CN104663679B - A kind of insecticide acaricide composition containing macrolide insecticide - Google Patents
A kind of insecticide acaricide composition containing macrolide insecticide Download PDFInfo
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- CN104663679B CN104663679B CN201310610965.8A CN201310610965A CN104663679B CN 104663679 B CN104663679 B CN 104663679B CN 201310610965 A CN201310610965 A CN 201310610965A CN 104663679 B CN104663679 B CN 104663679B
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Abstract
The invention belongs to field of pesticides, is related to a kind of insecticide acaricide composition containing macrolide insecticide.Composition contains two kinds of active components of A, B, and the ratio of weight and number between component A and the components of component B two is 1:99‑99:1;Active component A is selected from the chemical compounds I shown in following structural formula, and active component B kills insects mites agent selected from macrolides;The active component A structure is as follows, and composition of the invention has the advantages that synergy is obvious, delaying drug resistance, available for preventing and treating various pests.
Description
Technical field
The invention belongs to field of pesticides, is related to a kind of insecticide acaricide composition containing macrolide insecticide.
Background technology
Insecticide has obvious effect in terms of preventing and treating agriculture and forestry injurious insect or urban health insect.
Chinese invention patent CN101875633 discloses a kind of pyrazolyl acrylonitrile compound and its control insect pest and mite
Harmful purposes, wherein compound 5(Hereinafter referred to as chemical compounds I)Available for preventing and treating various pests, evil mite, especially have to evil mite prominent
The prevention effect gone out.
Insecticide containing single-activity component, is used continuously in control of insect, easily insect is developed immunity to drugs.It is logical
The insecticide for crossing two kinds of active components is compounded into blending ingredients by a certain percentage, can often improve preventive effect, reduces active ingredient
Dosage, it is cost-effective, while the generation of pest resistance to insecticide can be delayed.
Although generally disclose in the prior art chemical compounds I or its homologue can be produced with other Mixture Use of Insecticides it is additional
The advantages of and effect, but the technical scheme of the binary pesticide composition containing chemical compounds I has no specific disclosure.
The content of the invention
Present invention aims at a kind of insecticide acaricide composition containing macrolide insecticide is developed, to meet agricultural
With the demand increasingly improved to insecticide effect in terms of the pest control of urban health field and kind is constantly updated.
To achieve the above object, the technical solution adopted by the present invention is:
A kind of insecticide acaricide composition containing macrolide insecticide, composition contain two kinds of active components of A, B, group
The ratio of weight and number being divided between A and the components of component B two is 1:99-99:1;Active component A is selected from the chemical combination shown in following structural formula
Thing I, active component B kill insects mites agent selected from macrolides;
The active component A structure is as follows,
Described macrolides kills insects mites agent and is selected from AVM (Abamenctin), emamectin benzoate benzene first
Hydrochlorate (Emamectin benzoate), pleocidin (Spinosad), tetranactin (Tetranactin), ivermectin
(Ivermectin), ethyl pleocidin (Spinetoram), thunder cuticulin (Lepimectin), emaricin
(Emamectin) or milbemectin (Milbemectin), Carvacrol, Doramectin, Eprinomenctin,
Milbemycinoxime, Moxidectin, Sanguinarine or Selamectin etc..
The ratio of weight and number of two kinds of active components is 1 in the composition of the present invention:99-99:1.
The active component A is chemical compounds I, and active component B is selected from pleocidin;The ratio of weight and number of two kinds of active components
For 1:50-50:1;
The active component A is chemical compounds I, and active component B is selected from AVM;The ratio of weight and number of two kinds of active components
For 10:1-20:1.
The active component A is chemical compounds I, and active component B is selected from emamectin-benzoate;Two kinds of activearms
The ratio of weight and number divided is 20:1.
The composition of the present invention can be in that finished product preparation form provides.Therefore, present invention additionally comprises a kind of dosage form
Insecticides.Using composition as active component, be made as needed missible oil, suspending agent, water-dispersible granules, aqueous emulsion,
Soluble concentrate, wettable powder, water dispersible oil suspending agent etc..The cumulative amount of the active component of composition exists in preparation
Between 0.5%-95%, preferably cumulative amount is between 1%-85%.The content of active component depends on single in the composition of the present invention
Amount of application when solely using, also depends on mixed ratio and synergistic effect degree.The optimum range of active component content is according to combination
The preparation type of thing and it is different.
The preparation of the composition finished product preparation of the present invention can be prepared by common processing method, i.e., by active material and liquid
Carrier(Solvent)Or after solid carrier mixing, add one or more of surfactants such as emulsifying agent, dispersant, wetting agent, viscous
Mixture, stabilizer and defoamer etc..Contain at least one carrier and at least one surfactant in usual composition.Various
In the case of, it should be ensured that present composition active component is uniformly distributed.
Missible oil usually contains 10~50% active component, 2~20% emulsifying agents, and 0~20% other additives are for example stablized
Agent, bleeding agent etc., and solvent(Also contain cosolvent if necessary).
Suspending agent generally needs to be sanded, to obtain stable non-deposited flowable product.Usually contain 5 in suspending agent~
75% active component, 5~15% dispersants, 4~10% antifreezing agents, 0~10% other additives such as defoamer, preservative, stably
Agent, bleeding agent and thickener, and liquid-carrier surplus.
Water-dispersible granules are usually made 10~100 international standard sieve mesh(1.676~0.152mm)Particle, it can pass through
It is prepared by extruding, dipping or Spray granulation method.Usual water-dispersible granules contain 0.5~75% active component and 5~20%
Surfactant such as stabilizer, wetting dispersing agent, disintegrant and adhesive, and inert carrier surplus.
Wettable powder usually contains 10~85% active component, in addition to solid inert carrier, usually contains 3~10%
Dispersant, can also containing 0~10% stabilizer and(Or)Other additives, such as bleeding agent or sticker.
Aqueous emulsion is to mix to form oil phase by active compound, organic solvent, surfactant;Water, antifreezing agent are mixed,
Into homogeneous aqueous phase.With high-shear emulsion machine high speed shear oil phase, while aqueous phase is slowly added into oil phase, usual active ingredient
1~60%, surfactant 5~20%, antifreezing agent 2~10%, water surplus.
Microemulsion is to mix active compound, organic solvent, surfactant, water, into homogeneous aqueous phase.Generally have
Imitate composition 1~50%, surfactant 10~40%, antifreezing agent 2~10%, water surplus.
Soluble liquid is to mix active component, organic solvent, surfactant, into transparent and homogeneous liquid.
Usual active ingredient 1~50%, surfactant 6~20%, organic solvent surplus.
Water dispersible oil suspending agent is that active component, surfactant, oil based vehicle are added in sand mill and be sanded, until grain
Footpath is qualified, usual active ingredient 2~60%, surfactant 6~20%, oil based vehicle surplus.
Aqueous dispersion liquid and emulsion(Missible oil, wettable powder or concentrate as the present invention is diluted with water obtain
Composition)It is also within the scope of the invention.Above-mentioned emulsion can be water-in-oil type or oil-in-water type, can have thick
Paste-like consistency.
The preparation of the composition finished product preparation of the present invention can use well known to those skilled in the art(Liquid is solid
Body)Carrier and various auxiliary agents.Such as include but is not limited to following all kinds of materials.
Suitable liquid-carrier or solvent can be water, various aromatic hydrocarbons, aliphatic hydrocarbon, ketone, ethers etc., such as toluene, diformazan
Benzene, acetone, cyclohexanone, acetonitrile, benzene, hexamethylene, isopropanol, ethylene glycol, sorbierite, methanol, ethanol, butanol, dimethyl formyl
Amine, dimethyl sulfoxide (DMSO), N- methyl-pyrrolidons, tributyl phosphate, methyl iso-butyl ketone (MIBK), naphthalane, machine oil, petroleum ether, oleic acid first
One or more in ester, methylated soya oil or the molten fiber of methyl etc..The mixture of different liquids is often what is be applicable.
Suitable solid carrier includes natural or synthesis clay and silicate, includes suitable for the solid carrier of pulvis
The White Carbon black that naturally occurs, rock dust, chalk, quartz, clay, montmorillonite, sodium sulphate, white carbon, silica, diatom
Soil, float stone, gypsum, talcum, bentonite, kaolin, attapulgite, precipitated calcium carbonate, clay and the mineral matter ground of synthesis
(Such as microdispersed silicic acid or aluminum oxide).Suitable particulate vector include broken and classification natural rock such as calcite,
Marble, float stone, sepiolite and dolomite and the synthesis particle made of the powder of organic matter and inorganic matter.
Suitable co-solvents are methanol, phenol, isoamyl alcohol, dimethyl sulfoxide (DMSO), ethyl acetate, butanone, dimethylformamide, two
One or more in methyl sulfoxide, N- methyl-pyrrolidons, methyl oleate, methyl iso-butyl ketone (MIBK), the molten fiber of methyl etc..
Suitable emulsifying agent can be ethoxylated castor oil, polyoxyethylene (n20) phenethyl phenolic group oleic acid ester, alkyl virtue
Base polyoxyethylene poly-oxygen propylene aether, alkylaryl formaldehyde resin APEO, triphenyl vinyl phenol polyoxyethylene (n20) ether phosphorus
It is acidified triethanolamine salt, castor oil polyoxyethylene ether, alkyl vinyl aryl phenyl ether(YUS-SC3), diphenyl phenolic group polyoxy second
Alkene (n18) ether formaldehyde condensation products, the different thionic acid calcium of oleic acid, agriculture breast AEO-3, agriculture breast 0201B, agriculture breast 0203B, agriculture breast T-20, agriculture breast
T-85, agriculture breast S-80, agriculture breast 507#, agriculture breast 100#, agriculture breast 36#, agriculture breast 500#, agriculture breast 600#, Nongru-700 #, agriculture breast 1601#,
Agriculture breast 2201#, agriculture breast NP-7, agriculture breast OX-635, agriculture breast OX-653, agriculture breast NP-10, agriculture breast NP-15 etc..
Suitable dispersant can be the sodium salt, poly- of sodium lignin sulfonate, calcium lignosulfonate, alkyl naphthalene sulfonic acid condensation polymer
Carboxylate dispersants GY-D800, GY-D04, GY-D02, naphthalenesulfonic acid-formaldehyde condensate, condensation compound of methyl naphthalene sulfonic acid and formaldehyde, alkane
Base-diethylene glycol ether-sodium sulfonate, N- methyl-oleoyl-sodium taurocholate, methanonaphthalene sodium sulfonate, oleic acid methylaminoethyl sulphur
Sour sodium, epoxidized polyether, dispersant SP-28F, dispersant SP-SC3, alkylaryl APEO, dodecyl polyoxyethylene
Ether phosphate, polyaryl phenol polyethenoxy ether, to tertbutyl ether, piperonyl butoxide, alkyl amide taurate, alkyl naphthalene sulfonic acid
Salt formaldehyde condensation products(NNO), ethylene oxide-propylene oxide block copolymer APES formaldehyde condensation product, N- first
Base-oleoyl-sodium taurocholate, N- methyl-fatty acyl groups-sodium taurocholate APES formaldehyde condensation product, dibutyl
Sodium naphthalene sulfonate(Nekal BX), dibutyl naphthalenesulfonic acid formaldehyde condensation products, alkylphenol-polyethenoxy base ether formaldehyde condensation products sulfate,
Alkylphenol-polyethenoxy based phosphates etc..
Suitable wetting agent can be lauryl sodium sulfate, sodium sulphate, Morwet EFW, wetting agent SP-SC3266,
Isopropyl naphthalene sulfonate, alkylol polyoxyethylene base ether sodium sulfate, alkylphenol-polyethenoxy base ether formaldehyde condensation products sulfate, the moon
Lauryl sulfate, neopelex, calcium dodecyl benzene sulfonate, Negel aliphatic alcohol polyethenoxy base ether,
Alkylphenol-polyethenoxy base ether etc..
Suitable thickener can be synthesis(Such as carbonyl methylol alcohol, polyvinyl alcohol, polyvinyl acetate)Or natural water
Soluble polymer(Such as xanthans, gelatin, gum arabic, polyvinylpyrrolidone, aluminium-magnesium silicate, polyvinyl alcohol, poly- second two
Alcohol, phenolic resin, shellac, methylcellulose, soluble starch, carboxymethyl cellulose and sodium alginate etc.), with powder, particle
Or latex form is added in preparation.
Suitable defoamer is bubble enemy, silicone, C8-10 fatty alcohols, phosphoric acid ester, C10-20 saturated fat acids(Such as
Capric acid)And acid amides etc..
Suitable adhesive can be polyvinyl alcohol, polyvinyl acetate, xanthans, gelatin, carboxymethyl cellulose and sea
Mosanom etc..
Aerosol can be made during for preventing and treating city insect, it is necessary to add propellant wherein, bait formulation can also be made
Composition, in addition to containing active component, also containing one or more foodstuffs for being suitable to insect's food-taking, optional attractant and
Optional wetting agent.
Present invention additionally comprises the present composition to be prepared into Insecticiding-miticiding preparation control agriculture and forestry injurious insect or urban health insect
Purposes.It is particularly adapted to prevent and treat a variety of important agricultural pests such as mythimna separata, beet armyworm, bollworm, cutworm, wild cabbage night
Moth, apple skin worm, rice leaf roller, corn borer, striped rice borer, diamondback moth, cabbage caterpillar, fall webworms, tent caterpillar, dance poison
Moth, Asiatic migrotory locust, subterranean pest-insect, leaf miner, liriomyza bryoniae, aphid, cotton Tetranychus cinnabarinus, vegetables tetranychid, tetranychus viennensis, citrus are complete
Pawl mite, phyllocoptruta oleivora, apple tetranychus, Tetranychus urticae, goitre mite, flour mite etc., city insect such as termite, blattaria, ant, flies, mosquito
Class etc..For fruit tree such as apple, pears, citrus, lichee etc., Cereal such as wheat, rice etc., beans such as soybean, Kidney bean etc., cotton
Flower, vegetables such as wild cabbage, cauliflower, Chinese cabbage, rape, tomato, capsicum and flowers.During for preventing and treating city insect, it can be used for
Family, various public places, office space, and the trees of termite damage, dykes and dams etc. occur.
Present invention additionally comprises a kind of method for controlling insect pest, can impose on the present composition with effective dose needs to control
Insect or its growth medium on.The more suitable effective dose generally selected is 10 grams to 500 grams of per hectare, preferably effectively
Dosage is 15 grams to 100 grams of per hectare.
In addition, the composition for showing the present invention through indoor biological determination of activity has synergistic effect.For example, chemical compounds I with
AVM 10:1-20:In the range of 1, with emamectin-benzoate 20:Under 1 ratio, with pleocidin 1:
50-50:Good synergistic effect is shown in the range of 1 to Tetranychus cinnabarinus.
The invention has the advantages that:
1. the composition of the present invention shows obvious synergistic effect in certain ratio range, the compound pair is improved
The prevention effect of insect.
2. the present composition reduces the dosage of compound in the application, so as to reduce use cost, environment is reduced
Pollution.
It is anti-with it the problem of in the absence of cross resistance 3. the mechanism of action of each active ingredient is different in the present composition
The generation of pest resistance to insecticide can be delayed by controlling insect, and improve the prevention effect of antagonism population.
Embodiment
Specific examples below is used to the present invention be further described, but the present invention is only limitted to absolutely not these examples.It is real
Each component percentage composition or proportioning in example is applied to be by weight.Active component in each formula is calculated with effective content, composition
In each material can prepare by conventional methods.
Formulation Example
The preparation of embodiment 1, the missible oil of 22% avermectin compounds I
By recipe requirements, 2 parts of AVMs, 20 parts of chemical compounds Is, 5 parts of agriculture breast 0201B, 3 parts of agriculture breast 36#, 8 are separately added into
Part agriculture breast 2201#, 8 parts of methanol, dimethylbenzene are complemented in 100% addition mixing kettle, are uniformly mixed, are used hot bath if necessary
Dissolve by heating, you can obtain the missible oil of 22% avermectin compounds I.
Macrolides described by AVM alternative costs specification can also be killed to one kind in insects mites agent, shape
Cheng Xin 22% macrolides kills the missible oil of insects mites immunomodulator compounds I.
The preparation of embodiment 2,11% emamectin-benzoate chemical compounds I missible oil
By recipe requirements, 1 part of emamectin-benzoate, 10 parts of chemical compounds Is, 8 parts of agriculture breasts are separately added into
2201#, 4 parts of agriculture breast 600#, 2 parts of agriculture breast 1601#, 8 parts of dimethylformamides, 6 parts of methanol, dimethylbenzene complement to 100% addition and mixed
Close in kettle, be uniformly mixed, dissolved by heating if necessary with hot bath, you can obtain 11% emamectin benzoate benzoic acid
The missible oil of salt compound I.
Macrolides described by emamectin-benzoate alternative costs specification can also be killed insects mites
One kind in agent, form 11% new macrolides and kill the missible oil of insects mites immunomodulator compounds I.
The preparation of embodiment 3,50% pleocidin chemical compounds I wettable powder(1:1)
By recipe requirements, by 25 parts of pleocidin, 25 parts of chemical compounds Is, 2 parts of lauryl sodium sulfate, 2 parts of oleic acid methyl ammonia
It is base ethylsulfonic acid sodium, 4 parts of dibutyl naphthalenesulfonic acid formaldehyde condensation products, 4 parts of polycarboxylate salt dispersant GY-D800,5 parts of White Carbon blacks, light
Matter calcium carbonate complements to 100% and is sufficiently mixed, after ultra-fine pulverizer disintegrating, you can obtaining 50% pleocidin chemical compounds I can
WP.
Macrolides described by pleocidin alternative costs specification can also be killed to one kind in insects mites agent, shape
Cheng Xin 50% macrolides kills the wettable powder of insects mites immunomodulator compounds I.
The preparation of embodiment 4, the wettable powder of 42% avermectin compounds I
By recipe requirements, by 2 parts of AVMs, 40 parts of chemical compounds Is, 2 parts of lauryl sodium sulfate, 4 parts of dibutyl naphthalene sulphurs
Sour formaldehyde condensation products, 4 parts of sodium lignin sulfonates, 3 parts of alkylnaphthalene sulfonate formaldehyde condensation products, 8 parts of White Carbon blacks, bentonites complement to
100% is sufficiently mixed, after ultra-fine pulverizer disintegrating, you can obtains the wettable powder of 42% avermectin compounds I.
Macrolides described by AVM alternative costs specification can also be killed to one kind in insects mites agent, shape
Cheng Xin 42% macrolides kills the wettable powder of insects mites immunomodulator compounds I.
The preparation of embodiment 5,51% pleocidin chemical compounds I wettable powder
By recipe requirements, by 50 parts of pleocidin, 1 part of chemical compounds I, 2 parts of alkylphenol-polyethenoxy base ether formaldehyde condensation products
Sulfate, 4 parts of N- methyl-fatty acyl groups-sodium taurocholate APES formaldehyde condensation products, 4 parts of calcium lignosulfonates,
5 parts of White Carbon blacks, precipitated calcium carbonate complement to 100% and are sufficiently mixed, after ultra-fine pulverizer disintegrating, you can obtain sterilizing 51% more
Plain chemical compounds I wettable powder.
Macrolides described by pleocidin alternative costs specification can also be killed to one kind in insects mites agent, shape
Cheng Xin 51% macrolides kills the wettable powder of insects mites immunomodulator compounds I.
The preparation of embodiment 6, the aqueous emulsion of 21% avermectin compounds I
By recipe requirements, by 1 part of AVM, 20 parts of chemical compounds Is, 4 parts of agriculture breast 0201B, 8 parts of agriculture breast 507#, 3 parts of agriculture breasts
OX-635,8 parts of dimethyl sulfoxide (DMSO)s, 6 parts of cyclohexanone are added in mixing kettle, are stirred, are made to be dissolved into homogeneous oil phase, in high-speed stirring
Mix down, by excess water(Complement to 100%)It is added to oil phase, you can obtain 21% avermectin compounds I of favorable dispersibility
Aqueous emulsion.
Macrolides described by AVM alternative costs specification can also be killed to one kind in insects mites agent, shape
Cheng Xin 21% macrolides kills the aqueous emulsion of insects mites immunomodulator compounds I.
The preparation of embodiment 7,26% emamectin-benzoate chemical compounds I aqueous emulsion
By recipe requirements, by 25 parts of emamectin-benzoates, 1 part of chemical compounds I, 3 parts of DBSAs
Calcium, 3 parts of triphenyl vinyl phenol polyoxyethylene (n20) ether phosphoric acid triethanolamine salt, 3 parts of agriculture breast OX-653,7 parts of agriculture breast 2201#, 8
Part acetonitrile, 8 parts of methyl iso-butyl ketone (MIBK)s, 8 parts of dimethylbenzene are added in mixing kettles, are stirred, are made to be dissolved into homogeneous oil phase, at a high speed
Under stirring, by excess water(Complement to 100%)It is added to oil phase, you can obtain 26% emamectin benzoate benzene of favorable dispersibility
The aqueous emulsion of formate compounds I.
Macrolides described by emamectin-benzoate alternative costs specification can also be killed insects mites
One kind in agent, form 26% new macrolides and kill the aqueous emulsion of insects mites immunomodulator compounds I.
Embodiment 8,51% pleocidin chemical compounds I water-dispersible granules
By recipe requirements, by 1 part of pleocidin, 50 parts of chemical compounds Is, 4 parts of methanonaphthalene sodium sulfonates, 6 parts of N- methyl-oleoyls
Base-sodium taurocholate, 2 parts of neopelexes, 8 portions of soluble starches, 5 parts of sodium sulphate, bentonite complement to 100% and are added in
Together, co-grinding is carried out, then after adding water to mediate, adds in the comminutor equipped with certain specification screen cloth and is granulated.Then
Again through drying, screening (pressing screen cloth scope), you can obtain 51% pleocidin chemical compounds I water-dispersible granules.
Macrolides described by pleocidin alternative costs specification can also be killed to one kind in insects mites agent, shape
Cheng Xin 51% macrolides kills the water-dispersible granules of insects mites immunomodulator compounds I.
Embodiment 9, the water-dispersible granules of 21% avermectin compounds I
By recipe requirements, by 1 part of AVM, 20 parts of chemical compounds Is, 6 parts of ethylene oxide-propylene oxide block copolymer alkane
Base phenol polyethenoxy ether formaldehyde condensation products, 4 parts of methanonaphthalene sodium sulfonates, 2% dodecyl sodium sulfate, 1.5 parts of polyvinylpyrrolidines
Ketone, 8 portions of soluble starches, 15 parts of sodium sulphate, bentonite complement to 100% and are added together, and carry out co-grinding, then through adding water to pinch
After conjunction, add in the comminutor equipped with certain specification screen cloth and be granulated.Then again through drying, screening (pressing screen cloth scope), i.e.,
The available water-dispersible granules of 21% avermectin compounds I.
Macrolides described by AVM alternative costs specification can also be killed to one kind in insects mites agent, shape
Cheng Xin 21% macrolides kills the water-dispersible granules of insects mites immunomodulator compounds I.
Embodiment 10,51% pleocidin chemical compounds I water-dispersible granules
By recipe requirements, by 50 parts of pleocidin, 1 part of chemical compounds I, 1.5 parts of Morwet EFW, 4 parts of N- methyl-oleoyls
Sodium salt, 2 parts of sodium alginates, 5 portions of soluble starches, 15 parts of sodium sulphate, the silicon of base-sodium taurocholate, 5 parts of alkyl naphthalene sulfonic acid condensation polymers
Diatomaceous earth complements to 100% and is added together, and carries out co-grinding, then after adding water to mediate, adds the granulation equipped with certain specification screen cloth
It is granulated in machine.Then again through drying, screening (pressing screen cloth scope), you can obtain 51% pleocidin chemical compounds I moisture and dissipate
Property granula.
Macrolides described by pleocidin alternative costs specification can also be killed to one kind in insects mites agent, shape
Cheng Xin 51% macrolides kills the water-dispersible granules of insects mites immunomodulator compounds I.
Embodiment 11, the suspending agent of 40% avermectin compounds I
By recipe requirements, by 20 parts of AVMs, 20 parts of chemical compounds Is, 4 parts of polycarboxylate salt dispersant GY-D04,2 parts of agriculture breasts
1601#, 4 parts of agriculture breast 0203B, 0.1 part of xanthans, 0.5 part of white carbon, 5 parts of ethylene glycol, with water 100% is complemented to, sequentially added
Mixed into blending tank, first pass through high shear and carry out coarse crushing, homogenize, be then pumped into sand mill and carry out fine grinding, use granularity
The granularity of material is sanded in distribution instrument detection, after particle diameter reaches standard requirement, filtering, you can obtain 40% AVM chemical combination
The suspending agent of thing I.
Macrolides described by AVM alternative costs specification can also be killed to one kind in insects mites agent, shape
Cheng Xin 40% macrolides kills the suspending agent of insects mites immunomodulator compounds I.
Example 12,11% emamectin-benzoate chemical compounds I suspending agent(1:10)
By recipe requirements, by 10 parts of emamectin-benzoates, 1 part of chemical compounds I, 3 parts of dispersant SP-28F, 3
Part wetting agent SP-SC3266,2 parts of Nongru-700 #, 0.1 part of xanthans, 0.5 part of white carbon, 5 parts of ethylene glycol, complemented to water
100%, it is added sequentially to mix in blending tank, first passes through high shear and carry out coarse crushing, homogenize, then be pumped into sand mill
Row fine grinding, the granularity that material is sanded is detected with particles distribution instrument, after particle diameter reaches standard requirement, filtering, you can obtain 11% first
Amino abamectin benzoate chemical compounds I suspending agent.
Macrolides described by emamectin-benzoate alternative costs specification can also be killed insects mites
One kind in agent, form 11% new macrolides and kill the suspending agent of insects mites immunomodulator compounds I(1:10).
Example 13,42% ivermectin chemical compounds I suspending agent
By recipe requirements, by 2 parts of ivermectins, 40 parts of chemical compounds Is, 3 parts of dispersant SP-SC3,4 parts of naphthalene sulfonate formaldehydes
Condensation product, 3 parts of agriculture breast 0201B, 1 part of agriculture breast T-20,0.1 part of xanthans, 0.3 part of white carbon, 5 parts of ethylene glycol, complemented to water
100%, it is added sequentially to mix in blending tank, first passes through high shear and carry out coarse crushing, homogenize, then be pumped into sand mill
Row fine grinding, with particles distribution instrument detect be sanded material granularity, when particle diameter reach standard requirement after, filtering, you can obtain 42% she
Tie up the suspending agent of rhzomorph compound I.
Macrolides described by ivermectin alternative costs specification can also be killed to one kind in insects mites agent, shape
Cheng Xin 42% macrolides kills the suspending agent of insects mites immunomodulator compounds I.
Embodiment 14, the microemulsion of 26% avermectin compounds I
By recipe requirements, by 25 parts of AVMs, 1 part of chemical compounds I, 5 parts of diphenyl phenolic group polyoxyethylene (n18) ether formaldehyde
Condensation product, 8 parts of agriculture breast 507#, 3 parts of agriculture breast 1601#, 5 parts of agriculture breast NP15,8 parts of N- methyl-pyrrolidons, 5 parts of tributyl phosphates
Be added together, make to be dissolved into homogeneous oil phase, surplus complements to 100% with water, under high velocity agitation, by aqueous phase be added to oil phase or
Oil phase is added to aqueous phase, forms the microemulsion of 26% avermectin compounds I of favorable dispersibility.
Macrolides described by AVM alternative costs specification can also be killed to one kind in insects mites agent, shape
Cheng Xin 26% macrolides kills the microemulsion of insects mites immunomodulator compounds I.
Embodiment 15,13% emamectin-benzoate chemical compounds I soluble concentrate
By recipe requirements, by 0.5 part of emamectin-benzoate, 12.5 parts of chemical compounds Is, 10 parts of agriculture breast 2201#,
3 parts of agriculture breast 1601#, 5 parts of agriculture breast 500#, 3 parts of agriculture breast 100#, 8 parts of acetonitriles, 5 parts of methyl iso-butyl ketone (MIBK)s, 10 parts of dimethyl sulfoxide (DMSO)s,
The molten fiber of methyl complements to 100% and is well mixed, and is dissolved by heating if necessary with hot bath, 13% emamectin benzoate benzene can be made
The soluble concentrate of formate compounds I.
Macrolides described by emamectin-benzoate alternative costs specification can also be killed insects mites
One kind in agent, form 13% new macrolides and kill the soluble concentrate of insects mites immunomodulator compounds I.
Embodiment 16,20% pleocidin chemical compounds I water dispersible oil suspending agent
By recipe requirements, by 10 parts of pleocidin, 10 parts of chemical compounds Is, 5 parts of agriculture breast 0201B, 3 parts of agriculture breast 500#, 2 parts of agricultures
Newborn S-80,5 parts of agriculture breast AEO-3,3 parts of white carbons, 2 parts of agriculture breast T-85, methyl oleate complement to 100% and are added sequentially to blending tank
Middle mixing, first pass through high shear and carry out coarse crushing, homogenize, be then pumped into sand mill and carry out fine grinding, examined with particles distribution instrument
The granularity that material is sanded is surveyed, after particle diameter reaches standard requirement, filtering, you can obtain 20% pleocidin chemical compounds I moisture and dissipate
Property oil suspending agent
Macrolides described by pleocidin alternative costs specification can also be killed to one kind in insects mites agent, shape
Cheng Xin 20% macrolides kills the water dispersible oil suspending agent of insects mites immunomodulator compounds I.
Indoor biological determination of activity
Synergism determination of composition of the embodiment 17 containing chemical compounds I to Tetranychus cinnabarinus
For trying object:Tetranychus cinnabarinus(Tetranychus cinnabarinus Boisduval), into mite, indoor feeding
Sensitive strain.
Test condition:Temperature:24~26 DEG C, humidity:RH60%, illumination:L:D=14:10
Test method:Using pot-spraying method.The potted plant Kidney bean seedling of sizing of hot-house culture(2 true leaves), a piece of true leaf is stayed,
Mite 40-60 heads are connected into thereon.Examination material is handled with decoction using Airbrush spray-on processes, dried in the shade naturally.Blank control is first handled,
Then aforesaid operations are repeated from low to high according to experimental design dosage, often handle 4 repetitions.Test worm after processing is placed in
In observation ward, routine observation test worm response situation, number of dead and live insects is investigated after 72h, calculate the death rate.
Evaluation uses Bliss methods, and this method is one of classical way for evaluating mixture effect.Bliss proposes according to it
Independent joint action concept thinks, theoretical death rate P during Mixture Use of Insecticides can be calculated with following formula:
P=Pm+Pn(1-Pm)
PmFor the death rate of the first active component target when concentration is m(%);PnIt is n for the second active component concentration
When target the death rate(%).
If the actual of two kinds of active component targets after being mixed with finite concentration is more than theoretical death rate P,
Judge that two kinds of active components are used in mixed way with synergistic effect in the case where setting concentration, it is on the contrary then be antagonism.
It the results are shown in Table 1.
3 kinds of medicaments such as the chemical compounds I of table 1 and AVM are used in mixed way the synergism determination to Tetranychus cinnabarinus into mite
Claims (6)
- A kind of 1. insecticide acaricide composition that insects mites agent is killed containing macrolides, it is characterised in that:Composition contains A, B two Kind active component, active component A are selected from the chemical compounds I shown in following structural formula, and active component B is selected from AVM, methylamino Abamectin benzoate, pleocidin;Active component A structure is as follows:Chemical compounds I;The ratio of weight and number of active component A and pleocidin is 1:50-50:1;The ratio of weight and number of active component A and AVM is 10:1-20:1;The ratio of weight and number of active component A and emamectin-benzoate is 20:1.
- 2. according to the composition described in claim 1, it is characterised in that:Composition can be configured to missible oil, suspending agent, moisture and dissipate Property granula, aqueous emulsion, microemulsion, soluble concentrate, wettable powder or water dispersible oil suspending agent.
- 3. according to the composition described in claim 2, it is characterised in that:The cumulative amount of active component is in 0.5%- in composition Between 95%.
- 4. according to the composition described in claim 3, it is characterised in that:The cumulative amount of active component is in 1%-85% in composition Between.
- 5. a kind of insecticide acaricide composition that insects mites agent is killed containing macrolides according to described in claim 1, its feature exists In:The composition is used to prepare insecticidal/acaricidal agent, for controlling agriculture and forestry injurious insect or urban health insect.
- 6. according to the insecticide acaricide composition that insects mites agent is killed containing macrolides described in claim 5, it is characterised in that: With effective agent gauge, the composition for being prepared into insecticidal/acaricidal agent is imposed on to the insect for needing to control or the medium of its growth On.
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CN106614677A (en) * | 2015-10-30 | 2017-05-10 | 陕西韦尔奇作物保护有限公司 | Insecticidal pesticide composition containing SYP-9625 |
CN106889087A (en) * | 2017-03-20 | 2017-06-27 | 安徽省农业科学院植物保护与农产品质量安全研究所 | A kind of medicament composition and its application method |
CN107509735B (en) * | 2017-08-29 | 2020-09-11 | 浙江农林大学 | Synergistic acaricidal composition and use thereof |
CN107751193A (en) * | 2017-10-17 | 2018-03-06 | 重庆市农业科学院 | Ultra low volume liquids of the mite nitrile of azoles containing second and Ivermectin HCL and preparation method thereof |
CN109691451B (en) * | 2017-10-24 | 2021-03-05 | 沈阳中化农药化工研发有限公司 | Insecticidal and acaricidal synergistic composition containing ethacrylonitrile and application thereof |
CN109832285A (en) * | 2017-11-29 | 2019-06-04 | 江苏龙灯化学有限公司 | A kind of Pesticidal combination |
CN109832286A (en) * | 2017-11-29 | 2019-06-04 | 江苏龙灯化学有限公司 | A kind of Pesticidal combination |
CN111226955B (en) * | 2018-11-29 | 2021-11-19 | 沈阳中化农药化工研发有限公司 | Insecticidal and acaricidal composition containing macrolide insect/acarid |
CN112075431A (en) * | 2020-09-22 | 2020-12-15 | 中国农业科学院蔬菜花卉研究所 | Insecticidal and acaricidal composition and application thereof |
CN114431238A (en) * | 2020-11-04 | 2022-05-06 | 浙江省化工研究院有限公司 | Acaricide composition |
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