CN106922711A - A kind of composition pesticide containing Spiromesifen - Google Patents
A kind of composition pesticide containing Spiromesifen Download PDFInfo
- Publication number
- CN106922711A CN106922711A CN201710172883.8A CN201710172883A CN106922711A CN 106922711 A CN106922711 A CN 106922711A CN 201710172883 A CN201710172883 A CN 201710172883A CN 106922711 A CN106922711 A CN 106922711A
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- CN
- China
- Prior art keywords
- spiromesifen
- composition pesticide
- carbosulfan
- benfuracard micro
- pesticide containing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
- A01N47/24—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof containing the groups, or; Thio analogues thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
- A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
- A01N43/06—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom five-membered rings
- A01N43/12—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom five-membered rings condensed with a carbocyclic ring
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- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention provides a kind of composition pesticide containing Spiromesifen, its active ingredient is Spiromesifen and carbosulfan, two kinds of components of Benfuracard micro, and remaining is auxiliary material.The pest and disease damages such as composition pesticide of the invention preventing and treating planthopper, pear sucker have building performance, while consumption is few, controlling object is wide, reduces drug cost, reduces the pollution to environment.
Description
Technical field
The invention belongs to Chemical Control of Harmful Insects field, and in particular to a kind of composition pesticide containing Spiromesifen.
Background technology
Spiromesifen, common name Spiromesifen, the mechanism of action is to suppress the Fatty synthesis in mite class body, destroys acarid
Energetic supersession activity, disturb the biosynthesis of its fat-body, especially have preferable activity to larval stage, while can also produce
Raw ovarian duct closure function, reduces the fertility of acarid, greatly reduces spawning quantity..
Carbosulfan, adopted name：Carbosulfan, is the carbamates insecticidal/acaricidal agent commonly used, and is choline
The inhibitor of esterase, with tagging, stomach toxicity and systemic action, insecticidal spectrum is wide, and instant effect, the lasting period is long.
Benfuracard micro, adopted name is Benfuracarb, belongs to the low toxicity product of carbofuran, is the amino commonly used
Formate ester insecticidal/acaricidal agent, is the inhibitor of cholinesterase, with tagging, stomach toxicity and systemic action, is mainly used in anti-harnessing the river
Various sucking mouth parts and pests with chewing mouthparts of rice, cotton, corn and soybean, vegetables and fruit tree.
Planthopper, including brown paddy plant hopper Nilaparvata lugens, white backed planthopper Sogatella furcifera and ash fly
Lice Laodeobhax striatellus, are migratory pest, are distributed in national paddy fields, are the masters of rice crop
One of insect is wanted, except itself harm to paddy rice, 5 kinds of viruses that they propagate：Rice grassy stunt virus（RGSV）, paddy rice
Tingia stunt virus（RRSV）, oryza virus 3（RSV）, rice black-streaked dwarf virus（RBSDV）, south rice secret note
Dwarf virus（SRBSDV）, have a strong impact on the quality and yield of paddy rice.From phase late 1960s begin, planthopper and its pass band
Virosis be always just influence Asia Rice Production one of key factor.
Pear sucker, is directly endangered with inhaling bud, leaf, spray tip juice into, nymph thorn, and secreting mucus cause miscellaneous bacteria.Pears
Like cicada, body colour is generally pistac to wood louse adult, without speckle on wing.If polypide is oblate, incubates nymph is small, directly endangers
Peak period is 6 ~ July.
For a long time, people are mainly with chemical pesticide control planthopper, pear sucker, medicament used be mainly anabasine,
Organic phosphates, carbamates and AVM etc., but the use insecticide of a large amount of blindnesses for a long time, in addition planthopper, pears
The biological characteristics of wood louse itself, causes resistance level constantly to improve, and conventional medicament cannot obtain good preventing and treating effect
Really.Thus finding safe and efficient surrogate-data technique increasingly seems important.
The synergistic complex of agricultural chemicals is to expand chemical control scope, improve desinsection quick-acting and lasting effect, delay the anti-medicine of insect
Property effective measures, so far it is not yet found that Spiromesifen and carbosulfan, the Insecticiding-miticiding combination of Benfuracard micro
Thing is used for preventing and treating the relevant report of planthopper, pear sucker.
The content of the invention
It is an object of the invention to provide a kind of by Spiromesifen and carbosulfan or the mixture of Benfuracard micro, it is made
Compounded pesticides, for preventing and treating planthopper, pear sucker, effect is good, and dosage is low；And fly there is provided application said composition preventing and treating rice
The method of the insects such as lice, pear sucker.
The technical solution adopted by the present invention is as follows：
A kind of composition pesticide containing Spiromesifen, it is characterised in that be made up of effective constituents A and active ingredient B and auxiliary material,
Wherein effective constituents A is Spiromesifen, and active ingredient B is carbosulfan or Benfuracard micro.
The described composition pesticide containing Spiromesifen, it is characterised in that the mass ratio of effective constituents A and active ingredient B
It is 40:1-1:40.
The described composition pesticide containing Spiromesifen, it is characterised in that the mass ratio of effective constituents A and active ingredient B
It is 10:1-1:10.
The described composition pesticide containing Spiromesifen, it is characterised in that the mass ratio of effective constituents A and active ingredient B
It is 1:1-1:5.
The described composition pesticide containing Spiromesifen, it is characterised in that the formulation of the composition pesticide is missible oil, hangs
Floating agent, water-dispersible granules, wettable powder, microcapsule suspending agent.
Application method：Said preparation both can routinely spray, atomizing, be carried out greatly with machineries such as hot mist machine, aircrafts after can also diluting
Area dispenser, reduces the generation of insect.
Beneficial effects of the present invention：
Pesticidal combination of the invention compared with prior art, produces following beneficial effect：(1) compared with single dose, said composition
To insect notable synergistic, hence it is evident that improve prevention effect, drug cost is significantly reduced；（2）Insect is not likely to produce to the medicament
The resistance to the action of a drug, while also inhibits resistance of the insect to other agricultural chemicals；（3）Have quick-acting and long-acting functions concurrently to insect；(4) may be used
Field dosage is greatly reduced, environmental pollution and residues of pesticides are effectively reduced；（5）Compared with other conventional medicaments, production and
Use cost reduction；（6）Being controlled one medicine, a dispenser can simultaneously prevent and treat various pests, reduction prevents and treats recruitment cost more；(7) reduce
To the toxicity of other non-target organisms.
Experimental data
First, reagent agent：Spiromesifen active compound；Carbosulfan active compound；Benfuracard micro active compound
2nd, for examination insect：Paddy rice small brown rice planthopper；Pear sucker
3rd, assay method：
The method being combined using indoor bioassay and field control effectiveness test.
Draw the built agent of different ratio to paddy rice small brown rice planthopper and the common poison system of pear sucker by indoor bioassay first
Number, then by clear and definite its prevention effect of field control effectiveness test, determine the formula rate and optimum amount of built agent.
Indoor bioassay：Using glass-tube medicine embrane method.Active compound acetone is diluted to series concentration, with 0.5 mL pipettes
The mL of correct amount taking liquid 0.5, in adding capacity to be the teat glass of 20 mL（Standard test tube）, it is lain against on experimental bench simultaneously
Constantly roll, acetone is volatilized, medicament forms medicine film in glass-tube inwall, is compared with the glass tube for only adding acetone film forming, often
Concentration is repeated 4 times.The consistent adult 30 of development is accessed in often managing, mouth of pipe spun yarn net is sealed and is downwardly inclined 35 ° of placements, is located
5 h check number of dead and live insects after reason.With the statistical software processing datas of SPSS 17.0.
Field efficacy：The formula that indoor bioassay gained has synergistic effect is made missible oil（EC）, suspension emulsion（SE）, can
WP（WP）, water-dispersible granules（WDG）Tested.After setting cell sprays medicament, preventive effect is checked simultaneously to determine to be adapted to
Dosage.
Table 1, table 2 sets forth Spiromesifen and carbosulfan different proportion mixture to small brown rice planthopper, pear sucker adult
Virulence test result；
Table 3, table 4 sets forth Spiromesifen and Benfuracard micro different proportion mixture to small brown rice planthopper, the poison of pear sucker adult
Power result of the test；
The virulence of the Spiromesifen of table 1 and carbosulfan different proportion mixture to striatellus imago
The virulence of the Spiromesifen of table 2 and carbosulfan different proportion mixture to pear sucker
The virulence of the Spiromesifen of table 3 and Benfuracard micro different proportion mixture to striatellus imago
The virulence of the Spiromesifen of table 4 and Benfuracard micro different proportion mixture to pear sucker
By 1 ~ table of table 4 it can be seen that Spiromesifen and carbosulfan, Benfuracard micro different proportion mixture to small brown rice planthopper and
Pear sucker shows good synergistic effect.
Specific embodiment：
By Spiromesifen and carbosulfan, Benfuracard micro in varing proportions, excipients, wetting agent, filler etc. is added to help
Agent, has been made the formulations such as missible oil, suspension emulsion, water-dispersible granules, wettable powder, microcapsule suspending agent.In order to illustrate effect, under
Face is further illustrated with example 1 to example 10, but not limited to this.
(the 24% Spiromesifen carbosulfan suspension emulsion of embodiment 1）
Composition of raw materials：By mass percentage
Active component Spiromesifen 20%
Active component carbosulfan 4%
Sodium lignin sulfonate 3%
A-105 2%
BY140 2%
Aluminium-magnesium silicate 0.15%
Ethylene glycol 1%
Water surplus.
Preparation method is as follows：
According to formula, component is weighed in proportion, add ball mill ball milling 30 minutes, filtering is pumped into 3 points of dispersion tank high speed shear
It is fully ground through sand mill after clock, within 2 microns, grinding stirs control solid constituent particle diameter after terminating, and obtains final product
Suspension emulsion product.
(the 30% Spiromesifen carbosulfan missible oil of embodiment 2）
Composition of raw materials：By mass percentage
Active component Spiromesifen 15%
Active component carbosulfan 15%
Dimethylbenzene 20%
DMF 2%
Anhydrous calcium salt 5%
Tween 80 5%
Absolute ethyl alcohol surplus.
Preparation method：Active component is fully dissolved in dimethylbenzene, is stirred, add anhydrous calcium salt and tween
80, content then is adjusted with solvent DMF, adjust surplus with absolute ethyl alcohol.
Embodiment 3（36% Spiromesifen carbosulfan water dispersible granules）
Active component Spiromesifen 18%
Active component carbosulfan 18%
Methyl fatty acid amides benzene sulfonic acid calcium 4%
Sodium carbonate 3%
Sodium lignin sulfonate 4%
Attapulgite surplus.
Preparation method：By Spiromesifen, carbosulfan, Methyl fatty acid amides benzene sulfonic acid calcium, sodium carbonate, attapulgite one
Rise after being well mixed, 5 μm of particle diameter is crushed to through airslide disintegrating mill, obtain female powder, after female powder and sodium lignin sulfonate are sufficiently mixed
Granulation, drying, sieving, so as to water-dispersible granules are obtained.
Embodiment 4（36% Spiromesifen carbosulfan wettable powder）
Active component Spiromesifen 30%
Active component carbosulfan 6%
NNO 4.7%
Amine carbonate 3%
White carbon 10%
Attapulgite surplus.
Preparation method：Above-mentioned substance is uniformly mixed, mixture is crushed through airslide disintegrating mill, wettable powder is obtained.
Embodiment 5（12% Spiromesifen carbosulfan microcapsule suspending agent）
Active component Spiromesifen 10%
Active component carbosulfan 2%
Dimethylformamide 2%
Methyl diphenylene diisocyanate 3%
Fatty acid amide N methyl taurine sodium salt 2%
Ethylenediamine 0.5%
Gum arabic 2%
Polyvinyl alcohol 2%
Water polishing is to 100%
（1）By medicament dissolution in solvent, methyl diphenylene diisocyanate is added to be uniformly mixing to obtain oil phase；（2）In water
Emulsifying agent, adjuvant is added to be uniformly mixing to obtain water phase；（3）Water is added in oil phase, high speed homogenizing formation oil-in-water emulsion；
（4）Under 450 revs/min of speed conditions, ethylenediamine is added to participate in interface polymerization reaction, reaction temperature rises to 55 DEG C, is kept for 3 hours
Solidification encystation；（5）Dispersant, thickener are added, is stirred and is made microcapsule suspending agent.
(the 22% Spiromesifen Benfuracard micro suspension emulsion of embodiment 6）
Composition of raw materials：By mass percentage
Active component Spiromesifen 2%
Active component Benfuracard micro 20%
Sodium lignin sulfonate 3%
MOA-1 2%
600# 2%
Bentonite 0.15%
Ethylene glycol 1%
Water surplus.
Preparation method is as follows：
According to formula, component is weighed in proportion, add ball mill ball milling 30 minutes, filtering is pumped into 3 points of dispersion tank high speed shear
It is fully ground through sand mill after clock, within 2 microns, grinding stirs control solid constituent particle diameter after terminating, and obtains final product
Suspension emulsion product.
(the 30% Spiromesifen Benfuracard micro missible oil of embodiment 7）
Composition of raw materials：By mass percentage
Active component Spiromesifen 5%
Active component Benfuracard micro 25%
Dimethylbenzene 13%
DMF 2%
Anhydrous calcium salt 5%
Tween 80 5%
Carbon tetrachloride surplus.
Preparation method：Active component is fully dissolved in dimethylbenzene, is stirred, add anhydrous calcium salt and tween
80, content then is adjusted with solvent DMF, adjust surplus with carbon tetrachloride.
Embodiment 8（35% Spiromesifen Benfuracard micro water dispersible granules）
Active component Spiromesifen 5%
Active component Benfuracard micro 30%
Methyl fatty acid amides benzene sulfonic acid calcium 4.3%
Sodium carbonate 3%
Sodium lignin sulfonate 3.6%
Attapulgite surplus.
Preparation method：By Spiromesifen, Benfuracard micro, Methyl fatty acid amides benzene sulfonic acid calcium, sodium carbonate, attapulgite one
Rise after being well mixed, 5 μm of particle diameter is crushed to through airslide disintegrating mill, obtain female powder, after female powder and sodium lignin sulfonate are sufficiently mixed
Granulation, drying, sieving, so as to water-dispersible granules are obtained.
Embodiment 9（48% Spiromesifen Benfuracard micro wettable powder）
Active component Spiromesifen 8%
Active component Benfuracard micro 40%
NNO 5.6%
Amine carbonate 3.2%
White carbon 7.6%
Attapulgite surplus.
Preparation method：Above-mentioned substance is uniformly mixed, mixture is crushed through airslide disintegrating mill, wettable powder is obtained.
Embodiment 10（8% Spiromesifen Benfuracard micro microcapsule suspending agent）
Active component Spiromesifen 2%
Active component Benfuracard micro 10%
Dimethylformamide 2%
Methyl diphenylene diisocyanate 3%
Fatty acid amide N methyl taurine sodium salt 2%
Ethylenediamine 0.5%
Gum arabic 2%
Polyvinyl alcohol 2%
Water polishing is to 100%
（1）By medicament dissolution in solvent, methyl diphenylene diisocyanate is added to be uniformly mixing to obtain oil phase；（2）In water
Emulsifying agent, adjuvant is added to be uniformly mixing to obtain water phase；（3）Water is added in oil phase, high speed homogenizing formation oil-in-water emulsion；
（4）Under 450 revs/min of speed conditions, ethylenediamine is added to participate in interface polymerization reaction, reaction temperature rises to 55 DEG C, is kept for 3 hours
Solidification encystation；（5）Dispersant, thickener are added, is stirred and is made microcapsule suspending agent.
The use of the method for above-mentioned composition pesticide pest control evil mite is to add water to be made into suspension in the insect evil mite generation phase
Spraying is used, pest control evil mite.Medicament composition disclosed by the invention is to homoptera pests such as planthopper, Bemisia tabaci, aphids
Also there is significant effect.The present invention can routinely spray after can also the medicament of preparation be diluted by 500-5000 times, atomizing, or
Large area dispenser is carried out using big machineries such as hot mist machine, aircrafts, the generation of the insect evil mites such as tetranychid is reduced.
The Spiromesifen Benfuracard micro medicament composition of table 5 prevents and treats the crop field drug effect of planthopper
Finally, in addition it is also necessary to it is noted that listed above is only several specific embodiments of the invention.Obviously, the present invention not
It is limited to the embodiment of the above, there can also be many variations.One of ordinary skill in the art can be straight from present disclosure
The all deformations derived or associate are connect, the scope of protection of the invention is considered.
Claims (4)
1. a kind of composition pesticide containing Spiromesifen, it is characterised in that：By active ingredient Spiromesifen, carbosulfan or third
Carbosulfan and auxiliary material component are constituted.
2. a kind of composition pesticide containing Spiromesifen according to claim 1, it is characterised in that：The composition pesticide
In, the mass ratio of Spiromesifen and carbosulfan or Benfuracard micro is 20:1-1:40.
3. a kind of composition pesticide containing Spiromesifen according to claim 1, it is characterised in that：The composition pesticide
In, the mass ratio of Spiromesifen and carbosulfan or Benfuracard micro is 5:1-1:5.
4. a kind of composition pesticide containing Spiromesifen according to claim 1, it is characterised in that：The composition pesticide
Formulation be missible oil, suspension emulsion, water-dispersible granules, wettable powder, microcapsule suspending agent.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710172883.8A CN106922711A (en) | 2017-03-22 | 2017-03-22 | A kind of composition pesticide containing Spiromesifen |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710172883.8A CN106922711A (en) | 2017-03-22 | 2017-03-22 | A kind of composition pesticide containing Spiromesifen |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106922711A true CN106922711A (en) | 2017-07-07 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710172883.8A Pending CN106922711A (en) | 2017-03-22 | 2017-03-22 | A kind of composition pesticide containing Spiromesifen |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115812731A (en) * | 2022-12-21 | 2023-03-21 | 中农立华生物科技股份有限公司 | High-content carbosulfan microcapsule suspending agent and preparation method and application thereof |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN102578121A (en) * | 2011-12-19 | 2012-07-18 | 河南金田地农化有限责任公司 | Pesticide insecticidal and acaricidal composition containing spiroteramat |
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2017
- 2017-03-22 CN CN201710172883.8A patent/CN106922711A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102578121A (en) * | 2011-12-19 | 2012-07-18 | 河南金田地农化有限责任公司 | Pesticide insecticidal and acaricidal composition containing spiroteramat |
Non-Patent Citations (2)
| Title |
|---|
| 周成建 等: "丁硫克百威乳油防治柑桔锈壁虱效果评价", 《中国南方果树》 * |
| 黄婷: "锈螨危害对砂糖桔果实品质的影响与防治策略", 《农业与技术》 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115812731A (en) * | 2022-12-21 | 2023-03-21 | 中农立华生物科技股份有限公司 | High-content carbosulfan microcapsule suspending agent and preparation method and application thereof |
| CN115812731B (en) * | 2022-12-21 | 2024-04-09 | 中农立华生物科技股份有限公司 | High-content carbosulfan microcapsule suspending agent and preparation method and application thereof |
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