CN107889824A - A kind of insecticide acaricide composition - Google Patents

A kind of insecticide acaricide composition Download PDF

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Publication number
CN107889824A
CN107889824A CN201711268173.1A CN201711268173A CN107889824A CN 107889824 A CN107889824 A CN 107889824A CN 201711268173 A CN201711268173 A CN 201711268173A CN 107889824 A CN107889824 A CN 107889824A
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class
composition
active component
nachr
chemical compounds
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CN107889824B (en
Inventor
冯聪
宋玉泉
张国生
李轲轲
范晓溪
于海波
李斌
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Jiangsu Yangnong Chemical Co Ltd
Shenyang Sinochem Agrochemicals R&D Co Ltd
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Shenyang Sinochem Agrochemicals R&D Co Ltd
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    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
    • A01N57/10—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds
    • A01N57/16—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds containing heterocyclic radicals
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
    • A01N43/36—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom five-membered rings
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
    • A01N43/707—1,2,3- or 1,2,4-triazines; Hydrogenated 1,2,3- or 1,2,4-triazines
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having no bond to a nitrogen atom
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
    • A01N47/38—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the group >N—CO—N< where at least one nitrogen atom is part of a heterocyclic ring; Thio analogues thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/40—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having a double or triple bond to nitrogen, e.g. cyanates, cyanamides
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N51/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds having the sequences of atoms O—N—S, X—O—S, N—N—S, O—N—N or O-halogen, regardless of the number of bonds each atom has and with no atom of these sequences forming part of a heterocyclic ring
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
    • A01N57/10—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds
    • A01N57/14—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds containing aromatic radicals

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  • Life Sciences & Earth Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The invention belongs to field of pesticides, is related to a kind of insecticide acaricide composition.Composition contains two kinds of active components of A, B, and the ratio of weight and number between component A and the components of component B two is 1:99‑99:1；Active component A is selected from the chemical compounds I shown in following structural formula, and active component B is selected from organic phosphates, nAChR (nAChR) activator class, food refusal class, the uncoupling class of interference proton gradient influence oxidative phosphorylation, nereistoxin and blocks class, ecdysone receptor excitement class, aminobutyric acid (GABA) to gate chloride channel antagonism class, microbiology class or other class desinsection (mite) agent similar to thing, ryanodine receptor regulation class, Voltage-gated Sodium Channels；The active component A structure is as follows, and composition of the invention has the advantages that synergy is obvious, delaying drug resistance, available for preventing and treating various pests.

Description

A kind of insecticide acaricide composition
The application is the divisional application of Chinese invention patent application, and original application day is on November 26th, 2013, application number： 201310611186.X invention and created name：A kind of insecticide acaricide composition, publication number：CN 104663705A；Due to former Shen The unicity problem that auditor points out please be present, applicant proposes divisional application.
Technical field
The invention belongs to field of pesticides, is related to a kind of insecticide acaricide composition.
Background technology
Insecticide has obvious effect in terms of preventing and treating agriculture and forestry injurious insect or urban health insect.
Chinese invention patent CN101875633 discloses a kind of pyrazolyl acrylonitrile compound and its control insect pest and mite Harmful purposes, wherein compound 5 (hereinafter referred to as chemical compounds I) can be used for preventing and treating various pests, evil mite, especially have to evil mite prominent The prevention effect gone out.
Insecticide containing single-activity component, is used continuously in control of insect, easily insect is developed immunity to drugs.It is logical The insecticide for crossing two kinds of active components is compounded into blending ingredients by a certain percentage, can often improve preventive effect, reduces active ingredient Dosage, it is cost-effective, while the generation of pest resistance to insecticide can be delayed.
Although generally disclose in the prior art chemical compounds I or its homologue can be produced with other Mixture Use of Insecticides it is additional The advantages of and effect, but the technical scheme of the binary pesticide composition containing chemical compounds I has no specific disclosure.
The content of the invention
Present invention aims at a kind of insecticide acaricide composition is developed, to meet agricultural and urban health field pest control The demand that aspect is increasingly improved to insecticide effect and kind is constantly updated.
To achieve the above object, the technical solution adopted by the present invention is：
A kind of insecticide acaricide composition, composition contains two kinds of active components of A, B, between component A and the components of component B two Ratio of weight and number is 1:99-99:1；Active component A is selected from the chemical compounds I shown in following structural formula, and active component B is selected from organic Phosphorus, nAChR (nAChR) activator class, food refusal class, interference proton gradient influence the solution of oxidative phosphorylation Be coupled class, nereistoxin similar to thing, ryanodine receptor adjust class, Voltage-gated Sodium Channels block class, moulting hormone by Body excitement class, aminobutyric acid (GABA) gate chloride channel antagonism class, microbiology class or other class desinsection (mite) agent；
The active component A structure is as follows：
Described organic phosphates desinsection (mite) agent be selected from orthene (Acephate), chlopyrifos (Chlorpyifos), Rogor (Dimethoate), diazinon (Diazinon), malathion (Malation), Profenofos (Profenofos), triazole Phosphorus (Triazophos), terbufos (Terbufos) chlorfenviphos (Chlorfenvinphos), DDVP (Dichlorvos), Carbicron (Dicrotophos), dimethylvinphos (Dimethylvinphos), heptenophos (Heptenophos), Menite (Mevinphos), Azodrin (Monocrotophos), Naftalofos (Naftalofos), phosphamidon (Phosphamidon), the third worm Phosphorus (Propaphos), Ravap (Tetrachlorvinphos), phenthoate dimephenthoate cidial (Phenthoate), Acethion (Acethion), Chlorethoxyfos (Chlorethoxyfos), chlormephos (Chlormephos), disulfoton (Disulfoton), Ethodan (Ethion), phonamiphos (Ethoprophos), oxydemeton_methyl (Oxydemeton-methyl), thimet (Phoate), sulfotep (Sulfotep), fourth spy sulphur phosphorus (Terbufos), thiometon (Thiometon), Afos (Mecarbam), omethoate (Omethoate), vamidothion (Vamidothion), phoxim (Phoxin), Resistox (Coumaphos), Phosalone (Phosalone), pyraclofos (Pyraclofos), pyridaphethione (Pyridaphenthion), azinphos ethyl (Azinphos- Ethyl), azinphos-methyl (Azinphos-methyl), phosmet (Phosmet), isoxathion (Isoxathion), pyrazophos (Pyrazophos), chlorpyrifos-methyl (Chlorpyrifos-methyl), pirimiphos-methyl (Pirimiphos-methyl), fourth Yl pyrimidines phosphorus (Tebupirimfos), quinalphos (Quinalphos), methidathion (Methidathion), isazofos (Isazofos), cynock (Cyanophos), famphur (Famphur), fenifrothion (Fenitrothion), Entex (Fenthion), parathion (Parathion), parathion-methyl (Parathion-methyl), Toyodan (Prothiofos), Sulprofos (Sulprofos), Swebate (Temephos), metrifonate (Trichlorfon), phenothiazide (EPN), fenamiphos (Fenamiphos), isofenphos (Isofenphos), acephatemet (Methamidophos), propetamphos (Propetamphos), nitre Worm sulphur phosphorus, 2-dichloroethylk dimethyl phosphate (Naled) or cadusafos (Cadusafos)；
NAChR (nAChR) activator class desinsection (mite) agent is selected from Acetamiprid (Acetamiprid), thiophene Worm amine (Clothianidin), MTI-446 (Dinotefuran), imidacloprid (Imidacloprid), Nitenpyram (Nitenpyram), thiacloprid (Thiacloprid), Diacloden (Thiamethoxam), nicotine (Nicotine), flonicamid Nitrile (Sulfoxaflor), imidaclothiz (Imidaclothiz) or sulfone worm pyridine (Sulfoxaflor)；Food refusal class desinsection (mite) agent pyrrole Aphid ketone (Pymetrozine), fentin (Fentin) or the pungent salt of biguanides (Guazatine)；
Uncoupling class desinsection (mite) agent that interference proton gradient influences oxidative phosphorylation is selected from capillary (Chlorfenapyr), sulfluramid (Sulfluramid) or Tralopyril；
Nereistoxin is selected from bensultap (Bensultap), cartap similar to thing desinsection (mite) agent (Cartaphydrochloride), thiocyclam (Thiocyclam), dimehypo (Thiosultap-Sodium) or Cupric sulfate (Thiosultap-monosodium)；
Ryanodine receptor regulation class desinsection (mite) agent is selected from chlorantraniliprole (Chlorantraniliprole), cyanogen insect amide (Cyantraniliprole), fluorobenzene insect amide (Flubendiamide) or four chlorantraniliproles；
Voltage-gated Sodium Channels block class desinsection (mite) agent to be selected from indoxacarb (Indoxacarb) or metaflumizone (Metaflumizone)；
Aminobutyric acid (GABA) gate chloride channel antagonism class desinsection (mite) agent is selected from Niran (Chlordane), 5a,6,9,9a-hexahydro-6,9-methano-2,4 (Endosulfan), ethiprole (Ethiprole), ethiprole (Fipronil), acetyl worm nitrile (Acetoprole), butylene fluorine worm Nitrile (Flufiprole), Pyrafluprole or Pyriprole；
Microbiology class desinsection (mite) agent is selected from Dipel (Bacillus thuringiensis), Bacillus sphaericus (Bacillus sphaericus) or muscardine (Beauveria bassiana)；
Other class desinsection (mite) agent are selected from nimbin (Azadirachtin), ice crystal (Cryolite), boric acid (Borax), vikane (Sulfuryl fluoride), potassium antimony tartrate (Tartar emetic), phonetic worm amine (Flufenerim), Sulcofuron-sodium, Amitraz (Amitraz), Carzol (Formetanate) or jervine (Sabadilla)。
The ratio of weight and number of two kinds of active components is 1 in the composition of the present invention:99-99:1.
The active component A is chemical compounds I, and active component B is preferably Profenofos；The ratio of weight and number of two kinds of active components For 1:50-50:1；
The active component A is chemical compounds I, and active component B is preferably indoxacarb；The ratio of weight and number of two kinds of active components For 10:1-50:1；
The active component A is chemical compounds I, and active component B is preferably imidacloprid, Diacloden, capillary, ethiprole, poison Dead tick, Hostathion or Acetamiprid；The ratio of weight and number of two kinds of active components is 1:20-20:1；
The active component A is chemical compounds I, and active component B is preferably pymetrozine；The ratio of weight and number of two kinds of active components For 1:20-2:1.
The composition of the present invention can be in that finished product preparation form provides.Therefore, present invention additionally comprises a kind of dosage form Insecticides.Using composition as active component, be made as needed missible oil, suspending agent, water-dispersible granules, aqueous emulsion, Soluble liquid, wettable powder, oil-suspending agent etc..The cumulative amount of the active component of composition is in 0.5%- in preparation Between 95%, preferably cumulative amount is between 1%-85%.The content of active component depends on independent in the composition of the present invention Amount of application during use, also depend on mixed ratio and synergistic effect degree.The optimum range of active component content is according to composition Preparation type and it is different.
The preparation of the composition finished product preparation of the present invention can be prepared by common processing method, i.e., by active material and liquid After carrier (solvent) or solid carrier mixing, one or more of surfactants such as emulsifying agent, dispersant, wetting agent, viscous is added Mixture, stabilizer and defoamer etc..Contain at least one carrier and at least one surfactant in usual composition.Various In the case of, it should be ensured that present composition active component is uniformly distributed.
Missible oil usually contains 10~50% active component, and 2~20% emulsifying agents, 0~20% other additives are for example Stabilizer, bleeding agent etc., and solvent (also containing cosolvent if necessary).
Suspending agent generally needs to be sanded, to obtain stable non-deposited flowable product.Usually contain 5 in suspending agent~ 75% active component, 5~15% dispersants, 4~10% antifreezing agents, 0~10% other additives for example defoamer, preservative, Stabilizer, bleeding agent and thickener, and liquid-carrier surplus.
Water-dispersible granules are usually made 10~100 international standard sieve mesh (1.676~0.152mm) particle, can pass through It is prepared by extruding, dipping or Spray granulation method.Usual water-dispersible granules contain 0.5~75% active component and 5~20% Surfactant such as stabilizer, wetting dispersing agent, disintegrant and adhesive, and inert carrier surplus.
Wettable powder usually contains 10~85% active component, in addition to solid inert carrier, usually contain 3~ 10% dispersant, 0~10% stabilizer and (or) other additives, such as bleeding agent or sticker can also be contained.
Aqueous emulsion is to mix to form oil phase by active compound, organic solvent, surfactant；Water, antifreezing agent are mixed, Into homogeneous aqueous phase.With high-shear emulsion machine high speed shear oil phase, while aqueous phase is slowly added into oil phase, usual active ingredient 1~60%, surfactant 5~20%, antifreezing agent 2~10%, water surplus.
Microemulsion is to mix active compound, organic solvent, surfactant, water, into homogeneous aqueous phase.Generally have Imitate composition 1~50%, surfactant 10~40%, antifreezing agent 2~10%, water surplus.
Soluble liquid is to mix active component, organic solvent, surfactant, into transparent and homogeneous liquid. Usual active ingredient 1~50%, surfactant 6~20%, organic solvent surplus.
Water dispersible oil suspending agent is that active component, surfactant, oil based vehicle are added in sand mill and be sanded, until grain Footpath is qualified, usual active ingredient 2~60%, surfactant 6~20%, oil based vehicle surplus.
Aqueous dispersion liquid and emulsion are (missible oil, wettable powder or concentrate as the present invention is diluted with water obtain Composition) it is also within the scope of the invention.Above-mentioned emulsion can be water-in-oil type or oil-in-water type, can have thick Paste-like consistency.
The preparation of the composition finished product preparation of the present invention can use that well known to those skilled in the art (liquid is solid Body) carrier and various auxiliary agents.Such as include but is not limited to following all kinds of materials.
Suitable liquid-carrier or solvent can be water, various aromatic hydrocarbons, aliphatic hydrocarbon, ketone, ethers etc., such as toluene, diformazan Benzene, acetone, cyclohexanone, acetonitrile, benzene, hexamethylene, isopropanol, ethylene glycol, sorbierite, methanol, ethanol, butanol, dimethyl formyl Amine, dimethyl sulfoxide (DMSO), N- methyl-pyrrolidons, tributyl phosphate, methyl iso-butyl ketone (MIBK), naphthalane, machine oil, petroleum ether, oleic acid first One or more in ester, methylated soya oil or the molten fiber of methyl etc..The mixture of different liquids is often what is be applicable.
Suitable solid carrier includes natural or synthesis clay and silicate, includes suitable for the solid carrier of pulvis The White Carbon black that naturally occurs, rock dust, chalk, quartz, clay, montmorillonite, sodium sulphate, white carbon, silica, diatom Soil, float stone, gypsum, talcum, bentonite, kaolin, attapulgite, precipitated calcium carbonate, clay and the mineral matter ground of synthesis (such as microdispersed silicic acid or aluminum oxide).Suitable particulate vector include broken and classification natural rock such as calcite, Marble, float stone, sepiolite and dolomite and the synthesis particle made of the powder of organic matter and inorganic matter.
Suitable co-solvents are methanol, phenol, isoamyl alcohol, dimethyl sulfoxide (DMSO), tributyl phosphate, ethyl acetate, butanone, diformazan One in base formamide, dimethyl sulfoxide (DMSO), N- methyl-pyrrolidons, methyl oleate, methyl iso-butyl ketone (MIBK), the molten fiber of methyl etc. Kind is several.
Suitable emulsifying agent can be ethoxylated castor oil, polyoxyethylene (n20) phenethyl phenolic group oleic acid ester, alkyl virtue Base polyoxyethylene poly-oxygen propylene aether, alkylaryl formaldehyde resin APEO, triphenyl vinyl phenol polyoxyethylene (n20) ether phosphorus It is acidified triethanolamine salt, castor oil polyoxyethylene ether, alkyl vinyl aryl phenyl ether (YUS-SC3), diphenyl phenolic group polyoxy second Alkene (n18) ether formaldehyde condensation products, the different thionic acid calcium of oleic acid, agriculture breast AEO-3, agriculture breast 0201B, agriculture breast 0203B, agriculture breast T-20, agriculture breast T-85, agriculture breast S-80, agriculture breast 507#, agriculture breast 100#, agriculture breast 36#, agriculture breast 500#, agriculture breast 600#, Nongru-700 #, agriculture breast 1601#, Agriculture breast OX-2681, agriculture breast OX-8686, agriculture breast 2201#, agriculture breast NP-7, agriculture breast OX-635, agriculture breast OX-653, agriculture breast YUS- D935, agriculture breast YUS-CP120, agriculture breast YUS-A41B, agriculture breast YUS-D3020, agriculture breast NP-10, agriculture breast NP-15 etc..
Suitable dispersant can be the sodium salt, poly- of sodium lignin sulfonate, calcium lignosulfonate, alkyl naphthalene sulfonic acid condensation polymer Carboxylate dispersants GY-D800, polycarboxylate salt dispersant GY-D04, polycarboxylate salt dispersant GY-D02, naphthalene sulfonate formaldehyde contracting Compound, naphtholsulfonic acid formaldehyde condensation products sodium salt, condensation compound of methyl naphthalene sulfonic acid and formaldehyde, alkyl-diethylene glycol ether-sodium sulfonate, N- first Base-oleoyl-sodium taurocholate, detergent LS, methanonaphthalene sodium sulfonate, oleic acid methylaminoethyl sodium sulfonate, epoxidized polyether, point Powder SP-28F, dispersant SP-SC3, up to profit dispersant D909S, alkylaryl APEO, dodecyl polyoxyethylene Ether phosphate, polyaryl phenol polyethenoxy ether, to tertbutyl ether, piperonyl butoxide, alkyl amide taurate, alkyl naphthalene sulfonic acid Salt formaldehyde condensation products (NNO), ethylene oxide-propylene oxide block copolymer APES formaldehyde condensation product, N- first Base-fatty acyl group-sodium taurocholate, APES formaldehyde condensation product, pull open powder, dibutyl naphthalenesulfonic acid formaldehyde condensation Thing, alkylphenol-polyethenoxy base ether formaldehyde condensation products sulfate, alkylphenol-polyethenoxy based phosphates, dispersant YUS- NV1203, dispersant YUS-NV1420, dispersant YUS-WG4, dispersant YUS-TG285, dispersant YUS-WP1, dispersant YUS-110, dispersant YUS-EP60P, dispersant YUS-CH1100, etc..
Suitable wetting agent can be sodium sulphate, Morwet EFW, wetting agent SP-SC3266, wetting agent YUS-LXC, profit Humectant YUS-204, isopropyl naphthalene sulfonate, alkylol polyoxyethylene base ether sodium sulfate, the contracting of alkylphenol-polyethenoxy base ether formaldehyde Compound sulfate, sldium lauryl sulfate, neopelex, lauryl sodium sulfate, calcium dodecyl benzene sulfonate, alkyl Sodium naphthalene sulfonate aliphatic alcohol polyethenoxy base ether, alkylphenol-polyethenoxy base ether etc..
Suitable thickener can be synthesis (such as carbonyl methylol alcohol, polyvinyl alcohol, polyvinyl acetate) or natural water Soluble polymer (such as xanthans, gelatin, gum arabic, polyvinylpyrrolidone, aluminium-magnesium silicate, polyvinyl alcohol, poly- second two Alcohol, phenolic resin, shellac, methylcellulose, soluble starch, carboxymethyl cellulose and sodium alginate etc.), with powder, particle Or latex form is added in preparation.
Suitable defoamer is bubble enemy, silicone, C8-10Fatty alcohol, phosphoric acid ester, C10-20Saturated fat acids (such as last of the ten Heavenly stems Acid) and acid amides etc..
Suitable adhesive can be polyvinyl alcohol, polyvinyl acetate, xanthans, gelatin, carboxymethyl cellulose and sea Mosanom etc..
Aerosol can be made during for preventing and treating city insect, it is necessary to add propellant wherein, bait formulation can also be made Composition, in addition to containing active component, also containing one or more foodstuffs for being suitable to insect's food-taking, optional attractant and Optional wetting agent.
Present invention additionally comprises the present composition to be prepared into Insecticiding-miticiding preparation control agriculture and forestry injurious insect or urban health insect Purposes.Specifically, it is suitable for preventing and treating a variety of important agricultural pests such as mythimna separata, beet armyworm, bollworm, cutworm, wild cabbage night Moth, apple skin worm, rice leaf roller, corn borer, striped rice borer, diamondback moth, cabbage caterpillar, fall webworms, tent caterpillar, dance poison Moth, Asiatic migrotory locust, subterranean pest-insect, leaf miner, liriomyza bryoniae, aphid, cotton Tetranychus cinnabarinus, vegetables tetranychid, tetranychus viennensis, citrus are complete Pawl mite, phyllocoptruta oleivora, apple tetranychus, Tetranychus urticae, goitre mite, flour mite etc., city insect such as termite, blattaria, ant, flies, mosquito Class etc..For fruit tree such as apple, pears, citrus, lichee etc., Cereal such as wheat, rice etc., beans such as soybean, Kidney bean etc., cotton Flower, vegetables such as wild cabbage, cauliflower, Chinese cabbage, rape, tomato, capsicum and flowers.During for preventing and treating city insect, it can be used for Family, various public places, office space, and the trees of termite damage, dykes and dams etc. occur.
Present invention additionally comprises a kind of method for controlling insect pest, can impose on the present composition with effective dose needs to control Insect or its growth medium on.The more suitable effective dose generally selected is 10 grams to 500 grams of per hectare, preferably effectively Dosage is 15 grams to 100 grams of per hectare.
In addition, the composition for showing the present invention through indoor biological determination of activity has synergistic effect.For example, chemical compounds I with Ethiprole, capillary, Diacloden, imidacloprid, Acetamiprid, chlopyrifos, Hostathion are 1:20-20:Tetranychus cinnabarinus is shown in the range of 1 Certain synergistic effect is shown, chemical compounds I is with pymetrozine 1:20-2:More preferable increasing is shown in the range of 1 to Tetranychus cinnabarinus Effect acts on, and chemical compounds I is with indoxacarb 10:1-50:In the range of 1 and chemical compounds I and Profenofos are 1:50-50:To Zhu in the range of 1 Sand tetranychid shows certain synergistic effect.
The invention has the advantages that：
1. the composition of the present invention shows obvious synergistic effect in certain ratio range, the compound pair is improved The prevention effect of insect.
2. the present composition reduces the dosage of compound in the application, so as to reduce use cost, environment is reduced Pollution.
It is anti-with it the problem of in the absence of cross resistance 3. the mechanism of action of each active ingredient is different in the present composition The generation of pest resistance to insecticide can be delayed by controlling insect, and improve the prevention effect of antagonism population.
Embodiment
Specific examples below is used to the present invention be further described, but the present invention is only limitted to absolutely not these examples.It is real Each component percentage composition or proportioning in example is applied to be by weight.Active component in each formula is calculated with effective content, while group In compound prepared by the available usual manner of each material.
Formulation Example
The preparation of embodiment 1,21% Hostathion chemical compounds I missible oil
By recipe requirements, be separately added into 1 part of Hostathion, 20 parts of chemical compounds Is, 8 parts of agriculture breast OX-2681,1 part of agriculture breast 1601#, 5 parts of agriculture breast 600#, 10 parts of dimethylformamides, 5 parts of methanol, dimethylbenzene are complemented in 100% addition mixing kettle, are stirred It is even, dissolved by heating if necessary with hot bath, you can obtain 21% Hostathion chemical compounds I missible oil.
Can also be by the organic phosphates described by Hostathion alternative costs specification, nAChR (nAChR) activator class, food refusal class, interference proton gradient influence the uncoupling class of oxidative phosphorylation, nereistoxin similar to thing, fish Buddhist nun's fourth regulation class, Voltage-gated Sodium Channels block class, ecdysone receptor excitement class, aminobutyric acid (GABA) door One kind in chloride channel antagonism class, microbiology class, other class desinsection (mite) agent is controlled, forms 21% new active component B Chemical compounds I missible oil.
The preparation of embodiment 2,42% imidacloprid chemical compounds I wettable powder
By recipe requirements, by 40 parts of imidacloprids, 2 parts of chemical compounds Is, 2 parts of lauryl sodium sulfate, 3 parts of methanonaphthalene sulfonic acid Sodium, 4 parts of naphtholsulfonic acid formaldehyde condensation products sodium salts, 4 parts of condensation compound of methyl naphthalene sulfonic acid and formaldehyde, 5 parts of White Carbon blacks, precipitated calcium carbonates are supplied It is sufficiently mixed to 100%, after ultra-fine pulverizer disintegrating, that is, obtains 42% imidacloprid chemical compounds I wettable powder.
Can also be by the organic phosphates described by imidacloprid alternative costs specification, nAChR (nAChR) activator class, food refusal class, interference proton gradient influence the uncoupling class of oxidative phosphorylation, nereistoxin similar to thing, fish Buddhist nun's fourth regulation class, Voltage-gated Sodium Channels block class, ecdysone receptor excitement class, aminobutyric acid (GABA) door One kind in chloride channel antagonism class, microbiology class, other class desinsection (mite) agent is controlled, forms 42% new active component B Chemical compounds I wettable powder.
The preparation (1 of embodiment 3,40% Diacloden chemical compounds I wettable powder:1)
By recipe requirements, by 20 parts of Diaclodens, 20 parts of chemical compounds Is, 2 parts of neopelexes, 2 parts of pull open powders, 4 parts Dibutyl naphthalenesulfonic acid formaldehyde condensation products, 4 parts of sodium lignin sulfonates, 5 parts of White Carbon blacks, diatomite complement to 100% and are sufficiently mixed, warp After ultra-fine pulverizer disintegrating, you can obtain 40% Diacloden chemical compounds I wettable powder.
Can also be by the organic phosphates described by Diacloden alternative costs specification, nAChR (nAChR) activator class, food refusal class, interference proton gradient influence the uncoupling class of oxidative phosphorylation, nereistoxin similar to thing, fish Buddhist nun's fourth regulation class, Voltage-gated Sodium Channels block class, ecdysone receptor excitement class, aminobutyric acid (GABA) door One kind in chloride channel antagonism class, microbiology class, other class desinsection (mite) agent is controlled, forms 40% new active component B Chemical compounds I wettable powder.
The preparation of embodiment 4,11% imidacloprid chemical compounds I aqueous emulsion
By recipe requirements, by 10 parts of imidacloprids, 1 part of chemical compounds I, 5 parts of triphenyl vinyl phenol polyoxyethylene (n20) ether phosphoric acid Change triethanolamine salt, 6 parts of agriculture breast OX-2681,2 parts of agriculture breast 1601#, 8 parts of dimethylformamides, 15 parts of dimethylbenzene and add mixing kettle In, it is stirred, makes to be dissolved into homogeneous oil phase, under high velocity agitation, excess water (complementing to 100%) is added to oil phase, i.e., It can obtain 11% imidacloprid chemical compounds I aqueous emulsion of favorable dispersibility.
Can also be by the organic phosphates described by imidacloprid alternative costs specification, nAChR (nAChR) activator class, food refusal class, interference proton gradient influence the uncoupling class of oxidative phosphorylation, nereistoxin similar to thing, fish Buddhist nun's fourth regulation class, Voltage-gated Sodium Channels block class, ecdysone receptor excitement class, aminobutyric acid (GABA) door One kind in chloride channel antagonism class, microbiology class, other class desinsection (mite) agent is controlled, forms 11% new active component B Chemical compounds I missible oil.
The preparation (1 of embodiment 5,20% ethiprole chemical compounds I aqueous emulsion:1)
By recipe requirements, by 10 parts of ethiproles, 10 parts of chemical compounds Is, 6 parts of agriculture breasts, 2201,4 parts of agriculture breast OX-8686,2 parts of agricultures Newborn 1601#, 1 part of Nongru-700 #, 8 parts of N- methyl-pyrrolidons, 3 parts of tributyl phosphates, 8 parts of dimethylbenzene are added in mixing kettle, are stirred Mixing is mixed, makes to be dissolved into homogeneous oil phase, under high velocity agitation, excess water (complementing to 100%) is added to oil phase, you can obtain 20% ethiprole chemical compounds I aqueous emulsion of favorable dispersibility.
Can also be by the organic phosphates described by ethiprole alternative costs specification, nAChR (nAChR) activator class, food refusal class, interference proton gradient influence the uncoupling class of oxidative phosphorylation, nereistoxin similar to thing, fish Buddhist nun's fourth regulation class, Voltage-gated Sodium Channels block class, ecdysone receptor excitement class, aminobutyric acid (GABA) door One kind in chloride channel antagonism class, microbiology class, other class desinsection (mite) agent is controlled, forms 20% new active component B Chemical compounds I aqueous emulsion.
Embodiment 6,60% ethiprole chemical compounds I water-dispersible granules (1:1)
By recipe requirements, by 30 parts of ethiproles, 30 parts of chemical compounds Is, 7 parts of dispersant YUS-WG4,4 parts of alkyl naphthalene sulfonic acid contractings The sodium salt of polymers, 1.5 parts of lauryl sodium sulfate, 8 parts of sodium sulphate, 6 portions of soluble starches, bentonite complement to 100% and are added in Together, co-grinding is carried out, then after adding water to mediate, adds in the comminutor equipped with certain specification screen cloth and is granulated.Then Again through drying, screening (pressing screen cloth scope), you can obtain 60% ethiprole chemical compounds I water-dispersible granules.
Can also be by the organic phosphates described by ethiprole alternative costs specification, nAChR (nAChR) activator class, food refusal class, interference proton gradient influence the uncoupling class of oxidative phosphorylation, nereistoxin similar to thing, fish Buddhist nun's fourth regulation class, Voltage-gated Sodium Channels block class, ecdysone receptor excitement class, aminobutyric acid (GABA) door One kind in chloride channel antagonism class, microbiology class, other class desinsection (mite) agent is controlled, forms 60% new active component B Chemical compounds I water-dispersible granules.
Embodiment 7,44% imidacloprid chemical compounds I water-dispersible granules
By recipe requirements, by 4 parts of imidacloprids, 40 parts of chemical compounds Is, 5 parts of polycarboxylate salt dispersant GY-D800,5 parts of lignin Sodium sulfonate, 3 parts of dibutyl naphthalenesulfonic acid formaldehyde condensation products, 3 parts of sodium carboxymethylcelluloses, attapulgite complement to 100% and are added in one Rise, carry out co-grinding, then after adding water to mediate, add in the comminutor equipped with certain specification screen cloth and be granulated.Then again Through drying, screening (pressing screen cloth scope), you can obtain 44% imidacloprid chemical compounds I water-dispersible granules.
Can also be by the organic phosphates described by imidacloprid alternative costs specification, nAChR (nAChR) activator class, food refusal class, interference proton gradient influence the uncoupling class of oxidative phosphorylation, nereistoxin similar to thing, fish Buddhist nun's fourth regulation class, Voltage-gated Sodium Channels block class, ecdysone receptor excitement class, aminobutyric acid (GABA) door One kind in chloride channel antagonism class, microbiology class, other class desinsection (mite) agent is controlled, forms 44% new active component B Chemical compounds I water-dispersible granules.
Embodiment 8,21% imidacloprid chemical compounds I suspending agent
By recipe requirements, by 1 part of imidacloprid, 20 parts of chemical compounds Is, 4 parts of dispersant SP-28F, 2 parts of alkylnaphthalene sulfonate first Aldehyde condensate, 2 parts of agriculture breast 0201B, 0.1 part of xanthans, 0.3 part of white carbon, 5 parts of ethylene glycol, 100% is complemented to water, successively It is added in blending tank and mixes, first passes through high shear and carry out coarse crushing, homogenize, be then pumped into sand mill and carry out fine grinding, use The granularity of material is sanded in particles distribution instrument detection, after particle diameter reaches standard requirement, filtering, you can obtain 21% imidacloprid The suspending agent of compound I.
Can also be by the organic phosphates described by imidacloprid alternative costs specification, nAChR (nAChR) activator class, food refusal class, interference proton gradient influence the uncoupling class of oxidative phosphorylation, nereistoxin similar to thing, fish Buddhist nun's fourth regulation class, Voltage-gated Sodium Channels block class, ecdysone receptor excitement class, aminobutyric acid (GABA) door One kind in chloride channel antagonism class, microbiology class, other class desinsection (mite) agent is controlled, forms 21% new active component B Chemical compounds I suspending agent.
Example 9,30% Diacloden chemical compounds I suspending agent (1:1)
By recipe requirements, by 15 parts of Diaclodens, 15 parts of chemical compounds Is, 4 parts of dispersant SP-SC3,1 part of Morwet EFW, 4 The sodium salt of part alkyl naphthalene sulfonic acid condensation polymer, 1 part of agriculture breast 1601#, 0.1 part of xanthans, 0.2 part of white carbon, 5 parts of ethylene glycol, use water 100% is complemented to, is added sequentially to mix in blending tank, high shear is first passed through and carries out coarse crushing, homogenizes, be then pumped into sand milling Fine grinding is carried out in machine, the granularity that material is sanded is detected with particles distribution instrument, after particle diameter reaches standard requirement, filtering, you can To 30% Diacloden chemical compounds I suspending agent.
Can also be by the organic phosphates described by Diacloden alternative costs specification, nAChR (nAChR) activator class, food refusal class, interference proton gradient influence the uncoupling class of oxidative phosphorylation, nereistoxin similar to thing, fish Buddhist nun's fourth regulation class, Voltage-gated Sodium Channels block class, ecdysone receptor excitement class, aminobutyric acid (GABA) door One kind in chloride channel antagonism class, microbiology class, other class desinsection (mite) agent is controlled, forms 30% new active component B Chemical compounds I suspending agent (1:1).
Embodiment 10,21% capillary chemical compounds I microemulsion
By recipe requirements, by 1 part of capillary, 20 parts of chemical compounds Is, 4 parts of alkyl vinyl aryl phenyl ethers, 2 parts of agriculture breast 100#, 6 parts of diphenyl phenolic group polyoxyethylene (n18) ether formaldehyde condensation products, 6 parts of agriculture breast OX-2681,10 parts of N- methyl-pyrrolidons, 5 parts Tributyl phosphate is added together, and it is dissolved into homogeneous oil phase, and surplus complements to 100% with water, under high velocity agitation, by aqueous phase It is added to oil phase or oil phase is added to aqueous phase, forms 21% capillary chemical compounds I microemulsion of favorable dispersibility.
Can also be by the organic phosphates described by capillary alternative costs specification, nAChR (nAChR) activator class, food refusal class, interference proton gradient influence the uncoupling class of oxidative phosphorylation, nereistoxin similar to thing, fish Buddhist nun's fourth regulation class, Voltage-gated Sodium Channels block class, ecdysone receptor excitement class, aminobutyric acid (GABA) door One kind in chloride channel antagonism class, microbiology class, other class desinsection (mite) agent is controlled, forms 21% new active component B Chemical compounds I microemulsion.
Embodiment 11,21% imidacloprid chemical compounds I soluble concentrate
By recipe requirements, by 1 part of imidacloprid, 20 parts of chemical compounds Is, 5 parts of agriculture breast 0201B, 6 parts of agriculture breast OX-2681,2 parts of agricultures Newborn 1601#, 3 parts of agriculture breast 500#, 4 parts of tributyl phosphates, 6 parts of methyl iso-butyl ketone (MIBK)s, 10 parts of acetonitriles, the molten fiber of methyl complement to 100% is well mixed, is dissolved by heating if necessary with hot bath, 21% imidacloprid chemical compounds I soluble concentrate can be made.
Can also be by the organic phosphates described by imidacloprid alternative costs specification, nAChR (nAChR) activator class, food refusal class, interference proton gradient influence the uncoupling class of oxidative phosphorylation, nereistoxin similar to thing, fish Buddhist nun's fourth regulation class, Voltage-gated Sodium Channels block class, ecdysone receptor excitement class, aminobutyric acid (GABA) door One kind in chloride channel antagonism class, microbiology class, other class desinsection (mite) agent is controlled, forms 21% new active component B Chemical compounds I soluble concentrate.
Embodiment 12,21% Diacloden chemical compounds I water dispersible oil suspending agent
By recipe requirements, by 1 part of Diacloden, 20 parts of chemical compounds Is, 3 parts of agriculture breast S-80,5 parts of agriculture breast 0201B, 4 parts of agriculture breasts 500#, 3 parts of agriculture breast 1601#, 3 parts of white carbons, 15 parts of methyl oleates, methylated soya oil complement to 100% and are added sequentially to mix Close and mixed in tank, first pass through high shear and carry out coarse crushing, homogenize, be then pumped into sand mill and carry out fine grinding, use size distribution The granularity of material is sanded in instrument detection, after particle diameter reaches standard requirement, filtering, you can obtain 21% Diacloden chemical compounds I water Dispersed oil suspending agent.
Can also be by the organic phosphates described by Diacloden alternative costs specification, nAChR (nAChR) activator class, food refusal class, interference proton gradient influence the uncoupling class of oxidative phosphorylation, nereistoxin similar to thing, fish Buddhist nun's fourth regulation class, Voltage-gated Sodium Channels block class, ecdysone receptor excitement class, aminobutyric acid (GABA) door One kind in chloride channel antagonism class, microbiology class, other class desinsection (mite) agent is controlled, forms 21% new active component B Chemical compounds I water dispersible oil suspending agent.
Indoor biological determination of activity
Synergism determination of composition of the embodiment 13 containing chemical compounds I to Tetranychus cinnabarinus
For trying object：Tetranychus cinnabarinus (Tetranychus cinnabarinus Boisduval), into mite, indoor feeding Sensitive strain.
Test condition：Temperature：24~26 DEG C, humidity：RH 60%, illumination：L:D=14:10
Test method：Using pot-spraying method.The potted plant Kidney bean seedling of sizing (2 true leaves) of hot-house culture, stays a piece of true leaf, Mite 40-60 heads are connected into thereon.Examination material is handled with decoction using Airbrush spray-on processes, dried in the shade naturally.Blank control is first handled, Then aforesaid operations are repeated from low to high according to experimental design dosage and often handles 4 repetitions.Test worm after processing is placed in In observation ward, routine observation test worm response situation, number of dead and live insects is investigated after 72h, calculate the death rate.
Evaluation uses Bliss methods, and this method is one of classical way for evaluating mixture effect.Bliss proposes according to it Independent joint action concept thinks, theoretical death rate P during Mixture Use of Insecticides can be calculated with following formula：
P=Pm+Pn(1-Pm)
PmFor the death rate (%) of the first active component target when concentration is m；PnIt is for the second active component concentration The death rate (%) of target during n.
If the actual of two kinds of active component targets after being mixed with finite concentration is more than theoretical death rate P, Judge that two kinds of active components are used in mixed way with synergistic effect in the case where setting concentration, it is on the contrary then be antagonism.
It the results are shown in Table 1.
10 kinds of medicaments such as the chemical compounds I of table 1 and chlopyrifos are used in mixed way the synergism determination to Tetranychus cinnabarinus into mite

Claims (8)

  1. A kind of 1. insecticide acaricide composition, it is characterised in that：Composition contains two kinds of active components of A, B, component A and component B two Ratio of weight and number between component is 1:99-99:1；
    Active component A is selected from the chemical compounds I shown in following structural formula, and active component B is selected from nAChR (nAChR) activator class desinsection (mite) agent；
    The active component A structure is as follows：
  2. 2. according to the composition described in claim 1, it is characterised in that：
    In the component B nAChR (nAChR) activator class desinsection (mite) agent be selected from Acetamiprid, clothianidin, MTI-446, imidacloprid, Nitenpyram, thiacloprid, Diacloden, nicotine, sulfoxaflor, send worm pyridine, imidaclothiz or sulfone worm pyridine.
  3. 3. according to the composition described in claim 2, it is characterised in that：The ratio of weight and number of two kinds of active components of A, B is 1:20-20:1。
  4. 4. according to the composition described in claim 3, it is characterised in that：The active component A is chemical compounds I, and active component B is selected From imidacloprid, Diacloden or Acetamiprid；The ratio of weight and number of two kinds of active components is 1:20-20:1.
  5. 5. according to the composition described in claim 1, it is characterised in that：Composition can be configured to missible oil, suspending agent, moisture and dissipate Property granula, aqueous emulsion, microemulsion, soluble concentrate, wettable powder or water dispersible oil suspending agent.
  6. 6. according to the composition described in claim 5, it is characterised in that：The cumulative amount of active component is in 0.5%- in composition Between 95%.
  7. 7. according to the composition described in claim 6, it is characterised in that：The cumulative amount of active component is in 1%- in composition Between 85%.
  8. A kind of 8. application of insecticide acaricide composition according to described in claim 1, it is characterised in that：The composition is used to make Standby insecticidal/acaricidal agent, for controlling agricultural pests or urban health insect.
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CN107711876A (en) * 2017-11-25 2018-02-23 惠州市无龄康态健康科技有限公司 A kind of composition pesticide containing sulfur-phosphor and nitrile pyrrole mite ester
CN108124880A (en) * 2018-02-05 2018-06-08 广东省农业科学院植物保护研究所 The Pesticidal combination of the mite nitrile of azoles containing second and mono-amitraz hydrochloride
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