CN106561666A - Insecticidal composition containing flupyradifurone and cyclaniliprole - Google Patents
Insecticidal composition containing flupyradifurone and cyclaniliprole Download PDFInfo
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- CN106561666A CN106561666A CN201610992691.7A CN201610992691A CN106561666A CN 106561666 A CN106561666 A CN 106561666A CN 201610992691 A CN201610992691 A CN 201610992691A CN 106561666 A CN106561666 A CN 106561666A
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- Prior art keywords
- fluorine pyrrole
- insect amide
- pyrrole furanone
- ring bromine
- bromine insect
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
- A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
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- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention relates to an insecticidal composition containing flupyradifurone and cyclaniliprole. The weight ratio of the two effective ingredients is 1: 20 to 20: 1. The effective ingredients in the insecticidal composition account for 1-85% in percentages by mass, the balance being auxiliary components which are permitted to use and can be accepted. The insecticidal composition can be used for preparing a suspending agent, an emulsion in water, a microemulsion, missible oil, wettable powder, a micro-capsule suspending agent, water dispersible granules, soluble powder and soluble granules. The composition provided by the invention has an obvious synergic effect, so that the usage rate of pesticides can be reduced, and the insecticidal composition is environmental-friendly and safe.
Description
Technical field
The present invention relates to composition pesticide field, and in particular to be a kind of containing fluorine pyrrole furanone and ring bromine insect amide
Agricultural insecticide composition.
Background technology
Fluorine pyrrole furanone, English is general entitled：flupyradifurone；Developing code name is：BYI02960；Trade name：
Sivanto, Sivanto Prime etc..Its IUPAC is entitled：4- [(6- chloro-3-pyridyl ylmethyls) (2,2- bis- fluoro ethyl) amino]
Furans -2 (5H) -one；CAS accession number：[951659-40-8]；Relative molecular mass：288.7；Molecular formula：C12H11ClF2N2O2。
Its chemical structural formula is：
。
Fluorine pyrrole furanone had both accomplished quick, efficient and environmentally friendly when sucking pest is prevented and treated, and toxicity is low.
Especially, fluorine pyrrole furanone is to honeybee safety.
Ring bromine insect amide,（cyclaniliprole）, chemical name：The bromo- N- of 3- { the bromo- 4- of 2- chloro- 6- { [(1- cyclopropyl
Ethyl) amine] carbonyl } phenyl } -1- (3- chloro-2-pyridyls) -1H- pyrazoles -5- formamides, its structural formula is：
。
Ring bromine insect amide is a kind of novel bisamide insecticides of Japanese Shi Yuan industry companies exploitation, because of its mechanism of action
Wide concerned different from other bisamide classes, future is expected to be played a significant role in preventing and treating resistant insect field.The agent is to target
Mark pest efficient, to non-Target crops safety, the insecticidal activity with wide spectrum, can be used for fruit tree, vegetables, potato, tea tree, big
The various crop such as beans and cotton, has very to diamondback moth, prodenia litura, aleyrodid, aphid, thrips, housefly, liriomyza bryoniae, termite etc.
Good kill effect, and with good systemic activity, for preventing and treating Lepidoptera and sucking pest.
In the real process of agricultural production, it is the maximally efficient means for preventing and treating plant pest to apply chemical agent, but
It is to be easiest to generate the problem that the drug-fast generation of insect pest by chemical prevention insect pest.Practical application proves, agricultural chemicals single dose pair
Pest control effect is gradually reduced, and some pesticide activity component compoundings can reach raising drug effect, and delay insect pest drug-fast
Produce.We screen indoors and on the basis of field test, filter out fluorine pyrrole furanone and ring bromine insect amide is compounded, tool
There is obvious synergistic effect.And it is current not yet with regard to the composition pesticide and application of fluorine pyrrole furanone and the compounding of ring bromine insect amide
Reported.
The content of the invention
Present invention aims to the deficiencies in the prior art, there is provided a kind of applied widely, low cost, effect are good,
The fluorine pyrrole furanone of insect pest of the plant resistance problems and the Pesticidal combination of ring bromine insect amide can be solved.
The present invention is achieved by the following technical programs：
A kind of Pesticidal combination containing by fluorine pyrrole furanone and ring bromine insect amide, it is characterised in that including the first active component
（A）For fluorine pyrrole furanone, the second active component（B）For ring bromine insect amide, active components A and the preferred weight ratios of active component B
For 1:40～40:1, more preferably 1:20～20:1；In the Pesticidal combination of the present invention the first active component and the second activity into
The cumulant divided（Weight add and）For the composition total weight preferably 1～85%.
The Pesticidal combination is re-dubbed the formulation allowed on agricultural chemicals with known auxiliary agent and excipient：It for example can be breast
Oil, wettable powder, water dispersible granules, suspending agent, aqueous emulsion, microemulsion, suspension emulsion, dispersible oil-suspending agent, microcapsule suspension
In agent any one.
Two kinds of active ingredients show obvious synergistic effect in the Pesticidal combination of the present invention, and rice hoppers are prevented and treated
Effect is significant, shows excellent quick-acting and lasting effect, overcomes the shortcoming of each single dose.
Compared with prior art, the present invention has following beneficial effect：（1）Compared with single dose, the combination is to planthopper, leaf
Cicada, trialeurodes vaporariorum, the synergy of noctuid class pest substantially, overcome and have delayed the resistance to the action of a drug, expand preventing and treating spectrum, improve preventing and treating effect
Really；（2）Reduce preventing and treating recruitment, drug cost；（3）Alternative conventional medicine and the easily agricultural chemicals of generation resistance；（4）With single dose phase
Than two kinds of single dose combinations can reduce application cost.
Specific embodiment
In order that the objects, technical solutions and advantages of the present invention become more apparent, present invention specific examples below
Illustrate, but the present invention is limited to absolutely not these examples.Described below is only the present invention preferably embodiment, is used only for explaining
The present invention, but can not be therefore understands that being the restriction to the scope of the claims of the present invention.It should be pointed out that it is all the present invention spirit and
Any modification, equivalent or improvement for being made within principle etc., should be included within the scope of the present invention, therefore,
The protection domain of patent of the present invention should be defined by claims.
First, example of formulations
1st, embodiment 1：41% fluorine pyrrole furanone ring bromine insect amide wettable powder
Fluorine pyrrole furanone 40%
Ring bromine insect amide 1%
Lauryl sodium sulfate 3%
Sodium lignin sulfonate 6%
Diatomite 5%
White carbon 3%
Kaolin complements to 100%
The concrete procedure of processing of said composition wettable powder is：By above-mentioned formula by fluorine pyrrole furanone, ring bromine insect amide, 12
The mixing of sodium alkyl sulfate, sodium lignin sulfonate, diatomite, white carbon and kaolin, stirs in stirred tank, Jing air-flow powder
Broken machine is well mixed after crushing, you can the wettable powder containing fluorine pyrrole furanone and ring bromine insect amide of the present invention is obtained
Agent.
2nd, embodiment 2：21% fluorine pyrrole furanone ring bromine insect amide wettable powder
Fluorine pyrrole furanone 20%
Ring bromine insect amide 1%
Lauryl sodium sulfate 1.5%
Sodium lignin sulfonate 5%
White carbon 4%
Diatomite 3.5
Kaolin complements to 100%
The concrete procedure of processing of said composition wettable powder is：By above-mentioned formula by fluorine pyrrole furanone, ring bromine insect amide, 12
The mixing of sodium alkyl sulfate, sodium lignin sulfonate, diatomite, white carbon and kaolin, stirs in stirred tank, Jing air-flow powder
Broken machine is well mixed after crushing, you can the wettable powder containing fluorine pyrrole furanone and ring bromine insect amide of the present invention is obtained
Agent.
3rd, embodiment 3：11% fluorine pyrrole furanone ring bromine insect amide suspending agent
Fluorine pyrrole furanone 7%
Ring bromine insect amide 4%
Polyoxyethylene polyoxypropylene block copolymer 4%
Sodium lignin sulfonate 1.5%
Xanthans 0.22%
Aluminium-magnesium silicate 1.6%
Sodium Benzoate 0.22%
Propane diols 3%
Defoamer 1,860 0.5%
Water complements to 100%
The concrete procedure of processing of said composition suspending agent is：By in above-mentioned formula by water, polyoxyethylene polyoxypropylene block copolymerization
Thing, propane diols and defoamer 1860 are well mixed, and successively add sodium lignin sulfonate, aluminium-magnesium silicate, Jing again under stirring
High speed shear is well mixed, and adds fluorine pyrrole furanone and ring bromine insect amide, continues to shear mixing, subsequently into horizontal sand mill
Middle grinding, makes material particular diameter all in below 5um, adds xanthans and Sodium Benzoate, and shearing is uniform to be obtained institute of the present invention
The suspending agent containing fluorine pyrrole furanone and ring bromine insect amide stated.
4th, embodiment 4：10% fluorine pyrrole furanone ring bromine insect amide microemulsion
Fluorine pyrrole furanone 5%
Ring bromine insect amide 5%
1-METHYLPYRROLIDONE 12%
Cyclohexanone 6%
Methyl alcohol 4%
Calcium dodecyl benzene sulfonate 2%
OPEO 15%
Water complements to 100%
The concrete procedure of processing of said composition suspending agent is：By in above-mentioned formula by fluorine pyrrole furanone and ring bromine insect amide, N- first
The mixing of base pyrrolidones, methyl alcohol and cyclohexanone, after dissolving is transparent calcium dodecyl benzene sulfonate and octyl phenol polyoxyethylene are added
Ether, is stirring evenly and then adding into remaining water, and continuing to stir, it is of the present invention containing fluorine pyrrole furanone and ring bromine be obtained
The microemulsion of insect amide.
5th, embodiment 5：5% fluorine pyrrole furanone ring bromine insect amide microcapsule suspending agent
Fluorine pyrrole furanone 2%
Ring bromine insect amide 3%
Calcium dodecyl benzene sulfonate 3%
Phenethyl phenol polyoxyethylene poly-oxygen propylene aether 7%
Vegetable oil 10%
1-METHYLPYRROLIDONE 3%
Acrylate homopolymer sodium salt 3.5%
Sodium lignin sulfonate 1.2%
Polyvinyl alcohol 1.3%
Epoxidized soybean oil 0.2%
Dicyclohexyl methyl hydride diisocyanate 1.8%
Ethylenediamine 0.5%
Xanthans 0.2%
Sodium Benzoate 0.2%
Propane diols 3%
Water complements to 100%
The concrete procedure of processing of said composition microcapsule suspending agent is：By in above-mentioned formula by fluorine pyrrole furanone and ring bromine insect amide,
1-METHYLPYRROLIDONE, epoxidized soybean oil, dicyclohexyl methyl hydride diisocyanate and vegetable oil mixed dissolution, add dodecane
Base benzene sulfonic acid calcium and phenethyl phenol polyoxyethylene poly-oxygen propylene aether stir as oil phase；It is by above-mentioned formula that acrylic acid is equal
Polymers sodium salt, sodium lignin sulfonate, polyvinyl alcohol are dissolved completely in excess water as water phase, afterwards by oil phase it is mixed with water after
High speed shear uniformly emulsion, is slowly added to ethylenediamine under the conditions of being stirred for, and in 60 DEG C of heat preservation solidifications 1 hour, Zhi Houjia
Enter xanthans, Sodium Benzoate and propane diols and stir to can be prepared by fluorine pyrrole furanone of the present invention and ring bromine insect amide is micro-
Capsule suspending agent.
6th, embodiment 6：11% fluorine pyrrole furanone ring bromine insect amide aqueous emulsion
Fluorine pyrrole furanone 4%
Ring bromine insect amide 7%
OPEO 1.5%
Castor oil polyoxyethylene ether 7%
Dimethylbenzene 5%
Vegetable oil 5%
Cyclohexanone 10%
Propane diols 3%
Water complements to 100%
The concrete procedure of processing of said composition aqueous emulsion is：By in above-mentioned formula by fluorine pyrrole furanone and ring bromine insect amide, hexamethylene
Ketone, vegetable oil and dimethylbenzene mixed dissolution, stirring and dissolving uniformly adds afterwards OPEO and castor oil polyoxyethylene
Ether, continues to be stirring evenly and then adding into propane diols and water, and high speed shear is uniformly obtained of the present invention containing fluorine pyrrole furanone
With the aqueous emulsion of ring bromine insect amide.
7th, embodiment 7：21% fluorine pyrrole furanone ring bromine insect amide suspending agent
Fluorine pyrrole furanone 1%
Ring bromine insect amide 20%
Polyoxyethylene polyoxypropylene block copolymer 5%
Sodium lignin sulfonate 2.2%
Xanthans 0.20%
Aluminium-magnesium silicate 1.8%
Sodium Benzoate 0.20%
Propane diols 3%
Defoamer 1,860 0.5%
Water complements to 100%
The concrete procedure of processing of said composition suspending agent is：By in above-mentioned formula by water, polyoxyethylene polyoxypropylene block copolymerization
Thing, propane diols and defoamer 1860 are well mixed, and successively add sodium lignin sulfonate, aluminium-magnesium silicate, Jing again under stirring
High speed shear is well mixed, and adds fluorine pyrrole furanone and ring bromine insect amide, continues to shear mixing, subsequently into horizontal sand mill
Middle grinding, makes material particular diameter all in below 5um, adds xanthans and Sodium Benzoate, and shearing is uniform to be obtained institute of the present invention
The suspending agent containing fluorine pyrrole furanone and ring bromine insect amide stated.
8th, embodiment 8：41% fluorine pyrrole furanone ring bromine insect amide water dispersible granules
Fluorine pyrrole furanone 1%
Ring bromine insect amide 40%
Sodium lignin sulfonate 5%
Lauryl sodium sulfate 2.5%
Urea 5%
White carbon 5%
Cornstarch 5%
Kaolin complements to 100%
The concrete procedure of processing of said composition water dispersible granules is：By above-mentioned formula by fluorine pyrrole furanone, ring bromine insect amide, wooden
Plain sodium sulfonate, lauryl sodium sulfate, cornstarch, urea, white carbon and kaolin are well mixed, and enter back into airslide disintegrating mill
Crush, crushing rear material Jing mediate, subsequently into Squeezinggranulator granulation, enter back into fluid bed dryer drying, most after Jing it is whole
The water dispersible granules containing fluorine pyrrole furanone and ring bromine insect amide of the present invention are obtained after grain machine screening whole grain.
2nd, biologicall test example
1st, Toxicity Determination
To understand fluorine pyrrole furanone and definite virulence of the ring bromine insect amide mixture composition to planthopper, indoor virulence survey is first passed through
It is fixed for its proportioning is screened, clear and definite two kinds of medicaments compound by a certain percentage after co-toxicity coefficient（CTC）, CTC ＜ 80 are
Antagonism, 80≤CTC≤120 are summation action, and CTC ＞ 120 are synergistic effect.
Concrete test method：Respectively the mother liquor of each mixed agent is diluted to into five series concentrations, is respectively placed in standby in beaker
With.Using the method that leaf is followed by worm is first soaked, will be put in the liquid for having configured not in contact with the blade of the same size of any medicament
Immersion 5s, dries naturally after taking-up, in being put into insect box, then connects for examination nymph, raises under the conditions of 26 DEG C, each process
Be repeated 3 times, test worm number used repeated every time for 50, while setting blank, dead borer population is checked after 72h, calculate the death rate and
Corrected mortality, tries to achieve virulence regression equation and calculates LC50Value.If the control death rate is more than 10%, it is considered as invalid test.Meter
Calculate formula as follows：
The death rate（%）=（Borer population living after borer population-medicine living before medicine）Borer population × 100 living before/medicine
Corrected mortality（%）=（The treatment group death rate-control group the death rate）/（The 1- control group death rates）×100
Insect corrected mortality is converted into into probit value（y）, concentration for the treatment of（μg/ml）It is converted into logarithm value（x）, with least square
Method draws virulence regression equation, and thus calculates the LC of every kind of medicament50Value.Co-toxicity coefficient is calculated according to the abundant equations of Sun Yun
CTC.Computing formula is as follows（With fluorine pyrrole furanone as standard agent, its toxicity index is 100）：
The toxicity index of ring bromine insect amide（TI）The LC of=fluorine pyrrole furanone50The LC of ∕ ring bromine insect amides50×100
The actual toxicity index of M（ATI）The LC of=fluorine pyrrole furanone50The LC of ∕ M50×100
The theoretical toxicity index of M（TTI）TI × the P of=fluorine pyrrole furanoneFluorine pyrrole furanoneTI × the P of+ring bromine insect amideRing bromine insect amide
Co-toxicity coefficient（CTC）TTI × 100 of the ATI ∕ M of=M
In formula：M is the mixture of fluorine pyrrole furanone and ring bromine insect amide different ratio
PRing bromine insect amideFor the shared ratio in mixture of ring bromine insect amide
PFluorine pyrrole furanoneFor the shared ratio in mixture of fluorine pyrrole furanone
For trying insect：Rice hoppers
Test medicine is provided by Foshan Brightmart Crop Science Co., Ltd..Experimental design：Determine fluorine pyrrole through pilot study
Furanone and ring bromine insect amide active compound and effective lethasl concentration scope of the two different ratio mixture.Experimental result such as table 1：
As shown in Table 1, the Toxicity Determination of fluorine pyrrole furanone and ring bromine insect amide compounding to planthopper, co-toxicity coefficient is all higher than
120, the i.e. present composition have preferable synergistic function, and its effect is better than single dose.
2nd, field control effectiveness test
Experiment process：This experiment separately designs two dosings according to the difference of each composition, and dosing is active ingredient
The quality of fluorine pyrrole furanone and ring bromine insect amide and.Comparison medicament is 17% fluorine pyrrole furanone soluble concentrate and 20% ring bromine insect amide
Suspending agent and blank clean water experiment.
Test method：Each plot area is 66.7m2, it is repeated 3 times；Investigation drug effect side after investigating and prevent and treat before dispenser
Method is that 5 points of grab sample in test process area carry out insect population investigation according to national field test relevant criterion, calculate preventive effect.
Result of the test such as table 2：
As shown in Table 2, field control effectiveness test result shows, after fluorine pyrrole furanone and ring bromine insect amide compounding paddy rice can be effectively prevented and treated
Planthopper, the composition of the present invention has obvious synergistic function, and prevention effect is better than single dose, and preventive effect phase is long；
Paddy rice is had no adverse effects in test scope of medication, with using value.
Claims (7)
1. a kind of Pesticidal combination, it is characterised in that active component includes fluorine pyrrole furanone and ring bromine insect amide.
2. Pesticidal combination according to claim 1, it is characterised in that the weight of the fluorine pyrrole furanone and ring bromine insect amide
Amount is than being 1:40～40:1.
3. described Pesticidal combination is required according to any one of claim 1～2, it is characterised in that the fluorine pyrrole furanone
With the weight ratio preferably 1 of ring bromine insect amide:20～20:1.
4. described Pesticidal combination is required according to any one of claims 1 to 3, it is characterised in that the Pesticidal combination
It is aided with insecticidal preparation processing auxiliary element and is processed into any one formulation for being adapted to agriculturally use.
5. Pesticidal combination according to claim 4, it is characterised in that the formulation of the pesticide combination is suspending agent, water
In emulsion, microemulsion, missible oil, wettable powder, microcapsule suspending agent, water dispersible granules, solvable pulvis, soluble granule any one.
6. the Pesticidal combination according to any one of Claims 1 to 5 claim is used to prevent and kill off the use of crop pests
On the way.
7. purposes according to claim 6, it is characterised in that the crop pests are preferably planthopper.
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| CN201610992691.7A CN106561666A (en) | 2016-11-11 | 2016-11-11 | Insecticidal composition containing flupyradifurone and cyclaniliprole |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN107125253A (en) * | 2017-06-16 | 2017-09-05 | 江苏天容集团股份有限公司 | Pesticidal combination containing fluorine pyrrole furanone and cartap |
| CN110024792A (en) * | 2019-05-21 | 2019-07-19 | 青岛东生药业有限公司 | Agricultural double-crossed Pesticidal combination and its application |
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| CN105454238A (en) * | 2015-11-20 | 2016-04-06 | 广东中迅农科股份有限公司 | Pesticide composition containing flupyradifurone and fluopyram |
| CN105901007A (en) * | 2016-06-08 | 2016-08-31 | 成都科利隆生化有限公司 | Pesticidal composition containing cyclaniliprole and chloropyridine |
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| CN105454238A (en) * | 2015-11-20 | 2016-04-06 | 广东中迅农科股份有限公司 | Pesticide composition containing flupyradifurone and fluopyram |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107125253A (en) * | 2017-06-16 | 2017-09-05 | 江苏天容集团股份有限公司 | Pesticidal combination containing fluorine pyrrole furanone and cartap |
| CN110024792A (en) * | 2019-05-21 | 2019-07-19 | 青岛东生药业有限公司 | Agricultural double-crossed Pesticidal combination and its application |
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