CN108472229B - 油性睫毛用化妆料以及化妆方法 - Google Patents
油性睫毛用化妆料以及化妆方法 Download PDFInfo
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- CN108472229B CN108472229B CN201780006091.1A CN201780006091A CN108472229B CN 108472229 B CN108472229 B CN 108472229B CN 201780006091 A CN201780006091 A CN 201780006091A CN 108472229 B CN108472229 B CN 108472229B
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Abstract
一种油性睫毛用化妆料,其含有:(A)油溶性被膜形成剂3~40质量%、(B)HLB值为7~10的非离子型表面活性剂0.1~10质量%、(C)挥发性油剂20~70质量%以及(D)不挥发性油剂0.5~30质量%,所述(A)成分与(D)成分的比例[(A)/(D)(质量比)]为0.7/1~5.8/1,在含有熔点为50℃以上的固体油分的情况下,该固体油分的量为10质量%以下。该油性睫毛用化妆料,除了具有油性睫毛用化妆料所特有的优良的卷曲效果、以及持妆性(耐水性)之外,还具有优异的温水除去性,无需使用卸妆液而用温水就能容易地卸妆。
Description
技术领域
本发明涉及一种油性睫毛用化妆料及使用该化妆料的化妆方法,具体而言,涉及一种在温水中具有优异的除去性的油性睫毛用化妆料及用温水即可容易地除去(卸妆)的化妆方法。
背景技术
以睫毛膏为代表的睫毛用化妆料具有使睫毛向上卷曲并使睫毛看上去变粗和变长,从而使眼睛更加清澈的化妆效果。以往,虽已知油性型、油包水型及水包油型的乳化型、水性型等各种剂型的睫毛用化妆料,但最近,不使用卸妆液即可简单地除去的水包油型的乳化型睫毛膏正在变得流行。
但是,水包油型的乳化型睫毛膏可以容易地除去,即洗去性优异,然而,存在着难以维持特意形成的睫毛卷曲的问题。这是因为使用诸如睫毛夹等工具而物理地卷曲的睫毛,会由于接触水分而失去卷曲效果。
另一方面,油性睫毛用化妆料与水包油型、油包水型等乳化型睫毛用化妆料相比,具有更高的卷曲维持效果,并且具有优异的耐水性等持妆性能(参见专利文献1第0009段)。然而,油性型的睫毛用化妆料具有必须使用专用的卸妆液来卸妆的缺点。因此,为了改良卸妆时的除去性而进行深入研究,并提出:通过将油溶性树脂、脂肪酸皂、HLB值为12以上的非离子型表面活性剂以及挥发性油剂进行混合,以得到可用温水除去的油性睫毛用化妆料(专利文献2)。然而,根据本发明人的实验,使用脂肪酸皂或具有高HLB值的非离子型表面活性剂作为表面活性剂而制备的油性睫毛用化妆料仍不能说具有足够的除去性,此外,对于汗液与泪液的耐水性也仍不充分。
另外,专利文献3提出了一种眼部化妆料,其含有油胶凝剂、高粘性烃油剂、极性油剂以及挥发性油剂,该文献记载了这种化妆料具有良好的持妆性、被膜光滑、涂抹时的光泽优异、并且清洁性优异(权利要求1以及第0007段)。另外,还记载了当将化妆料中的表面活性剂,特别是HLB值小于10的非离子型表面活性剂和HLB值为10以上的非离子型表面活性剂组合使用时,清洁性得到提高(参照第0023~0025段),在实施例中记载了组合使用了HLB值14的聚乙二醇单月桂酸酯和HLB值5.3的异硬脂基甘油醚的混合例(参照实施例1~2以及4~6、表1)。虽然根据这些实施例,所得到的化妆料被评价为具有优异的清洁性,但是这里的清洁性的评价方法是通过将油性清洁剂涂抹在睫毛上后用肥皂清洗,而关于仅用温水卸妆时的化妆料的除去性没有任何的记载(参照第0039段)。
此外,专利文献4公开了由具有特定化学结构的酪醇衍生物构成的防腐杀菌剂(参见权利要求1)以及含有该酪醇衍生物的化妆料(参见权利要求3),在配方例30~32中,含有油溶性被膜形成剂、非离子型表面活性剂、挥发性油剂、非挥发性油剂以及油性胶凝剂,此外,还公开了分别以10质量%和5质量%(总计15质量%)的比例含有蜂蜡和巴西棕榈蜡的油包水型睫毛膏。专利文献4所记载的发明的技术特征在于提供新型防腐杀菌剂,但关于作为其使用实例之一的油包水型睫毛膏显示出什么样的特性没有任何公开。
专利文献5进一步公开了油性睫毛用化妆料,其含有:(A)熔点为55~70℃的蜡6~35质量%、(B)HLB值为5~10的表面活性剂0.1~10质量%、(C)挥发性烃10~90质量%,总蜡中含有85质量%以上的成分(A),并且含有油溶性被膜形成剂以及不挥发性油剂作为任选成分(参照权利要求1)。在实施例1~3中,公开了油性睫毛用化妆料,其通过将蜡、非离子型表面活性剂、挥发性油剂、油溶性被膜形成剂、不挥发性油剂以及油性胶凝剂混合调制而成。在本发明中,由于以6~35质量%的比例含有熔点为55~70℃的蜡,因此存在睫毛的光泽难以出现的问题,另外,由于油溶性被膜形成剂的含量比不挥发性油剂的含量多,因此存在温水中的除去性不充分的问题。
现有技术文献
专利文献
专利文献1:日本特开2006-306829号公报
专利文献2:日本特开2006-265216号公报
专利文献3:日本特开2008-115120号公报
专利文献4:日本特开2007-039340号公报
专利文献5:日本特开2012-1403384号公报
发明内容
发明所解决的问题
本发明是在上述背景技术下完成的,其目的在于提供一种油性睫毛用化妆料,其在维持油性睫毛用化妆料所具有的优异的卷曲效果和耐水性的同时,与水包油型睫毛用化妆料一样无需使用卸妆液,只需用温水即可容易地洗去。
解决问题的技术手段
为解决上述问题,本发明人进行了努力研究,结果发现了一种油性睫毛用化妆料以完成本发明,在该油性睫毛用化妆料中以特定比例含有油溶性树脂和不挥发性液体油,并通过使用具有特定HLB值的非离子型表面活性剂作为表面活性剂,以获得卷曲效果优异、耐水性较高、同时能够用温水容易地卸妆的化妆膜。
由此,本发明提供了一种油性睫毛用化妆料,其含有:(A)油溶性被膜形成剂3~40质量%、(B)HLB值为7~10的非离子型表面活性剂0.1~10质量%、(C)挥发性油剂20~70质量%以及(D)不挥发性油剂0.5~30质量%,所述(A)成分与(D)成分的比例[(A)/(D)(质量比)]为0.7/1~5.8/1,在含有熔点为50℃以上的固体油分的情况下,该固体油分的量为10质量%以下。
发明效果
本发明的油性睫毛用化妆料,除了具有油性睫毛用化妆料所特有的优良的卷曲效果、以及持妆性(耐水性)之外,还具有优异的温水洗去性。此外,根据本发明的化妆方法,不使用卸妆液而用温水就能容易地卸妆。
具体实施方式
本发明的油性睫毛用化妆料,其含有:(A)油溶性被膜形成剂、(B)HLB值为7~10的非离子型表面活性剂、(C)挥发性油剂以及(D)不挥发性油剂作为必需成分。
作为(A)成分的油溶性被膜形成剂,只要其能溶解于油性成分中以形成被膜就没有特别限制,作为具体的例子,可列举:三甲基硅烷氧基硅酸酯、部分交联的有机聚硅氧烷、三甲基硅烷氧基甲硅烷基丙基氨基甲酸酯、氟改性有机硅、丙烯酸改性有机硅、有机硅树枝状大分子改性树脂化合物等有机硅型树脂、松香酸季戊四醇酯、松香酸甘油酯等松香酸型树脂、小烛树脂、聚乙酸乙烯酯型树脂、聚乙烯基异丁基醚、聚异丁烯等。需要说明的是,小烛树脂是通过用有机溶剂分级萃取小烛树蜡而得到的树脂成分,树脂成分的含量优选为65质量%以上,更优选为85质量%以上。
其中,三甲基硅烷氧基硅酸酯、松香型树脂和小烛树脂在化妆效果的持久性以及卷曲效果的方面优异。作为市售品,可列举:预先将三甲基硅烷氧基硅酸酯溶解在溶剂中的X-21-5595、KF-7312J、KF-7312F(均由信越化学工业公司制造)、作为氢化松香酸甘油酯的PINCRYSTAL KE-311(Harima化成公司制造)、小烛树脂E-1(日本Natural Products公司制造)等。这些可以单独使用,或适当地组合使用。
(A)成分的油溶性被膜形成剂的含量相对于化妆料总量为3~40质量%,优选为5~35质量%,更优选为7~30质量%。如果(A)成分过少,则睫毛的光泽、卷曲效果、耐水性变得不足,如果过多,则难以用温水洗去,且使用时难以涂抹于睫毛处。
(表面活性剂)
在本发明中,使用非离子型表面活性剂作为(B)成分。所使用的非离子型表面活性剂的HLB值必须在7~10的范围内,特别优选为8~9。如果HLB值小于该范围,则不能改良在温水中的洗去性,相反,如果HLB值大于该范围,则耐水性降低。此外,即便使用阴离子型表面活性剂或阳离子型表面活性剂代替非离子型表面活性剂,也不能得到具有优异的耐水性的睫毛用化妆料。
作为用作(B)成分的非离子型表面活性剂的具体例,可列举:聚甘油硬脂酸酯-6、聚甘油三硬脂酸酯-10、聚甘油油酸酯-6等聚甘油脂肪酸酯;PEG-10氢化蓖麻油、PEG-20氢化蓖麻油等聚氧乙烯硬化蓖麻油;PEG-5硬脂酸酯、PEG-6异硬脂酸酯等聚氧乙烯脂肪酸酯;鲸蜡醇聚醚-4、油醇聚醚-6、硬脂醇聚醚-6等聚氧乙烯烷基醚;硬脂醇聚醚-12硬脂酸酯、月桂醇聚醚-10异硬脂酸酯等聚氧乙烯烷基醚脂肪酸酯;PEG-6甘油异硬脂酸酯、PEG-20甘油三异硬脂酸酯、PEG-20甘油三硬脂酸酯等甘油聚氧乙烯脂肪酸酯;PEG-20氢化蓖麻油异硬脂酸酯、PEG-40氢化蓖麻油三异硬脂酸酯等聚氧乙烯氢化蓖麻油脂肪酸酯;聚氧乙烯脱水山梨糖醇脂肪酸酯、聚氧乙烯聚氧丙烯共聚物、由聚氧乙烯聚氧丙烯共聚物和长链醇形成的醚、由聚丁二醇聚甘油共聚物和长链醇形成的醚等。其中,优选使用聚氧乙烯脂肪酸酯,甘油聚氧乙烯脂肪酸酯和聚氧乙烯烷基醚脂肪酸酯。
当非离子型表面活性剂在分子中含有脂肪酸残基时,作为该脂肪酸残基,优选肉豆蔻酸、棕榈酸、硬脂酸、异硬脂酸、油酸等具有10~22个碳原子的高级脂肪酸的残基。对于市售品,可优选使用“Emalex GWS-320”(PEG-20甘油基三硬脂酸酯;日本Emulsion公司制造;HLB值8)、“UNIOX GT-20IS”(PEG-20甘油异硬脂酸酯;日本油脂公司制造;HLB值8)、“Emalex PEIS-6EX”(PEG-6异硬脂酸酯;日本Emulsion公司制造;HLB值9)、“Emalex SWS-12”(硬脂醇聚醚-12硬脂酸酯;日本Emulsion公司制造;HLB值8)等。
(B)成分可以单独使用,也可以将2种以上组合使用。(B)成分的使用量在全组分中为0.1~10质量%,优选为0.5~8质量%,更优选为1~6质量%。当(B)成分的量过少时,温水中的除去性降低,而过多时,耐水性降低。
在本发明中,除组分(B)外,还可以适当地组合使用HLB值大于10的非离子型表面活性剂、阴离子型表面活性剂、阳离子型表面活性剂或两性型表面活性剂。然而,由于这些表面活性剂有时会降低化妆料的耐水性,因此在含有这些表面活性剂的情况下,其含量在全组分中为2质量%以下,优选为0.5质量%以下,更优选为0.1质量%以下。进一步优选将这些表面活性剂的含量限制在0.05质量%以下。
(挥发性油剂)
本发明中使用的(C)成分的挥发性油剂,只要是在通常的化妆料中所使用的挥发性油剂即可,没有特别的限定。通常在常压下的沸点为60℃~260℃,优选为100~220℃,作为具体例子,可以列举为:异十二烷、异十六烷、以碳原子数8~16的化合物为主要成分的饱和异链烷烃类烃油(例如氢化聚异丁烯)等烃油以及挥发性硅油等。市售品可列举为:丸善石油化学公司制造的Marcasol R、出光兴产公司制造的IP Solvent 1620及IP Solvent2028等。其中,从储存稳定性、挥发速度的观点出发,优选使用异十二烷、以碳原子数为8~16的化合物作为主要成分的氢化聚异丁烯。
所述(C)成分的使用量在全组分中为20~70质量%,优选为30~65质量%,更优选为35~60质量%。如果(C)成分的量过少,则卷曲效果和耐水性降低。如果(C)成分的量过多,则睫毛上的残留成分减少,体积效果和卷曲效果降低。
(不挥发性油剂)
本发明中所使用的(D)成分的不挥发性油剂是具有比所述(C)成分更高的沸点的,且在常温下为液状或糊状的油剂。这种不挥发性油剂只要是用于通常的化妆料中的,就没有特别的限制,可以是动物油、植物油、合成油中的任意一种。作为不挥发性油剂的具体例,可列举:甘油三(乙基己酸)酯、二异硬脂酸苹果酸酯、聚甘油异硬脂酸酯-2、二甘油三异硬脂酸酯、十聚甘油十异硬脂酸酯、由二聚酸和二聚二醇形成的低聚酯、季戊四醇四异硬脂酸酯、二甘油二异硬脂酸酯、异辛酸鲸蜡酯、肉豆蔻酸异丙酯、棕榈酸异丙酯、肉豆蔻酸辛基十二烷基酯、新戊二醇二辛酸酯、胆固醇脂肪酸酯、荷荷巴油等酯类;聚丁烯、聚异丁烯、重质液体异链烷烃、液体石蜡、α-烯烃低聚物、角鲨烷、凡士林、聚异丁烯的烃类;橄榄油、蓖麻油、貂油、澳洲坚果油等的油脂类;异硬脂酸、油酸等的脂肪酸类;油醇、异硬脂醇等的高级醇类;低聚合度二甲基聚硅氧烷、高聚合度二甲基聚硅氧烷、甲基苯基聚硅氧烷、交联型有机聚硅氧烷、氟改性聚硅氧烷等的硅油类;全氟聚醚等的氟型油剂类;羊毛脂、乙酸羊毛脂、异丙基羊毛脂脂肪酸酯、羊毛脂醇等的羊毛脂衍生物类。另外,作为(D)成分的不挥发性油剂可以是HLB值小于7的在常温下为液状或糊状的非离子型表面活性剂。(D)不挥发性油剂可以单独使用,也可以将2种以上组合使用。
(D)不挥发性油剂的混合量在全组分中为0.5~30质量%,优选为1~20质量%,特别优选为2~15质量%。通过在该范围内混合(D)成分,可以得到具有优异卷曲效果、耐水性和温水中的除去性的化妆料。
在本发明中,需要以如下比例含有(A)油溶性被膜形成剂和(D)不挥发性油剂:(A)油溶性被膜形成剂/(D)不挥发性油剂(质量比)为0.7/1~5.8/1,优选为1/1~5.8/1,更优选为1.5/1~5.5/1。
(A)成分的比例过大时,温水中的除去性降低,相反,过小时则耐水性降低。
在本发明的化妆料中,除了所述(A)~(D)的各成分之外,还可以混合油性胶凝剂作为(E)成分。通过混合油性胶凝剂,可以获得具有容易涂覆到睫毛上的适度粘性的化妆料,并且容易使体系稳定在均匀状态。作为油性胶凝剂,可以列举:糊精脂肪酸酯、菊粉脂肪酸酯、蔗糖脂肪酸酯、淀粉脂肪酸酯、有机改性粘土矿物、金属皂、12-羟基硬脂酸等。
所述糊精脂肪酸酯是由糊精或还原糊精与高级脂肪酸形成的酯,可以列举例如糊精棕榈酸酯、糊精棕榈酸/2-乙基己酸酯等。作为市售品,可以列举:糊精棕榈酸酯(“Rheopearl KL 2”、“Rheopearl TL 2”)与糊精棕榈酸/2-乙基己酸酯(“Rheopearl TT2”)(均由千叶制粉公司制造)等。作为所述蔗糖脂肪酸酯,包括蔗糖硬脂酸酯和蔗糖乙酸硬脂酸酯等,具体可列举:“糖蜡S-10E”、“DK酯S-160”、“糖蜡A-10E”(均由第一工业制药公司制造)等。
所述有机改性粘土矿物,可以列举:利用有机极性化合物和有机阳离子取代介于粘土矿物(例如蒙脱石、皂石、锂蒙脱石、膨润土等)的结晶层之间的变换性阳离子获得的物质等。具体可列举:二甲基二硬脂基铵锂蒙脱石(=二硬脂基二甲基锂蒙脱石)、二甲基二硬脂基铵膨润土(=季铵盐-18膨润土)、双十八烷基二甲基铵盐改性蒙脱土、十八烷基二甲基苄基铵盐改性蒙脱石、双十六烷基二甲基铵盐改性蒙脱石等。作为市售品,例如可列举:“Bentone 38 V”(=二硬脂基二甲基锂蒙脱石)、“Bentone 34”(=季铵盐-18膨润土)、“Bentone 27”(=苄基二甲基二硬脂基铵锂蒙脱石)(均由Elementis公司制造)等。作为所述金属皂,可以列举:硬脂酸铝、硬脂酸钙等。(E)成分可以使用1种或2种以上。
(E)成分的混合量相对于本发明的化妆料总量优选为1~30质量%,更优选为3~25质量%,特别优选为5~20质量%。通过混合(E)成分,能够使用刷子将足够的量涂覆在睫毛上而容易获得适当的粘性,并且能够改善体系的稳定性。
在本发明的化妆料中,可以混合色料作为(F)成分。色料只要是在化妆料领域中通常使用的即可,对其形状、粒径和粒子结构没有特别限定。作为形状的具体例,可列举:球形、板形、针形等。粒径的具体例可列举:烟雾状、微粒子、颜料级等。另外,粒子结构可以是多孔质或无孔质。
(F)色料的具体例可列举无机粉末类、光亮性粉末类、有机粉末类、色素粉末类、金属粉末类、复合粉末类等。更具体地说,可以列举:滑石、云母、高岭土、碳酸钙、二氧化硅、氧化锌、二氧化钛、氧化铁红、氧化铁黄、氧化铁黑、群青、铁蓝、炭黑、低氧化钛、钴紫、氧化铬、氢氧化铬、钛酸钴、氯氧化铋、云母钛珍珠颜料等无机颜料;聚酰胺类树脂、聚乙烯类树脂、聚丙烯酸类树脂、聚酯类树脂、氟树脂、纤维素类树脂、聚苯乙烯类树脂、苯乙烯-丙烯酸共聚树脂等共聚树脂;聚丙烯类树脂、硅树脂、氨基甲酸酯树脂等有机高分子树脂粉末;红色201号、红色202号、红色204号、红色205号、红色220号、红色226号、红色228号、红色405号、橙色203号、黄色205号、黄色4号、黄色5号、蓝色1号、蓝色404号、绿色3号等的锆、钡或铝色淀等有机颜料;叶绿素、β-胡萝卜素等天然色素;染料等。这些色料可以单独使用或将两种以上组合使用。其中,优选使用黑色色料,特别是氧化铁黑和炭黑。
(F)色料的混合量可以适当进行选择。优选为0.1~20质量%,更优选为0.5~15质量%。当色料的混合量过大时,附着性容易降低,反之,当色料的混合量过小时色料的效果有时会不充分。
本发明的油性睫毛用化妆料可以含有少量的水作为(G)成分。水的含量的优选为化妆料总量的5质量%以下,若在该范围内,则(B)成分的非离子型表面活性剂和水为可溶解状态,即其中油性成分作为分散介质存在,并且(B)成分和水形成反胶束的状态。其结果为,(B)成分的非离子型表面活性剂更容易溶解在由(A)成分和(C)成分形成的油剂中,即使长期储存也不会发生(B)成分的分离和析出,储存稳定性得到改善。特别是,当水的含量为0.1~3质量%时,该效果显著。
本发明的油性睫毛用化妆料,在不损害本发明的效果的范围内,除了上述成分之外还可含有其他的通常化妆料中所使用的成分,例如:固体油分、多元醇、低级醇、紫外线吸收剂、紫外线散射剂、保湿剂、香料、抗氧化剂、防腐剂、螯合剂、消泡剂、纤维、染料、各种提取物等。作为固体油分,可以列举:熔点为50℃以上的动物性蜡、植物性蜡、矿物性蜡、硅蜡、合成蜡等,但是由于含量多时,涂抹时的睫毛的光泽降低,因此在含有时优选为10质量%以下,更优选为5质量%以下。
本发明的油性睫毛用化妆料可以根据常规方法制备。例如,可以通过将全部原料加热,并在均匀搅拌下令其冷却来制造。此外,还可以通过预先将色料与一部分油性成分和/或表面活性剂成分混炼,然后与其余成分加热混合来制得。
本发明的油性睫毛用化妆料可以用于睫毛膏、睫毛膏用基底、睫毛膏用涂层、睫毛化妆液等。化妆料的形态可以根据用途进行适当选择,例如可以是乳状、液状等。本发明的油性睫毛用化妆料,可以使用刷子、树脂成型涂布工具、金属成型涂布工具等适当的工具涂布在睫毛上。
使用本发明的油性睫毛用化妆料进行化妆时,在除去油性睫毛用化妆料时,可不使用通常使用的卸妆液,而仅使用35℃~45℃左右的温水即可容易地卸妆。
实施例
在下文中,将列举实施例和比较例以更具体地描述本发明,但是本发明不受到这些实施例的限定。需要说明的是,除非另有说明,下文描述中的配方中的混合量为基于总量的质量%。另外,下文的实施例和比较例中的油性睫毛用化妆料的评价方法如下所述。
(评价方法a~e)
关于下述评价项目a~e,10名评价者对自己的睫毛涂布各个样品,再根据下述(1)所示的评价标准以从0至6这7个等级来评分。算出10位评价者的合计评分,再根据下述(2)中所示的4个等级判断标准来对油性睫毛用化妆料的性能进行判定。需要说明的是,评价项目c的耐水性和卷曲效果的持续性是通过涂布6小时后的化妆料的晕染程度进行评价,以及评价项目d的卷曲效果持续性是通过涂布6小时后的卷曲状态进行评价。另外,评价项目e的温水(40℃)中的除去性I,通过将市售的棉花浸在40℃的温水(自来水)中,再用该棉花中夹住涂布后的睫毛并晕染30秒后擦去,通过肉眼观察睫毛上样品的残留量来进行评价。
(评价项目)
a.体积效果
b.卷曲效果
c.耐水性(常温)I
d.卷曲效果的持续性
e.温水(40℃)中的除去性I
(1)评价标准
(评分):(评价)
6:非常好
5:好
4:较好
3:普通
2:较差
1:差
0:非常差
(2)4个等级判定标准
(判定):(合计评分)
◎:总计46~60分
○:总计31~45分
△:总计16~30分
×:总计0~15分
(评价方法f和g)
(评价方法f和g)
关于温水(40℃)中的除去性和耐水性,除了评价项目e或c中的评价以外,还分别进行下述f或g中所示的评价。
评价方法f:耐水性(温水)Ⅱ
将市售的棉花浸在20℃的自来水中,再将涂有0.005g各个样品的“假睫毛”夹入棉花中,晕染30秒后,从假睫毛根部朝前端摩擦30次,再观察样品向棉花的转移情况,并根据下述(3)中所示的4个等级标准进行评价及判定。需要说明的是,样品向棉花的转移量通过如下方式估算:将使用充分含有卸妆乳(产品名称:Mandom公司制造,卸妆水(UruochimizuCleansing Lotion))的棉花进行与上述相同的操作时的转移量作为100%,将完全未转移的情况作为0%,通过肉眼估算大致的转移量。
评价方法g:温水(40℃)中的除去性II
将市售的棉花浸在40℃的自来水中,再用棉花夹住涂有0.005g样品的“假睫毛”,晕染30秒后,从假睫毛根部朝前端摩擦30次,观察化妆料向棉花的转移状况,以与所述(3)同样的方式推定样品向棉花的转移量,并根据下述(4)中所示的4个等级判定标准进行评价及判定。
(3)4个等级判定标准(耐水性试验)
(判定):(评价标准)
◎:10%以下
○:超过10%至50%以下
△:超过50%至90%以下
×:超过90%
(4)4个等级判定标准(温水中的除去性试验)
(判定):(评价标准)
◎:超过90%
○:超过50%至90%以下
△:超过10%至50%以下
×:10%以下
实施例1~5和比较例1~4
<油性睫毛膏>
根据下述制造程序制备表1中所示配方的睫毛膏,并且采用以下方法对令睫毛看上去变厚的化妆效果(体积效果/卷曲效果)、该化妆效果的持久性(耐水性/卷曲效果)、以及用温水除去的难易度进行感官评价。其结果也一并显示在表1中。
(制造工序)
(1)将表1中所示的(A)~(D)成分加热至约110℃,并混合均匀。
(2)将表1中所示的(E)~(H)成分添加于上述(1)中得到的混合溶液中,并混合均匀。
(3)将上述(2)中制备的混合溶液填充到容器中以形成油性睫毛膏。
[表1]
※1:商品名Creasil ID CG(THE INNOVATION COMPANY公司)
※2:商品名Rheopearl KL2(千叶制粉公司)
※3:商品名PINECRYSTAL KE-311(Harima化成公司)
※4:商品名糖蜡A-10E(第一工业制药公司)
※5:商品名S Face IS-201P(阪本药品工业公司)
※6:商品名T.I.O.(日清Oirio公司)
※7:商品名硅酮KF-96A 200 CS(信越化学工业公司)
※8:商品名EMALEX GWS-320(日本Emulsion公司)
※9:商品名X-21-5595(信越化学工业公司)
从表1的结果可知,实施例1~5的睫毛膏与比较例1~4的睫毛膏相比,具有更优异的卷曲效果、耐水性及其持续性,且不需使用睫毛膏专用的卸妆液而仅用温水即可除去。另一方面,在仅含有5%(A)成分的油溶性被膜形成剂的比较例1中,在耐水性、卷曲效果和化妆效果的持续性的方面并不令人满意,另外在含有29%油溶性被膜形成剂的比较例3和4中,在温水中的除去性的方面并不令人满意。
实施例6~9和比较例5~10
<油性睫毛膏>
通过与上述相同的制造程序制备表2中所示配方的睫毛膏,并且通过上述评价方法f和g对耐水性和温水中的除去性进行评价。其结果与配方一并表示在表2中。
[表2]
※10:商品名Uniox GT-20IS(日本油脂公司)
※11:商品名EMALEX-SWS-12(日本Emulsion公司)
※12:商品名EMALEX PEIS-6 EX(日本Emulsion公司)
※13:商品名EMALEX-GWS-304(日本Emulsion公司)
※14:商品名EMALEX RWIS-320(日本Emulsion公司)
※15:商品名EMALEX 615(日本Emulsion公司)
※16:商品名Rheodol TW-O 120 V(花王公司)
※17:商品名NIKKOL MYS-40V(日光化学公司)
由表2的结果可知,实施例6~10的睫毛膏比比较例5~10的睫毛膏具有更优异的耐水性和温水中的除去性。另一方面,在混合有HLB值为2或者6的非离子型表面活性剂的比较例5及比较例6、以及未混合非离子型表面活性剂的比较例10中,温水中的除去性不足,在混合有HLB值为12以上的非离子型表面活性剂的比较例7~9中,耐水性较差。
实施例10
<睫毛膏用基底>
使用下面所示的成分,根据以下制造工序制备睫毛膏用基底。
(制造工序)
A.将成分(1)~(14)在约110℃下加热混合并使其均匀。
B.将上述A中获得的混合溶液填充在容器中以形成睫毛膏用基底。
在使用市售的睫毛膏之前,通过将以上述方式得到的睫毛膏基底涂布在睫毛上,能够提高睫毛膏的卷曲效果、耐水性和化妆效果的持续性,另外,仅用约40℃的温水,就可以容易地将该睫毛膏用基底与睫毛膏一起除去。
工业实用性
本发明提供了一种油性睫毛用化妆料,其除了具有油性睫毛用化妆料所特有的卷曲效果、持妆性(耐水性)之外,还具有优异的温水除去性。另外,当使用这种油性睫毛用化妆料时,可以不用卸妆液而用温水即可容易地卸妆,因此卸妆效率较高。
Claims (11)
1.一种油性睫毛用化妆料,其含有:
(A)油溶性被膜形成剂3~40质量%、(B)HLB值为7~10的非离子型表面活性剂0.1~10质量%、(C)在常压下的沸点为60℃~260℃的挥发性油剂20~70质量%以及(D)不挥发性油剂0.5~30质量%,
所述(A)成分与(D)成分的比例[(A)/(D)(质量比)]为0.7/1~5.8/1,
在含有熔点为50℃以上的固体油分的情况下,该固体油分的量为10质量%以下。
2.根据权利要求1所述的油性睫毛用化妆料,其还含有(E)油性胶凝剂0.5~40质量%。
3.根据权利要求1或2所述的油性睫毛用化妆料,其还含有(F)色料0.1~20质量%。
4.根据权利要求1或2所述的油性睫毛用化妆料,其还含有(G)水5质量%以下。
5.根据权利要求1或2所述的油性睫毛用化妆料,其中,所述的熔点为50℃以上的固体油分的含量为5质量%以下。
6.根据权利要求1或2所述的油性睫毛用化妆料,其中,在含有HLB值大于10的非离子型表面活性剂、阴离子型表面活性剂、阳离子型表面活性剂或两性表面活性剂的情况下,所述HLB值大于10的非离子型表面活性剂、阴离子型表面活性剂、阳离子型表面活性剂或两性表面活性剂的含量的上限为0.5质量%。
7.根据权利要求1或2所述的油性睫毛用化妆料,其中,所述(A)成分为三甲基硅烷氧基硅酸酯、松香树脂或者小烛树脂。
8.根据权利要求1或2所述的油性睫毛用化妆料,其中,所述(B)成分为聚氧乙烯脂肪酸酯、聚氧乙烯脂肪酸甘油酯或脂肪酸聚氧乙烯烷基醚。
9.根据权利要求2所述的油性睫毛用化妆料,其中,所述(E)成分为糊精脂肪酸酯、菊糖脂肪酸酯、蔗糖脂肪酸酯、淀粉脂肪酸酯、金属皂或12-羟基硬脂酸。
10.根据权利要求1或2所述的油性睫毛用化妆料,其为睫毛膏或睫毛膏用基底。
11.一种化妆方法,其包括:使用权利要求1~10中任一项所述的油性睫毛用化妆料对睫毛进行化妆,并且用温水而不使用卸妆液将该化妆除去。
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CN1679477A (zh) * | 2004-02-03 | 2005-10-12 | 莱雅公司 | 用于角蛋白纤维浓密化妆的化妆组合物 |
JP2007039340A (ja) * | 2005-07-05 | 2007-02-15 | Kanebo Cosmetics Inc | 防腐殺菌剤及び皮膚外用組成物 |
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JP6097417B1 (ja) | 2017-03-15 |
KR101932898B1 (ko) | 2018-12-27 |
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US20190015311A1 (en) | 2019-01-17 |
CN108472229A (zh) | 2018-08-31 |
WO2017122757A1 (ja) | 2017-07-20 |
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