CN107125253A - Pesticidal combination containing fluorine pyrrole furanone and cartap - Google Patents
Pesticidal combination containing fluorine pyrrole furanone and cartap Download PDFInfo
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- CN107125253A CN107125253A CN201710454920.4A CN201710454920A CN107125253A CN 107125253 A CN107125253 A CN 107125253A CN 201710454920 A CN201710454920 A CN 201710454920A CN 107125253 A CN107125253 A CN 107125253A
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- Prior art keywords
- cartap
- fluorine pyrrole
- pyrrole furanone
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- furanone
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
- A01N47/12—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof containing a —O—CO—N< group, or a thio analogue thereof, neither directly attached to a ring nor the nitrogen atom being a member of a heterocyclic ring
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
- A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
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- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
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- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a kind of Pesticidal combination containing fluorine pyrrole furanone and cartap, said composition contains active component fluorine pyrrole furanone and cartap, and the wherein mass ratio of fluorine pyrrole furanone and cartap is 1：(1~50).The Pesticidal combination of the present invention is on the basis of original preventive effect is kept, also with synergistic effect；Insecticidal spectrum is not only expanded, and insect can be delayed to develop immunity to drugs medicament.The price of fluorine pyrrole furanone is far above cartap, and the present invention compounds cartap and a small amount of fluorine pyrrole furanone, and its insecticidal effect reduces production cost apparently higher than alone fluorine pyrrole furanone or cartap, alleviates the financial burden of peasant.
Description
Technical field
The invention belongs to pesticide field, and in particular to a kind of killing containing active component fluorine pyrrole furanone and cartap simultaneously
Worm composition.
Background technology
In recent years, science compounding is carried out with two or more insecticide, to expand insecticidal spectrum or improve anti-
Effect is controlled, is found broad application.As AVM and Cupric sulfate, imidacloprid and Cupric sulfate, chlopyrifos and Cupric sulfate, Buprofezin with
The agricultural chemicals of the compoundings such as Cupric sulfate is applied in agricultural production.
Paddy rice is China's staple food crop, and the snout moth's larva of rice and planthopper are the primary pests in Rice Cropping, wherein again
With rice leaf roller, striped rice borer and brown paddy plant hopper, white backed planthopper harm for very.
Rice leaf roller (Cnaphalocrocis medinalis Guenee) be China paddy rice producing region primary pest it
One, it is distributed widely in each rice region.It is caused harm paddy rice with larva, is sewed leaf into vertical bud, is hidden and wherein take food epicuticle and mesophyll, only stay
White lower epidermis.Seedling stage aggrieved influence paddy rice normal growth, in addition it is withered；Tillering stage to the jointing stage is aggrieved, and tiller is reduced, plant
Shorten, breeding time postpones；Particularly heading is killed to full heading time sword-like leave after booting, and influence is blossomed and beared fruit, and Empty grain rate is improved, thousand
Decline again.General underproduction 2-3 is into, weight up to more than 5 one-tenth, and big rice leaf when occurring is a piece of withered white, or even No kernels or seeds are gathered, as in a year of scarcity.
Rice leaf roller is a kind of migratory pest, and from north, 1~11 generation occurred for south-year；Rice leaf roller was from 2003
Since national break out occurs for China, higher level has been maintained always, year, occurring area was more than 300,000,000 mu times.Show as：Peak
Secondary increase, it is main to move peak increase；Occurrence scope expands, area increase；Field generations are overlapping serious, and harm time is long；The south of the River, the Changjiang river
Middle and lower reaches, southwest-northeast portion are retransmitted year after year.
Rice hoppers (rice planthopper) belong to Homoptera Delphacidae.Hazard rice mainly have brown paddy plant hopper, it is white
Three kinds of backward flight lice and small brown rice planthopper.It is brown paddy plant hopper and white backed planthopper that harm is heavier, early rice early stage based on white backed planthopper, the later stage with
Based on brown paddy plant hopper；Middle late rice is based on brown paddy plant hopper.
Planthopper is caused harm to paddy rice, except directly thorn inhales juice, makes growth retardation, and rice clump is agglomerating withered when serious, even
The complete dead stalk lodging in field is outer, and spawning can also stab plant, destroy conducting tissue, hinder nutriment transport and transmitted virus disease.
At present, preventing and treating the snout moth's larva of rice and plant hopper compounded pesticides various types, mainly have to planthopper prevention effect compared with
Formula of the good imidacloprid, Acetamiprid with preventing and treating the pesticide compositionals such as the preferable Cupric sulfate of snout moth's larva effect, Hostathion.
However, because the resistance of nicotinoids agricultural chemicals such as imidacloprid, Acetamiprid increases quickly, with the accumulation of use time,
Prevention effect constantly declines, and mu dosage is dramatically increased, and not only increases and controls worm cost, and has aggravated the influence to environment.
Particularly imidacloprid, Acetamiprid not only have resistance, but also the bee colony that pollen is propagated in nature are killed tight
Weight, therefore the propagation plant pollen of the bee colony in nature is reduced, the breeding chain of plant in nature is blocked, to life naturally
State diversity causes serious threat.Therefore can imidacloprid can be continuing with, and be produced in agricultural management department and agricultural chemicals administrative department
Heated argument is given birth to.EFSA (EFSA) issues a public proclamation title, will reset the nicotinoids such as imidacloprid, Acetamiprid
The toxicity criterion of agricultural chemicals.Canadian pest control management organization (PMRA) is by the ambient wind of nicotinic insecticide imidacloprid
Again evaluated danger.Environmental Protection Agency began to open to the progress review of nicotinic insecticide imidacloprid early in 2009.Bar
Western Environmental Protection Administration (IBAMA) will also reappraise nicotinic insecticide imidacloprid.
The content of the invention
The invention aims to overcome or delay insect to develop immunity to drugs, expand pest control spectrum, accomplish once
Dispenser, it is simultaneous to control various pests there is provided a kind of insecticidal spectrum extensively and with the significant Pesticidal combination of synergistic effect.
The purpose of the present invention can be reached by following measures：
A kind of Pesticidal combination containing fluorine pyrrole furanone and cartap, said composition contains active component fluorine pyrrole furanone
And cartap, the wherein mass ratio of fluorine pyrrole furanone and cartap is 1：1~50.
The proportioning of fluorine pyrrole furanone and cartap in the present composition can be according to specific situation of applying in zone of reasonableness
Inside it is adjusted, the weight ratio of both such as fluorine pyrrole furanone and cartap is 1：(1~50), 1：(2~45), 1：(2~40),
1：(2~35), 1：(2~30), 1：(2~25), 1：(2~20), 1：(2~15), 1：(2~10), 1：(5~50), 1：(5~
45)、1：(5~40), 1：(5~35), 1：(5~30), 1：(5~25), 1：(5~20), 1：(5~15), 1：(5~10), 1：
(10~40), 1：(10~30), 1：(10~20), 1：(20~30) etc..In some preferred schemes, the weight ratio of the two can be with
For 1：50、1：45、1：40、1：39、1：38、1：37、1：36、1：35、1：34、1：33、1：32、1：31、1：30、1：29、1：28、
1：27、1：26、1：25、1：24、1：23、1：22、1：21、1：20、1：19、1：18、1：17、1：16、1：15、1：14、1：13、1：
12、1：11、1：10、1：9、1：8、1：7、1：6、1：5、1：4、1：3、1：2、1：1 etc..
The mass content of active ingredient fluorine pyrrole furanone and cartap can be 5~90%, preferably 5 in the present composition
~80%, further preferred 20~80%, still more preferably 30~50%.
The composition of the present invention can be equipped with insecticides adjuvant, agriculture be made using fluorine pyrrole furanone and cartap as active component
Acceptable formulation on medicine, such as solvable pulvis, wettable powder, water dispersible granules, suspending agent, granule, aqua.
This Pesticidal combination containing fluorine pyrrole furanone and cartap can be applied to preventing and treating lepidoptera pest and perverse suction mouthful
Device insect is in terms of crop pests, being especially applicable to prevent and treat the harm aspect of the snout moth's larva of rice and plant hopper to crops.
Fluorine pyrrole furanone (flupyradifurone) is new butenolide class compound, with brand-new chemical constitution,
The mechanism of action is novel, low to honeybee toxicity, available for many crops, effectively prevents and treats main sucking pest, is that insect resists
Property administer important tool.Fluorine pyrrole furanone had both accomplished quick, efficient when preventing and treating sucking pest, and to environment friend
Good, toxicity is low.Especially fluorine pyrrole furanone overcomes the critical defect of the bionical insecticide of anabasine to honeybee safety, therefore,
Fluorine pyrrole furanone future market Worth Expecting.
Fluorine pyrrole furanone can be used for many crops, such as paddy rice, wheat, corn, sorghum, vegetables, fruit tree, coffee, cocoa
Crop, prevents and treats sucking pest such as plant hopper, aphid, aleyrodid, wood louse, leafhopper, scale insect, beetle, leaf mining with high selectivity
Fly, mealybug, soft a red-spotted lizard, diaphorina citri, weevil and thrips etc..It is all effective to all growth periods including larva and adult.
Formulation rate is：50~100g a.i./hm2.The insect effect for resisting anabasine insecticide is especially good, and to honeybee safety, and
Contribute to plant growth, improve crop quality.
Cartap (cartap) is the analog of artificial synthesized nereistoxin, into insect bodies in be quickly converted to clam worm
Toxin or Dihydronereistoxin element.The medicine is acetylcholine competitive inhibitor, with it is stronger tag, stomach toxicity and Uptake and translocation are made
With having good prevention effect to the larva of lepidoptera pest.Cartap belongs to biomimetic type agricultural chemicals, and small, non-resistant is influenceed on natural enemy,
It is free from environmental pollution without residual hazard, it is the comparatively ideal medicament of integrated pest management.The medicament can effectively prevent and treat paddy rice, vegetables, small
Various pests on the crops such as wheat, corn, tealeaves, fruit tree, particularly have to paddy rice rice leaf roller, striped rice borer, yellow rice borer etc.
Special efficacy.To aquatile low toxicity.
In summary, both medicaments are all safe and environment-friendly type agricultural chemicals, but two kinds of medicament lists of fluorine pyrrole furanone and cartap
Respectively there are advantage and disadvantage when solely using, such as cartap is good to lepidoptera pest such as striped rice borer, yellow rice borer, rice leaf roller effect, to rice
The perverse suction mouthpart insect effect such as plant hopper is poor, and fluorine pyrrole furanone to sucking pest as planthopper etc. show it is excellent
Prevention effect, but it is poor to lepidoptera pest prevention effect.
It is active ingredient, the different ratio stated according to the present invention, with this area using fluorine pyrrole furanone and cartap
Formulations of pesticide processing insecticides adjuvant known to interior technical staff, with formulations of pesticide processing side known to a person skilled in the art
Method, can be processed into the various formulations of pesticide.
The Pesticidal combination containing fluorine pyrrole furanone and cartap of the present invention has the advantage that to be with beneficial effect：1、
Insecticidal range is expanded, accomplishes a dispenser, various pests are simultaneous to be controlled；2nd, the lasting period is long, and resistance increases slow；3rd, low toxicity, low-residual,
It is environmentally safe；4th, using compound formulation, reduced when the consumption of two kinds of insecticides is than single use, so as to improve desinsection effect
Really, security is added, environmental pollution is reduced.
Embodiment
Below by specific embodiment detailed description come the present invention is furture elucidated, but be not to the present invention limit
System, is only illustrated.
Embodiment 1：Fluorine pyrrole furanone is determined with cartap different ratio to the co-toxicity coefficient of paddy rice rice leaf roller
In order to confirm fluorine pyrrole furanone and cartap mixture, be with synergistic effect, summation action or antagonism, I
Recipe determination research has been carried out to fluorine pyrrole furanone and cartap first, the object of indoor biometricses is set to and given birth in China paddy rice
The striped rice borer of most serious is endangered in production, specific measure situation and result are as follows：
The data provided according to agriculture chemical examination institution of the Ministry of Agriculture, the recommended dose of fluorine pyrrole furanone preventing and treating planthopper is 5-
7 grams of effective ingredient/mus, it is 45-54 grams of effective ingredient/mu that cartap, which prevents and treats the recommended dose of paddy rice rice leaf roller, as
Foundation, experimental design proportioning is 1: 1,1: 2,1: 5,1: 10,1: 20,1: 30,1: 40,1: 50, and totally 8 processing, separately set fluorine pyrrole furan
Ketone, two single doses of cartap of muttering are handled.
Test medication and use 95% fluorine pyrrole furanone active compound and 95% cartap active compound, dissolved active compound using solvent, root
According to the matched proportion density of setting, concentration liquid needed for being configured to is standby.
Indoor biometricses method is：Using capillary micro intravenous drip method, capillary micro intravenous drip device volume is 1.0 μ L.With micro-
Measure dropper by decoction by head drop in the back side of the instar larvae of rice leaf roller 3, each concentration handles the larva of 30 or so, often
5 larvas are put into a diameter of 9cm culture dish, and a small amount of feed built in ware is another to be made with 30 larvas of acetone drop for taking food
For control.Larva after processing is still placed in receptacle, and the death rate is checked after 48h.Data are handled with SPSS software statistics.Ask
Go out toxicity regression formula, the lethal concentration of 50, coefficient correlation etc., and co-toxicity coefficient is obtained with the abundant methods of Sun Yun.
The co-toxicity of mixture preparation is represented using Sun Yunpei co-toxicity coefficient method：
Theoretical toxicity index TTI=Σ (medicine effective ingredients of the toxicity index ATI of certain medicine × in mixture of mixture preparation
Percentage).
Synergistic effect criterion after two kinds of effective ingredient compoundings：
It is synergistic effect when CTC is more than 120, is antagonism during less than 80, is addition when 80~120.
It is 92.86 μ g/mL to the lethal concentration of 50 of rice leaf roller that experiment, which determines fluorine pyrrole furanone, and cartap is vertical to rice
The lethal concentration of 50 of leaf roll snout moth's larva is 29.36 μ g/mL.Fluorine pyrrole furanone is set to the toxicity index of rice leaf roller as 100, then is killed
The red toxicity index to rice leaf roller of snout moth's larva is 316.28.The toxicity index of variant proportioning processing rice leaf roller, altogether poison system
Number is shown in Table 1.
Table 1：The toxicity test result of fluorine pyrrole furanone, cartap different ratio to rice leaf roller
Above-mentioned data result is analyzed to show, when fluorine pyrrole furanone is compounded with cartap by above-mentioned different proportion, the compounding
Formula is 1:2-1:Co-toxicity coefficient when 40 is all higher than 120, shows to be respectively provided with synergistic effect.Illustrate two kinds of effective part compoundings
Afterwards, there can be preferable synergistic effect.When the ratio of fluorine pyrrole furanone and cartap is 1: 10,1：When 20, co-toxicity coefficient reaches
More than 200, wherein the ratio of fluorine pyrrole furanone and cartap be 1: 10 when, co-toxicity coefficient reaches 218, in all formulas most
Height, synergistic effect is the most notable.
Embodiment 2：Fluorine pyrrole furanone is determined with cartap different ratio to the co-toxicity coefficient of rice hoppers
In order to confirm that fluorine pyrrole furanone, to perverse suction mouthpart insect, is with synergistic effect, is added and makees with cartap mixture
With still antagonism, we with above fluorine pyrrole furanone and 8 formulas of cartap mixture, are carried out to rice hoppers again
Toxicity Determination.From rice hoppers 3 age nymph, assay method uses infusion process.
Test worm is put into the funnel rolled well with filter paper, taken with liquid-transfering gun as above decoction 3mL in funnel, test worm is existed
In decoction keep 30 seconds, be put in after taking-up on filter paper and suck unnecessary decoction, by test worm be transferred to glass support scolite (diameter 1.8cm,
High 8cm) in be put into the wet soil and fresh rice leaf of appropriate water content (about 18%), plug is to prevent the worm from escaping beyond the Great Wall
Ease.Test worm death condition is investigated after 5 days, death standard is that those of skill in the art touch polypide with writing brush, motionless, or can not be normal
The person of creeping is calculated as death.
It is 9.38 μ g/mL to the lethal concentration of 50 of planthopper that experiment, which determines fluorine pyrrole furanone, and cartap is to planthopper
The lethal concentration of 50 is 55.83 μ g/mL, sets fluorine pyrrole furanone to the toxicity index of planthopper as 100, then cartap is to planthopper
Toxicity index be 17.42.Variant proportioning processing is shown in Table 2 to the toxicity index of planthopper, co-toxicity coefficient：
Table 2：The Toxicity Determination result of fluorine pyrrole furanone, cartap different ratio to rice hoppers
From table 2 it can be seen that fluorine pyrrole furanone and cartap mixture 1:2-1:Have to rice hoppers 3 age nymph when 40
Synergistic effect.When wherein fluorine pyrrole furanone and cartap weight ratio are 1: 20, co-toxicity coefficient reaches 212.55, and synergistic effect is the most
Significantly.
The toxicity test result data of the table of summary two, fluorine pyrrole furanone and cartap different proportion mixture, when both
When ratio is 1: 2 to 1: 40, synergistic effect is respectively provided with to paddy rice rice leaf roller and planthopper, wherein 1：10、1：20 proportioning
Synergistic effect it is the most notable.The present invention is not merely to reduce Pesticide use amount, it is often more important that expands insecticidal spectrum, accomplishes
Dispenser, various pests are simultaneous to be controlled, and saves agriculture sheet, mitigates the labor intensity of peasant.
For this, we have carried out trial-manufacture of sample from following proportioning, and have carried out the test of pesticide effectiveness.
Below with specific example of formulations to be further described the present invention, but the present invention be only limited to absolutely not it is following
These embodiments.Percentage is weight percentage in formula.
Embodiment 3：40% fluorine pyrrole furanone cartap wettable powder
Embodiment 4：The 50% solvable pulvis of fluorine pyrrole furanone cartap
Embodiment 5：80% fluorine pyrrole furanone cartap water dispersible granules
Embodiment 6：5% fluorine pyrrole furanone cartap granular preparation
Embodiment 7：20% fluorine pyrrole furanone cartap aqua
Embodiment 8：30% fluorine pyrrole furanone cartap suspending agent
By six embodiments more than made from fluorine pyrrole furanone and the various different ratios of cartap, carry out preventing and treating paddy rice rice and indulge
Leaf roll snout moth's larva and the field control effectiveness test of planthopper, while by solvable with 17% fluorine pyrrole furanone soluble concentrate, 50% cartap
Synergistic effect after the Contrast on effect of pulvis, checking compounding.Test site is Nanjing, and the time is September 3 in 2016
Day, experiment totally eight processing, each three repetitions of processing, cell random alignment, plot area 9*5m2, the plantation of all cells
Custom is identical with local planting habit.
Investigation standard is：By 5 point samplings, random 5 points of samplings per cell, every is investigated 5 clumps, totally 25 clumps.In before dispenser
With the 1st after dispenser, the quantity of 7,15 days rice leaf roller larvaes for investigating the 25 clumps of paddy rice respectively and planthopper nymph, carry out in detail
Record, calculates prevention effect.Specific data (data are the average value of three repetitions) are shown in Table 3.
Table 3：Fluorine pyrrole furanone, cartap single dose and complex preparation are to paddy rice rice leaf roller, the field medicine of planthopper
Imitate result of the test
As can be seen from the above data, after fluorine pyrrole furanone and cartap different ratio are compounded, effective using identical
, will be apparently higher than two kinds of single doses, all formulas to the integrated control effect of paddy rice rice leaf roller and planthopper under doses
There is obvious synergistic effect.When cartap content is high in formula, the prevention effect to rice leaf roller is preferable, to planthopper
Prevention effect it is more relatively poor, when fluorine pyrrole furanone content is high in formula, the prevention effect to rice leaf roller slightly has
Decline, but it is preferable to the prevention effect of planthopper.This result also truly reflects the characteristic of the two medicaments.From upper table data
Find out, the preventive effect that complex preparation preventive effect of 7 days after medicine is higher than 15 days after the preventive effect of 1 day after medicine, medicine is slightly below after medicine 7 days
Preventive effect.Compared with single dose, the preventive effect of complex preparation is improved.In summary, complex preparation expands insecticidal spectrum, extends and holds
The effect phase, times for spraying is reduced, save recruitment, alleviated peasant's labor intensity, reduce dosage, reduce peasant's medication
Cost.
Claims (10)
1. a kind of Pesticidal combination containing fluorine pyrrole furanone and cartap, it is characterised in that said composition contains active component fluorine
Pyrrole furanone and cartap, the wherein mass ratio of fluorine pyrrole furanone and cartap are 1：(1~50).
2. composition according to claim 1, it is characterised in that the quality of fluorine pyrrole furanone and cartap in said composition
Than for 1：(2~40).
3. composition according to claim 2, it is characterised in that the quality of fluorine pyrrole furanone and cartap in said composition
Than for 1：(5~30).
4. composition according to claim 3, it is characterised in that the quality of fluorine pyrrole furanone and cartap in said composition
Than for 1：(10~20).
5. composition according to claim 1, it is characterised in that active component fluorine pyrrole furanone and kill snout moth's larva in said composition
Red mass content is 5~90%.
6. composition according to claim 5, it is characterised in that active component fluorine pyrrole furanone and kill snout moth's larva in said composition
Red mass content is 5~80%.
7. composition according to claim 1, it is characterised in that said composition is using fluorine pyrrole furanone and cartap as activity
Composition, is equipped with insecticides adjuvant, and acceptable formulation on agricultural chemicals is made.
8. composition according to claim 7, it is characterised in that the formulation is selected from solvable pulvis, wettable powder, water
Dispersible granule, suspending agent, granule or aqua.
9. the composition described in claim 1 is in terms of preventing and treating lepidoptera pest and perverse suction mouthpart insect are to crop pests
Using.
10. the composition described in claim 1 is in the preventing and treating snout moth's larva of rice and plant hopper to the application in terms of murrain.
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Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101466705A (en) * | 2006-03-31 | 2009-06-24 | 拜尔农作物科学股份公司 | Substituted enaminocarbonyl compounds |
| CN106342843A (en) * | 2016-08-27 | 2017-01-25 | 深圳诺普信农化股份有限公司 | Insecticide composition containing haloxyfop furanone |
| CN106561666A (en) * | 2016-11-11 | 2017-04-19 | 佛山市盈辉作物科学有限公司 | Insecticidal composition containing flupyradifurone and cyclaniliprole |
-
2017
- 2017-06-16 CN CN201710454920.4A patent/CN107125253A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101466705A (en) * | 2006-03-31 | 2009-06-24 | 拜尔农作物科学股份公司 | Substituted enaminocarbonyl compounds |
| CN106342843A (en) * | 2016-08-27 | 2017-01-25 | 深圳诺普信农化股份有限公司 | Insecticide composition containing haloxyfop furanone |
| CN106561666A (en) * | 2016-11-11 | 2017-04-19 | 佛山市盈辉作物科学有限公司 | Insecticidal composition containing flupyradifurone and cyclaniliprole |
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