CN104412991A - Binary insecticide composition and application thereof - Google Patents

Binary insecticide composition and application thereof Download PDF

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Publication number
CN104412991A
CN104412991A CN201310407921.5A CN201310407921A CN104412991A CN 104412991 A CN104412991 A CN 104412991A CN 201310407921 A CN201310407921 A CN 201310407921A CN 104412991 A CN104412991 A CN 104412991A
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pymetrozine
active component
composition
binary
pesticide composition
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CN104412991B (en
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李轲轲
宋玉泉
王丽颖
杨辉斌
姜斌
李斌
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Shenyang Sinochem Agrochemicals R&D Co Ltd
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Shenyang Research Institute of Chemical Industry Co Ltd
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Abstract

The invention belongs to the field of insecticides and relates to a binary insecticide composition and application thereof. An active ingredient I of the binary insecticide composition is tetrachlorantraniliprole, and an active ingredient II of the binary insecticide composition is pymetrozine, wherein the structural formula of tetrachlorantraniliprole is as shown in the specification; the pymetrozine refers to a pyridine compound; and a weight part ratio between the two active ingredients is 1:99 to 99:1. The composition disclosed by the invention has the characteristics of obvious synergistic effect, capabilities of delaying resistance, reducing the cost and controlling different types of injurious insects and the like and can be used for controlling various types of agricultural and forest pests.

Description

Binary pesticide composition and application thereof
Technical field
The invention belongs to field of pesticides, relate to a kind of binary pesticide composition and application thereof.
Background technology
Insecticide is that a class is for preventing and treating the agricultural chemicals of agriculture and forestry and vector harmful insect or mite pest.
Chinese invention patent CN101333213A discloses a kind of 1-substituted pyridyl-pyrazol acid amide compounds and controls the purposes of insect pest and disease, wherein compound 1.25(tetra-chlorantraniliprole) can be used for preventing and treating various pests, especially to lepidoptera pest, there is outstanding control efficiency.
Pymetrozine belongs to pyridines or Triazinone insecticide, is brand-new non-killing livestock property insecticide, and the sucking pest of this product to various crop shows excellent control efficiency.Sucking pest one touches pymetrozine and produces lancet blocking action, and stop taking food, till death, this process is irreversible for final hunger; And this medicament has action of contace poison to insect, systemic activity can be used for preventing and treating most of homoptera pest, especially aphid section, Aleyrodidae, Cicadellidae and Delphacidae insect.These two kinds of active components by a certain percentage mixture become, and can prevent and treat two or more insects simultaneous, reduce repeated drug taking number of times, cost-saving, alleviate workload.
Summary of the invention
The object of the invention is to meet the demand that agriculture and forestry pest control aspect day by day improves insecticide effect and kind is constantly updated, and provides a kind of binary pesticide composition and application thereof.
For achieving the above object, the technical solution used in the present invention is:
A kind of binary pesticide composition: active component one is four chlorantraniliproles, and active component two is pymetrozine; Described four chlorantraniliprole structural formulas are as follows:
Wherein, the ratio of weight and number between two kinds of active components is 1:99-99:1.
Further, the ratio of weight and number between two kinds of active components is 1:20-20:1.
Composition can be made into missible oil, suspending agent, water-dispersible granules, aqueous emulsion, microemulsion, soluble liquid, wetting powder or oil-suspending agent.
In composition active component percentage by weight between 0.5%-95%.
Say further, in composition active component percentage by weight between 1%-85%.
The application of binary pesticide composition is characterized in that: described composition can be used as the insecticide controlling agriculture and forestry injurious insect.
Described composition imposes on the medium of insect or its growth needing to control with effective dose; Apply the effective dose that dosage is per hectare 10 grams-500 grams.
Say further, apply the effective dose that dosage is per hectare 15 grams-100 grams.
Tool of the present invention has the following advantages:
One is that composition of the present invention shows synergy or summation action in certain ratio range, improves the control efficiency of this compound to insect.
Two is using dosages that said composition reduces compound in the application, thus reduces use cost, reduces environmental pollution.
Three is that the mechanism of action of each active ingredient in said composition is different, can be used for preventing and treating different types of insect, delays pest resistance to insecticide and produce.
Embodiment
A kind of binary pesticide composition, active component one is four chlorantraniliproles, and structural formula is as follows:
The preparation of this material is simultaneously that compound 1.25(in the Chinese invention patent document of CN101333213A is hereinafter referred to as four chlorantraniliproles see publication number).
Active component two is selected from pymetrozine; The all commercially available acquisition of described material.Demonstrate binary pesticide composition of the present invention through indoor biological determination of activity and there is good synergy or summation action.
Composition of the present invention can provide in dosage form.Make missible oil, suspending agent, water-dispersible granules, aqueous emulsion, microemulsion, soluble liquid, wetting powder, oil-suspending agent etc. as required.In composition, the percentage by weight cumulative amount of active component is between 0.5%-95%, and preferred cumulative amount is between 1%-85%.In composition of the present invention, the content of active component depends on amount of application when being used alone, and also depends on mixed ratio and synergistic effect degree.The optimum range of active component content is different according to the preparation type of composition.
The preparation of composite preparation of the present invention can be prepared by the processing method of routine, after mixing with liquid-carrier (solvent) or solid carrier by active substance, add one or more auxiliary agents as emulsifier, dispersant, wetting agent, adhesive, stabilizing agent and defoamer etc.Containing at least one carrier and at least one surfactant in usual composition.In all cases, should guarantee that present composition active component is uniformly distributed.
The active component of missible oil usually containing 10-75%, 2-20% emulsifier, other additive such as stabilizing agent, bleeding agent, the corrosion inhibitor etc. of 0-20%, and solvent (if desired also containing cosolvent).
Suspending agent needs sand milling usually, to obtain stable non-deposited flowable product.Usually containing 5-50% active component in suspending agent, 5-15% dispersant, 0.1-10% wetting agent, 4-10% antifreezing agent, other additive of 0-10% is as defoamer, preservative, stabilizing agent, bleeding agent and thickener, and liquid-carrier surplus.
(aqueous dispersion) granula makes 10-100 international standard sieve mesh (1.676-0.152mm) particle usually, can by extruding, dipping or Spray granulation method preparation, usually (aqueous dispersion) granule contains the active component of 0.5-80% and auxiliary agent such as dispersant, wetting agent, disintegrant and the adhesive of 5-20%, and inert carrier surplus.
The active component of wetting powder usually containing 10-85%, except solid inert carrier, the dispersant usually containing 3-10%, can also contain wetting agent and (or) other additive of 0-10%, such as bleeding agent or stabilizing agent.
Aqueous emulsion is that former medicine, organic solvent, surfactant mixing are formed oil phase, water, antifreezing agent is mixed, becomes transparent and homogeneous liquid.With high-shear emulsion machine high speed shear oil phase, slowly aqueous phase is added oil phase, usual active component 1-60%, surfactant 5-20%, antifreezing agent 2-10%, water surplus simultaneously.
Microemulsion is mixed former medicine, organic solvent, surfactant, water, becomes transparent and homogeneous aqueous phase.Usual active component 1-50%, surfactant 10-40%, antifreezing agent 2-10%, water surplus.
Soluble liquid is mixed active component, organic solvent, surfactant, becomes transparent and homogeneous liquid.Usual active component 1-50%, surfactant 6-20%, organic solvent surplus.
Oil-suspending agent is by having active component, surfactant, oil based vehicle to add sand milling in sand mill, until particle diameter is qualified, and usual active component 2-60%, surfactant 6-20%, oil based vehicle surplus.
Moisture dispersion liquid and emulsion (composition that missible oil as of the present invention in dilute with water, wetting powder or concentrate obtain) are also within the scope of the invention.Above-mentioned emulsion can be water-in-oil type or oil-in-water type, can have dense thick paste-like consistency.
The preparation of composite preparation of the present invention can adopt known (liquid or solid) carrier of those skilled in the art and various auxiliary agent.Such as include but not limited to following all kinds of material.
Suitable liquid-carrier or solvent can be water, various aromatic hydrocarbons, aliphatic hydrocarbon, ketone, ethers etc., as one or more in toluene, dimethylbenzene, acetone, cyclohexanone, dimethylbenzene, benzene, cyclohexane, isopropyl alcohol, ethylene glycol, sorbierite, methyl alcohol, ethanol, butanols, dimethyl formamide, naphthalane, machine oil, benzinum etc.
Suitable solid carrier comprises clay that is natural or synthesis and silicate, and the solid carrier being applicable to pulvis comprises the mineral matter (as microdispersed silicic acid or aluminium oxide) ground of the rock dust of natural formation, chalk, quartz, clay, imvite, silica, diatomite, float stone, gypsum, talcum, bentonite, kaolin, potter's clay and synthesis.The particulate vector be applicable to comprises the broken synthesis particle made with natural rock such as calcite, marble, float stone, sepiolite and dolomite of classification and by the powder of organic matter and inorganic matter.
Suitable cosolvent is one or more in methyl alcohol, phenol, isoamyl alcohol, dimethyl sulfoxide (DMSO), ethyl acetate, butanone, dimethyl formamide etc.
Suitable emulsifier can be ethoxylated castor oil, polyoxyethylene (n 20) phenethyl phenol ether through reaction oleate, alkylaryl polyoxyethylene poly-oxygen propylene aether, alkylaryl formaldehyde resin APEO, agriculture breast 0201B, agriculture breast 0203B, agriculture breast T-20, agriculture breast S-80, agriculture breast 507#, agriculture breast 100#, agriculture breast 36#, agriculture breast 600#, agriculture breast 1601#, agriculture breast 2201#, agriculture breast OX-8686, agriculture breast 1601#, agriculture breast NP-15, agriculture breast OX-2681 etc.
Suitable dispersant can be sodium lignin sulfonate, calcium lignosulfonate, condensation compound of methyl naphthalene sulfonic acid and formaldehyde, methyl naphthalene sulfonate formaldehyde condensate, methanonaphthalene sodium sulfonate, oleic acid methylaminoethyl sodium sulfonate, epoxidized polyether, to tertbutyl ether, piperonyl butoxide, alkyl amide taurate, dibutyl naphthalenesulfonic acid formaldehyde condensation products, alkylphenol-polyethenoxy based phosphates, methylcellulose etc.
Suitable wetting agent can be sodium sulphate, sldium lauryl sulfate, methanonaphthalene sodium sulfonate, neopelex, calcium dodecyl benzene sulfonate, Negel aliphatic alcohol polyethenoxy base ether, alkylphenol-polyethenoxy base ether etc.
Suitable thickener can be synthesis (as carbonyl methylol, polyvinyl alcohol, polyvinyl acetate) or natural water-soluble polymer (as xanthans, gelatin, gum Arabic, polyvinylpyrrolidone, aluminium-magnesium silicate, polyvinyl alcohol, polyethylene glycol, phenolic resins, shellac, carboxymethyl cellulose and sodium alginate etc.), adds in preparation with powder, particle or latex form.
Suitable defoamer is bubble enemy, silicone, C8-10 fatty alcohol, phosphoric acid ester, C10-20 saturated fat acids (as capric acid) and acid amides etc.
Suitable oxidant is: potassium chlorate, sodium chlorate, potassium perchlorate, sodium nitrate, potassium nitrate, potassium permanganate etc.
Suitable adhesive can be polyvinyl alcohol, polyvinyl acetate, xanthans, gelatin, carboxymethyl cellulose and sodium alginate etc.
Composition of the present invention is suitable for preventing and treating multiple important agriculture and forestry injurious insect, as mythimna separata, beet armyworm, cotton bollworm, cutworm, tomato moth, apple skin worm, rice leaf roller, corn borer, striped rice borer, diamond-back moth, cabbage caterpillar, fall webworm, tent caterpillar, gypsymoth, leaf miner, leafhopper class, Phytophthira, aleyrodid class, plant hopper etc.For fruit tree as apple, pears, citrus, lichee etc., Cereal is as wheat, paddy rice etc., and beans is as soybean, Kidney bean etc., and cotton, vegetables are as wild cabbage, cauliflower, Chinese cabbage, rape, tomato, capsicum and flowers etc.Therefore, the present composition can control agriculture and forestry injurious insect.
Following specific embodiment is for further describing the present invention, but the present invention is only limitted to absolutely not these examples.In embodiment, each component percentages or proportioning are all by weight.Active component in each formula calculates with effective content.
Formulation Example
The preparation of embodiment 1,20% 4 chlorantraniliprole pymetrozine missible oil
By recipe requirements, by weight percentage, 10% 4 chlorantraniliprole, 10% pymetrozine, 6% agriculture breast 0201B, 4% agriculture breast 0203B, 1.5% agriculture breast 1601#, 5% methyl alcohol, surplus are dimethylbenzene, mix, use hot bath heating for dissolving if desired, namely obtain 10% 4 chlorantraniliprole pymetrozine missible oil.
The preparation of embodiment 2,45% 4 chlorantraniliprole pymetrozine wetting powder
By recipe requirements, by weight percentage, 1% 4 chlorantraniliprole, 30% pymetrozine, 2% lauryl sodium sulfate, 4% calcium lignosulfonate, 8% condensation compound of methyl naphthalene sulfonic acid and formaldehyde, 6% White Carbon black, 2% detergent LS, surplus are precipitated calcium carbonate, abundant mixing, after ultra-fine pulverizer disintegrating, namely obtain 45% 4 chlorantraniliprole pymetrozine wetting powder.
The preparation of embodiment 3,10% 4 chlorantraniliprole pymetrozine water emulsion
By recipe requirements, by weight percentage, 5% 4 chlorantraniliprole, 5% pymetrozine, 10% agriculture breast 2201#, 4.5% alkylaryl polyoxyethylene poly-oxygen propylene aether, 2.5% piperonyl butoxide, 10% cyclohexanone, 5% glycerine, be added together, make to be dissolved into homogeneous oil phase.Fill up surplus under high velocity agitation, with water, join oil phase, form 10% 4 chlorantraniliprole pymetrozine water emulsion of favorable dispersibility.
The preparation of embodiment 4,40% 4 chlorantraniliprole pymetrozine water-dispersible granules
By recipe requirements; by weight percentage; 10% 4 chlorantraniliprole, 30% pymetrozine, 8% naphthalenesulfonic acid-formaldehyde condensate, 4% methyl naphthalene sulfonate formaldehyde condensate, 6%N-methyl-oleoyl-sodium taurocholate, 10% sodium sulphate, surplus are kaolin; carry out co-grinding; add water again after mediating, add in the comminutor that certain specification screen cloth is housed and carry out granulation.And then drying, screening (by screen cloth scope) namely obtain 40% 4 chlorantraniliprole pymetrozine water-dispersible granules.
The preparation of embodiment 5,30% 4 chlorantraniliprole pymetrozine suspension agent
By recipe requirements, by weight percentage, by 10 part of four chlorantraniliprole, 20 parts of pymetrozines, 3 parts of methyl naphthalene sulfonate formaldehyde condensates, 3 parts of sodium lignin sulfonates, 6 parts of agriculture breast 0201B, 0.3 part of xanthans, 0.6 part of white carbon, 5 parts of ethylene glycol, 52.1 parts of water, add in sand milling still, carry out porphyrize, make 30% 4 chlorantraniliprole pymetrozine suspension agent.
The preparation of embodiment 6,10% 4 chlorantraniliprole pymetrozine soluble concentrate
By recipe requirements, by weight percentage, by 5 part of four chlorantraniliprole, 5 parts of pymetrozines, 15 parts of agriculture breast 2201#, 2 parts of agriculture breast T-20,8 parts of agriculture breast NP-15,12 parts of dimethyl formamides, 8 parts of methyl alcohol, 45 parts of methyl alcohol, mix, use hot bath heating for dissolving if desired, 9% 4 chlorantraniliprole pymetrozine soluble concentrate can be obtained.
The preparation of embodiment 7,30% 4 chlorantraniliprole pymetrozine oil suspending agent
By recipe requirements, by weight percentage, by 10 part of four chlorantraniliprole, 20 parts of pymetrozines, 3 parts of agriculture breast S-80,2 parts of agriculture breast T-20,6 parts of agriculture breast 0201B, 3 parts of agriculture breast 600#, 2 parts of white carbons, 54 parts of methylated soya oil, add in sand milling still, carry out porphyrize, make 30% 4 chlorantraniliprole pymetrozine oil suspending agent.
Indoor biological determination of activity
Embodiment 8 four chlorantraniliprole and pymetrozine used in combination to corn borer toxicity determination test
For examination object: corn borer (Ostrinia furnacalis), 3 instar larvaes, the sensitive strain of indoor feeding.
Test condition: temperature: 24-26 DEG C, humidity: RH60%, illumination: L:D=14:10
Test medication liquid making method: active component four chlorantraniliprole, the pymetrozine that accurately take insecticide of the present invention with electronic analytical balance respectively, then former medicine is added proper amount of acetone to dissolve, after dissolving completely, desired concn mother liquor is mixed with the water containing 0.1% Tween 80, in the ratio in insecticide of the present invention between two kinds of active components, above-mentioned mother liquor is hybridly prepared into mixed solution by a certain percentage, is diluted to the serial liquid of tool finite concentration gradient by experimental scheme dosage respectively.
Test method: adopt artificial feed culture plate method, 24 well culture plates of selection standard cleaning, every hole adds 1ml artificial feed, after cooled and solidified, adds 0.05ml liquid with continuous sampler to each hole of culture plate, then puts shady and cool place nature and dries in the shade.Select in the examination worm access culture plate of neat and consistent, 1, every hole, often processes repetition 4 times.Be placed in observation ward by the examination worm after process, routine observation examination worm response situation, 72h " Invest, Then Investigate " is dead, borer population of living.
With Abbott formulae discovery corrected mortality, appliance computer program obtains each the virulence regression equation formula, the LC that use with for examination single dose and variant proportioning 50value and 95% confidence limit, by Sun Yunpei (Sun Y-P) method, obtain the co-toxicity coefficient that each proportioning is mixed, evaluate.If co-toxicity coefficient is summation action close to 100, be synergistic effect apparently higher than 100, be starkly lower than 100 for antagonism.
Result of the test is in table 1.As can be seen from the table, each proportioning is mixed all shows synergistic effect to corn borer for trying for four chlorantraniliproles and pymetrozine.
Table 1: four chlorantraniliprole pymetrozines are to the indoor joint toxicity measuring result of corn borer
Embodiment 9 four chlorantraniliprole and pymetrozine used in combination to brown planthopper toxicity determination test
For examination object: brown planthopper (Nilaparvata lugens Stal), nymph, the sensitive strain of indoor feeding.
Test condition: temperature: 24-26 DEG C, humidity: RH60%, illumination: L:D=14:10
Drug solution preparation method is with embodiment 8.Test method: adopt pot-spraying method, it is in the plastic basin of 9cm that 4-5 leaf phase rice seedlings is transplanted into diameter, cauline leaf spraying process is carried out after slow seedling, with rice strain even medicine and not dripping be as the criterion, after rice seedling dries in the shade naturally, the nymph selecting neat and consistent is connected on rice seedling, covers in case examination worm escapes with cloche, repeat, if clear water is treated to blank for 3 times.Be placed in observation ward by the examination worm after process, routine observation examination worm response situation, 96h " Invest, Then Investigate " is dead, borer population of living.
Calculation Estimation method is with embodiment 8.
Result of the test is in table 2.As can be seen from the table, during four chlorantraniliproles are mixed for examination proportioning with pymetrozine, 1:10,1:5 two proportionings are shown as summation action to brown planthopper, and other each proportionings all show synergistic effect.
Table 2: four chlorantraniliprole pymetrozines are to the indoor joint toxicity measuring result of brown planthopper 3 nymph in age
Embodiment 10 4 chlorantraniliprole and pymetrozine used in combination to diamond-back moth toxicity determination test
For examination object: diamond-back moth (Plutella xylostella), 3 instar larvaes, the sensitive strain of indoor feeding.
Test condition: temperature: 24 ~ 26 DEG C, humidity: RH60%, illumination: L:D=14:10
Test medication liquid making method: active component four chlorantraniliprole, the pymetrozine that accurately take insecticide of the present invention with electronic analytical balance respectively, then former medicine is added proper amount of acetone to dissolve, after dissolving completely, desired concn mother liquor is mixed with the water containing 0.1% Tween 80, in the ratio in insecticide of the present invention between two kinds of active components, above-mentioned mother liquor is hybridly prepared into mixed solution by a certain percentage, is diluted to the serial liquid of tool finite concentration gradient by experimental scheme dosage respectively.
Test method: adopt infusion process to process, the cabbage leaves of greenhouse culture is fetched, makes diameter 2cm leaf dish, leaf dish is flooded 5s in liquid, dries in the shade after taking-up, put into the 9cm culture dish being lined with filter paper, select in the examination worm access culture dish of neat and consistent, often process repetition 4 times.Be placed in observation ward by the examination worm after process, routine observation examination worm response situation, 72h " Invest, Then Investigate " is dead, borer population of living.
Mixture effect assessment adopts Bliss method, and the independent joint action concept that Bliss proposes according to it is thought, theoretical lethality P during Mixture Use of Insecticides can calculate with following formula:
P=Pm+Pn(1-Pm)
Pm is the actual measurement lethality (%) of the first active component target when concentration is m; The actual measurement lethality (%) of Pn is the second active component working concentration when being n target.
If two kinds of active components are being greater than theoretical lethality P with the actual of the rear target of finite concentration mixing, are then judging that two kinds of active components are used in combination under setting concentration and there is synergistic effect, otherwise be then antagonism.
Result of the test is in table 3.As can be seen from the table, four chlorantraniliproles and pymetrozine are shown as synergistic effect for each proportioning of examination to diamond-back moth.
Table 3: four chlorantraniliprole pymetrozines are to the indoor joint toxicity measuring result of diamond-back moth
The composition of embodiment 11 containing four chlorantraniliproles is to the synergism determination of black bean aphid
For examination object: black bean aphid (Aphis craccivora), if 3 age in days aphids, the sensitive strain of indoor feeding.
Test condition: temperature: 24-26 DEG C, humidity: RH60%, illumination: L:D=14:10
Drug solution preparation method is with embodiment 16.Test method: adopt band worm plant infusion process.With broad bean seedling for carrier, using clear water process as blank, 2 repetitions are established in test.Get band worm plant, in the liquid prepared, flood 10s, remove unnecessary liquid by wall, cloche made by oneself by cover, move into observation ward and carry out cultivation observation.96h " Invest, Then Investigate " is dead, borer population of living.
With Abbott formulae discovery corrected mortality, appliance computer program obtains each the virulence regression equation formula, the LC that use with for examination single dose and variant proportioning 50value and 95% confidence limit.
Mixture effect assessment adopts Bliss method, and the independent joint action concept that Bliss proposes according to it is thought, theoretical lethality P during Mixture Use of Insecticides can calculate with following formula:
P=Pm+Pn(1-Pm)
Pm is the actual measurement lethality (%) of the first active component target when concentration is m; The actual measurement lethality (%) of Pn is the second active component working concentration when being n target.
If two kinds of active components are being greater than theoretical lethality P with the actual of the rear target of finite concentration mixing, are then judging that two kinds of active components are used in combination under setting concentration and there is synergistic effect, otherwise be then antagonism.
Four chlorantraniliproles and pymetrozine all show synergistic effect for each proportioning of examination to black bean aphid, the results are shown in Table 4.
The composition of table 4 containing four chlorantraniliproles is to black bean aphid nymph synergism determination

Claims (8)

1. a binary pesticide composition, is characterized in that: active component one is four chlorantraniliproles, and active component two is pymetrozine; Described four chlorantraniliprole structural formulas are as follows:
Wherein, the ratio of weight and number between two kinds of active components is 1:99-99:1.
2. according to binary pesticide composition according to claim 1, it is characterized in that: the ratio of weight and number between two kinds of active components is 1:20-20:1.
3. according to binary pesticide composition according to claim 1, it is characterized in that: composition can be made into missible oil, suspending agent, water-dispersible granules, aqueous emulsion, microemulsion, soluble liquid, wetting powder or oil-suspending agent.
4., according to binary pesticide composition according to claim 3, it is characterized in that: in composition active component percentage by weight between 0.5%-95%.
5., according to binary pesticide composition according to claim 4, it is characterized in that: in composition active component percentage by weight between 1%-85%.
6. an application for binary pesticide composition according to claim 1, is characterized in that: described composition can be used as the insecticide controlling agriculture and forestry injurious insect.
7. by the application of binary pesticide composition according to claim 6, it is characterized in that: described composition imposes on the insect of needs control or the medium of its growth with effective dose; Apply the effective dose that dosage is per hectare 10 grams-500 grams.
8. by the application of binary pesticide composition according to claim 7, it is characterized in that: apply the effective dose that dosage is per hectare 15 grams-100 grams.
CN201310407921.5A 2013-09-06 2013-09-06 Binary pesticide composition and application thereof Active CN104412991B (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105941424A (en) * 2016-05-31 2016-09-21 河北博嘉农业有限公司 Agricultural insecticidal composition capable of preventing and treating rice planthopper

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101333213A (en) * 2008-07-07 2008-12-31 中国中化集团公司 1-substituted pyridyl-pyrazol acid amide compounds and use thereof
CN101720769A (en) * 2010-01-08 2010-06-09 张志高 Insecticidal composition containing pymetrozine and chlorantraniliprole
CN103931630A (en) * 2013-01-18 2014-07-23 陕西汤普森生物科技有限公司 Insecticide composition containing SYP9080

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101333213A (en) * 2008-07-07 2008-12-31 中国中化集团公司 1-substituted pyridyl-pyrazol acid amide compounds and use thereof
CN101720769A (en) * 2010-01-08 2010-06-09 张志高 Insecticidal composition containing pymetrozine and chlorantraniliprole
CN103931630A (en) * 2013-01-18 2014-07-23 陕西汤普森生物科技有限公司 Insecticide composition containing SYP9080

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105941424A (en) * 2016-05-31 2016-09-21 河北博嘉农业有限公司 Agricultural insecticidal composition capable of preventing and treating rice planthopper

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