CN103155929B - Binary pesticide composition and application thereof - Google Patents
Binary pesticide composition and application thereof Download PDFInfo
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Abstract
The invention discloses a binary pesticide composition. A first active component is selected from a compound A; a second active component is selected from macrolide pesticides; the macrolide pesticides comprises avermectin, emamectin benzoate, spinosad, ethyl spinosad, emamectin benzoate or milbemectin and the like; and the compound A has the following structure described in the specification. The composition provided by the invention has the characteristics of obvious synergy, delayed pesticide resistance and the like, and can preventing and treating a plurality of pests.
Description
Technical field
The invention belongs to field of pesticides, relate to a kind of binary insecticides and uses thereof.
Background technology
Insecticide has obvious effect aspect control agriculture and forestry injurious insect or urban health insect.
Chinese invention patent CN 101333213A discloses a kind of 1-substituted pyridyl-pyrazol acid amide compounds and has controlled the purposes of insect pest and disease, wherein compound 1.25 (hereinafter to be referred as compd A) can be used for preventing and treating various pests, especially lepidoptera pest is had to outstanding control efficiency.
The insecticide that contains single-activity component uses continuously in control of insect, easily makes insect develop immunity to drugs.Insecticide by two kinds of active components by a certain percentage mixture becomes blending ingredients, often can improve preventive effect, reduces the consumption of active ingredient, cost-saving, can delay the generation of pest resistance to insecticide simultaneously.
Although disclose general compd A in prior art or its homologue can produce additional advantage and effect with other Mixture Use of Insecticides, it is concrete open that the technical scheme of the binary insecticides that contains compd A has no.
Summary of the invention
The object of the invention is to develop a kind of binary insecticides that contains compd A, insecticide effect is day by day improved to the demand of constantly updating with kind to meet agricultural and pest control aspect, urban health field.
Technical scheme of the present invention is as follows:
A kind of binary insecticides, active component one is selected from compd A, and active component two is selected from macrolide insecticides;
Described compd A has following structure:
Described macrolide insecticides comprises Avermectin (Abamectin), emamectin-benzoate (Emamectin benzoate is called for short first dimension salt), pleocidin (spinosad), ethyl pleocidin (spinetoram), emaricin (emamectin) or milbemectin (milbemectin) etc.
The preferred Avermectin of active component two, first dimension salt or pleocidin in binary insecticides of the present invention.
In binary insecticides of the present invention, the ratio of weight and number of two kinds of active components is 1: 99～99: 1, is preferably 1: 20～20: 1.
Indoor biological activity determination demonstrates binary insecticides of the present invention and has synergistic effect.For example, compd A and Avermectin have shown good synergistic effect to multiple target at 1: 20～20: 1 in scope; Compd A and first dimension salt in 5: 1～1: 2 scope, compd A and pleocidin all demonstrated synergistic effect at 5: 1～1: 1 in scope.
Composition of the present invention can be finished product preparation form to be provided.Therefore, the present invention also comprises a kind of insecticides of dosage form.Taking binary insecticides as active component, make as required missible oil, suspending agent, water-dispersible granules, aqueous emulsion, soluble liquid, wetting powder, oil-suspending agent etc.In composition, the cumulative amount of active component is between 0.5%～95%, and preferably cumulative amount is between 1%-85%.The amount of application when content of active component depends on independent use in composition of the present invention, also depends on mixed ratio and synergistic effect degree.The optimum range of active component content is different according to the preparation type of composition.
The preparation of composition finished product preparation of the present invention can be prepared by common processing method, after mixing with liquid-carrier (solvent) or solid carrier by active substance, add one or more surfactants as emulsifier, dispersant, wetting agent, adhesive, stabilizing agent and defoamer etc.Conventionally in composition, contain at least one carrier and at least one surfactant.In all cases, should guarantee that present composition active component is uniformly distributed.
Missible oil contains 10～50% active component conventionally, 2～20% emulsifier, other additives of 0～20% such as stabilizing agent, bleeding agent, corrosion inhibitor etc., and solvent (also containing if desired cosolvent).
Suspending agent needs sand milling conventionally, to obtain stable non-deposition flowable product.In suspending agent, conventionally contain 5～75% active components, 5～15% dispersants, 0.1～10% thixotropic agent, 4～10% antifreezing agents, other additives of 0～10% are as defoamer, preservative, stabilizing agent, bleeding agent and thickener, and liquid-carrier surplus.
Water-dispersible granules is made 10～100 international standard sieve mesh (1.676～0.152mm) particles conventionally, can be by extruding, dipping or the preparation of mist projection granulating method.Conventionally water-dispersible granules contains 0.5～75% active component and 5～20% surfactant for example stabilizing agent, wetting dispersing agent, disintegrant and adhesive, and inert carrier surplus.
Wetting powder contains 10～85% active component conventionally, except solid inert carrier, conventionally contains 3～10% dispersant, can also contain 0～10% stabilizing agent and (or) other additives, for example bleeding agent or sticker.
Aqueous emulsion is that former medicine, organic solvent, surfactant are mixed to formation oil phase; Water, antifreezing agent are mixed, become transparent and homogeneous water.With high-shear emulsion machine high speed shear oil phase, slowly water is added to oil phase, active ingredient 1～60% conventionally, surfactant 5～20%, antifreezing agent 2～10%, water surplus simultaneously.
Microemulsion is that former medicine, organic solvent, surfactant, water are mixed, and becomes transparent and homogeneous water.Conventionally active ingredient 1～50%, surfactant 10～40%, antifreezing agent 2～10%, water surplus.
Soluble liquid is that active component, organic solvent, surfactant are mixed, and becomes transparent and homogeneous liquid.Conventionally active ingredient 1～50%, surfactant 6～20%, organic solvent surplus.
Oil-suspending agent is that active component, surfactant, oil base carrier are added to sand milling in sand mill, until particle diameter is qualified, and active ingredient 2～60% conventionally, surfactant 6～20%, oil base carrier surplus.
Moisture dispersion liquid and emulsion (composition that missible oil as of the present invention in dilute with water, wetting powder or concentrate obtain) are also within the scope of the invention.Above-mentioned emulsion can be water-in-oil type or oil-in-water type, can there is dense thick pulpous state denseness.
The preparation of composition finished product preparation of the present invention can adopt known (liquid or solid) carrier of those skilled in the art and various auxiliary agent.For example include but not limited to following all kinds of material.
Suitable liquid-carrier or solvent can be water, various aromatic hydrocarbons, aliphatic hydrocarbon, ketone, ethers etc., as one or more in toluene, dimethylbenzene, acetone, cyclohexanone, dimethylbenzene, benzene, cyclohexane, isopropyl alcohol, ethylene glycol, sorbierite, methyl alcohol, ethanol, butanols, dimethyl formamide, naphthalane, machine oil, benzinum etc.
Suitable solid carrier comprises natural or synthetic clay and silicate, and the solid carrier that is applicable to pulvis comprises the rock dust of natural formation, chalk, quartz, clay, imvite, silica, diatomite, float stone, gypsum, talcum, bentonite, kaolin, potter's clay and the synthetic mineral matter grinding (as microdispersed silicic acid or aluminium oxide).Applicable particulate vector comprises the synthetic particle that broken natural rock for example calcite, marble, float stone, sepiolite and dolomite and the powder by organic matter and inorganic matter with classification are made.
Suitable cosolvent is one or more in methyl alcohol, phenol, isoamyl alcohol, dimethyl sulfoxide (DMSO), ethyl acetate, butanone, dimethyl formamide etc.
Suitable emulsifier can be ethoxylated castor oil, polyoxyethylene (n20) phenethyl phenol ether through reaction oleate, alkylaryl polyoxyethylene poly-oxygen propylene aether, alkylaryl formaldehyde resin APEO, agriculture breast 0201B, agriculture breast 0203B, agriculture breast T-20, agriculture breast S-80, agriculture breast 507#, agriculture breast 100#, agriculture breast 36#, agriculture breast 600#, agriculture breast 1601#, agriculture breast 2201# etc.
Suitable dispersant can be sodium lignin sulfonate, calcium lignosulfonate, condensation compound of methyl naphthalene sulfonic acid and formaldehyde, methyl naphthalene sulfonate formaldehyde condensate, methanonaphthalene sodium sulfonate, oleic acid methylamino ethylsulfonic acid sodium, epoxidized polyether, to tertbutyl ether, piperonyl butoxide, alkyl amide taurate, dibutyl naphthalene sulfonic acid-formaldehyde condensation product, alkylphenol-polyethenoxy based phosphates, methylcellulose etc.
Suitable wetting agent can be sodium sulphate, sldium lauryl sulfate, methanonaphthalene sodium sulfonate, neopelex, calcium dodecyl benzene sulfonate, Negel aliphatic alcohol polyethenoxy base ether, alkylphenol-polyethenoxy base ether etc.
Suitable thickener can be (as carbonyl methylol, polyvinyl alcohol, polyvinyl acetate) or the natural water-soluble polymer (as xanthans, gelatin, gum Arabic, polyvinylpyrrolidone, aluminium-magnesium silicate, polyvinyl alcohol, polyethylene glycol, phenolic resins, shellac, carboxymethyl cellulose and sodium alginate etc.) synthesizing, and adds in preparation with powder, particle or latex form.
Suitable defoamer is bubble enemy, silicone, C8～10 fatty alcohol, phosphoric acid ester, C10～20 saturated fat acids (as capric acid) and acid amides etc.
Suitable oxidant is: potassium chlorate, sodium chlorate, potassium perchlorate, sodium nitrate, potassium nitrate, potassium permanganate etc.
Suitable adhesive can be polyvinyl alcohol, polyvinyl acetate, xanthans, gelatin, carboxymethyl cellulose and sodium alginate etc.In addition, defoamer can be silicone etc.
While being used for preventing and treating city insect, can make aerosol, need to add therein propellant, also bait formulation composition be can make, except containing active component, one or more foodstuffs that are suitable for insect's food-taking, optional attractant and optional wetting agent also contained.
Composition of the present invention is suitable for preventing and treating multiple important agriculture and forestry injurious insect or urban health insect, as mythimna separata, beet armyworm, cotton bollworm, cutworm, tomato moth, apple skin worm, rice leaf roller, corn borer, striped rice borer, diamond-back moth, cabbage caterpillar, fall webworm, tent caterpillar, gypsymoth, Asiatic migratory locust, soil insect, leaf miner, liriomyza bryoniae, aphid, mite class etc., city insect is as termite, blattaria, ant, fly class, mosquito class etc.For fruit tree, as apple, pears, citrus, lichee etc., Cereal is as wheat, paddy rice etc., and beans is as soybean, Kidney bean etc., and cotton, vegetables are as wild cabbage, cauliflower, Chinese cabbage, rape, tomato, capsicum etc., and flowers.While being used for preventing and treating city insect, can be for family, various public place, office space, and there are trees, the dykes and dams etc. of termite damage.Therefore, the present invention also comprises the purposes of present composition control agriculture and forestry injurious insect or urban health insect.
The present invention also comprises a kind of method of controlling insect pest, the present composition can be imposed on and needs on the insect of control or the medium of its growth with effective dose.Conventionally the comparatively suitable effective dose of selecting is 10 grams to 500 grams of per hectares, and preferably effective dose is 15 grams to 100 grams of per hectares.
Tool of the present invention has the following advantages:
The one, composition of the present invention shows obvious synergistic effect in certain ratio range, has improved the control efficiency of this compound to insect.
The 2nd, said composition reduces the using dosage of compound in application, thereby reduces use cost, reduces environmental pollution.
The 3rd,, there is not the problem of cross resistance in the mechanism of action difference of each active ingredient in said composition, can delay the generation of pest resistance to insecticide with its pest control, and improve the control efficiency of antagonism population.
Embodiment
Following specific embodiment is used for further describing the present invention, but the present invention only limits to absolutely not these examples.In embodiment, each component percentage composition or proportioning are all by weight.Active component in each formula is calculated with effective content.
Formulation Example
The preparation of embodiment 1,6% Avermectin compd A missible oil
By formula requirement, add respectively 1.5 parts of Avermectin, 4.5 parts of compd As, 7 parts of agriculture breast 0201B, 3 parts of agriculture breast NP-15,2 parts of Nongru-700s, 12 parts of dimethyl formamides, dimethylbenzene to complement to 100%, mix, use if desired hot bath heating for dissolving, obtain 6% Avermectin compd A missible oil.
The preparation of embodiment 2,20% Avermectin compd A wetting powder
By formula requirement, 5 parts of Avermectin, 15 parts of compd As, 2 parts of lauryl sodium sulfate, 6 parts of naphtholsulfonic acid formaldehyde condensation products sodium salts, 4 parts of sodium lignin sulfonates, 5 parts of White Carbon blacks, bentonite etc. are complemented to 100%, fully mix, after ultra-fine pulverizer disintegrating, obtain 20% Avermectin compd A wetting powder.
The preparation of embodiment 3,20% first dimension salt compound A wetting powder
By formula requirement, by 10 parts of first dimension salt, 10 parts of compd As, 2 parts of lauryl sodium sulfate, 6 parts of cresol sulfonic acid formaldehyde condensation products sodium salts, 4 parts of sodium lignin sulfonates, 3 parts tertbutyl ether, 2 parts of detergent LS, 5 parts of White Carbon blacks, precipitated calcium carbonates are supplied to surplus etc. and fully mix, after ultra-fine pulverizer disintegrating, obtain 20% first dimension salt compound A wetting powder.
The preparation of embodiment 4,8% Avermectin compd A aqueous emulsion
By formula requirement, 2 parts of Avermectin, 6 parts of compd As, 8 parts of alkylaryl polyoxyethylene poly-oxygen propylene aethers, 2201,15 parts of dimethyl formamides of 15 parts of agriculture breasts, 0.5 part of tetradecanol are added together, make to be dissolved into even oil phase, under high-speed stirred, excess water is joined to oil phase, complement to 100%, form 8% aqueous emulsion of favorable dispersibility.
The preparation of embodiment 5,6% first dimension salt compound A aqueous emulsion
By formula requirement, 2 portions of first dimension salt, 4 parts of compd As, 8 parts of polyoxyethylene (n20) phenethyl phenol ether through reaction oleate, 3 parts of calcium dodecyl benzene sulfonates, 2 parts of agriculture breast 507#, 5 parts of cyclohexanone, 3 parts of dimethylbenzene, 1 part of ten sorbierite are added together, make to be dissolved into even oil phase, under high-speed stirred, the water of surplus is joined to oil phase, form 6% first dimension salt compound A aqueous emulsion of favorable dispersibility.
Embodiment 6,60% pleocidin compd A water-dispersible granules
By formula requirement; 30 parts of pleocidin, 30 parts of compd As, 6 parts of methanonaphthalene sodium sulfonates, 5 parts of naphtholsulfonic acid formaldehyde condensation products, 5 parts of epoxidized polyethers, 5 portions of soluble starches, 5 parts of sodium sulphate, 5 parts of gypsum bentonites, bentonites are supplied to surplus etc. and carried out co-grinding; after adding water again and mediating, add and in the comminutor that certain specification screen cloth is housed, carry out granulation.And then drying, screening (by screen cloth scope) obtain 60% pleocidin compd A water-dispersible granules.
Embodiment 7,50% Avermectin compd A water-dispersible granules
By formula requirement; 12.5 parts of Avermectin, 37.5 parts of compd As, 15 parts of methyl naphthalene sulfonate formaldehyde condensates, 5 parts of sodium alginates, 5 parts of PEG 8000s, 15 parts of sodium sulphate, bentonite etc. are complemented to 100%; carry out co-grinding; after adding water again and mediating, add and in the comminutor that certain specification screen cloth is housed, carry out granulation.And then drying, screening (by screen cloth scope) obtain 50% Avermectin compd A water-dispersible granules.
Embodiment 8,10% Avermectin compd A suspending agent
By formula requirement, 5 parts of Avermectin, 5 parts of compd As, 1601,6 parts of agriculture breast 0201B of 3 parts of agriculture breasts, 0.3 part of xanthans, 0.5 part of white carbon, 5 portions of ethylene glycol, waters are complemented to 100%, add in sand milling still, carry out porphyrize, make 10% Avermectin compd A suspending agent.
Embodiment 9,12% pleocidin compd A suspending agent
By formula requirement, 4 parts of pleocidin, 8 parts of compd As, 3 parts of sodium lignin sulfonates, 5 parts of naphthalenesulfonic acid-formaldehyde condensates, 1601,3 parts of agricultures breast 0201B of 2 parts of agriculture breasts, 0.1 part of xanthans, 0.2 part of white carbon, 5 parts of ethylene glycol, water are supplied to surplus etc. to add in sand milling still, carry out porphyrize, make 12% pleocidin compd A suspending agent.
Embodiment 10,10% first dimension salt compound A suspending agent
By formula requirement, 5 parts of first dimension salt, 5 parts of compd As, 1 part of agriculture breast S-80,2 parts of Nongru-700 #, 5 parts of agriculture breast 0203B, 4 parts of sodium lignin sulfonates, 3 parts of nekal formaldehyde condensation products, 0.5 part of xanthans, 0.8 part of white carbon, 5 parts of ethylene glycol, water are supplied to surplus etc. to add in sand milling still, carry out porphyrize, make 10% first dimension salt compound A suspending agent.
Embodiment 11,10% pleocidin compd A suspending agent
By formula requirement, 5 parts of pleocidin, 5 parts of compd As, 3 parts of naphthalenesulfonic acid-formaldehyde condensates, 5 parts of methyl naphthalene sulfonate formaldehyde condensates, 3 parts of agriculture breast NP-7,3 parts of agriculture breast 0201B, 3 parts of triethyl phosphates, 5 parts of ethylene glycol, water are supplied to surplus etc. to add in sand milling still, carry out porphyrize, make 10% pleocidin compd A suspending agent.
Embodiment 12,10% Avermectin compd A microemulsion
By formula requirement, by 5 parts of Avermectin, 5 parts of compd As, 10 parts of diphenyl phenolic group polyoxyethylene (n
18) ether formaldehyde condensation products, 2201,5 parts of Nongru-700s of 10 parts of agriculture breasts
#, 10 parts of ethyl acetate, 15 parts of cyclohexanone, be added together, make to be dissolved into even oil phase, surplus water complements to 100%, under high-speed stirred, water is joined to oil phase or oil phase is joined to water, form 10% Avermectin compd A microemulsion of favorable dispersibility.
Embodiment 13,15% Avermectin compd A soluble concentrate
By formula requirement, by 5 parts of Avermectin, 10 parts of compd As, 15 parts of agriculture breasts 507
#, 5 parts of 1601,6 parts of agriculture breasts 100 of agriculture breast
#, 12 parts of dimethyl formamides, 10 parts of methyl alcohol, 20 parts of dimethyl sulfoxide (DMSO)s, 17 parts of molten fibers of methyl mix, and use if desired hot bath heating for dissolving, can make 15% Avermectin compd A soluble concentrate.
Embodiment 14,30% Avermectin compd A oil-suspending agent
By formula requirement, 15 parts of Avermectin, 15 parts of compd As, 6 parts of agriculture breast 0201B, 2 parts of Nongru-700s, 5 parts of agriculture breast S-80,10 parts of methyl oleates, 3 parts of white carbons, 1 part of agriculture breast T-20, surplus are complemented to 100% with the soybean oil that methylates, add in sand milling still, carry out porphyrize, make 30% Avermectin compd A oil-suspending agent.
Indoor biological activity determination
The synergism determination of the composition that embodiment 15 contains compd A to diamond-back moth
For trying object: diamond-back moth (Plutella xylostella), 2 instar larvaes, the sensitive strain of indoor feeding.
Test condition: temperature: 24～26 DEG C, humidity: RH 60%, illumination: L: D=14: 10
Test method: adopt infusion process to process, the cabbage leaves of greenhouse culture is fetched, make diameter 2cm leaf dish, leaf dish is flooded to 5s in liquid, after taking-up, dry in the shade, put into the 9cm culture dish that is lined with filter paper, select in the examination worm access culture dish of neat and consistent, every processing repeats 4 times.Examination worm after treatment is placed in observation ward, routine observation examination worm response situation, 48h " Invest, Then Investigate " is dead, the borer population of living, and calculates lethality.
Evaluating and adopting Bliss method, the method is one of classical way of evaluating mixture effect.Bliss thinks according to the independent joint action concept of its proposition, and theoretical lethality P when Mixture Use of Insecticides can calculate with following formula:
P＝P
m+P
n(1-P
m)
P
mit is the lethality (%) of the first active component target in the time that concentration is m; P
nit is the lethality (%) of the second active component working concentration target while being n.
If the actual of two kinds of active components target after mixing with finite concentration is greater than theoretical lethality P, judges that the mixing use under setting concentration of two kinds of active components has synergistic effect, otherwise be antagonism.
The results are shown in Table 1.
The composition that table 1 contains compd A is to diamond-back moth 2 instar larvae synergism determination
Embodiment 16 compd As mix use to diamond-back moth toxicity determination test with Avermectin
For trying object: diamond-back moth (Plutella xylostella), 3 instar larvaes, the sensitive strain of indoor feeding.
Test condition: temperature: 24～26 DEG C, humidity: RH 60%, illumination: L: D=14: 10
Test medication liquid making method: accurately take respectively reagent agent with electronic analytical balance, after adding appropriate solvent to dissolve completely two kinds of former medicines respectively, be mixed with desired concn mother liquor with the water containing 0.1% Tween 80, two kinds of active ingredient mother liquors are hybridly prepared into mixed solution by a certain percentage, are diluted to respectively the serial liquid of tool finite concentration gradient by experimental scheme dosage.
Test method: adopt infusion process to process, the cabbage leaves of greenhouse culture is fetched, make diameter 2cm leaf dish, leaf dish is flooded to 5s in liquid, after taking-up, dry in the shade, put into the 9cm culture dish that is lined with filter paper, select in the examination worm access culture dish of neat and consistent, every processing repeats 4 times.Examination worm after treatment is placed in observation ward, routine observation examination worm response situation, 48h " Invest, Then Investigate " is dead, the borer population of living.
By abbott formula calculation correction lethality, appliance computer program is obtained each for examination single dose and mixed virulence regression equation formula, LC50 value and 95% confidence limit of variant proportioning, by Sun Yunpei (Sun Y-P) method, obtain the mixed co-toxicity coefficient of each proportioning, evaluate.If co-toxicity coefficient approaches 100 for summation action, apparently higher than 100 being synergistic effect, be starkly lower than 100 for antagonism.
Result of the test is in table 2.As can be seen from the table, for trying, each proportioning is mixed all shows synergistic effect to diamond-back moth to compd A with Avermectin.
Table 2: the indoor joint toxicity measuring result of compd A Abamectin on Plutella
Embodiment 17 compd As mix use to striped rice borer toxicity determination test with Avermectin
For trying object: striped rice borer (Chilo suppressalis), 2 instar larvaes, the sensitive strain of indoor feeding.
Test condition: temperature: 25～27 DEG C, humidity: RH 60%, illumination: L: D=14: 10
Liquid compound method is with embodiment 16.
Test method: adopt artificial feed culture plates method, 24 well culture plates of selection standard cleaning, every hole adds 1ml artificial feed, after cooled and solidified, adds 0.05ml liquid with continuous sampler to each hole of culture plate, then puts shady and cool place nature and dries in the shade.Select in the examination worm access culture plate of neat and consistent, 1, every hole, every processing repeats 4 times.Examination worm after treatment is placed in observation ward, routine observation examination worm response situation, 72h " Invest, Then Investigate " is dead, the borer population of living.Calculate evaluation method with embodiment 16.
Result of the test is in table 3.As can be seen from the table, for trying, each proportioning is mixed all shows synergistic effect to striped rice borer to compd A with Avermectin.
Table 3: compd A Avermectin is to the indoor joint toxicity measuring result of striped rice borer
Embodiment 18 compd As mix use to corn borer toxicity determination test with Avermectin
For trying object: corn borer (Ostrinia furnacalis), 3 instar larvaes, the sensitive strain of indoor feeding.
Test condition: temperature: 23～25 DEG C, humidity: RH 60%, illumination: L: D=14: 10
Liquid compound method is with embodiment 16, and test method, with embodiment 17, is calculated evaluation method with embodiment 16.
Result of the test is in table 4.As can be seen from the table, for trying, each proportioning is mixed all shows synergistic effect to corn borer to compd A with Avermectin.
Table 4: compd A Avermectin is to the indoor joint toxicity measuring result of corn borer
Claims (6)
1. a binary insecticides, active component one is selected from compd A, has following structure:
Active component two is selected from Avermectin; The ratio of weight and number of two kinds of active components is 1:20～20:1.
2. according to composition claimed in claim 1, it is characterized in that: can make as required missible oil, suspending agent, water-dispersible granules, aqueous emulsion, microemulsion, soluble liquid, wetting powder or oil-suspending agent.
3. according to composition claimed in claim 2, it is characterized in that: in composition, the cumulative amount of active component is between 0.5%-95%.
4. according to composition claimed in claim 3, it is characterized in that: in composition, the cumulative amount of active component is between 1%-85%.
5. one kind according to the purposes of binary insecticides control agriculture and forestry injurious insect claimed in claim 1 or urban health insect.
6. a method of controlling insect pest, is characterized in that: composition claimed in claim 1 is imposed on the insect of needs control or the medium of its growth with effective dose.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201410280575.3A CN104304271B (en) | 2011-12-09 | 2011-12-09 | A kind of binary pesticide composition and purposes |
| CN201110410182.6A CN103155929B (en) | 2011-12-09 | 2011-12-09 | Binary pesticide composition and application thereof |
| CN201410280883.6A CN104351189B (en) | 2011-12-09 | 2011-12-09 | Binary pesticide composition and uses thereof |
| PCT/CN2012/086186 WO2013083084A1 (en) | 2011-12-09 | 2012-12-07 | Synergistic composition with insecticidal activity |
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| CN105746526B (en) * | 2013-01-16 | 2018-06-26 | 陕西汤普森生物科技有限公司 | A kind of Pesticidal combination for containing four chlorantraniliproles and biogenic substances |
| CN104672025A (en) * | 2013-12-03 | 2015-06-03 | 广西新方向化学工业有限公司 | Chlorantraniliprole-containing pesticide fertilizer composition |
| CN103651433A (en) * | 2013-12-19 | 2014-03-26 | 北京燕化永乐生物科技股份有限公司 | Pesticide composite |
| CN103651385A (en) * | 2013-12-19 | 2014-03-26 | 北京燕化永乐生物科技股份有限公司 | Insecticidal composition |
| CN103651434A (en) * | 2013-12-19 | 2014-03-26 | 北京燕化永乐生物科技股份有限公司 | Complex insecticide |
| CN104186479A (en) * | 2014-08-11 | 2014-12-10 | 广东中迅农科股份有限公司 | Insecticidal composition containing chlorantraniliprole and spinosad |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101333213A (en) * | 2008-07-07 | 2008-12-31 | 中国中化集团公司 | 1-substituted pyridyl-pyrazol acid amide compounds and use thereof |
| CN101747318A (en) * | 2008-12-11 | 2010-06-23 | 中国中化集团公司 | 1-(3,5-dichloro-pyridyl)-1H-5-pyrazole carboxylic acid ester compound |
| CN102020633A (en) * | 2009-09-21 | 2011-04-20 | 中国中化股份有限公司 | Method for preparing 1-(3,5- dichloropyridine-2-yl)-pyrazolecarboxamide compounds |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GT200500179BA (en) * | 2004-07-01 | 2008-10-29 | SYNERGIST MIXTURES OF ANTRANILAMIDE AGENTS FOR THE CONTROL OF INVERTEBRATE PESTS | |
| TWI484910B (en) * | 2006-12-01 | 2015-05-21 | Du Pont | Liquid formulations of carboxamide arthropodicides |
| KR101812362B1 (en) * | 2010-04-27 | 2017-12-26 | 스미또모 가가꾸 가부시키가이샤 | Pesticidal composition and its use |
-
2011
- 2011-12-09 CN CN201410280883.6A patent/CN104351189B/en active Active
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Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101333213A (en) * | 2008-07-07 | 2008-12-31 | 中国中化集团公司 | 1-substituted pyridyl-pyrazol acid amide compounds and use thereof |
| CN101747318A (en) * | 2008-12-11 | 2010-06-23 | 中国中化集团公司 | 1-(3,5-dichloro-pyridyl)-1H-5-pyrazole carboxylic acid ester compound |
| CN102020633A (en) * | 2009-09-21 | 2011-04-20 | 中国中化股份有限公司 | Method for preparing 1-(3,5- dichloropyridine-2-yl)-pyrazolecarboxamide compounds |
Non-Patent Citations (3)
| Title |
|---|
| JP特开2011-246455A 2011.12.08 |
| 刘开林 等.害虫及害螨对阿维菌素抗药性研究进展.《昆虫知识》.2007,第44卷(第2期),第195页. |
| 害虫及害螨对阿维菌素抗药性研究进展;刘开林 等;《昆虫知识》;20070330;第44卷(第2期);第195页 * |
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| CN104351189A (en) | 2015-02-18 |
| CN103155929A (en) | 2013-06-19 |
| CN104351189B (en) | 2016-01-20 |
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