CN103155935B - Binary pesticide composition - Google Patents
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- CN103155935B CN103155935B CN201110410254.7A CN201110410254A CN103155935B CN 103155935 B CN103155935 B CN 103155935B CN 201110410254 A CN201110410254 A CN 201110410254A CN 103155935 B CN103155935 B CN 103155935B
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Abstract
The invention discloses a binary pesticide composition. A first active component is selected from a compound A; a second active component is selected from indoxacarb or refined indoxacarb; and the compound A has the following structure described in the specification. The composition provided by the invention has the characteristics of obvious synergy, delayed pesticide resistance and the like, and can preventing and treating a plurality of pests.
Description
Technical field
The invention belongs to field of pesticides, relate to a kind of binary pesticide composition.
Background technology
Insecticide is protecting various crops, fruit tree, vegetables, afforestation and ornamental plants etc. from having obvious effect in pest damage.
Chinese invention patent CN 101333213A discloses a kind of 1-substituted pyridyl-pyrazol acid amide compounds and controls the purposes of insect pest and disease, wherein compound 1.25 (hereinafter referred to as compd A) can be used for preventing and treating various pests, especially has outstanding control efficiency to lepidoptera pest.
Insecticide containing single-activity component, control of insect uses continuously, easily makes insect develop immunity to drugs.By the insecticide of two kinds of active components, mixture becomes blending ingredients by a certain percentage, often can improve preventive effect, reduces the consumption of active ingredient, cost-saving, can delay the generation of pest resistance to insecticide simultaneously.
Although disclose compd A or its homologue and other Mixture Use of Insecticides in prior art general can produce additional advantage and effect, the technical scheme of the binary pesticide composition containing compd A has no concrete open.
Summary of the invention
The object of the invention is to develop a kind of binary pesticide composition containing compd A, to meet the demand that agricultural and pest control aspect, urban health field day by day improve insecticide effect and kind is constantly updated.
Technical scheme of the present invention is as follows:
A kind of binary pesticide composition, active component one is selected from compd A, and active component two is selected from indoxacarb or smart indoxacarb; Described compd A has following structure:
In binary pesticide composition of the present invention, the ratio of weight and number of two kinds of active components is 1: 99 ~ 99: 1, is preferably 1: 20 ~ 20: 1.
Indoor biological determination of activity demonstrates binary pesticide composition of the present invention and has good synergistic effect.Active component two in composition both can be indoxacarb (i.e. the mixture of S isomer and R isomer) also can be smart indoxacarb (100%S isomer).Because R isomer does not have activity, when using indoxacarb as active component two, active ingredient is with S isomer.
Composition of the present invention can provide in finished product preparation form.Therefore, the present invention also comprises a kind of insecticides of dosage form.Take binary pesticide composition as active component, make missible oil, suspending agent, water-dispersible granules, aqueous emulsion, soluble liquid, wetting powder, oil-suspending agent etc. as required.In composition, the cumulative amount of active component is between 0.5% ~ 95%, and preferred cumulative amount is between 1%-85%.In composition of the present invention, the content of active component depends on amount of application when being used alone, and also depends on mixed ratio and synergistic effect degree.The optimum range of active component content is different according to the preparation type of composition.
The preparation of composition finished product preparation of the present invention can be prepared by common processing method, after mixing with liquid-carrier (solvent) or solid carrier by active substance, add one or more surfactants as emulsifier, dispersant, wetting agent, adhesive, stabilizing agent and defoamer etc.Containing at least one carrier and at least one surfactant in usual composition.In all cases, should guarantee that present composition active component is uniformly distributed.
Missible oil contains the active component of 10 ~ 50% usually, 2 ~ 20% emulsifier, other additives such as stabilizing agent, bleeding agent, the corrosion inhibitor etc. of 0 ~ 20%, and solvent (if desired also containing cosolvent).
Suspending agent needs sand milling usually, to obtain stable non-deposited flowable product.Usually containing 5 ~ 75% active components in suspending agent, 5 ~ 15% dispersants, 0.1 ~ 10% thixotropic agent, 4 ~ 10% antifreezing agents, other additives of 0 ~ 10% are as defoamer, preservative, stabilizing agent, bleeding agent and thickener, and liquid-carrier surplus.
(aqueous dispersion) granule makes 10 ~ 100 international standard sieve mesh (1.676 ~ 0.152mm) particles usually, can by extruding, dipping or Spray granulation method preparation, usually (aqueous dispersion) granule contains the active component of 0.5 ~ 75% and surfactant such as stabilizing agent, wetting dispersing agent, disintegrant and the adhesive of 5 ~ 20%, and inert carrier surplus.
Wetting powder contains the active component of 10 ~ 85% usually, except solid inert carrier, usually contains the dispersant of 3 ~ 10%, can also contain stabilizing agent and (or) other additives of 0 ~ 10%, such as bleeding agent or sticker.
Aqueous emulsion is that former medicine, organic solvent, surfactant mixing are formed oil phase, water, antifreezing agent is mixed, becomes transparent and homogeneous aqueous phase.With high-shear emulsion machine high speed shear oil phase, slowly aqueous phase is added oil phase, usual active ingredient 1 ~ 60%, surfactant 5 ~ 20%, antifreezing agent 2 ~ 10%, water surplus simultaneously.
Microemulsion is mixed former medicine, organic solvent, surfactant, water, becomes transparent and homogeneous aqueous phase.Usual active ingredient 1 ~ 50%, surfactant 10 ~ 40%, antifreezing agent 2 ~ 10%, water surplus.
Soluble liquid is mixed active component, organic solvent, surfactant, becomes transparent and homogeneous liquid.Usual active ingredient 1 ~ 50%, surfactant 6 ~ 20%, organic solvent surplus.
Oil-suspending agent is by having active component, surfactant, oil based vehicle to add sand milling in sand mill, until particle diameter is qualified, and usual active ingredient 2 ~ 60%, surfactant 6 ~ 20%, oil based vehicle surplus.
Moisture dispersion liquid and emulsion (composition that missible oil as of the present invention in dilute with water, wetting powder or concentrate obtain) are also within the scope of the invention.Above-mentioned emulsion can be water-in-oil type or oil-in-water type, can have dense thick paste-like consistency.
The preparation of composition finished product preparation of the present invention can adopt known (liquid or solid) carrier of those skilled in the art and various auxiliary agent.Such as include but not limited to following all kinds of material.
Suitable liquid-carrier or solvent can be water, various aromatic hydrocarbons, aliphatic hydrocarbon, ketone, ethers etc., as one or more in toluene, dimethylbenzene, acetone, cyclohexanone, dimethylbenzene, benzene, cyclohexane, isopropyl alcohol, ethylene glycol, sorbierite, methyl alcohol, ethanol, butanols, dimethyl formamide, naphthalane, machine oil, benzinum etc.
Suitable solid carrier comprises clay that is natural or synthesis and silicate, and the solid carrier being applicable to pulvis comprises the mineral matter (as microdispersed silicic acid or aluminium oxide) ground of the rock dust of natural formation, chalk, quartz, clay, imvite, silica, diatomite, float stone, gypsum, talcum, bentonite, kaolin, potter's clay and synthesis.The particulate vector be applicable to comprises the broken synthesis particle made with natural rock such as calcite, marble, float stone, sepiolite and dolomite of classification and by the powder of organic matter and inorganic matter.
Suitable cosolvent is one or more in methyl alcohol, phenol, isoamyl alcohol, dimethyl sulfoxide (DMSO), ethyl acetate, butanone, dimethyl formamide etc.
Suitable emulsifier can be ethoxylated castor oil, polyoxyethylene (n20) phenethyl phenol ether through reaction oleate, alkylaryl polyoxyethylene poly-oxygen propylene aether, alkylaryl formaldehyde resin APEO, agriculture breast 0201B, agriculture breast 0203B, agriculture breast T-20, agriculture breast S-80, agriculture breast 507#, agriculture breast 100#, agriculture breast 36#, agriculture breast 600#, agriculture breast 1601#, agriculture breast 2201# etc.
Suitable dispersant can be sodium lignin sulfonate, calcium lignosulfonate, condensation compound of methyl naphthalene sulfonic acid and formaldehyde, methyl naphthalene sulfonate formaldehyde condensate, methanonaphthalene sodium sulfonate, oleic acid methylaminoethyl sodium sulfonate, epoxidized polyether, to tertbutyl ether, piperonyl butoxide, alkyl amide taurate, dibutyl naphthalenesulfonic acid formaldehyde condensation products, alkylphenol-polyethenoxy based phosphates, methylcellulose etc.
Suitable wetting agent can be sodium sulphate, sldium lauryl sulfate, methanonaphthalene sodium sulfonate, neopelex, calcium dodecyl benzene sulfonate, Negel aliphatic alcohol polyethenoxy base ether, alkylphenol-polyethenoxy base ether etc.
Suitable thickener can be synthesis (as carbonyl methylol, polyvinyl alcohol, polyvinyl acetate) or natural water-soluble polymer (as xanthans, gelatin, gum Arabic, polyvinylpyrrolidone, aluminium-magnesium silicate, polyvinyl alcohol, polyethylene glycol, phenolic resins, shellac, carboxymethyl cellulose and sodium alginate etc.), adds in preparation with powder, particle or latex form.
Suitable defoamer is bubble enemy, silicone, C8 ~ 10 fatty alcohol, phosphoric acid ester, C10 ~ 20 saturated fat acids (as capric acid) and acid amides etc.
Suitable oxidant is: potassium chlorate, sodium chlorate, potassium perchlorate, sodium nitrate, potassium nitrate, potassium permanganate etc.
Suitable adhesive can be polyvinyl alcohol, polyvinyl acetate, xanthans, gelatin, carboxymethyl cellulose and sodium alginate etc.In addition, defoamer can be silicone etc.
Aerosol can be made during for preventing and treating city insect, need to add propellant wherein, also bait formulation composition be can make, except containing except active component, also the foodstuff of insect's food-taking, optional attractant and optional wetting agent are suitable for containing one or more.
Composition of the present invention is suitable for the multiple important agriculture and forestry injurious insect of control or urban health insect, as mythimna separata, beet armyworm, cotton bollworm, cutworm, tomato moth, apple skin worm, rice leaf roller, corn borer, striped rice borer, diamond-back moth, cabbage caterpillar, fall webworm, tent caterpillar, gypsymoth, Asiatic migratory locust, soil insect, leaf miner, liriomyza bryoniae, aphid, mite class etc., city insect is as termite, blattaria, ant, fly class, mosquito class etc.For fruit tree as apple, pears, citrus, lichee etc., Cereal is as wheat, paddy rice etc., and beans is as soybean, Kidney bean etc., and cotton, vegetables are as wild cabbage, cauliflower, Chinese cabbage, rape, tomato, capsicum etc., and flowers.During for preventing and treating city insect, may be used for family, various public place, office space, and the trees, dykes and dams etc. of termite damage occur.Therefore, the present invention also comprises the purposes that the present composition controls agriculture and forestry injurious insect or urban health insect.
The present invention also comprises a kind of method controlling insect pest, the present composition can be imposed on the medium of insect or its growth needing to control with effective dose.The comparatively suitable effective dose of usual selection is per hectare 10 grams to 500 grams, and preferred effective dose is per hectare 15 grams to 100 grams.
Tool of the present invention has the following advantages:
One is that composition of the present invention shows obvious synergistic effect in certain ratio range, improves the control efficiency of this compound to insect.
Two is using dosages that said composition reduces compound in the application, thus reduces use cost, reduces environmental pollution.
Three is that the mechanism of action of each active ingredient in said composition is different, there is not the problem of cross resistance, can delay the generation of pest resistance to insecticide with its pest control, and improve the control efficiency of antagonism population.
Embodiment
Following specific embodiment is for further describing the present invention, but the present invention is only limitted to absolutely not these examples.In embodiment, each component percentages or proportioning are all by weight.Active component in each formula calculates with effective content.
Formulation Example
The preparation of embodiment 1,10% compd A indoxacarb missible oil
By recipe requirements, 5 parts of compd As, 5 parts of indoxacarbs, 6 parts of agriculture breast 0201B, 4 parts of agriculture breast 0203B, 1.5 parts of agriculture breasts 1601,5 parts of methyl alcohol, dimethylbenzene are complemented to 100%, mix, use hot bath heating for dissolving if desired, namely obtain 10% compd A indoxacarb missible oil.
The preparation of embodiment 2,60% compd A indoxacarb wetting powder
By recipe requirements, by 15 parts of compd As, 45 parts of indoxacarbs, 2 parts of lauryl sodium sulfate, 4 parts of calcium lignosulfonates, 8 parts of condensation compound of methyl naphthalene sulfonic acid and formaldehyde, 2 parts 100% is complemented to tertbutyl ether, 6 parts of White Carbon blacks, 2 parts of detergent LS, precipitated calcium carbonates etc., abundant mixing, after ultra-fine pulverizer disintegrating, namely obtain 60% compd A indoxacarb wetting powder.
The preparation of embodiment 3,15% compd A indoxacarb aqueous emulsion
By recipe requirements, by 5 parts of compd As, 10 parts of indoxacarbs, 10 parts of agriculture breasts, 2201,4.5 parts of alkylaryl polyoxyethylene poly-oxygen propylene aethers, 2.5 parts of piperonyl butoxides, 10 parts of cyclohexanone, 5 parts of glycerine, be added together, make to be dissolved into homogeneous oil phase.Under high velocity agitation, water is complemented to 100%, join oil phase, form 15% compd A indoxacarb aqueous emulsion of favorable dispersibility.
The preparation of embodiment 4,9% compd A indoxacarb aqueous emulsion
By recipe requirements, by 6 parts of compd As, 3 parts of indoxacarbs, 8.5 parts of agriculture breast 507#, 3.5 parts of agriculture breast OX-8686,3 parts of agriculture breasts, 1601,8 parts of dimethyl formamides, 0.5 part of tetradecanol, 5 parts of ethylene glycol, be added together, make to be dissolved into homogeneous oil phase.Under high velocity agitation, water is complemented to 100%, join oil phase, form 9% compd A indoxacarb aqueous emulsion of favorable dispersibility.
The preparation of embodiment 5,60% compd A indoxacarb water-dispersible granules
By recipe requirements; 45 parts of compd As, 15 parts of indoxacarbs, 8 parts of naphthalenesulfonic acid-formaldehyde condensates, 4 parts of methyl naphthalene sulfonate formaldehyde condensates, 6 parts of N-methyl-oleoyl-sodium taurocholates, 10 parts of sodium sulphate, kaolin etc. are complemented to 100%; carry out co-grinding; add water again after mediating, add in the comminutor that certain specification screen cloth is housed and carry out granulation.And then drying, screening (by screen cloth scope) namely obtain 60% compd A indoxacarb water-dispersible granules.
The preparation of embodiment 6,10% compd A indoxacarb suspending agent
By recipe requirements, 7.5 parts of compd As, 2.5 parts of indoxacarbs, 3 parts of methyl naphthalene sulfonate formaldehyde condensates, 3 parts of sodium lignin sulfonates, 6 parts of agriculture breast 0201B, 0.3 part of xanthans, 0.6 part of white carbon, 5 parts of ethylene glycol, water are complemented to 100%, add in sand milling still, carry out porphyrize, make 10% compd A indoxacarb suspending agent.
Embodiment 7,10% compd A indoxacarb soluble concentrate
By recipe requirements, 2.5 parts of compd As, 7.5 parts of indoxacarbs, 15 parts of agriculture breasts, 2201,2 parts of agriculture breast T-20,8 parts of agriculture breast NP-15,12 parts of dimethyl formamides, 8 parts of methyl alcohol, the molten fibers of methyl are complemented to 100%, mix, use hot bath heating for dissolving if desired, 10% compd A indoxacarb soluble concentrate can be obtained.
The preparation of embodiment 8,6% compd A indoxacarb microemulsion
By recipe requirements, by 2 parts of compd As, 4 parts of indoxacarbs, 5 parts of triphenyl vinyl phenol polyoxyethylene (n
20) ether phosphoric acid triethanolamine salt, 8 parts of peaceful breasts 36
#, 10 parts of agriculture breast OX-2681,20 parts of cyclohexanone, 8 parts of cyclohexanol are added together, make to be dissolved into homogeneous oil phase.Excess water, 5 parts of ethylene glycol are mixed, become homogeneous aqueous phase.Under high velocity agitation, aqueous phase joined oil phase or oil phase is joined aqueous phase, forming 6% compd A indoxacarb microemulsion of favorable dispersibility.
The preparation of embodiment 9,30% compd A indoxacarb oil-suspending agent
By recipe requirements, by 7.5 parts of compd As, 22.5 parts of indoxacarbs, 3 parts of agriculture breast S-80,2 parts of agriculture breast T-20,6 parts of agriculture breasts 0201B, 3 parts of agriculture breasts 500
#, 2 parts of white carbon, surplus methylated soya oil, add in sand milling still, carry out porphyrize, make 30% compd A indoxacarb oil-suspending agent.
Indoor biological determination of activity
Embodiment 10 compd A and indoxacarb used in combination to corn borer toxicity determination test
For examination object: corn borer (Ostrinia furnacalis), 3 instar larvaes, the sensitive strain of indoor feeding.
Test condition: temperature: 24 ~ 26 DEG C, humidity: RH 60%, illumination: L: D=14: 10
Test medication liquid making method: accurately take reagent agent respectively with electronic analytical balance, respectively two kinds of former medicines are added after appropriate solvent dissolves completely, desired concn mother liquor is mixed with the water containing 0.1% Tween 80, two kinds of active ingredient mother liquors are hybridly prepared into mixed solution by a certain percentage, are diluted to the serial liquid of tool finite concentration gradient by experimental scheme dosage respectively.
Test method: adopt artificial feed culture plate method, 24 well culture plates of selection standard cleaning, every hole adds 1ml artificial feed, after cooled and solidified, adds 0.05ml liquid with continuous sampler to each hole of culture plate, then puts shady and cool place nature and dries in the shade.Select in the examination worm access culture plate of neat and consistent, 1, every hole, often processes repetition 4 times.Be placed in observation ward by the examination worm after process, routine observation examination worm response situation, 72h " Invest, Then Investigate " is dead, borer population of living.
With abbott formulae discovery corrected mortality, appliance computer program obtains each virulence regression equation formula, LC50 value and 95% confidence limit used with for examination single dose and variant proportioning, by Sun Yunpei (SunY-P) method, obtain the co-toxicity coefficient that each proportioning is mixed, evaluate.If co-toxicity coefficient is summation action close to 100, is synergistic effect apparently higher than 100, is starkly lower than 100 for picking up anti-effect.
Result of the test is in table 1.As can be seen from the table, each proportioning is mixed all shows synergistic effect to corn borer for trying for compd A and indoxacarb.
Table 1: compd A indoxacarb is to the indoor joint toxicity measuring result of corn borer
Embodiment 11 compd A and indoxacarb used in combination to beet armyworm toxicity determination test
For examination object: beet armyworm (Spodoptera exigua), 3 instar larvaes, the sensitive strain of indoor feeding.
Test condition: temperature: 24 ~ 26 DEG C, humidity: RH 60%, illumination: L: D=14: 10
Drug solution preparation method is with embodiment 10.Test method: adopt infusion process to process, the cabbage leaves of greenhouse culture is fetched, makes diameter 2cm leaf dish, leaf dish is flooded 5s in liquid, dries in the shade after taking-up, put into the 9cm culture dish being lined with filter paper, select in the examination worm access culture dish of neat and consistent, often process repetition 4 times.Be placed in observation ward by the examination worm after process, routine observation examination worm response situation, 48h " Invest, Then Investigate " is dead, borer population of living.
Calculation Estimation method is with embodiment 10.
Result of the test is in table 2.As can be seen from the table, each proportioning is mixed all shows synergistic effect to beet armyworm for trying for compd A and indoxacarb.
Table 2: compd A indoxacarb is to the indoor joint toxicity measuring result of beet armyworm
Claims (6)
1. a binary pesticide composition, active component one is selected from compd A, and active component two is selected from indoxacarb or smart indoxacarb; Described compd A has following structure:
The ratio of weight and number of two kinds of active components is 1:20 ~ 20:1.
2. according to composition according to claim 1, it is characterized in that: missible oil, suspending agent, water-dispersible granules, aqueous emulsion, microemulsion, soluble liquid, wetting powder or oil-suspending agent can be made as required.
3. according to composition according to claim 2, it is characterized in that: in composition, the cumulative amount of active component is between 0.5%-95%.
4. according to composition according to claim 3, it is characterized in that: in composition, the cumulative amount of active component is between 1%-85%.
5. one kind controls the purposes of corn borer, beet armyworm according to binary pesticide composition according to claim 1.
6. control a method for corn borer, beet armyworm, it is characterized in that: by composition according to claim 1 with effective dose impose on needs control corn borer, beet armyworm or its growth medium on.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201110410254.7A CN103155935B (en) | 2011-12-09 | 2011-12-09 | Binary pesticide composition |
| PCT/CN2012/086186 WO2013083084A1 (en) | 2011-12-09 | 2012-12-07 | Synergistic composition with insecticidal activity |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201110410254.7A CN103155935B (en) | 2011-12-09 | 2011-12-09 | Binary pesticide composition |
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| CN103155935B true CN103155935B (en) | 2015-05-13 |
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Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN103931641A (en) * | 2013-01-19 | 2014-07-23 | 陕西汤普森生物科技有限公司 | Insecticidal composition containing silvchongxian'an and carbamate |
| CN104672025A (en) * | 2013-12-03 | 2015-06-03 | 广西新方向化学工业有限公司 | Chlorantraniliprole-containing pesticide fertilizer composition |
| CN103651386A (en) * | 2013-12-19 | 2014-03-26 | 北京燕化永乐生物科技股份有限公司 | Insecticidal composition containing chlorfenapyr |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2006068669A1 (en) * | 2004-07-26 | 2006-06-29 | E.I. Dupont De Nemours And Company | Mixtures of anthranilamide invertebrate pest control agents |
| CN101014247A (en) * | 2004-07-01 | 2007-08-08 | 杜邦公司 | Synergistic mixtures of anthranilamide invertebrate pest control agents |
| CN101646349A (en) * | 2006-12-01 | 2010-02-10 | 杜邦公司 | Liquid formulations of carboxamide arthropodicides |
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Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101014247A (en) * | 2004-07-01 | 2007-08-08 | 杜邦公司 | Synergistic mixtures of anthranilamide invertebrate pest control agents |
| WO2006068669A1 (en) * | 2004-07-26 | 2006-06-29 | E.I. Dupont De Nemours And Company | Mixtures of anthranilamide invertebrate pest control agents |
| CN1988803A (en) * | 2004-07-26 | 2007-06-27 | 杜邦公司 | Mixtures of anthranilamide invertebrate pest control agents |
| CN101646349A (en) * | 2006-12-01 | 2010-02-10 | 杜邦公司 | Liquid formulations of carboxamide arthropodicides |
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