CN104026146B - A kind of binary insecticides and purposes - Google Patents

A kind of binary insecticides and purposes Download PDF

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Publication number
CN104026146B
CN104026146B CN201310073306.5A CN201310073306A CN104026146B CN 104026146 B CN104026146 B CN 104026146B CN 201310073306 A CN201310073306 A CN 201310073306A CN 104026146 B CN104026146 B CN 104026146B
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insecticides
parts
binary
active component
insect
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CN104026146A (en
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宋玉泉
李轲轲
王丽颖
范晓溪
常秀辉
班兰凤
高亮
杨辉斌
李斌
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Shenyang Sciencreat Chemicals Co Ltd
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Shenyang Sciencreat Chemicals Co Ltd
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Abstract

The invention belongs to field of pesticides, relate to a kind of binary insecticides and purposes. Insecticides, active component one is tetrachloro insect amide, active component two is organophosphorus ester insecticides; Described tetrachloro insect amide structural formula is as follows, and described organophosphorus ester insecticides is Profenofos, chlopyrifos, Hostathion, phoxim, malathion or fenifrothion; Wherein, the ratio of weight and number between two kinds of active components is 1:99-99:1. Composition of the present invention has the advantages such as synergy is obvious, delaying drug resistance, can be used for preventing and treating various pests.

Description

A kind of binary insecticides and purposes
Technical field
The invention belongs to field of pesticides, relate to a kind of binary insecticides and purposes.
Background technology
Pesticide has obvious effect aspect control agriculture and forestry injurious insect or urban health insect.
Chinese invention patent CN101333213A discloses a kind of 1-substituted pyridyl-pyrazol acid amideThe purposes of compound and control insect pest and disease, wherein compound 1.25(is hereinafter to be referred as tetrachloro worm acylAmine) can be used for preventing and treating various pests, especially lepidoptera pest is had to outstanding prevention effect.
The pesticide that contains single-activity component uses continuously in control of insect, easily makes insect produceThe raw resistance to the action of a drug. Pesticide by two kinds of active components by a certain percentage mixture becomes blending ingredients, oftenCan improve preventive effect, reduce the consumption of active ingredient, cost-saving, can delay the anti-medicine of insect simultaneouslyThe generation of property.
Although disclose general tetrachloro insect amide or its homologue in prior art with other Mixture Use of InsecticidesCan produce additional advantage and effect, but the skill of the binary insecticides that contains tetrachloro insect amideIt is concrete open that art scheme has no.
Summary of the invention
The object of the invention is to meet agricultural and imitate pesticide pest control aspect, urban health fieldThe demand that fruit is day by day improved and kind is constantly updated, provides a kind of binary insecticides and purposes.
For achieving the above object, the technical solution used in the present invention is:
A kind of binary insecticides, active component one is tetrachloro insect amide, active component two is for havingMachine phosphoric acid ester pesticide;
Described tetrachloro insect amide structural formula is as follows:
Described organophosphorus ester insecticides is Profenofos, chlopyrifos, Hostathion, phoxim, horse tractionSulphur phosphorus or fenifrothion; Wherein, the ratio of weight and number between two kinds of active components is 1:99-99:1.
Further, active component one is tetrachloro insect amide, and active component two is Profenofos, poisons with poisonTick, Hostathion, phoxim, malathion or fenifrothion; Wherein, between two kinds of active componentsRatio of weight and number is 1:20-20:1.
Composition can be made into missible oil, suspending agent, water-dispersible granules, aqueous emulsion, microemulsion, solvableProperty liquor, wettable powder or oil-suspending agent.
In composition, the percentage by weight of active component is between 0.5%-95%.
Further, in composition the percentage by weight of active component between 1%-85%.
The purposes of binary insecticides, described composition can be used as control agriculture and forestry injurious insect or city is defendedThe pesticide of raw insect.
Described composition imposes on and needs on the insect of control or the medium of its growth with effective dose; ApplyDosage is the effective dose of 10 grams-500 grams of per hectares.
Further, apply the effective dose that dosage is 15 grams-100 grams of per hectares.
Tool of the present invention has the following advantages:
The one, composition of the present invention shows obvious synergistic effect in certain ratio range, improvesThe prevention effect of this compound to insect.
The 2nd, the present composition reduces the using dosage of compound in application, uses into thereby reduceThis, reduce environmental pollution.
The 3rd,, there is not cross resistance in the mechanism of action difference of each active ingredient in the present compositionProblem, can delay the generation of pest resistance to insecticide with its pest control, and raising antagonism populationPrevention effect.
Detailed description of the invention
A kind of binary insecticides, active component one is tetrachloro insect amide, structural formula is as follows:
Active component two is organophosphorus ester insecticides, is specially Profenofos (Profenofos), poisonDead tick (Chlorpyrifos), Hostathion (Triazophos), phoxim (Phoxim), horse traction sulphurPhosphorus (Malathion) or fenifrothion (Fenitrothion) etc.
Indoor biological activity determination demonstrates binary insecticides of the present invention and has synergistic effect.
Composition of the present invention can be finished product preparation form to be provided. Make as required missible oil, suspensionAgent, water-dispersible granules, aqueous emulsion, microemulsion, soluble liquid, wettable powder, oil suspendAgent etc. In composition, the percentage by weight cumulative amount of active component is between 0.5%-95%, preferably tiredLong-pending content is between 1%-85%. In composition of the present invention, the content of active component depends on independent useTime amount of application, also depend on mixed ratio and synergistic effect degree. The best model of active component contentEnclose different according to the preparation type of composition.
The preparation of composite preparation of the present invention can be prepared by conventional processing method, by active material withAfter liquid-carrier (solvent) or solid carrier mix, add one or more auxiliary agents as emulsifying agent, pointPowder, wetting agent, adhesive, stabilizing agent and defoamer etc. Conventionally in composition, contain at least oneCarrier and at least one surfactant. In all cases, should guarantee the active group of the present compositionDivide and be uniformly distributed.
Missible oil contains the active component of 10-75% conventionally, 2-20% emulsifying agent, other additive of 0-20%Such as stabilizing agent, bleeding agent, corrosion inhibitor etc., and solvent (also containing if desired cosolvent).
Suspending agent needs sand milling conventionally, to obtain stable non-deposition flowable product. Common in suspending agentContain 5-50% active component, 5-15% dispersant, 0.1-10% wetting agent, 4-10% antifreezing agent, 0-10%Other additive as defoamer, anticorrisive agent, stabilizing agent, bleeding agent and thickener, and liquid carriesBody surplus.
Water-dispersible granules is made 10-100 international standard sieve mesh (1.676-0.152mm) particle conventionally,Can be by extruding, dipping or the preparation of mist projection granulating method. Conventionally water-dispersible granules contains 0.5-80%Active component and auxiliary agent for example dispersant, wetting agent, disintegrant and the adhesive of 5-20%, and lazyProperty carrier surplus.
Wettable powder contains the active component of 10-85% conventionally, except solid inert carrier, conventionallyThe dispersant that contains 3-10%, can also contain wetting agent and (or) other additive of 0-10%, exampleAs bleeding agent or stabilizing agent.
Aqueous emulsion is that former medicine, organic solvent, surfactant are mixed to formation oil phase; By water, antifreezing agentMix, become transparent and homogeneous water. With high-shear emulsion machine high speed shear oil phase, slowly simultaneouslyWater is added to oil phase, active component 1-60% conventionally, surfactant 5-20%, antifreezing agent 2-10%,Water surplus.
Microemulsion is that former medicine, organic solvent, emulsifying agent, water are mixed, and becomes transparent and homogeneous liquid.Conventionally active component 1-50%, surfactant 10-40%, antifreezing agent 2-10%, water surplus.
Soluble liquid is that active component, organic solvent, surfactant are mixed, and becomes homogeneousTransparency liquid. Conventionally active component 1-50%, surfactant 6-20%, organic solvent surplus.
Oil-suspending agent is that active component, surfactant, oil base carrier are added to sand milling in sand mill, straightQualified to particle diameter, active component 2-60% conventionally, surfactant 6-20%, oil base carrier surplus.
Moisture dispersion liquid and emulsion (missible oil as of the present invention in dilute with water, wettable powder or concentratedThe composition that thing obtains) also within the scope of the invention. Above-mentioned emulsion can be water-in-oil type orOil-in-water type, can there is dense thick pulpous state denseness.
The preparation of composite preparation of the present invention can adopt those skilled in the art known (liquid orSolid) carrier and various auxiliary agent. For example include but not limited to following all kinds of material.
Suitable liquid-carrier or solvent can be water, various aromatic hydrocarbons, aliphatic hydrocarbon, ketone, ethers etc.,As toluene, dimethylbenzene, acetone, cyclohexanone, dimethylbenzene, benzene, cyclohexane, isopropyl alcohol, ethylene glycol,In sorbierite, methyl alcohol, ethanol, butanols, dimethyl formamide, naphthalane, machine oil, benzinum etc.One or more.
Suitable solid carrier comprises natural or synthetic clay and silicate, is applicable to consolidating of pulvisBody carrier comprise natural formation rock dust, chalk, quartz, clay, imvite, silica,Diatomite, float stone, gypsum, talcum, bentonite, kaolin, potter's clay and the synthetic mineral that grindMatter (as microdispersed silicic acid or aluminium oxide). Applicable particulate vector comprises the natural of broken and classificationRock for example calcite, marble, float stone, sepiolite and dolomite and by organic matter and inorganic matterThe synthetic particle that powder is made.
Suitable cosolvent is methyl alcohol, phenol, isoamyl alcohol, dimethyl sulfoxide (DMSO), ethyl acetate, butanone, twoOne or more in NMF etc.
Suitable emulsifying agent can be ethoxylated castor oil, polyoxyethylene (n20) phenethyl phenol ether through reaction oleic acidEster, alkylaryl polyoxyethylene poly-oxygen propylene aether, alkylaryl formaldehyde resin APEO, agriculture breast0201B, agriculture breast 0203B, agriculture breast T-20, agriculture breast S-80, agriculture breast 507#, agriculture breast 100#, agriculture breast36#, agriculture breast 600#, agriculture breast 1601#, agriculture breast 2201#, Nongru-700 #, agriculture breast NP-7 etc.
Suitable dispersant can be sodium lignin sulfonate, calcium lignosulfonate, methyl naphthalene sulfonic acid and formaldehyde contractingCompound, methyl naphthalene sulfonate formaldehyde condensate, methanonaphthalene sodium sulfonate, oleic acid methylamino ethyl sulphurAcid sodium, epoxidized polyether, to tertbutyl ether, piperonyl butoxide, alkyl amide taurate, dibutylNaphthalene sulfonic acid-formaldehyde condensation product, alkylphenol-polyethenoxy based phosphates, methylcellulose etc.
Suitable wetting agent can be sodium sulphate, sldium lauryl sulfate, methanonaphthalene sodium sulfonate, dodecaneBase benzene sulfonic acid sodium salt, calcium dodecyl benzene sulfonate, Negel aliphatic alcohol polyethenoxy base ether, alkaneBase phenol polyethenoxy base ether etc.
Suitable thickener can be (as carbonyl methylol, polyvinyl alcohol, the polyvinyl acetate) synthesizingOr natural water-soluble polymer (as xanthans, gelatin, gum arabic, polyvinylpyrrolidone,Aluminium-magnesium silicate, polyvinyl alcohol, polyethylene glycol, phenolic resins, shellac, carboxymethyl cellulose and marine algaAcid sodium etc.), add in preparation with powder, particle or latex form.
Suitable defoamer for bubble enemy, silicone, C8-10 fatty alcohol, phosphoric acid ester, C10-20 fullAnd fatty acid (as capric acid) and acid amides etc.
Suitable oxidant is: potassium chlorate, sodium chlorate, potassium perchlorate, sodium nitrate, potassium nitrate, heightPotassium manganate etc.
Suitable adhesive can be polyvinyl alcohol, polyvinyl acetate, xanthans, gelatin, carboxylic firstBase cellulose and sodium alginate etc.
While being used for preventing and treating city insect, can make aerosol, need to add therein propellant, also canTo make bait formulation composition, except containing active component, also contain one or more and be suitable for insect's food-takingFoodstuff, optional attractant and optional wetting agent.
Composition of the present invention is suitable for preventing and treating multiple important agriculture and forestry injurious insect or urban health insect, asMythimna separata, beet armyworm, bollworm, cutworm, lopper worm, apple skin worm, rice leaf roller,Corn borer, striped rice borer, diamondback moth, cabbage caterpillar, fall webworms, tent caterpillar, gypsymoth, East AsiaMigratory locusts, subterranean pest-insect, leaf miner, liriomyza bryoniae, aphid, grub, mite class etc., city insect is as in vainAnt, blattaria, ant, fly class, mosquito class etc. Be used for fruit tree as apple, pears, citrus, lichee etc.,Cereal is as wheat, paddy rice etc., and beans is as soybean, Kidney bean etc., and cotton, vegetables are as wild cabbage, flower coconut palmDish, Chinese cabbage, rape, tomato, capsicum etc., and flowers. While being used for preventing and treating city insect, canFor family, various public place, office space, and trees, the dykes and dams etc. of generation termite damage.Therefore, the present composition can be controlled agriculture and forestry injurious insect or urban health insect.
Following specific embodiment is used for further describing the present invention, but the present invention only limits to absolutely not theseExample. In embodiment, each component percentage composition or proportioning are all by weight. Active component in each formulaCalculate with effective content.
Formulation Example
The preparation of embodiment 1,10% Profenofos tetrachloro insect amide missible oil
By formula requirement, meter by weight, add respectively 5 parts of Profenofos, 5 parts of tetrachloro insect amides,7 parts of agricultures breast 0201B, 3 parts of agriculture breast NP-15,2 parts of Nongru-700 #, 12 parts of dimethyl formamides, 66Part dimethylbenzene, mixes, and uses if desired hot bath heating for dissolving, obtains 10% Profenofos tetrachloroInsect amide missible oil.
Described tetrachloro insect amide, structural formula is as follows:
The Chinese invention patent document that the preparation of this material is simultaneously CN101333213A referring to publication numberIn compound 1.25(hereinafter to be referred as tetrachloro insect amide).
The preparation of embodiment 2,18% Profenofos tetrachloro insect amide wettable powder
By formula requirement, meter by weight, by 3 parts of Profenofos, 15 parts of tetrachloro insect amides, 2 partsLauryl sodium sulfate, 6 parts of naphtholsulfonic acid formaldehyde condensation products sodium salts, 4 parts of sodium lignin sulfonates, 5 partsWhite Carbon black, 65 parts of bentonites, fully mix, and after ultra-fine pulverizer disintegrating, obtains the 18% the third brominesPhosphorus tetrachloro insect amide wettable powder.
The preparation of embodiment 3,20% chlopyrifos tetrachloro insect amide wettable powder
By formula requirement, meter by weight, by 10 portions of chlopyrifos, 10 parts of tetrachloro insect amides, 2 partsLauryl sodium sulfate, 6 parts of cresol sulfonic acid formaldehyde condensation products sodium salts, 4 parts of sodium lignin sulfonates, 2 parts cleanLotion LS, 5 parts of White Carbon blacks, 61 parts of precipitated calcium carbonates, fully mix, after ultra-fine pulverizer disintegrating,Obtain 20% chlopyrifos tetrachloro insect amide wettable powder.
The preparation of embodiment 4,15% Profenofos tetrachloro insect amide aqueous emulsion
By formula requirement, meter by weight, by 2.5 parts of Profenofos, 12.5 parts of tetrachloro insect amides, 8Part alkylaryl polyoxyethylene poly-oxygen propylene aether, 5 parts of agriculture breast 2201#, 15 parts of dimethyl formamides, 0.5Part tetradecanol is added together, and makes to be dissolved into even oil phase, under high-speed stirred, adds 56.5 parts of water,Form 15% Profenofos tetrachloro insect amide aqueous emulsion of favorable dispersibility.
The preparation of example 5,10% chlopyrifos tetrachloro insect amide aqueous emulsion
By formula requirement, meter by weight, by 5 portions of chlopyrifos, 5 parts of tetrachloro insect amides, 8 parts of polyoxiesEthene (n20) phenethyl phenol ether through reaction oleate, 3 parts of calcium dodecyl benzene sulfonates, 2 parts of agriculture breast 507#, 5 partsDimethyl formamide, 3 parts of tetradecanols, 1 part of ten sorbierite are added together, and make to be dissolved into even oil phase,Under high-speed stirred, add 68 parts of water, form 10% chlopyrifos tetrachloro insect amide water of favorable dispersibilityEmulsion.
The preparation of example 6,20% Hostathion tetrachloro insect amide water-dispersible granules
By formula requirement, meter by weight, by 10 parts of Hostathions, 10 parts of tetrachloro insect amides, 6 parts of AsiasMethyl naphthalene sulfonic acid sodium, 5 parts of naphtholsulfonic acid formaldehyde condensation products, 5 parts of epoxidized polyethers, 5 portions of soluble starches,5 parts of sodium sulphate, 5 parts of white carbons, add 49 parts of bentonites to mend, carry out co-grinding, then the kneading that adds waterAfter, add and in the comminutor that certain specification screen cloth is housed, carry out granulation. And then drying, screening (are pressedScreen cloth scope) obtain 20% Hostathion tetrachloro insect amide water-dispersible granules.
The preparation of embodiment 7,50% phoxim tetrachloro insect amide water-dispersible granules
By formula requirement, meter by weight, by 25 parts of phoxims, 25 parts of tetrachloro insect amides, 15Part methyl naphthalene sulfonate formaldehyde condensate, 5 parts of sodium alginates, 5 parts of PEG 8000s, 15 parts of sulphurAcid sodium, 10 parts of bentonites, carry out co-grinding, then add water after kneading, adds certain specification sieve is housedIn the comminutor of net, carry out granulation. And then drying, screening (by screen cloth scope) obtain 50% pungent sulphurPhosphorus tetrachloro insect amide water-dispersible granules.
The preparation of embodiment 8,10% Profenofos tetrachloro insect amide suspending agent
By formula requirement, meter by weight, by 5 parts of Profenofos, 5 parts of tetrachloro insect amides, 3 parts of agriculturesBreast 1601#, 6 parts of agricultures breast 0201B, 0.3 part of xanthans, 0.5 part of white carbon, 5 parts of ethylene glycol, 75.2Part water, adds in sand milling still, carries out porphyrize, makes 10% Profenofos tetrachloro insect amide suspending agent.
The preparation of example 9,12% Hostathion tetrachloro insect amide suspending agent
By formula requirement, meter by weight, by wooden to 2 parts of Hostathions, 10 parts of tetrachloro insect amides, 3 partsElement sodium sulfonate, 5 parts of naphthalenesulfonic acid-formaldehyde condensates, 1601,3 parts of agricultures breast 0201B of 2 parts of agriculture breasts, 0.1 partXanthans, 0.2 part of white carbon, 5 parts of ethylene glycol, 69.7 parts of water. Add in sand milling still, carry out porphyrize,Make 12% Hostathion tetrachloro insect amide suspending agent.
The preparation of example 10,10% chlopyrifos tetrachloro insect amide suspending agent
By formula requirement, meter by weight, by 5 portions of chlopyrifos, 5 parts of tetrachloro insect amides, 1 part of agriculture breastS-80,2 parts of Nongru-700 #, 5 parts of agriculture breast 0203B, 4 parts of sodium lignin sulfonates, 3 parts of dibutyl naphthalene sulfonic acidsSodium formaldehyde condensation product, 0.5 part of xanthans, 0.8 part of white carbon, 5 parts of ethylene glycol, 68.7 parts of water. AddIn sand milling still, carry out porphyrize, make 10% chlopyrifos tetrachloro insect amide suspending agent.
The preparation of example 11,10% phoxim tetrachloro insect amide suspending agent
By formula requirement, meter by weight, by 5 parts of phoxims, 5 parts of tetrachloro insect amides, 3 parts of naphthalene sulphursAcid sodium formaldehyde condensation product, 5 parts of methyl naphthalene sulfonate formaldehyde condensates, 3 parts of agriculture breast NP-7,3 parts of agriculture breasts0201B, 3 parts of triethyl phosphates, 5 parts of ethylene glycol, 68 parts of water. Add in sand milling still, carry out porphyrize,Make 10% phoxim tetrachloro insect amide suspending agent.
The preparation of embodiment 12,10% chlopyrifos tetrachloro insect amide microemulsion
By formula requirement, meter by weight, by 5 portions of chlopyrifos, 5 parts of tetrachloro insect amides, 10 partsDiphenyl phenolic group polyoxyethylene (n18) ether formaldehyde condensation products, 10 parts of agricultures breast 2201#, 5 parts of Nongru-700 #,15 parts of cyclohexanone, be added together, make to be dissolved into even oil phase, add 50 parts of water, under high-speed stirred,Water is joined to oil phase or oil phase is joined to water, form 10% chlopyrifos four of favorable dispersibilityChlorantraniliprole microemulsion.
The preparation of embodiment 13,20% Profenofos tetrachloro insect amide soluble concentrate
By formula requirement, meter by weight, by 10 parts of Profenofos, 10 parts of tetrachloro insect amides, 15Part agriculture breast 507#, 5 parts of agriculture breast 1601#, 6 parts of agriculture breast 100#, 12 parts of dimethyl formamides, 20 partsDimethyl sulfoxide (DMSO), 21 parts of methyl alcohol, use hot bath heating for dissolving if desired, can make 20% Profenofos fourChlorantraniliprole soluble concentrate.
The preparation of embodiment 14,30% Hostathion tetrachloro insect amide oil-suspending agent
By formula requirement, meter by weight, by 15 parts of Hostathions, 15 parts of tetrachloro insect amides, 6 partsAgriculture breast 0201B, 2 parts of Nongru-700 #, 5 parts of agriculture breast S-80,10 parts of methyl oleates, 3 parts of white carbons,1 part of agriculture breast T-20,43 portions of soybean oils that methylate, add in sand milling still, carries out porphyrize, makes 30%Hostathion tetrachloro insect amide oil-suspending agent.
Indoor biological activity determination
The synergism determination of the composition that embodiment 15 contains tetrachloro insect amide to beet armyworm
For trying object: beet armyworm (Spodopteraexigua), 3 instar larvaes, indoor feedingSensitive strain.
Test condition: temperature: 24~26 DEG C, humidity: RH60%, illumination: L:D=14:10
Test medication liquid making method: accurately take respectively in pesticide of the present invention with electronic analytical balanceActive component tetrachloro insect amide, Profenofos, chlopyrifos, Hostathion, former medicine is added to proper amount of acetoneAfter dissolving completely, be mixed with desired concn mother liquor with the water containing 0.1% Tween 80, by desinsection of the present inventionRatio in agent between two kinds of active components, is hybridly prepared into mixing by a certain percentage by above-mentioned mother liquor moltenLiquid, is diluted to respectively the serial liquid of tool finite concentration gradient by experimental design dosage.
Test method: adopt man-made feeds culture plate method, 24 well culture plates of selection standard cleaning, everyHole adds 1ml man-made feeds, after cooled and solidified, adds with continuous sampler to each hole of culture plate0.05ml liquid, then puts shady and cool place nature and dries in the shade. Select in the examination worm access culture plate of neat and consistent,1, every hole, every processing repeats 4 times. Examination worm after treatment is placed in observation ward to routine observation examinationWorm response situation, 72h " Invest, Then Investigate " is dead, the borer population of living.
By the Abbott formula calculation correction death rate, evaluating and adopting Bliss method, the method is to evaluate to mixOne of classical way of agent effect. Bliss thinks according to the independent joint action concept of its proposition, desinsectionTheoretical death rate P when agent is mixed can calculate with following formula:
P=Pm+Pn(1-Pm)
PmIt is the death rate (%) of the first active component target in the time that concentration is m; PnIt is the second active componentThe death rate of target (%) when working concentration is n.
If the actual of two kinds of active components target after mixing with finite concentration is greater than theoretical deadThe rate of dying P, judges that the mixing use under setting concentration of two kinds of active components has synergistic effect, otherwiseFor antagonism.
Result of the test shows: tetrachloro insect amide and Profenofos, chlopyrifos, Hostathion be mixed all demonstrationThe proportioning of synergistic effect, detailed results is in table 1.
The composition that table 1 contains tetrachloro insect amide is to beet armyworm 2 instar larvae synergism determination
The synergism determination of the composition that embodiment 16 contains tetrachloro insect amide to corn borer
For trying object: corn borer (Ostriniafurnacalis), 3 instar larvaes, indoor feedingSensitive strain.
Test condition: temperature: 23~25 DEG C, humidity: RH60%, illumination: L:D=14:10
Test medication liquid making method: accurately take respectively the desinsection in the present invention with electronic analytical balanceActive component tetrachloro insect amide, phoxim, malathion, fenifrothion, then add respectively appropriateAfter acetone dissolves completely, be mixed with desired concn mother liquor with the water containing 0.1% Tween 80, by the present inventionRatio in pesticide between two kinds of active components, is hybridly prepared into mixed by above-mentioned mother liquor by a certain percentageClose solution, be diluted to respectively the serial liquid of tool finite concentration gradient by experimental design dosage.
Test method: adopt man-made feeds culture plate method, 24 well culture plates of selection standard cleaning, everyHole adds 1ml man-made feeds, after cooled and solidified, adds with continuous sampler to each hole of culture plate0.05ml liquid, then puts shady and cool place nature and dries in the shade. Select in the examination worm access culture plate of neat and consistent,1, every hole, every processing repeats 4 times. Examination worm after treatment is placed in observation ward to routine observation examinationWorm response situation, 72h " Invest, Then Investigate " is dead, the borer population of living. Calculate evaluation method with embodiment 15.
Result of the test shows: tetrachloro insect amide with phoxim, malathion, fenifrothion is mixed all hasThe proportioning that shows synergistic effect, detailed results is in table 2.
The composition that table 2 contains tetrachloro insect amide is to corn borer 2 instar larvae synergism determination

Claims (7)

1. a binary insecticides, is characterized in that: active component one is tetrachloro insect amide,Described tetrachloro insect amide structural formula is as follows:
Active component two is Hostathion; Wherein, the ratio of weight and number between two kinds of active components is20:1-10:1 and 1:1-1:20.
2. according to binary insecticides claimed in claim 1, it is characterized in that: composition canMake missible oil, suspending agent, water-dispersible granules, aqueous emulsion, microemulsion, soluble liquid, wettableProperty pulvis or oil-suspending agent.
3. according to binary insecticides claimed in claim 2, it is characterized in that: in compositionThe percentage by weight of active component is between 0.5%-95%.
4. according to binary insecticides claimed in claim 3, it is characterized in that: in compositionThe percentage by weight of active component is between 1%-85%.
5. a purposes for binary insecticides claimed in claim 1, is characterized in that: instituteState composition and can be used as the pesticide of controlling agriculture and forestry injurious insect or urban health insect.
6. by the purposes of binary insecticides claimed in claim 5, it is characterized in that: described inComposition imposes on and needs on the insect of control or the medium of its growth with effective dose; Apply dosage for everyThe effective dose that hectare is 10 grams-500 grams.
7. by the purposes of binary insecticides claimed in claim 6, it is characterized in that: applyDosage is the effective dose of 15 grams-100 grams of per hectares.
CN201310073306.5A 2013-03-07 2013-03-07 A kind of binary insecticides and purposes Active CN104026146B (en)

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CN105613530B (en) * 2014-11-03 2018-04-27 中化农化有限公司 A kind of disinsection prophylaxis composition pesticide containing four chlorantraniliproles and its application
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CN101333213B (en) * 2008-07-07 2011-04-13 中国中化股份有限公司 1-substituted pyridyl-pyrazol acid amide compounds and use thereof
CN103960280A (en) * 2013-01-24 2014-08-06 陕西汤普森生物科技有限公司 High-efficiency insecticidal composition containing tetrachlorantraniliprole

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