CN106937642A - A kind of medicament composition of the mite of azoles containing second nitrile - Google Patents

A kind of medicament composition of the mite of azoles containing second nitrile Download PDF

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Publication number
CN106937642A
CN106937642A CN201710163622.XA CN201710163622A CN106937642A CN 106937642 A CN106937642 A CN 106937642A CN 201710163622 A CN201710163622 A CN 201710163622A CN 106937642 A CN106937642 A CN 106937642A
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CN
China
Prior art keywords
mite
nitrile
azoles
medicament composition
diacloden
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710163622.XA
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Chinese (zh)
Inventor
任学祥
张勇
叶正和
苏贤岩
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Institute of Plant Protection and Agricultural Products Quality Safety of AAAS
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Institute of Plant Protection and Agricultural Products Quality Safety of AAAS
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Application filed by Institute of Plant Protection and Agricultural Products Quality Safety of AAAS filed Critical Institute of Plant Protection and Agricultural Products Quality Safety of AAAS
Priority to CN201710163622.XA priority Critical patent/CN106937642A/en
Publication of CN106937642A publication Critical patent/CN106937642A/en
Pending legal-status Critical Current

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Classifications

    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N51/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds having the sequences of atoms O—N—S, X—O—S, N—N—S, O—N—N or O-halogen, regardless of the number of bonds each atom has and with no atom of these sequences forming part of a heterocyclic ring
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
    • A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/40—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having a double or triple bond to nitrogen, e.g. cyanates, cyanamides

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  • Life Sciences & Earth Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The invention discloses the medicament composition of a kind of mite nitrile of azoles containing second and MTI-446, clothianidin, Diacloden, thiacloprid, imidacloprid, Acetamiprid or Nitenpyram, common formulations are made with suitable agricultural agent by active ingredient second azoles mite nitrile and MTI-446, clothianidin, Diacloden, thiacloprid, imidacloprid, Acetamiprid or Nitenpyram.Significantly, there is notable synergistic effect, can reduce dosage in the present invention, delay the resistance to the action of a drug of single medicament, economic, efficient, environmental protection to the crop control of pest mite such as European red mite effect between two medicaments.

Description

A kind of medicament composition of the mite of azoles containing second nitrile
Technical field
The invention belongs to insect evil mite chemical prevention field, and in particular to a kind of medicament composition of the mite of azoles containing second nitrile.
Background technology
Second azoles mite nitrile, chemical name：(z) -2- (4- tert-butyl-phenyls) -2- cyano group -1- (1- ethyl -3- methylpyrazoles -5- Base) vinyl-PA ester is to change pesticide chemical in Shenyang to research and develop Co., Ltd using nitrile pyrrole mite ester as guide's chemical combination The compound with high acaricidal activity found after thing, transformation, to the low toxicities such as honeybee, bird, fish, silkworm, preventing and treating citrus red mite, apple Fruit tetranychid, cotton spider mites and the contour effect of vegetables tetranychid.
Anabasine insecticide includes clothianidin, MTI-446, Diacloden, imidacloprid, Nitenpyram, Acetamiprid etc..To same Wing mesh insect, mite class etc. have good preventive effect.
Different type of action insecticidal/acaricidal agents are compounded, and can be very good to improve prevention effect, expand prevention and treatment range, section About drug cost, not yet finds that second azoles mite nitrile prevents and treats the relevant report of evil mite with anabasine insecticide mixture at present.
The content of the invention
It is an object of the invention to provide a kind of medicament composition of the mite of azoles containing second nitrile, complex preparation is made, for preventing and treating work Thing evil mite, effect is good, and dosage is low；And there is provided the method for preventing and treating the insects such as evil mite using said composition.
The technical solution adopted by the present invention is as follows：
A kind of medicament composition of the mite of azoles containing second nitrile, it is characterised in that：Be made up of effective constituents A and B and auxiliary material, wherein effectively into It is second azoles mite nitrile to divide A, and active ingredient B is in MTI-446, clothianidin, Diacloden, thiacloprid, imidacloprid, Nitenpyram, Acetamiprid One kind.
A kind of medicament composition of the described mite of azoles containing second nitrile, it is characterised in that：In the medicament composition, active ingredient A and active ingredient B mass ratio are 40:1-1:40.
A kind of medicament composition of the described mite of azoles containing second nitrile, it is characterised in that：In the medicament composition, active ingredient A and active ingredient B mass ratio are 10:1-1:10.
A kind of medicament composition of the described mite of azoles containing second nitrile, it is characterised in that：The formulation of the medicament composition is breast Oil, suspending agent, water-dispersible granules, wettable powder, microcapsule suspending agent.
Application method：Said preparation both can routinely spray, atomizing, pouring root, be entered after can also diluting with machineries such as hot mist machine, aircrafts Row large area dispenser, reduces the generation of evil mite.
Beneficial effects of the present invention：
The medicament composition of the present invention compared with prior art, produces following beneficial effect：(1) compared with single dose, said composition To insect evil mite notable synergistic, hence it is evident that improve prevention effect, significantly reduce drug cost；（2）Insect evil mite is to the medicament The resistance to the action of a drug is not likely to produce, while also inhibits resistance of the evil mite to other agricultural chemicals；（3）Insect evil mite is had concurrently quick-acting and long-acting Function；(4) field dosage can be greatly reduced, environmental pollution and residues of pesticides are effectively reduced；（5）With other conventional medicaments Compare, production and use cost reduction；（6）Being controlled one medicine, a dispenser can prevent and treat various pests simultaneously more, reduce preventing and treating recruitment into This；(7) toxicity to other non-target organisms is reduced.
Experimental data
Using the method for indoor bioassay.
Co-toxicity coefficient of the built agent to cotton spider mites of different ratio is drawn by indoor bioassay first, then passes through field Its clear and definite prevention effect of the test of pesticide effectiveness, determines the formula rate and optimum amount of built agent.
Indoor bioassay：Using slide infusion process.
Missible oil is made in the formula for having synergistic effect obtained by indoor bioassay（EC）, suspension emulsion（SE）, wettable powder （WP）, water-dispersible granules（WDG）, microcapsule suspending agent（CS）Tested.
Table 1, table 2, table 3, table 4, table 5, table 6, table 7 sets forth second azoles mite nitrile and MTI-446, clothianidin, Diacloden, The virulence of thiacloprid, imidacloprid, Nitenpyram, Acetamiprid compounding to European red mite.
The second azoles mite nitrile of table 1 and the dinotefuran mixed virulence to European red mite
The virulence of the second azoles mite nitrile of table 2 and clothianidin mixture to European red mite
The virulence of the second azoles mite nitrile of table 3 and Diacloden mixture to European red mite
The virulence of the second azoles mite nitrile of table 4 and thiacloprid mixture to European red mite
The virulence of the second azoles mite nitrile of table 5 and imidacloprid mixture to European red mite
The virulence of the second azoles mite nitrile of table 6 and Nitenpyram mixture to European red mite
The virulence of the second azoles mite nitrile of table 7 and Acetamiprid mixture to European red mite
By 1 ~ table of table 7 it can be seen that second azoles mite nitrile and MTI-446, clothianidin, Diacloden, thiacloprid, imidacloprid, Acetamiprid, alkene Pyridine worm amine is 40:1~1:Good synergistic effect is shown in the range of 40 to European red mite.
Embodiment：
By second azoles mite nitrile and MTI-446, clothianidin, Diacloden, thiacloprid, imidacloprid, Acetamiprid, Nitenpyram in varing proportions, The auxiliary agents such as excipients, wetting agent, filler are added, missible oil, suspension emulsion, water-dispersible granules, wettable powder, micro-capsule has been made The formulations such as suspending agent.In order to illustrate effect, further it is illustrated to example 7 with example 1 below, but not limited to this.
(the 22% second azoles mite nitrile MTI-446 suspending agent of embodiment 1）
Composition of raw materials：By mass percentage
Active component second azoles mite nitrile 2%
Active component MTI-446 20%
Sodium lignin sulfonate 3%
BY120 2%
600# 2%
Xanthans 0.15%
Propane diols 1%
Water surplus.
Preparation method is as follows：
According to formula, component is weighed in proportion, ball mill ball milling is added 30 minutes, filtering is pumped into 3 points of dispersion tank high speed shear It is fully ground after clock through sand mill, control solid constituent particle diameter is within 2 microns, and grinding stirs after terminating, and produces Suspending agent product.
(the 30% second fenpyroximate clothianidin missible oil of embodiment 2）
Composition of raw materials：By mass percentage
Active component second fenpyroximate 15%
Active component clothianidin 15%
Dimethylbenzene 20%
DMF 2%
Anhydrous calcium salt 5%
Tween 80 5%
Carbon tetrachloride surplus.
Preparation method：Active component is fully dissolved in dimethylbenzene, stirred, anhydrous calcium salt and tween is added 80, content then is adjusted with solvent DMF, surplus is adjusted with carbon tetrachloride.
Embodiment 3（36% second azoles mite nitrile Diacloden water dispersible granules）
Active component second azoles mite nitrile 18%
Active component Diacloden 18%
Methyl fatty acid amides benzene sulfonic acid calcium 4%
Sodium carbonate 3%
Sodium lignin sulfonate 4%
Attapulgite surplus.
Preparation method：Second azoles mite nitrile, Diacloden, Methyl fatty acid amides benzene sulfonic acid calcium, sodium carbonate, attapulgite are mixed together After closing uniformly, 5 μm of particle diameter is crushed to through airslide disintegrating mill, female powder is obtained, granulated after female powder and sodium lignin sulfonate are sufficiently mixed, Drying, sieving, so that water-dispersible granules are made.
Embodiment 4（55% second azoles mite nitrile thiacloprid wettable powder）
Active component second azoles mite nitrile 5%
Active component thiacloprid 50%
Wooden sodium 4.7%
Amine carbonate 3%
White carbon 10%
Attapulgite surplus.
Preparation method：Above-mentioned substance is uniformly mixed, mixture is crushed through airslide disintegrating mill, wettable powder is made.
Embodiment 5（11% second azoles mite nitrile imidacloprid microcapsule suspending agent）
Active component second azoles mite nitrile 1%
Active component imidacloprid 10%
Dimethylformamide 2%
Methyl diphenylene diisocyanate 3%
Fatty acid amide N methyl taurine sodium salt 2%
Ethylenediamine 0.5%
Gum arabic 2%
Polyvinyl alcohol 2%
Water polishing is to 100%
（1）By medicament dissolution in solvent, add methyl diphenylene diisocyanate and be uniformly mixing to obtain oil phase；（2）In water Add emulsifying agent, adjuvant and be uniformly mixing to obtain aqueous phase；（3）Aqueous phase is added in oil phase, high speed homogenizing formation oil-in-water emulsion； （4）Under 450 revs/min of speed conditions, add ethylenediamine and participate in interface polymerization reaction, reaction temperature rises to 55 DEG C, is kept for 3 hours Solidify encystation；（5）Dispersant, thickener are added, stirs and microcapsule suspending agent is made.
(the 41% second azoles mite nitrile Nitenpyram suspending agent of embodiment 6）
Composition of raw materials：By mass percentage
Active component second azoles mite nitrile 1%
Active component Nitenpyram 40%
Sodium lignin sulfonate 3%
A-105 2%
600# 2%
Xanthans 0.15%
Propane diols 1%
Water surplus.
Preparation method is as follows：
According to formula, component is weighed in proportion, ball mill ball milling is added 30 minutes, filtering is pumped into 3 points of dispersion tank high speed shear It is fully ground after clock through sand mill, control solid constituent particle diameter is within 2 microns, and grinding stirs after terminating, and produces Suspending agent product.
Embodiment 4（33% second azoles mite nitrile acetamiprid wettable powder）
Active component second azoles mite nitrile 3%
Active component thiacloprid 30%
Wooden sodium 3.7%
Amine carbonate 3%
White carbon 10%
Attapulgite surplus.
Preparation method：Above-mentioned substance is uniformly mixed, mixture is crushed through airslide disintegrating mill, wettable powder is made.
The method for preventing and treating evil mite using above-mentioned composition pesticide is to occur the phase in evil mite to add water and be made into suspension spray and use, Pest control evil mite.Medicament composition disclosed by the invention also has significant effect to homoptera pests such as planthopper, Bemisia tabacis. The present invention can routinely spray after can also the medicament of preparation be diluted by 500-5000 times, atomizing, or utilize hot mist machine, aircraft Large area dispenser is carried out Deng big machinery, the generation of the insect evil mites such as tetranychid is reduced.

Claims (4)

1. a kind of medicament composition of the mite of azoles containing second nitrile, it is characterised in that：It is made up of effective constituents A and B and auxiliary material, wherein effectively Composition A is second azoles mite nitrile, and active ingredient B is MTI-446, clothianidin, Diacloden, thiacloprid, imidacloprid, Nitenpyram, Acetamiprid In one kind.
2. a kind of medicament composition of the mite of azoles containing second nitrile according to claim 1, it is characterised in that：The medicament composition In, effective constituents A and active ingredient B mass ratio are 40:1-1:40.
3. a kind of medicament composition of the mite of azoles containing second nitrile according to claim 1, it is characterised in that：The medicament composition In, effective constituents A and active ingredient B mass ratio are 10:1-1:10.
4. a kind of medicament composition of the mite of azoles containing second nitrile according to claim 1, it is characterised in that：The medicament composition Formulation be missible oil, suspending agent, water-dispersible granules, wettable powder, microcapsule suspending agent.
CN201710163622.XA 2017-03-20 2017-03-20 A kind of medicament composition of the mite of azoles containing second nitrile Pending CN106937642A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109122692A (en) * 2018-10-18 2019-01-04 江苏省农业科学院 A kind of pesticide and miticide farm chemical composition with synergistic function

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104663705A (en) * 2013-11-26 2015-06-03 中国中化股份有限公司 Pest-killing and mite-killing composition
CN106614677A (en) * 2015-10-30 2017-05-10 陕西韦尔奇作物保护有限公司 Insecticidal pesticide composition containing SYP-9625

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104663705A (en) * 2013-11-26 2015-06-03 中国中化股份有限公司 Pest-killing and mite-killing composition
CN106614677A (en) * 2015-10-30 2017-05-10 陕西韦尔奇作物保护有限公司 Insecticidal pesticide composition containing SYP-9625

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109122692A (en) * 2018-10-18 2019-01-04 江苏省农业科学院 A kind of pesticide and miticide farm chemical composition with synergistic function
CN109122692B (en) * 2018-10-18 2020-08-07 江苏省农业科学院 Insecticidal and acaricidal pesticide composition with synergistic effect

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Application publication date: 20170711