 4
- 238000013329 compounding Methods 0.000 claims description 4
- 150000004867 thiadiazoles Chemical class 0.000 claims description 4
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 3
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 claims description 3
- 229910052788 barium Inorganic materials 0.000 claims description 3
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical group [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 claims description 3
- 229910052791 calcium Inorganic materials 0.000 claims description 3
- 239000011575 calcium Substances 0.000 claims description 3
- 238000005984 hydrogenation reaction Methods 0.000 claims description 3
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 claims description 3
- 239000003755 preservative agent Substances 0.000 claims description 3
- 230000002335 preservative effect Effects 0.000 claims description 3
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 3
- PQQKPALAQIIWST-UHFFFAOYSA-N oxomolybdenum Chemical compound [Mo]=O PQQKPALAQIIWST-UHFFFAOYSA-N 0.000 claims description 2
- 239000000314 lubricant Substances 0.000 claims 8
- 230000003647 oxidation Effects 0.000 abstract description 12
- 238000007254 oxidation reaction Methods 0.000 abstract description 12
- 238000005299 abrasion Methods 0.000 abstract description 3
- 230000007613 environmental effect Effects 0.000 abstract description 3
- 230000000694 effects Effects 0.000 description 6
- 239000003921 oil Substances 0.000 description 6
- 239000010802 sludge Substances 0.000 description 5
- 238000005260 corrosion Methods 0.000 description 4
- 230000007797 corrosion Effects 0.000 description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- KOAKAVACKLBGBC-UHFFFAOYSA-N C1(=CC=CC=C1)C(C(=O)OCCC(C(C(C(C)C)C(C)(C)C)O)C(C)(C)C)C Chemical compound C1(=CC=CC=C1)C(C(=O)OCCC(C(C(C(C)C)C(C)(C)C)O)C(C)(C)C)C KOAKAVACKLBGBC-UHFFFAOYSA-N 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 230000003064 anti-oxidating effect Effects 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
- C10M169/04—Mixtures of base-materials and additives
- C10M169/048—Mixtures of base-materials and additives the additives being a mixture of compounds of unknown or incompletely defined constitution, non-macromolecular and macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/14—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to carbon atoms of six-membered aromatic rings
- C10M2207/144—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to carbon atoms of six-membered aromatic rings containing hydroxy groups
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/28—Esters
- C10M2207/284—Esters of aromatic monocarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
- C10M2215/06—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to carbon atoms of six-membered aromatic rings
- C10M2215/064—Di- and triaryl amines
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/02—Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/04—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
- C10M2219/044—Sulfonic acids, Derivatives thereof, e.g. neutral salts
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/10—Heterocyclic compounds containing sulfur, selenium or tellurium compounds in the ring
- C10M2219/104—Heterocyclic compounds containing sulfur, selenium or tellurium compounds in the ring containing sulfur and carbon with nitrogen or oxygen in the ring
- C10M2219/106—Thiadiazoles
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
- C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
- C10M2223/04—Phosphate esters
- C10M2223/045—Metal containing thio derivatives
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2227/00—Organic non-macromolecular compounds containing atoms of elements not provided for in groups C10M2203/00, C10M2207/00, C10M2211/00, C10M2215/00, C10M2219/00 or C10M2223/00 as ingredients in lubricant compositions
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- C10M2229/04—Siloxanes with specific structure
- C10M2229/041—Siloxanes with specific structure containing aliphatic substituents
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- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
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Abstract
本发明公开了一种清洁润滑油,涉及润滑油的技术领域,本发明包括如下质量百分含量的组分:纳米氧化锌:1%~4%;有机钼:2%~5%;抗泡剂:0.5 %~3%;复合抗氧化剂:3%~5%;硼酸盐添加剂:1%~3%;金属清净剂:0.5%~5%;复合分散剂:0.5%~5%;滑石粉:0.5 %~3%;防锈剂:0.1~0.5%;基础油:余量。本发明的清洁润滑油具有优异的耐磨性、抗氧化性、高温稳定性,能够一定程度上修复磨损,兼具环保优点。
Description
技术领域
本发明涉及清洁润滑油的技术领域,具体是一种清洁润滑油。
背景技术
汽车的核心零部件之一是发动机,发动机的性能发挥决定了汽车短周期驾驶体验和长周期的使用寿命。因此,发动机润滑油的添加成为提高发动机性能的重要手段。
发动机润滑油工作环境极为恶劣,表现为温度高、温差大、负荷重、运动速度快,易受环境因素影响等。
因此,发动机润滑油需要兼具满足耐磨性、耐高温性、抗氧化性和防腐性能等性能要求。
润滑油添加剂的引入为改善基础油性能提供了有利增益,但现有的润滑油在满足抗氧化性和抗磨性能的同时,存在高温性能差、油泥多等缺点。
发明内容
本发明提出了一种清洁润滑油,包括如下质量百分含量的组分:纳米氧化锌:1% ~4%;有机钼:2% ~ 5%;抗泡剂:0.5 % ~ 3%;复合抗氧化剂:3% ~ 5%;硼酸盐添加剂:1% ~3%;金属清净剂:0.5% ~ 5%;复合分散剂:0.5% ~ 5%;滑石粉:0.5 % ~ 3%;防锈剂:0.1 ~0.5%;基础油:余量。
本发明的进一步设置为:所述复合抗氧剂为受阻酚类抗氧剂、3,5-二叔丁基-4-羟基苯丙酸异辛酯、丁辛基二苯胺、噻二唑衍生物复配而成。
本发明的进一步设置为:所述复合分散剂为硼化聚异丁烯丁二酰亚胺、仲烷基二硫代磷酸锌、酚类无灰分散剂复配而成。
本发明的进一步设置为:所述金属清净剂为高碱值烷基水杨酸镁、硼化高碱值烷基水杨酸镁、高碱值硫化烷基水杨酸钙中的一种或多种。
本发明的进一步设置为:所述有机钼为硫化二烷基二硫代磷酸氧钼、二烷基二硫代磷酸钼中的一种或多种。
本发明的进一步设置为:所述基础油为全加氢工艺生产的III类基础油。
本发明的进一步设置为:所述防腐剂为磺酸钡。
本发明的进一步设置为:所述抗泡剂为甲基硅油。
本发明的有益技术效果为:
本发明的清洁润滑油具有优异的耐磨性、抗氧化性、高温稳定性,能够一定程度上修复磨损,兼具环保优点。
具体实施方式
下面来描述本发明的优选实施方式。本领域技术人员应当理解的是,这些实施方式仅仅用于解释本发明的技术原理,并非旨在限制本发明的保护范围。
本发明提出了一种清洁润滑油,包括如下质量百分含量的组分:纳米氧化锌:1% ~4%;有机钼:2% ~ 5%;抗泡剂:0.5 % ~ 3%;复合抗氧化剂:3% ~ 5%;硼酸盐添加剂:1% ~3%;金属清净剂:0.5% ~ 5%;复合分散剂:0.5% ~ 5%;滑石粉:0.5 % ~ 3%;防锈剂:0.1 ~0.5%;基础油:余量。
复合抗氧剂为受阻酚类抗氧剂、3,5-二叔丁基-4-羟基苯丙酸异辛酯、丁辛基二苯胺、噻二唑衍生物复配而成。复合抗氧剂具有如下效果:
(1)受阻酚类抗氧剂:能有效控制因氧化而引起的油品黏度增长与酸值增大;
(2)3,5-二叔丁基-4-羟基苯丙酸异辛酯:高温条件抗氧化性突出,与胺型抗氧化剂(丁辛基二苯胺)复合使用效果有叠加。
(3)丁辛基二苯胺:热安定性好、高温条件下抗氧化性能突出;
(4)噻二唑衍生物:良好的抑制铜片腐蚀性能和抗氧化性,对于有机钼对铜片腐蚀作用优良。
复合分散剂为硼化聚异丁烯丁二酰亚胺、仲烷基二硫代磷酸锌、酚类无灰分散剂复配而成。复合分散剂具有如下效果:
(1)硼化聚异丁烯丁二酰亚胺:具有良好清净性和低温油泥分散性、极好耐高温性,一定程度的抗氧化性和抗磨性,不含氯;
(2)仲烷基二硫代磷酸锌(ZDDP):良好抗氧抗腐蚀性能、极压抗磨性能,与金属清净剂、无灰分散剂复合使用效果显著;
(3)酚类无灰分散剂:具有良好的高温稳定性和高温分散性,但低温油泥分散性不佳,需与丁二酰亚胺复配提升性能。
金属清净剂为高碱值烷基水杨酸镁、硼化高碱值烷基水杨酸镁、高碱值硫化烷基水杨酸钙中的一种或多种。
有机钼为硫化二烷基二硫代磷酸氧钼、二烷基二硫代磷酸钼中的一种或多种。
基础油为全加氢工艺生产的III类基础油。
防腐剂为磺酸钡。
抗泡剂为甲基硅油。
实施例1
本实施例提供的清洁润滑油,包括如下组分,以质量百分数表示如下:基础油90.9%,纳米氧化锌1 %,有机钼2%,抗泡剂0.5%,复合抗氧剂3%,纳米硼酸盐1 %,金属清净剂0.5%,复合分散剂0.5%,滑石粉0.5%,防锈剂0.1%。此种组成下汽车发动机润滑油耐磨性、抗氧化性较差。
实施例2
本实施例提供的清洁润滑油包括如下组分,以质量百分数表示如下:基础油64.5%,纳米氧化锌4%,有机钼5%,抗泡剂4%,复合抗氧剂5%,纳米硼酸盐4 %,金属清净剂5%,复合分散剂5%,滑石粉3%,防锈剂0.5%。此种组成下汽车发动机润滑油耐磨性、抗氧化性、高温稳定性较优,能够一定程度上修复磨损。
实施例3
本实施例提供的清洁润滑油包括如下组分,以质量百分数表示如下:基础油78.45%,纳米氧化锌2.5%,有机钼3.5%,抗泡剂1.75%,复合抗氧剂4%,纳米硼酸盐2%,金属清净剂2.75%,复合分散剂2.75%,滑石粉2%,防锈剂0.3%。此种组成下汽车发动机润滑油耐磨性、抗氧化性、高温稳定性良好,能够一定程度上修复磨损。
虽然已经参考优选实施例对本发明进行了描述,但在不脱离本发明的范围的情况下,可以对其进行各种改进并且可以用等效物替换其中的部件,尤其是,只要不存在结构冲突,各个实施例中所提到的各项技术特征均可以任意方式组合起来。本发明并不局限于文中公开的特定实施例,而是包括落入权利要求的范围内的所有技术方案。
Claims (8)
1.一种清洁润滑油,其特征在于:包括如下质量百分含量的组分:纳米氧化锌:1% ~4%;有机钼:2% ~ 5%;抗泡剂:0.5 % ~ 3%;复合抗氧化剂:3% ~ 5%;硼酸盐添加剂:1% ~3%;金属清净剂:0.5% ~ 5%;复合分散剂:0.5% ~ 5%;滑石粉:0.5 % ~ 3%;防锈剂:0.1 ~0.5%;基础油:余量。
2.根据权利要求1所述的清洁润滑油,其特征在于:所述复合抗氧剂为受阻酚类抗氧剂、3,5-二叔丁基-4-羟基苯丙酸异辛酯、丁辛基二苯胺、噻二唑衍生物复配而成。
3.根据权利要求1所述的清洁润滑油,其特征在于:所述复合分散剂为硼化聚异丁烯丁二酰亚胺、仲烷基二硫代磷酸锌、酚类无灰分散剂复配而成。
4.根据权利要求1所述的清洁润滑油,其特征在于:所述金属清净剂为高碱值烷基水杨酸镁、硼化高碱值烷基水杨酸镁、高碱值硫化烷基水杨酸钙中的一种或多种。
5.根据权利要求1所述的清洁润滑油,其特征在于:所述有机钼为硫化二烷基二硫代磷酸氧钼、二烷基二硫代磷酸钼中的一种或多种。
6.根据权利要求1所述的清洁润滑油,其特征在于:所述基础油为全加氢工艺生产的III类基础油。
7.根据权利要求1所述的清洁润滑油,其特征在于:所述防腐剂为磺酸钡。
8.根据权利要求1所述的清洁润滑油,其特征在于:所述抗泡剂为甲基硅油。
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