CN108602945B - 聚乳酸与天然油的酯交换 - Google Patents

聚乳酸与天然油的酯交换 Download PDF

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Publication number
CN108602945B
CN108602945B CN201780009096.XA CN201780009096A CN108602945B CN 108602945 B CN108602945 B CN 108602945B CN 201780009096 A CN201780009096 A CN 201780009096A CN 108602945 B CN108602945 B CN 108602945B
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China
Prior art keywords
polylactic acid
oil
transesterified
temperature
glycol
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CN201780009096.XA
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English (en)
Chinese (zh)
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CN108602945A (zh
Inventor
G·B·肯尼翁
A·P·姆加亚
B·拉玛林加姆
昌正缅
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Henkel AG and Co KGaA
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Henkel IP and Holding GmbH
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
    • C08G63/06—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from hydroxycarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
    • C08G63/06—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from hydroxycarboxylic acids
    • C08G63/08—Lactones or lactides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
    • C08G63/60—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from the reaction of a mixture of hydroxy carboxylic acids, polycarboxylic acids and polyhydroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/78—Preparation processes
    • C08G63/82—Preparation processes characterised by the catalyst used
    • C08G63/85—Germanium, tin, lead, arsenic, antimony, bismuth, titanium, zirconium, hafnium, vanadium, niobium, tantalum, or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/91—Polymers modified by chemical after-treatment
    • C08G63/912—Polymers modified by chemical after-treatment derived from hydroxycarboxylic acids
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/40—Substitution reactions at carbon centres, e.g. C-C or C-X, i.e. carbon-hetero atom, cross-coupling, C-H activation or ring-opening reactions
    • B01J2231/49—Esterification or transesterification
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0201—Oxygen-containing compounds
    • B01J31/0211—Oxygen-containing compounds with a metal-oxygen link
    • B01J31/0212—Alkoxylates

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Polyesters Or Polycarbonates (AREA)
CN201780009096.XA 2016-02-01 2017-02-01 聚乳酸与天然油的酯交换 Active CN108602945B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201662289432P 2016-02-01 2016-02-01
US62/289,432 2016-02-01
PCT/US2017/015927 WO2017136373A1 (en) 2016-02-01 2017-02-01 Transesterification of polylactic acid with natural oils

Publications (2)

Publication Number Publication Date
CN108602945A CN108602945A (zh) 2018-09-28
CN108602945B true CN108602945B (zh) 2020-05-15

Family

ID=59500157

Family Applications (1)

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CN201780009096.XA Active CN108602945B (zh) 2016-02-01 2017-02-01 聚乳酸与天然油的酯交换

Country Status (7)

Country Link
US (2) US10294328B2 (ja)
EP (1) EP3411423B1 (ja)
JP (1) JP6788679B2 (ja)
KR (1) KR102190885B1 (ja)
CN (1) CN108602945B (ja)
BR (1) BR112018014886B1 (ja)
WO (1) WO2017136373A1 (ja)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108602945B (zh) * 2016-02-01 2020-05-15 汉高知识产权控股有限责任公司 聚乳酸与天然油的酯交换
US11891480B2 (en) 2016-02-01 2024-02-06 Henkel Ag & Co. Kgaa Laminating adhesives using polyester from transesterification of polylactic acid with natural oils
EP3774988A4 (en) * 2018-04-06 2021-12-29 Henkel IP & Holding GmbH Laminating adhesives using polyester from transesterification of polylactic acid with natural oils
CN111454553A (zh) * 2020-05-18 2020-07-28 长沙乐远化工科技有限公司 一种改性聚乳酸材料及制备方法
CN112724435B (zh) * 2020-12-29 2024-01-02 中北大学 一种可降解杏仁油/聚乳酸薄膜及其制备方法与应用

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1817939A (zh) * 2006-03-22 2006-08-16 南昌大学 原位酯交换低聚乳酸合成可降解性芳香/脂肪共聚酯的方法
CN101104680A (zh) * 2007-07-30 2008-01-16 南昌大学 三元反应性共混制备可降解共聚酯的方法
WO2009058367A1 (en) * 2007-11-01 2009-05-07 Cargill, Incorporated Natural oil-derived polyester polyols and polyurethanes made therefrom
CN101851326A (zh) * 2010-05-26 2010-10-06 华南理工大学 一种聚氨酯弹性体及其制备方法

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Publication number Priority date Publication date Assignee Title
US6664363B1 (en) * 1998-02-23 2003-12-16 Stepan Company Low viscosity polyester polyols and methods for preparing same
JP2006143829A (ja) * 2004-11-18 2006-06-08 Kanebo Ltd ポリ乳酸系樹脂成形品及びその製造方法
US8394410B2 (en) * 2005-01-20 2013-03-12 Massachusetts Institute Of Technology Soft polylactides
US20090209727A1 (en) * 2008-02-20 2009-08-20 Centre Valorisation Industriel Agroressources, Association Loi 1901 Process for the production of a material that is degradable in a natural environment with a renewable carbon base
CN101671476B (zh) 2008-09-11 2013-04-10 拜耳材料科技(中国)有限公司 芳香族聚碳酸酯与聚乳酸的共混物及其制备方法和用途
CN102282194B (zh) * 2009-01-16 2015-02-25 生物基础塑料开发有限公司 聚乳酸树脂组合物和聚乳酸树脂用添加剂
WO2011074328A1 (ja) * 2009-12-14 2011-06-23 日本電気株式会社 ポリ乳酸系ポリオール組成物、その製造方法、ウレタン樹脂組成物、その製造方法及び成形体
ES2724497T3 (es) * 2010-05-17 2019-09-11 Cj Cheiljedang Corp Acido poliláctico para lograr tenacidad con polihidroxialcanoatos
CN102850743A (zh) * 2012-10-09 2013-01-02 广东益德环保科技有限公司 一种生物降解材料及其制备方法和应用
WO2015119976A1 (en) * 2014-02-04 2015-08-13 Abbott Cardiovascular Systems Inc. Modified pla polymer and method of making and using
CN104448270B (zh) * 2014-11-18 2016-07-06 中国科学院长春应用化学研究所 一种脂肪族-芳香族-聚乳酸多嵌段共聚物
CN108602945B (zh) * 2016-02-01 2020-05-15 汉高知识产权控股有限责任公司 聚乳酸与天然油的酯交换

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1817939A (zh) * 2006-03-22 2006-08-16 南昌大学 原位酯交换低聚乳酸合成可降解性芳香/脂肪共聚酯的方法
CN101104680A (zh) * 2007-07-30 2008-01-16 南昌大学 三元反应性共混制备可降解共聚酯的方法
WO2009058367A1 (en) * 2007-11-01 2009-05-07 Cargill, Incorporated Natural oil-derived polyester polyols and polyurethanes made therefrom
CN101851326A (zh) * 2010-05-26 2010-10-06 华南理工大学 一种聚氨酯弹性体及其制备方法

Also Published As

Publication number Publication date
KR102190885B1 (ko) 2020-12-14
JP6788679B2 (ja) 2020-11-25
EP3411423B1 (en) 2021-06-30
EP3411423A1 (en) 2018-12-12
KR20180104302A (ko) 2018-09-20
BR112018014886B1 (pt) 2022-08-02
EP3411423A4 (en) 2019-10-09
US20200031994A1 (en) 2020-01-30
CN108602945A (zh) 2018-09-28
US10294328B2 (en) 2019-05-21
US10941246B2 (en) 2021-03-09
WO2017136373A1 (en) 2017-08-10
BR112018014886A2 (pt) 2018-12-18
JP2019503428A (ja) 2019-02-07
US20180327545A1 (en) 2018-11-15

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