CN104663672B - One kind contains the acaricidal insecticide acaricide composition of acarid growth inhibitor class - Google Patents
One kind contains the acaricidal insecticide acaricide composition of acarid growth inhibitor class Download PDFInfo
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Abstract
The invention belongs to field of pesticides, is related to one kind and contains the acaricidal insecticide acaricide composition of acarid growth inhibitor class.Composition contains two kinds of active components of A, B, and the ratio of weight and number between component A and the components of component B two is 1:99~99:1；Active component A is selected from the chemical compounds I shown in following structural formula, and active component B is selected from acarid growth inhibitor class acaricide；The active component A structure is as follows, and composition of the invention has the advantages that synergy is obvious, delaying drug resistance, available for preventing and treating various pests.
Description
Technical field
The invention belongs to field of pesticides, is related to a kind of containing the acaricidal Insecticiding-miticiding combination of acarid growth inhibitor class
Thing.
Background technology
Insecticide has obvious effect in terms of preventing and treating agriculture and forestry injurious insect or urban health insect.
Chinese invention patent CN101875633 discloses a kind of pyrazolyl acrylonitrile compound and its control insect pest and mite
Harmful purposes, wherein compound 5（Hereinafter referred to as chemical compounds I）Available for preventing and treating various pests, evil mite, especially have to evil mite prominent
The prevention effect gone out..
Insecticide containing single-activity component, is used continuously in control of insect, easily insect is developed immunity to drugs.It is logical
The insecticide for crossing two kinds of active components is compounded into blending ingredients by a certain percentage, can often improve preventive effect, reduces active ingredient
Dosage, it is cost-effective, while the generation of pest resistance to insecticide can be delayed.
Although generally disclose in the prior art chemical compounds I or its homologue can be produced with other Mixture Use of Insecticides it is additional
The advantages of and effect, but the technical scheme of the binary pesticide composition containing chemical compounds I has no specific disclosure.
The content of the invention
Present invention aims at exploitation one kind to contain the acaricidal insecticide acaricide composition of acarid growth inhibitor class, with full
Sufficient agricultural and the demand that pest control aspect in urban health field is increasingly improved to insecticide effect and kind is constantly updated.
To achieve the above object, the technical solution adopted by the present invention is：
One kind contains the acaricidal insecticide acaricide composition of acarid growth inhibitor class, and composition contains two kinds of activity of A, B
Component, active component A are selected from the chemical compounds I shown in following structural formula, and active component B is selected from acarid growth inhibitor class mite killing
Agent；
The active component A structure is as follows,：
The active component B is selected from clofentezine (Clofentezine), cyromazine (Cyromazine), Hexythiazox
Or etoxazole (Etoxazole) (Hexythiazox).
The ratio of weight and number of two kinds of active components is 1 in the composition of the present invention:99-99:1.
The active component A is chemical compounds I, and active component B is preferably clofentezine；The ratio of weight and number of two kinds of active components
Preferably 1:20-20:1, more preferably 1:19-19:1；
The active component A is chemical compounds I, and active component B is preferably etoxazole；The ratio of weight and number of two kinds of active components
Preferably 1:20-20:1.
The composition of the present invention can be in that finished product preparation form provides.Therefore, present invention additionally comprises a kind of dosage form
Insecticides.Using composition as active component, be made as needed missible oil, suspending agent, water-dispersible granules, aqueous emulsion,
Soluble concentrate, wettable powder, water dispersible oil suspending agent etc..The cumulative amount of the active component of composition is 0.5% in preparation
Between~95%, preferably cumulative amount is between 1%-85%.The content of active component depends on individually making in the composition of the present invention
The amount of application of used time, also depend on mixed ratio and synergistic effect degree.The optimum range of active component content is according to composition
Preparation type and it is different.
The preparation of the composition finished product preparation of the present invention can be prepared by common processing method, i.e., by active material and liquid
Carrier（Solvent）Or after solid carrier mixing, add one or more of surfactants such as emulsifying agent, dispersant, wetting agent, viscous
Mixture, stabilizer and defoamer etc..Contain at least one carrier and at least one surfactant in usual composition.Various
In the case of, it should be ensured that present composition active component is uniformly distributed.
Missible oil usually contains 10~50% active component, 2~20% emulsifying agents, and 0~20% other additives are for example stablized
Agent, bleeding agent etc., and solvent（Also contain cosolvent if necessary）.
Suspending agent generally needs to be sanded, to obtain stable non-deposited flowable product.Usually contain 5 in suspending agent~
75% active component, 5~15% dispersants, 4~10% antifreezing agents, 0~10% other additives such as defoamer, preservative, stably
Agent, bleeding agent and thickener, and liquid-carrier surplus.
Water-dispersible granules are usually made 10~100 international standard sieve mesh（1.676~0.152mm）Particle, it can pass through
It is prepared by extruding, dipping or Spray granulation method.Usual water-dispersible granules contain 0.5~75% active component and 5~20%
Surfactant such as stabilizer, wetting dispersing agent, disintegrant and adhesive, and inert carrier surplus.
Wettable powder usually contains 10~85% active component, in addition to solid inert carrier, usually contains 3~10%
Dispersant, can also containing 0~10% stabilizer and（Or）Other additives, such as bleeding agent or sticker.
Aqueous emulsion is to mix to form oil phase by active compound, organic solvent, surfactant；Water, antifreezing agent are mixed,
Into homogeneous aqueous phase.With high-shear emulsion machine high speed shear oil phase, while aqueous phase is slowly added into oil phase, usual active ingredient
1~60%, surfactant 5~20%, antifreezing agent 2~10%, water surplus.
Microemulsion is to mix active compound, organic solvent, surfactant, water, into homogeneous aqueous phase.Generally have
Imitate composition 1~50%, surfactant 10~40%, antifreezing agent 2~10%, water surplus.
Soluble liquid is to mix active component, organic solvent, surfactant, into transparent and homogeneous liquid.
Usual active ingredient 1~50%, surfactant 6~20%, organic solvent surplus.
Water dispersible oil suspending agent is that active component, surfactant, oil based vehicle are added in sand mill and be sanded, until grain
Footpath is qualified, usual active ingredient 2~60%, surfactant 6~20%, oil based vehicle surplus.
Aqueous dispersion liquid and emulsion（Missible oil, wettable powder or concentrate as the present invention is diluted with water obtain
Composition）It is also within the scope of the invention.Above-mentioned emulsion can be water-in-oil type or oil-in-water type, can have thick
Paste-like consistency.
The preparation of the composition finished product preparation of the present invention can use well known to those skilled in the art（Liquid is solid
Body）Carrier and various auxiliary agents.Such as include but is not limited to following all kinds of materials.
Suitable liquid-carrier or solvent can be water, various aromatic hydrocarbons, aliphatic hydrocarbon, ketone, ethers etc., such as toluene, diformazan
Benzene, acetone, cyclohexanone, acetonitrile, benzene, hexamethylene, isopropanol, ethylene glycol, sorbierite, methanol, ethanol, butanol, dimethyl formyl
Amine, dimethyl sulfoxide (DMSO), N- methyl-pyrrolidons, tributyl phosphate, methyl iso-butyl ketone (MIBK), naphthalane, machine oil, petroleum ether, oleic acid first
One or more in ester, methylated soya oil or the molten fiber of methyl etc..The mixture of different liquids is often what is be applicable.
Suitable solid carrier includes natural or synthesis clay and silicate, includes suitable for the solid carrier of pulvis
The White Carbon black that naturally occurs, rock dust, chalk, quartz, white carbon, clay, montmorillonite, silica, diatomite, float stone,
Gypsum, talcum, bentonite, kaolin, attapulgite, precipitated calcium carbonate, clay and the mineral matter ground of synthesis（As differential dissipates
Silicic acid or aluminum oxide）.Suitable particulate vector includes broken and classification natural rock such as calcite, marble, floated
Stone, sepiolite and dolomite and the synthesis particle made of the powder of organic matter and inorganic matter.
Suitable co-solvents are methanol, phenol, isoamyl alcohol, dimethyl sulfoxide (DMSO), ethyl acetate, butanone, dimethylformamide, two
One or more in methyl sulfoxide, N- methyl-pyrrolidons, methyl oleate, methyl iso-butyl ketone (MIBK), the molten fiber of methyl etc..
Suitable emulsifying agent can be ethoxylated castor oil, polyoxyethylene (n20) phenethyl phenolic group oleic acid ester, alkyl virtue
Base polyoxyethylene poly-oxygen propylene aether, alkylaryl formaldehyde resin APEO, the different thionic acid calcium of oleic acid, triphenyl vinyl phenol gather
Oxygen ethene (n20) ether phosphoric acid triethanolamine salt, agriculture breast AEO-3, agriculture breast AEO-3, agriculture breast 0201B, agriculture breast 0203B, agriculture breast T-
20th, agriculture breast T-85, agriculture breast S-80, agriculture breast 507#, agriculture breast 100#, agriculture breast 36#, agriculture breast 500#, agriculture breast 600#, Nongru-700 #, agriculture
Newborn 1601#, agriculture breast 2201#, agriculture breast NP-7, agriculture breast NP-10, agriculture breast NP-15, agriculture breast OP-10 etc..
Suitable dispersant can be sodium lignin sulfonate, calcium lignosulfonate, the sodium salt of alkyl naphthalene sulfonic acid condensation polymer, naphthalene
Phenol sulfonic acid formaldehyde condensation products sodium salt, naphthalenesulfonic acid-formaldehyde condensate, cresol sulfonic acid formaldehyde condensation products sodium salt, methyl naphthalene sulfonic acid and formaldehyde
Condensation product, alkyl-diethylene glycol ether-sodium sulfonate, N- methyl-oleoyl-sodium taurocholate, methanonaphthalene sodium sulfonate, oleic acid methyl
Aminoethylsulfonic acid sodium, epoxidized polyether, to tertbutyl ether, piperonyl butoxide, alkyl amide taurate, dibutyl naphthalenesulfonic acid first
Aldehyde condensate, alkylphenol-polyethenoxy based phosphates, detergent LS, pull open powder etc..
Suitable wetting agent can be sodium sulphate, Morwet EFW, isopropyl naphthalene sulfonate, alkylol polyoxyethylene base ether
Sodium sulphate, alkylphenol-polyethenoxy base ether formaldehyde condensation products sulfate, sldium lauryl sulfate, methanonaphthalene sodium sulfonate, dodecane
Base benzene sulfonic acid sodium salt, calcium dodecyl benzene sulfonate, lauryl sodium sulfate, Negel aliphatic alcohol polyethenoxy base ether, alkane
Base phenol polyethenoxy base ether etc..
Suitable thickener can be synthesis（Such as carbonyl methylol alcohol, polyvinyl alcohol, polyvinyl acetate）Or natural water
Soluble polymer（Such as xanthans, gelatin, gum arabic, polyvinylpyrrolidone, aluminium-magnesium silicate, polyvinyl alcohol, poly- second two
Alcohol, phenolic resin, shellac, methylcellulose, soluble starch, carboxymethyl cellulose and sodium alginate etc.）, with powder, particle
Or latex form is added in preparation.
Suitable defoamer is bubble enemy, silicone, the fatty alcohol of C8~10, phosphoric acid ester, the saturated fat acids of C10~20
（Such as capric acid）And acid amides etc..
Suitable adhesive can be polyvinyl alcohol, polyvinyl acetate, xanthans, gelatin, soluble starch, carboxymethyl fibre
Dimension element and sodium alginate etc..
Aerosol can be made during for preventing and treating city insect, it is necessary to add propellant wherein, bait formulation can also be made
Composition, in addition to containing active component, also containing one or more foodstuffs for being suitable to insect's food-taking, optional attractant and
Optional wetting agent.
Present invention additionally comprises the purposes that inventive composition is prepared into Insecticiding-miticiding preparation control agriculture and forestry injurious insect.The group of the present invention
Compound is suitable for preventing and treating a variety of important agricultural pests such as blister mite, cotton Tetranychus cinnabarinus, vegetables tetranychid, tetranychus viennensis, citrus
Panonychus citri, phyllocoptruta oleivora, apple tetranychus, Tetranychus urticae, goitre mite, flour mite etc..For fruit tree such as apple, pears, citrus, lichee etc.,
Cereal such as wheat, rice etc., beans such as soybean, Kidney bean etc., cotton, vegetables for example wild cabbage, cauliflower, Chinese cabbage, rape, tomato,
Capsicum and flowers.During for preventing and treating city insect, it can be used for family, various public places, office space, and trees
Deng.
Present invention additionally comprises a kind of method for controlling insect pest, can impose on the present composition with effective dose needs to control
Insect or its growth medium on.The more suitable effective dose generally selected is 10 grams to 500 grams of per hectare, preferably effectively
Dosage is 15 grams to 100 grams of per hectare.
In addition, the composition for showing the present invention through indoor biological determination of activity has synergistic effect.For example, chemical compounds I with
Clofentezine, etoxazole are 1:20-20:Good synergistic effect is shown in the range of 1 to Tetranychus cinnabarinus.Chemical compounds I and four simultaneously
Mite piperazine is 19:1-1:More preferable synergistic effect is shown in the range of 19 to Tetranychus cinnabarinus.
The invention has the advantages that：
1. the composition of the present invention shows obvious synergistic effect in certain ratio range, the compound pair is improved
The prevention effect of insect.
2. the present composition reduces the dosage of compound in the application, so as to reduce use cost, environment is reduced
Pollution.
It is anti-with it the problem of in the absence of cross resistance 3. the mechanism of action of each active ingredient is different in the present composition
The generation of pest resistance to insecticide can be delayed by controlling insect, and improve the prevention effect of antagonism population.
Embodiment
Specific examples below is used to the present invention be further described, but the present invention is only limitted to absolutely not these examples.It is real
Each component percentage composition or proportioning in example is applied to be by weight.Active component in each formula is calculated with effective content, while group
Each material can prepare in a conventional manner in compound.
Formulation Example
The preparation of embodiment 1,20% clofentezine chemical compounds I missible oil
By recipe requirements, 1 part of clofentezine, 19 parts of chemical compounds Is, 7 parts of agriculture breast 0201B, 3 parts of agriculture breast NP-15,2 are separately added into
Part agriculture breast 1601#, 6 parts of N- methyl-pyrrolidons, dimethylbenzene complement to 100%, are well mixed, and are heated if necessary with hot bath molten
Solution, that is, obtain 20% clofentezine chemical compounds I missible oil missible oil.
Can also be by one kind in the acarid growth inhibitor class acaricide described by clofentezine alternative costs specification, shape
The Cheng Xin missible oil of 20% acarid growth inhibitor class acaricide compound I.
The preparation of embodiment 2,40% clofentezine chemical compounds I wettable powder
By recipe requirements, by 38 parts of clofentezines, 2 parts of chemical compounds Is, 2 parts of lauryl sodium sulfate, 3 parts of naphtholsulfonic acid formaldehyde
Condensation product sodium salt, 6 parts of calcium lignosulfonates, 5 parts of White Carbon blacks, precipitated calcium carbonates etc. complement to 100%, are sufficiently mixed, through superfine powder
After broken machine crushes, that is, obtain 40% clofentezine chemical compounds I wettable powder.
Can also be by one kind in the acarid growth inhibitor class acaricide described by clofentezine alternative costs specification, shape
The Cheng Xin wettable powder of 20% acarid growth inhibitor class acaricide compound I.
The preparation of embodiment 3,40% etoxazole chemical compounds I wettable powder（1:1）
By recipe requirements, by 20 parts of etoxazoles, 20 parts of chemical compounds Is, 2 parts of lauryl sodium sulfate, 5 parts of cresol sulfonic acid formaldehyde
Condensation product sodium salt, 4 parts of pull open powders, 2 parts of detergent LS, 5 parts of White Carbon blacks, precipitated calcium carbonates supply 100%, are sufficiently mixed, through ultra-fine
After pulverizer crushes, that is, obtain 40% etoxazole chemical compounds I wettable powder wettable powder.
Can also be by one kind in the acarid growth inhibitor class acaricide described by etoxazole alternative costs specification, shape
The Cheng Xin wettable powder of 20% acarid growth inhibitor class acaricide compound I.
The preparation of embodiment 4,20% Hexythiazox chemical compounds I aqueous emulsion
By recipe requirements, by 18 parts of Hexythiazoxs, 2 parts of chemical compounds Is, 8 parts of polyoxyethylene (n20) phenethyl phenolic group oleic acid ester,
15 parts of agriculture breast 2201#, 4 parts of agriculture breast 1601#, 10 parts of cyclohexanone, 8 parts of dimethyl sulfoxide (DMSO) mixing, it is stirred to dissolve into uniform oil
Phase, under high velocity agitation, by excess water（Complement to 100%）It is added to oil phase, you can form 20% thiophene mite of favorable dispersibility
Ketone chemical compounds I aqueous emulsion.
Can also be by one kind in the acarid growth inhibitor class acaricide described by Hexythiazox alternative costs specification, shape
The Cheng Xin aqueous emulsion of 20% acarid growth inhibitor class acaricide compound I.
The preparation of embodiment 5,40% etoxazole chemical compounds I aqueous emulsion（1:1）
By recipe requirements, by 20 parts of etoxazoles, 20 parts of chemical compounds Is, 8 parts of agriculture breasts 2201,6 parts of calcium dodecyl benzene sulfonates, 5
Part Nongru-700 #, 5 parts of N- methyl-pyrrolidons, 8 parts of tributyl phosphates are added together, and homogeneous oil phase are stirred to dissolve into, in height
Under speed stirring, by the water of surplus（Complement to 100%）It is added to oil phase, you can form 40% etoxazole chemical combination of favorable dispersibility
The aqueous emulsion of thing I.
Can also be by one kind in the acarid growth inhibitor class acaricide described by etoxazole alternative costs specification, shape
The preparation of the Cheng Xin aqueous emulsion of 20% acarid growth inhibitor class acaricide compound I（1:1）.
Embodiment 6,60% clofentezine chemical compounds I water-dispersible granules（1:1）
By recipe requirements, by 30 parts of clofentezines, 30 parts of chemical compounds Is, 5 parts of methanonaphthalene sodium sulfonates, 5 parts of naphtholsulfonic acid formaldehyde
Condensation product sodium salt, 1 part of Morwet EFW, 10 parts of soluble starches, attapulgites supply 100%, are added together, and carry out mixed powder
It is broken, then after adding water to mediate, add in the comminutor equipped with certain specification screen cloth and be granulated.Then (pressed through drying, screening again
Screen cloth scope), you can obtain 60% clofentezine chemical compounds I water-dispersible granules.
Can also be by one kind in the acarid growth inhibitor class acaricide described by clofentezine alternative costs specification, shape
The Cheng Xin water-dispersible granules of 20% acarid growth inhibitor class acaricide compound I（1:1）.
Embodiment 7,40% clofentezine chemical compounds I water-dispersible granules
By recipe requirements, by 4 parts of clofentezines, 36 parts of chemical compounds Is, 12 parts of methyl naphthalene sulfonate formaldehyde condensates, 5 parts of N- first
Base-oleoyl-sodium taurocholate, 1.5 parts of polyvinylpyrrolidones, 8 parts of soluble starches, bentonites etc. complement to 100%, are added in
Together, co-grinding is carried out, then after adding water to mediate, adds in the comminutor equipped with certain specification screen cloth and is granulated.Then
Again through drying, screening (pressing screen cloth scope), you can obtain 40% clofentezine chemical compounds I water-dispersible granules.
Can also be by one kind in the acarid growth inhibitor class acaricide described by clofentezine alternative costs specification, shape
The Cheng Xin water-dispersible granules of 20% acarid growth inhibitor class acaricide compound I.
Embodiment 8,20% cyromazine chemical compounds I suspending agent
By recipe requirements, by 1 part of cyromazine, 19 parts of chemical compounds Is, 2 parts of agriculture breast 1601#, 2 parts of agriculture breast T-20,4 parts of agriculture breasts
0201B, 2 parts of methyl naphthalene sulfonate formaldehyde condensates, 0.2 part of xanthans, 0.8 part of white carbon, 5 parts of ethylene glycol, complemented to water
100%, it is added sequentially to mix in blending tank, first passes through high shear and carry out coarse crushing, homogenize, then be pumped into sand mill
Row fine grinding, the granularity that material is sanded is detected with particles distribution instrument, after particle diameter reaches standard requirement, filtering, you can obtain 20% and go out
The suspending agent of fly amines I.
Can also be by one kind in the acarid growth inhibitor class acaricide described by cyromazine alternative costs specification, shape
The Cheng Xin suspending agent of 20% acarid growth inhibitor class acaricide compound I.
Example 9,50% clofentezine chemical compounds I suspending agent（1:1）
By recipe requirements, by 25 parts of clofentezines, 25 parts of chemical compounds Is, 2 parts of naphthalenesulfonic acid-formaldehyde condensates, 1 part of Morwet
EFW, 2 parts of agriculture breast T-20,4 parts of agriculture breast 0203B, 0.1 part of xanthans, 0.3 part of white carbon, 5 parts of ethylene glycol, complemented to water
100%, it is added sequentially to mix in blending tank, first passes through high shear and carry out coarse crushing, homogenize, then be pumped into sand mill
Row fine grinding, the granularity that material is sanded is detected with particles distribution instrument, after particle diameter reaches standard requirement, filtering, you can obtain 50% 4
Mite piperazine chemical compounds I suspending agent.
Can also be by one kind in the acarid growth inhibitor class acaricide described by clofentezine alternative costs specification, shape
The Cheng Xin suspending agent of 20% acarid growth inhibitor class acaricide compound I（1:1）.
Embodiment 10,20% Hexythiazox chemical compounds I microemulsion
By recipe requirements, by 1 part of Hexythiazox, 19 parts of chemical compounds Is, 10 parts of triphenyl vinyl phenol polyoxyethylene (n20) ether phosphoric acid
Change triethanolamine salt, 6 parts of agriculture breast OP-10,8 parts of agriculture breast 2201#, 2 parts of Nongru-700 #, 6 parts of N- methyl-pyrrolidons, 3 parts of phosphoric acid
Triethyl is added together, and makes to be dissolved into homogeneous oil phase, surplus complements to 100% with water, and under high velocity agitation, aqueous phase is added to
Oil phase is added to aqueous phase by oil phase, forms 20% Hexythiazox chemical compounds I microemulsion of favorable dispersibility.
Can also be by one kind in the acarid growth inhibitor class acaricide described by Hexythiazox alternative costs specification, shape
The Cheng Xin microemulsion of 20% acarid growth inhibitor class acaricide compound I.
Embodiment 11,20% Hexythiazox chemical compounds I soluble concentrate
By recipe requirements, by 1 part of Hexythiazox, 19 parts of chemical compounds Is, 12 parts of agriculture breast 2201#, 3 parts of agriculture breast 1601#, 4 parts of agriculture breasts
0201B, 10 parts of dimethylformamides, 6 parts of methanol, 20 parts of dimethyl sulfoxide (DMSO)s, the molten fiber of methyl complement to 100% and are well mixed, must
Dissolved by heating when wanting with hot bath, 20% Hexythiazox chemical compounds I soluble concentrate can be made.
Can also be by one kind in the acarid growth inhibitor class acaricide described by Hexythiazox alternative costs specification, shape
The Cheng Xin soluble concentrate of 20% acarid growth inhibitor class acaricide compound I.
Embodiment 12,20% clofentezine chemical compounds I water dispersible oil suspending agent
By recipe requirements, by 1 part of clofentezine, 19 parts of chemical compounds Is, 5 parts of agriculture breast 0201B, 3 parts of agriculture breast S-80,4 parts of agriculture breasts
500#, 3 parts of agriculture breast 1601#, 10 parts of methyl oleates, 3 parts of white carbons, 1 part of agriculture breast T-20, methylated soya oil complement to 100%
It is added sequentially to mix in blending tank, first passes through high shear and carry out coarse crushing, homogenize, be then pumped into sand mill and carry out carefully
Mill, the granularity that material is sanded is detected with particles distribution instrument, after particle diameter reaches standard requirement, filtering, you can obtain 20% 4 mite
Piperazine chemical compounds I water dispersible oil suspending agent.
Can also be by one kind in the acarid growth inhibitor class acaricide described by clofentezine alternative costs specification, shape
The Cheng Xin water dispersible oil suspending agent of 20% acarid growth inhibitor class acaricide compound I.
Indoor biological determination of activity
Synergism determination of composition of the embodiment 13 containing chemical compounds I to Tetranychus cinnabarinus
For trying object：Tetranychus cinnabarinus（Tetranychus cinnabarinus Boisduval）, into mite, indoor feeding
Sensitive strain.
Test condition：Temperature：24~26 DEG C, humidity：RH60%, illumination：L:D=14:10
Test method：Using pot-spraying method.The potted plant Kidney bean seedling of sizing of hot-house culture（2 true leaves）, a piece of true leaf is stayed,
Mite 40-60 heads are connected into thereon.Examination material is handled with decoction using Airbrush spray-on processes, dried in the shade naturally.Blank control is first handled,
Then aforesaid operations are repeated from low to high according to experimental design dosage, often handle 4 repetitions.Test worm after processing is placed in
In observation ward, routine observation test worm response situation, number of dead and live insects is investigated after 72h, calculate the death rate.
Evaluation uses Bliss methods, and this method is one of classical way for evaluating mixture effect.Bliss proposes according to it
Independent joint action concept thinks, theoretical death rate P during Mixture Use of Insecticides can be calculated with following formula：
P=Pm+Pn(1-Pm)
PmFor the death rate of the first active component target when concentration is m（%）；PnIt is n for the second active component concentration
When target the death rate（%）.
If the actual of two kinds of active component targets after being mixed with finite concentration is more than theoretical death rate P,
Judge that two kinds of active components are used in mixed way with synergistic effect in the case where setting concentration, it is on the contrary then be antagonism.
It the results are shown in Table 1.
The chemical compounds I of table 1 is used in mixed way the synergism determination to Tetranychus cinnabarinus into mite with clofentezine, etoxazole
The chemical compounds I of embodiment 14 is used in mixed way to Tetranychus cinnabarinus toxicity determination test with clofentezine
For trying object：Tetranychus cinnabarinus（Tetranychus cinnabarinus Boisduval）, into mite, indoor feeding
Sensitive strain.
Test condition：Temperature：24~26 DEG C, humidity：RH60%, illumination：L:D=14:10
Test medication liquid making method：Reagent agent is accurately weighed respectively with electronic analytical balance, respectively by two kinds of active compounds
Appropriate solvent acetone is added, after being completely dissolved, required concentration mother liquor is configured to the water containing 0.1% Tween 80, by two kinds effectively
Mixed solution is hybridly prepared into by a certain percentage into decomposition mother solution, is diluted to tool finite concentration gradient respectively by experimental design dosage
Serial decoction.
Test method：Using pot-spraying method.The potted plant Kidney bean seedling of sizing of hot-house culture（2 true leaves）, a piece of true leaf is stayed,
Mite 40-60 heads are connected into thereon.Examination material is handled with decoction using Airbrush spray-on processes, dried in the shade naturally.Blank control is first handled,
Then aforesaid operations are repeated from low to high according to experimental design dosage, often handle 4 repetitions.Test worm after processing is put
In in observation ward, routine observation test worm response situation, number of dead and live insects is investigated after 72h, calculates the death rate.
Corrected mortality is calculated with abbott formula, appliance computer program is obtained each mixed for examination single dose and variant proportioning
Virulence regression equation, LC50 values and 95% confidence limit, with Sun Yunpei (Sun Y-P) method, obtain that each proportioning is mixed to be total to
Malicious coefficient, is evaluated.If co-toxicity coefficient is summation action close to 100, hence it is evident that is synergistic effect higher than 100, hence it is evident that less than 100
For antagonism.
Result of the test is shown in Table 2.As can be seen from the table, chemical compounds I is mixed to cinnabar leaf for trying each proportioning with clofentezine
Mite shows synergistic effect.
Table 2：Chemical compounds I clofentezine is to joint toxicity measuring result in Tetranychus cinnabarinus room
Claims (7)
1. one kind contains the acaricidal insecticide acaricide composition of acarid growth inhibitor class, it is characterised in that：Composition contains A, B
Two kinds of active components, the ratio of weight and number between component A and the components of component B two are 1:20-20:1；
Active component A is selected from the chemical compounds I shown in following structural formula, and the chemical compounds I structure is as follows：
Chemical compounds I;
The active component B is selected from clofentezine or etoxazole.
2. according to the composition described in claim 1, it is characterised in that：Active component A is selected from the chemical compounds I shown in structural formula,
Active component B is selected from clofentezine；The ratio of weight and number of two kinds of active components is 1:19-19:1.
3. according to the composition described in claim 1, it is characterised in that：Composition can be configured to missible oil, suspending agent, moisture and dissipate
Property granula, aqueous emulsion, microemulsion, soluble concentrate, wettable powder or water dispersible oil suspending agent.
4. according to the composition described in claim 3, it is characterised in that：The cumulative amount of active component is in 0.5%- in composition
Between 95%.
5. according to the composition described in claim 4, it is characterised in that：The cumulative amount of active component is in 1%-85% in composition
Between.
A kind of 6. answering containing the acaricidal insecticide acaricide composition of acarid growth inhibitor class according to described in claim 1
With, it is characterised in that：The composition is used to prepare insecticidal/acaricidal agent, for controlling agricultural pests or urban health insect.
7. according to the application containing the acaricidal insecticide acaricide composition of acarid growth inhibitor class described in claim 6, its
It is characterised by：With effective agent gauge, the composition for being prepared into insecticidal/acaricidal agent is imposed on to the insect for needing to control or its life
On long medium.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310611078.2A CN104663672B (en) | 2013-11-26 | 2013-11-26 | One kind contains the acaricidal insecticide acaricide composition of acarid growth inhibitor class |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310611078.2A CN104663672B (en) | 2013-11-26 | 2013-11-26 | One kind contains the acaricidal insecticide acaricide composition of acarid growth inhibitor class |
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| CN106605657A (en) * | 2015-10-24 | 2017-05-03 | 陕西韦尔奇作物保护有限公司 | Pesticide combination containing SYP-9625 |
| CN106417321A (en) * | 2016-08-23 | 2017-02-22 | 青岛东生药业有限公司 | Compound miticide as well as dose form and use thereof |
| CN106937634A (en) * | 2017-03-15 | 2017-07-11 | 安徽省农业科学院植物保护与农产品质量安全研究所 | A kind of acaricide composition and its application method |
| CN109691451B (en) * | 2017-10-24 | 2021-03-05 | 沈阳中化农药化工研发有限公司 | Insecticidal and acaricidal synergistic composition containing ethacrylonitrile and application thereof |
| CN109122692B (en) * | 2018-10-18 | 2020-08-07 | 江苏省农业科学院 | Insecticidal and acaricidal pesticide composition with synergistic effect |
| CN111226927B (en) * | 2018-11-29 | 2021-06-01 | 沈阳中化农药化工研发有限公司 | Insecticidal and acaricidal composition containing mite growth inhibitor acaricide |
| CN114586796A (en) * | 2020-12-04 | 2022-06-07 | 浙江省化工研究院有限公司 | Acaricidal composition containing oxazofen |
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| CN101875633A (en) * | 2009-04-29 | 2010-11-03 | 中国中化股份有限公司 | Pyrazolyl acrylonitrile compound and application thereof |
| CN102438987A (en) * | 2009-05-22 | 2012-05-02 | 日产化学工业株式会社 | Crystals of cyenopyrafen and its preparation methods |
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| JP2003201280A (en) * | 2001-10-24 | 2003-07-18 | Nissan Chem Ind Ltd | Acrylonitrile compound |
| JP2008150302A (en) * | 2006-12-15 | 2008-07-03 | Nissan Chem Ind Ltd | Insecticidal or acaricidal composition |
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| CN101875633A (en) * | 2009-04-29 | 2010-11-03 | 中国中化股份有限公司 | Pyrazolyl acrylonitrile compound and application thereof |
| CN102438987A (en) * | 2009-05-22 | 2012-05-02 | 日产化学工业株式会社 | Crystals of cyenopyrafen and its preparation methods |
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