CN106342818A - Pesticide composition containing chlorantraniliprole and fluopyram and use thereof - Google Patents
Pesticide composition containing chlorantraniliprole and fluopyram and use thereof Download PDFInfo
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- CN106342818A CN106342818A CN201610754289.5A CN201610754289A CN106342818A CN 106342818 A CN106342818 A CN 106342818A CN 201610754289 A CN201610754289 A CN 201610754289A CN 106342818 A CN106342818 A CN 106342818A
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- fluopyram
- rynaxypyr
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
- A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
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Abstract
The invention relates to a pesticide composition containing chlorantraniliprole and fluopyram and an use thereof. The pesticide composition contains chlorantraniliprole and fluopyram. The weight ratio of effective ingredients such as chlorantraniliprole to fluopyram is 1:80-80:1. The total weight of effective ingredients such as chlorantraniliprole and fluopyram accounts for the weight percentage of 0.02% to 90% in the composition. The composition can be prepared into a suspension concentrate, wettable powder, water dispersible granules, granules, water emulsion, microemulsion or ultra-low volume liquid. The pesticide composition is mainly used for preventing crops such as peanuts, potatoes, and corns from plant diseases and insect pests such as nematode diseases and underground insect grubs.
Description
Technical field
The invention belongs to technical field of pesticide is and in particular to a kind of pesticide containing Rynaxypyr and fluopyram
Compositionss.
Technical background
Rynaxypyr (chlorantraniliprole), the Lepidoptera of remarkable high-efficiency broad spectrum, main beetle and aleyrodid
Insecticide, just has reliable and stable preventive effect under low dosage, stops immediately taking food, the drug effect phase is longer, rainwater-proof rinses, and is making
Any period of thing growth provide at once with permanent protection.Its mechanism of action is different from other kind of insecticides, can be in conjunction with elder brother
Ryanodine receptor in polypide, suppresses insect's food-taking, causes polypide to shrink, ultimately results in insect dead.
Fluopyram (fluopyram), is a kind of pyridine ethyl Benzoylamide series bactericidal agent, by hindering in respiratory chain
The mould electron transfer of succinic acid dehydrogenation and suppress mitochondrial respiratory.Can be used for preventing and kill off including Fructus Vitis viniferae, pears and core fruits and vegetables and land for growing field crops
The multiple diseases such as the gray mold in 70 interior various crop such as crop, powdery mildew, sclerotiniose.
Holotrichia diomphalia Batess, the heaviest to the harm mainly spring and autumn of orchard nursery, seedling and other crops.It is tender that Holotrichia diomphalia Batess sting food seedling
Stem, potato class tuber is drilled to eyelet, when plant withered and yellow and dead when, it is transferred to other plant again and continues harm.Additionally, because of Qi
The wound that Scarabaeiform causes also can induce disease.Wherein phytophagous Holotrichia diomphalia Batess feeding habits extensively, endanger multiple kinds of crops, industrial crops and flowers
Nursery stock, the eating just seed of sowing, root, tuber and seedling, is global subterranean pest-insect, harm is very big.
Plant pathogeny line insect refers to can colonize in plant body, and endangers its host, causes production loss or product matter
Amount declines, and causes a class nematicide of plant disease, main inclusion encapsulation nematicide, root-knot nematode, aphelenchoides and Ditylenchus dipsaci etc..Its
As one of main agricultural pests, Crop damage can be caused every year to reach 78,000,000,000 dollars.Nematicide can parasitize several in plant body
Any position, presents various Disease symptoms, and as weak in plant growing way, lopsided or even whole strain is withered, partial line in addition
Worm can also propagate some funguses and bacterial disease, thus leading to bigger economic loss.
At present, due to the too high preventing and treating effect so that pest resistance to insecticide just gradually strengthens, to insect of single-dose product usage frequency
Fruit substantially reduces, even if increasing dosage also do not reach preferable prevention effect.
Content of the invention
It is an object of the invention to provide a kind of composition pesticide containing Rynaxypyr and fluopyram, work in coordination with and increase
Effect effect is notable, and preventive effect is good, and dosage is low, and the lasting period is long, slows down Drug resistance simultaneously.
The weight of said composition effective ingredient Rynaxypyr and fluopyram than for 1-80:80-1, preferably 20:
1-1:40.
Said composition effective ingredient Rynaxypyr and fluopyram percentage by weight in the composition are
0.02%-90%；
This constituent also can comprise dispersant, emulsifying agent, antifreezing agent, thickening agent, defoamer, wetting agent, glue according to dosage form
Knot agent, disintegrating agent, slow releasing agent, the part in coating agent, supply 100% with carrier, filler or solvent.
This compositions effective ingredient is Rynaxypyr and fluopyram, then allocate the insecticides adjuvant of corresponding dosage form into can
Make suspending agent, wettable powder, water dispersible granules, granule, aqueous emulsion, microemulsion or ultra low volume liquids.
The above dispersant is naphthalene sulfonate, lignosulfonates, polycarboxylate, Ketohexamethylene formaldehyde condensation products, alkyl
Benzene sulfonate, alkylphenol polyoxyethylene, fatty alcohol-polyoxyethylene ether, castor oil polyoxyethylene ether, fatty alcohol-polyoxyethylene ether
One or more of formaldehyde condensation products sulfate.
The above emulsifying agent is alkylphenol polyoxyethylene, styrylphenol polyoxyethylene ether, polyoxyethylene nonyl phenyl second
Alkene ether, styrylphenol polyoxyethylene ether phosphate ester, aliphatic alcohol polyethenoxy ester, alkyl polyoxyethylene sulfate salt, phenethyl
One or more of phenol polyethenoxy polyethenoxy ether.
The above antifreezing agent is ethylene glycol, propylene glycol, glycerol, one or more of carbamide.
The above thickening agent is xanthan gum, arabic gum, aluminium-magnesium silicate, polyvinyl alcohol, carboxymethyl cellulose, Guar
Glue, one or more of sodium alginate.
The above defoamer is organic silicone oil defoamer, c8-10 aliphatic alcohols compound, in silicone defoamer
Plant or multiple.
The above solvent is Ketohexamethylene, dimethyldecamide, solvent naphtha, n- methyl pyrrolidone, ethyl acetate, acetic acid
Secondary butyl ester, methyl oleate, Oleum Terebinthinae, toluene, dimethylbenzene, benzyl alcohol, n-butyl alcohol, isopropanol, ethanol, methanol, in water equal solvent
One or more.
The above wetting agent is sodium lauryl sulphate, calcium dodecyl benzene sulfonate, pull open powder, tea saponin, alkylnaphthalene
One or more of wetting agent such as sodium sulfonate.
The above binding agent is starch, sucrose, carboxymethyl cellulose, polyvinyl alcohol, Macrogol 8000, magnesium silicate
Aluminum, one or more of organobentonite.
Above-described coating agent is polyester resin, Polyvinylpyrrolidone, polyvinyl alcohol, cellulose nitrate film former, fourth
One or more of diene resin film former, acrylic resin film former, polyurethane finishing agent combine.
The above disintegrating agent is sodium sulfate, ammonium sulfate, carbamide, sodium chloride, calcium nitrate, magnesium nitrate, in ammonium chloride
Plant or multiple.
Described slow releasing agent is one of arabic gum, polyvinyl alcohol.
Described carrier is ammonium dihydrogen phosphate, white carbon, calcium sulfate, Kaolin, kieselguhr, quartz sand, brick slag, carbonic acid
One of calcium, attapulgite, aluminium-magnesium silicate, bentonite, stone powder, potassium dihydrogen phosphate, dalcium biphosphate, fertilizer or one kind with
Upper combination.
Above-described carrier is ammonium dihydrogen phosphate, white carbon, calcium sulfate, Kaolin, kieselguhr, quartz sand, brick slag, carbon
One of sour calcium, attapulgite, aluminium-magnesium silicate, bentonite, stone powder, potassium dihydrogen phosphate, dalcium biphosphate, fertilizer or one kind
Combination of the above.
The above filler is white carbon, carbamide, sodium sulfate, ammonium sulfate, Kaolin, precipitated calcium carbonate, bentonite, diatom
One or more of soil.
When the dosage form of described composition pesticide is suspending agent, its component includes: Rynaxypyr 1%-80%, fluorine pyrrole
Bacterium amide 1%-80%, dispersant 0.1%-10%, antifreezing agent 0.1%-5%, thickening agent 0.1%-3%, defoamer 0.01%-
0.5%, water supplies 100%.
When the dosage form of described composition pesticide is water dispersible granules, its component includes: Rynaxypyr 1%-80%,
Fluopyram 1%-80%, dispersant 0.1%-10%, wetting agent 0.1%-5%, disintegrating agent 0.1%-10%, binding agent
0.1%-5%, filler supplies 100%.
When the dosage form of described composition pesticide is wettable powder, its component includes: Rynaxypyr 1%-80%,
Fluopyram 1%-80%, dispersant 0.1%-10%, wetting agent 0.1%-5%, filler supplies 100%.
When the dosage form of described composition pesticide is granule, its component Rynaxypyr 0.01%-3%, fluorine pyrrole bacterium
Amide 0.01%-3%, auxiliary agent 1%-15%, slow releasing agent 0.1%-3%, disintegrating agent 1%-10%, binding agent 0.1%-5%, bag
Membrane 0.1-0.5%, carrier supplies 100%.
When the dosage form of described composition pesticide is aqueous emulsion, its component includes: Rynaxypyr 1%-80%, fluorine pyrrole
Bacterium amide 1%-80%, solvent 5%-30%, emulsifying agent 0.5%-12%, dispersant 0.1%-10%, antifreezing agent 0.1%-
5%, water supplies 100%.
When the dosage form of described composition pesticide is microemulsion, its component includes: Rynaxypyr 1%-80%, fluorine pyrrole
Bacterium amide 1%-80%, solvent 5%-30%, emulsifying agent 0.5%-12%, dispersant 0.1%-10%, water supplies 100%.
When the dosage form of described composition pesticide is ultra low volume liquids, its component includes: Rynaxypyr 1%-
80%, fluopyram 1%-80%, emulsifying agent 0.5%-12%, dispersant 0.1%-10%, solvent supplies 100%.
Composition pesticide synergistic function provided by the present invention substantially, can be used for preventing and treating Semen arachidis hypogaeae, Rhizoma Solani tuber osi, Semen Maydiss etc.
The pest and disease damage such as the nematicide of crop and subterranean pest-insect Holotrichia diomphalia Batess, preventive effect is good, and dosage is low, and the lasting period is long, slows down Drug resistance simultaneously.
Specific embodiment
With reference to embodiment, the present invention is described in further detail, below the side of being preferable to carry out of the only present invention
Formula, protection scope of the present invention is not limited thereto, any those skilled in the art in technical scope disclosed by the invention,
All similar replacements and change are all included within the scope of the present invention.Therefore, protection scope of the present invention Ying Yiquan
The protection domain of sharp claim is defined.
First, prepare embodiment
The suspending agent of embodiment 1, containing chlorantraniliprole and fluopyram
Component includes: Rynaxypyr 20%, fluopyram 10%, lignosulfonates 2%, fatty alcohol polyoxy second
Alkene ether 3%, ethylene glycol 5%, aluminium-magnesium silicate 1%, xanthan gum 0.15%, organic silicon defoamer 0.4%, water supplies 100%.
Preparation technology is: weighs material, by water, lignosulfonates, fatty alcohol polyoxy second by above-mentioned mass percent
Alkene ether, ethylene glycol, aluminium-magnesium silicate, xanthan gum, defoamer mix homogeneously, then add Rynaxypyr and fluorine pyrrole while stirring
Bacterium amide.By above-mentioned material mixing shearing 30 minutes, make material mix homogeneously.It is ground to particle diameter d90 micro- less than 5 in sand mill
Rice, obtains final product 30% Rynaxypyr fluopyram suspending agent.
The suspending agent of embodiment 2, containing chlorantraniliprole and fluopyram
Component includes: Rynaxypyr 15%, fluopyram 15%, alkylbenzenesulfonate 2%, polyoxyethylene nonyl phenyl second
Alkene ether 4.5%, carbamide 5%, aluminium-magnesium silicate 0.4%, xanthan gum 0.2%, organic silicon defoamer 0.5%, water supplies 100%.
Preparation technology is: weighs material, by water, alkylbenzenesulfonate, polyoxyethylene nonyl phenyl second by above-mentioned mass percent
Alkene ether, carbamide, aluminium-magnesium silicate, xanthan gum, organic silicon defoamer mix homogeneously, then while stirring add Rynaxypyr and
Fluopyram.By above-mentioned material mixing shearing 30 minutes, make material mix homogeneously.It is ground to particle diameter d90 little in sand mill
In 5 microns, obtain final product 30% Rynaxypyr fluopyram suspending agent.
The wettable powder of embodiment 3, containing chlorantraniliprole and fluopyram
Component includes: Rynaxypyr 40%, fluopyram 30%, naphthalene sulfonate 5%, styrylphenol polyoxy
Ethylene ether phosphate 3%, sodium lauryl sulphate 2%, white carbon 4%, Kaolin supplies 100%.
Preparation technology is: weighs material by above-mentioned mass percent, by Rynaxypyr, fluopyram, LOMAR PWA EINECS 246-676-2
Salt, styrylphenol polyoxyethylene ether phosphate ester, sodium lauryl sulphate, white carbon, Kaolin puts into mixing and blending machine and stirs
Mix uniformly, below comminution by gas stream to 800 mesh, obtain final product 70% Rynaxypyr fluopyram wettable powder.
The wettable powder of embodiment 4, containing chlorantraniliprole and fluopyram
Component includes: Rynaxypyr 50%, fluopyram 20%, naphthalene sulfonate 4%, phenethyl phenol polyoxyethylene
Polyethenoxy ether 4%, sodium lauryl sulphate 3%, white carbon 2%, kieselguhr supplies 100%.
Preparation technology is: weighs material by above-mentioned mass percent, by Rynaxypyr, fluopyram, LOMAR PWA EINECS 246-676-2
Salt, phenethyl phenol polyoxyethylene poly-oxygen propylene aether, sodium lauryl sulphate, white carbon, Kaolin puts into mixing and blending machine stirring
Uniformly, comminution by gas stream obtains final product 70% Rynaxypyr fluopyram wettable powder to 800 mesh.
The water dispersible granules of embodiment 5, containing chlorantraniliprole and fluopyram
Component includes: Rynaxypyr 25%, fluopyram 15%, lignosulfonates 3%, alkyl polyoxyethylene
Sulfonate 3%, white carbon 3%, sodium sulfate 10%, polyvinyl alcohol 0.1%, Kaolin supplies 100%.
Preparation technology is: weighs material by above-mentioned mass percent, by Rynaxypyr, fluopyram, lignin
Sulfonate, alkyl polyoxyethylene sulfate salt, white carbon, ammonium sulfate, Kaolin puts into mix homogeneously in mixer, then enters circulation of qi promoting
Stream is pulverized.Add the good material of comminution by gas stream in mixer, the aqueous solution that spray people contains polyvinyl alcohol carries out fluidized bed prilling,
It is qualified to moisture to dry under the conditions of 50-80 degree, obtains final product 40% Rynaxypyr fluopyram water dispersible granules.
The water dispersible granules of embodiment 6, containing chlorantraniliprole and fluopyram
Component includes: Rynaxypyr 35%, fluopyram 5%, Ketohexamethylene formaldehyde condensation products 3%, polycarboxylate
5%, sodium lauryl sulphate 4%, white carbon 3%, ammonium sulfate 10%, starch 4%, kieselguhr supplies 100%.
Preparation technology is: weighs material by above-mentioned mass percent, by Rynaxypyr, fluopyram, Ketohexamethylene
Formaldehyde condensation products, polycarboxylate, sodium lauryl sulphate, white carbon, ammonium sulfate, kieselguhr puts into mix homogeneously in mixer,
Then carry out comminution by gas stream.Add the good material of comminution by gas stream in mixer, the spray amyloid aqueous solution of people enters fluid bed and makes
Grain, it is qualified to moisture to dry under the conditions of 50-80 degree, obtains final product 40% Rynaxypyr fluopyram water dispersible granules.
Embodiment 7, containing chlorantraniliprole and fluopyram granule
Component includes: Rynaxypyr 2.5%, fluopyram 0.5%, polycarboxylate 2%, calcium lignosulfonate
4%, polyvinyl alcohol 3.5%, polyester resin 0.5%, arabic gum 2%, brick slag is mended to 100%.
Preparation technology: Rynaxypyr, fluopyram, polycarboxylate, calcium lignosulfonate, polyvinyl alcohol gather
Female powder is obtained through comminution by gas stream after ester mixed with resin is uniform；Arabic gum water dissolution is obtained the aqueous solution of coating agent；Weigh
Brick slag is placed in coating equipment in sugar production line, adds a certain amount of coating agent aqueous solution stirring moistening carrier, add mother in equipment
Powder mix and blend, is eventually adding remaining peplos agent solution mixing and stirring, and the good granule of above-mentioned peplos is passed through drying
Equipment dry qualified after testing after obtain 3% Rynaxypyr fluopyram granule.
Embodiment 8, containing chlorantraniliprole and fluopyram granule
Component includes: Rynaxypyr 2.0%, fluopyram 1%, dioctyl sodium sulfosuccinate 1.5%, butyl
Sodium naphthalene sulfonate 4%, carboxymethyl cellulose 4%, butadiene resin film former 0.3%, polyvinyl alcohol 3%, quartz sand mend to
100%.
Preparation technology: by Rynaxypyr, fluopyram, dioctyl sodium sulfosuccinate, sodium butylnaphthalenesulfonate, carboxylic
Methylcellulose, obtains female powder through comminution by gas stream after polyvinyl alcohol is uniform；Butadiene resin film former water dissolution is obtained
Aqueous solution to coating agent；Weigh quartz sand to be placed in coating equipment in sugar production line, add a certain amount of coating agent aqueous solution to mix in equipment
Close stirring moistening carrier, add female powder mix and blend, be eventually adding remaining peplos agent solution mixing and stirring, will be above-mentioned
The good granule of peplos by drying equipment dry qualified after testing after obtain 3% Rynaxypyr fluopyram granule
Agent.
The aqueous emulsion of embodiment 9, containing chlorantraniliprole and fluopyram
Component includes: Rynaxypyr 10%, fluopyram 5%, dimethyldecamide 8%, dimethylbenzene 5%, benzene
Ethyl phenol polyoxyethylene poly-oxygen propylene aether 4%, fatty alcohol-polyoxyethylene ether formaldehyde condensation products sulfate 2.5%, carbamide 5%, water
Supply 100%.
Preparation technology is: weighs material by above-mentioned mass percent, by dimethylbenzene, dimethyldecamide, phenethyl phenol is gathered
Oxygen ethylene polyethenoxy ether, fatty alcohol-polyoxyethylene ether formaldehyde condensation products sulfate, Rynaxypyr, fluopyram puts into
In reactor, mixing and stirring is oil phase, and it is aqueous phase that carbamide is put into mix homogeneously in water, stirs in 3000 revs/min of high speed shear
Mix down, oil phase is added in aqueous phase, shearing dispersion 1 hour, obtain final product 15% Rynaxypyr fluopyram aqueous emulsion.
The aqueous emulsion of embodiment 10, containing chlorantraniliprole and fluopyram
Component includes: Rynaxypyr 5%, fluopyram 10%, dimethyldecamide 10%, Ketohexamethylene 5%, fat
Fat polyoxyethylenated alcohol 3.5%, fatty alcohol-polyoxyethylene ether formaldehyde condensation products sulfate 4%, ethylene glycol 4%, water is supplied
100%.
Preparation technology is: weighs material by above-mentioned mass percent, by Ketohexamethylene, dimethyldecamide, fatty alcohol polyoxy
Vinyl Ether, fatty alcohol-polyoxyethylene ether formaldehyde condensation products sulfate, Rynaxypyr, fluopyram puts into mixed in reactor
Conjunction is stirred for oil phase, and it is aqueous phase that ethylene glycol is put into mix homogeneously in water, under 3000 revs/min of high shear agitation, will
Oil phase adds in aqueous phase, shearing dispersion 1 hour, obtains final product 15% Rynaxypyr fluopyram aqueous emulsion.
The microemulsion of embodiment 11, containing chlorantraniliprole and fluopyram
Component includes: Rynaxypyr 10%, fluopyram 10%, Ketohexamethylene 10%, dimethyldecamide 10%,
Fatty alcohol-polyoxyethylene ether 3, fatty alcohol-polyoxyethylene ether formaldehyde condensation products sulfate 5%, calcium dodecyl benzene sulfonate 4%, water
Supply 100%.
Preparation technology is: weighs material by above-mentioned mass percent, by Ketohexamethylene, dimethyldecamide, fatty alcohol polyoxy
Vinyl Ether, fatty alcohol-polyoxyethylene ether formaldehyde condensation products sulfate, calcium dodecyl benzene sulfonate, Rynaxypyr, fluorine pyrrole bacterium
It is oil phase that amide puts into mixing and stirring in reactor, adds water to, in oil phase, be uniformly mixed, obtains final product 20% chlorine worm benzene
Methanamide fluopyram microemulsion.
The microemulsion of embodiment 12, containing chlorantraniliprole and fluopyram
Component includes: Rynaxypyr 15%, fluopyram 5%, dimethylbenzene 20%, Ketohexamethylene 5%, poly alkyl alcohol
Oxygen vinyl Ether 3%, fatty alcohol-polyoxyethylene ether formaldehyde condensation products sulfate 5%, calcium dodecyl benzene sulfonate 5%, water is supplied
100%.
Preparation technology is: weigh material by above-mentioned mass percent, by Ketohexamethylene, and dimethylbenzene, fatty alcohol-polyoxyethylene ether,
Fatty alcohol-polyoxyethylene ether formaldehyde condensation products sulfate, calcium dodecyl benzene sulfonate, Rynaxypyr, fluopyram puts into
In reactor, mixing and stirring is oil phase, adds water to, in oil phase, be uniformly mixed, obtains final product 20% Rynaxypyr fluorine
Pyrrole bacterium amide microemulsion.
The ultra low volume liquids of embodiment 13, containing chlorantraniliprole and fluopyram
Component includes: Rynaxypyr 15%, fluopyram 35%, dimethyldecamide 15%, fatty alcohol polyoxy
Vinyl Ether 4%, calcium dodecyl benzene sulfonate 5%, solvent naphtha supplies 100%.
Preparation technology is: weighs material by above-mentioned mass percent, by above-mentioned active compound, solvent, emulsifying agent mix and blend is molten
Solve as homogeneous oil phase, obtain final product 50% Rynaxypyr fluopyram ultra low volume liquids.
The ultra low volume liquids of embodiment 14, containing chlorantraniliprole and fluopyram
Component includes: Rynaxypyr 20%, fluopyram 30%, dimethyldecamide 15%, fatty alcohol polyoxy
Vinyl Ether formaldehyde condensation products sulfate 4%, calcium dodecyl benzene sulfonate 5%, solvent naphtha supplies 100%.
Preparation technology is: weighs material by above-mentioned mass percent, by above-mentioned active compound, solvent, emulsifying agent mix and blend is molten
Solve as homogeneous oil phase, obtain final product 50% Rynaxypyr fluopyram ultra low volume liquids.
2nd, preventive effect embodiment
Application Example 1
Rynaxypyr and fluopyram indoor joint toxicity measuring test
By Rynaxypyr and fluopyram respectively in the ratio mixture in effective ingredient table 1.Test method: " in
Magnificent people's republic agricultural industry criteria ny/t1154.1-2006 ", " People's Republic of China (PRC) agricultural industry criteria ny/
T1154.7-2006 ", using drop method.Check within 24 hours dead borer population, calculate mortality rate.Blank is equivalent clear water.Each
Process 6 Concentraton gradient of setting.Carry out statistical analysiss with spss statistical analysis software, calculate the lc50 of each medicament, to comment according to this
The activity to test worm for the valency reagent agent, calculates co-toxicity coefficient (ctc) according to Sun Yunpei.
Actual measurement toxicity index=standard agent lc50/ reagent agent lc50*100
Single dose theoretical toxicity index=single dose actual measurement content in mixture for the toxicity index * single dose
Mixture theoretical toxicity index=each single dose theoretical toxicity index sum
Toxicity index/mixture theoretical toxicity index * 100 of co-toxicity coefficient=mixture actual measurement
Evaluation criterion: ctc≤80 are antagonism, 80<ctc<120 is summation action, and ctc>=120 are potentiation, real
Test result and refer to table 1.
Table 1 Rynaxypyr and the toxicity test result of fluopyram different ratio peanut grub
| Medicament | Proportioning | lc50(mg/l) | Co-toxicity coefficient (ctc) |
| Rynaxypyr (a) | ---- | 5.84 | / |
| Fluopyram (b) | ---- | 9.28 | / |
| a:b | 80:1 | 2.64 | 120.7 |
| a:b | 60:1 | 2.39 | 121.4 |
| a:b | 40:1 | 1.86 | 132.3 |
| a:b | 20:1 | 1.69 | 169.8 |
| a:b | 5:1 | 1.54 | 172.4 |
| a:b | 1:1 | 1.38 | 188.5 |
| a:b | 1:5 | 2.65 | 213.5 |
| a:b | 1:20 | 4.47 | 179.7 |
| a:b | 1:40 | 5.24 | 173.2 |
| a:b | 1:60 | 10.38 | 123.6 |
| a:b | 1:80 | 10.43 | 121.4 |
From measurement result table 1: Rynaxypyr and fluopyram press effective ingredient mass ratio 1:80-80:1 ratio
All there is potentiation to peanut grub, co-toxicity coefficient (ctc) is all higher than 120, wherein when both press 20:1-1:40 ratio after example mixture
It is especially pronounced to the potentiation of peanut grub after example is compounding.
Application Example 2
Indoors on the basis of toxicity test, carry out field medicine effect test checking.Controlling object: peanut grub.Sample plot
Point: Henan Zhenyang.Comparison medicament: 20% Rynaxypyr suspending agent sc, 41.7% fluopyram sc.
Result of the test shows: Rynaxypyr Biphenthrin granule preventing and treating peanut grub excellent, compares two kinds
Single dose complex preparation prevention effect is notable, illustrates that two kinds of effective ingredient have good potentiation after compounding, the lasting period is long.
Application Example 3
Indoors on the basis of toxicity test, carry out field medicine effect test checking.Controlling object: Rhizoma Solani tuber osi Holotrichia diomphalia Batess.Experiment
Place: Shandong Province Tengzhou City.Comparison medicament: 20% Rynaxypyr suspending agent sc, 41.7% fluopyram sc.
Result of the test shows: Rynaxypyr Biphenthrin granule preventing and treating Rhizoma Solani tuber osi Holotrichia diomphalia Batess excellent, compares two
Plant single dose complex preparation prevention effect notable, illustrate that two kinds of effective ingredient have good potentiation after compounding, the lasting period is long.
Application Example 4
Indoors on the basis of toxicity test, carry out field medicine effect test checking.Controlling object: potato nematode disease.Real
Test place: Shandong Province Tengzhou City.Comparison medicament: 20% Rynaxypyr suspending agent sc, 41.7% fluopyram sc.
Result of the test shows: Rynaxypyr Biphenthrin granule preventing and treating potato nematode disease excellent, compares
Two kinds of single dose complex preparation prevention effects are notable, illustrate that two kinds of effective ingredient have good potentiation after compounding, the lasting period is long.
Application Example 5
Indoors on the basis of toxicity test, carry out field medicine effect test checking.Controlling object: Semen Maydiss nematicide.Experiment
Place: Shaanxi Province Liquan County.Comparison medicament: 20% Rynaxypyr suspending agent sc, 41.7% fluopyram sc.
Result of the test shows: Rynaxypyr Biphenthrin granule preventing and treating Semen Maydiss nematicide excellent, compares two
Plant single dose complex preparation prevention effect notable, illustrate that two kinds of effective ingredient have good potentiation after compounding, the lasting period is long.
Application Example 6
Indoors on the basis of toxicity test, carry out field medicine effect test checking.Controlling object: Semen arachidis hypogaeae nematicide.Experiment
Place: Shaanxi Province Liquan County.Comparison medicament: 20% Rynaxypyr suspending agent sc, 41.7% fluopyram sc.
Result of the test shows: Rynaxypyr Biphenthrin granule preventing and treating Semen arachidis hypogaeae nematicide excellent, compares two
Plant single dose complex preparation prevention effect notable, illustrate that two kinds of effective ingredient have good potentiation after compounding, the lasting period is long.
Claims (7)
1. a kind of composition pesticide containing Rynaxypyr and fluopyram is it is characterised in that effective ingredient is chlorine worm
Benzoylamide and fluopyram.
2. a kind of composition pesticide containing Rynaxypyr and fluopyram it is characterised in that: effective ingredient chlorine worm benzene
The weight of Methanamide and fluopyram is than for 1-80:80-1.
3. a kind of composition pesticide containing Rynaxypyr and fluopyram it is characterised in that: effective ingredient chlorine worm benzene
The weight of Methanamide and fluopyram is than for 20:1-1:40.
4. the composition pesticide of the Rynaxypyr according to claim 1,2 or 3 and fluopyram, its feature exists
In: described effective ingredient Rynaxypyr and fluopyram percentage by weight in the composition is 0.02%-90%.
5. the composition pesticide of the Rynaxypyr according to claim 1,2 or 3 and fluopyram, its feature exists
Be suspending agent in: the dosage form of described composition pesticide, wettable powder, water dispersible granules, granule, aqueous emulsion, microemulsion or
Ultra low volume liquids.
6. the composition pesticide of the containing chlorantraniliprole according to claim 1,2 or 3 and fluopyram is in preventing and treating flower
Life, Rhizoma Solani tuber osi, the purposes of the pest and disease damage of seeding corn and other crops.
7. purposes as claimed in claim 5 is it is characterised in that described pest and disease damage is to control Semen arachidis hypogaeae, Rhizoma Solani tuber osi, seeding corn and other crops
Nematicide and subterranean pest-insect Holotrichia diomphalia Batess.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610754289.5A CN106342818A (en) | 2016-08-28 | 2016-08-28 | Pesticide composition containing chlorantraniliprole and fluopyram and use thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610754289.5A CN106342818A (en) | 2016-08-28 | 2016-08-28 | Pesticide composition containing chlorantraniliprole and fluopyram and use thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106342818A true CN106342818A (en) | 2017-01-25 |
Family
ID=57855983
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610754289.5A Pending CN106342818A (en) | 2016-08-28 | 2016-08-28 | Pesticide composition containing chlorantraniliprole and fluopyram and use thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106342818A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109362740A (en) * | 2018-12-04 | 2019-02-22 | 陕西西大华特科技实业有限公司 | Contain Rynaxypyr and fluopyram, the seed coat agent of gamma cyhalothrin and purposes |
| CN110384103A (en) * | 2019-08-14 | 2019-10-29 | 陕西西大华特科技实业有限公司 | Contain benziothiazolinone and fluopyram, the seed coat agent of Rynaxypyr and purposes |
| CN113575595A (en) * | 2021-09-06 | 2021-11-02 | 上海明德立达生物科技有限公司 | Pesticide composition, preparation and application thereof |
| CN113647396A (en) * | 2021-09-07 | 2021-11-16 | 四川眉山凯尔化工有限公司 | Composition for killing nematodes and preparation method thereof |
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| CN1423631A (en) * | 2000-02-16 | 2003-06-11 | 石原产业株式会社 | Phenacylamine derivatives, production thereof and pest controllers containing the derivatives |
| CN101484007A (en) * | 2006-07-06 | 2009-07-15 | 拜尔农作物科学股份公司 | Pesticidal composition comprising a pyridylethylbenzamide derivative and an insecticide compound |
| CN102421290A (en) * | 2009-03-25 | 2012-04-18 | 拜尔农作物科学股份公司 | Nematicidal, insecticidal, and acaricidal combination of active substances, comprising pyridylethyl benzamide and insecticide |
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Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN1423631A (en) * | 2000-02-16 | 2003-06-11 | 石原产业株式会社 | Phenacylamine derivatives, production thereof and pest controllers containing the derivatives |
| CN101484007A (en) * | 2006-07-06 | 2009-07-15 | 拜尔农作物科学股份公司 | Pesticidal composition comprising a pyridylethylbenzamide derivative and an insecticide compound |
| CN102421290A (en) * | 2009-03-25 | 2012-04-18 | 拜尔农作物科学股份公司 | Nematicidal, insecticidal, and acaricidal combination of active substances, comprising pyridylethyl benzamide and insecticide |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109362740A (en) * | 2018-12-04 | 2019-02-22 | 陕西西大华特科技实业有限公司 | Contain Rynaxypyr and fluopyram, the seed coat agent of gamma cyhalothrin and purposes |
| CN109362740B (en) * | 2018-12-04 | 2020-11-10 | 陕西嘉益蓝德生物工程有限公司 | Seed coating agent containing chlorantraniliprole, fluopyram and lambda-cyhalothrin and application |
| CN110384103A (en) * | 2019-08-14 | 2019-10-29 | 陕西西大华特科技实业有限公司 | Contain benziothiazolinone and fluopyram, the seed coat agent of Rynaxypyr and purposes |
| CN113575595A (en) * | 2021-09-06 | 2021-11-02 | 上海明德立达生物科技有限公司 | Pesticide composition, preparation and application thereof |
| CN113647396A (en) * | 2021-09-07 | 2021-11-16 | 四川眉山凯尔化工有限公司 | Composition for killing nematodes and preparation method thereof |
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