CN107156152A - Pesticidal combination containing trifluoro-benzene pyrimidine and bensultap - Google Patents

Pesticidal combination containing trifluoro-benzene pyrimidine and bensultap Download PDF

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CN107156152A
CN107156152A CN201710479388.1A CN201710479388A CN107156152A CN 107156152 A CN107156152 A CN 107156152A CN 201710479388 A CN201710479388 A CN 201710479388A CN 107156152 A CN107156152 A CN 107156152A
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bensultap
trifluoro
benzene pyrimidine
composition
pyrimidine
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许网保
虞国新
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JIANGSU TIANRONG GROUP CO Ltd
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JIANGSU TIANRONG GROUP CO Ltd
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    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/90Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N41/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom
    • A01N41/02Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom containing a sulfur-to-oxygen double bond
    • A01N41/04Sulfonic acids; Derivatives thereof
    • A01N41/08Sulfonic acid halides; alpha-Hydroxy-sulfonic acids; Amino-sulfonic acids; Thiosulfonic acids; Derivatives thereof

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  • Life Sciences & Earth Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The invention discloses a kind of Pesticidal combination containing trifluoro-benzene pyrimidine and bensultap, said composition contains active component trifluoro-benzene pyrimidine and bensultap, and the wherein mass ratio of trifluoro-benzene pyrimidine and bensultap is 1:1~100.The Pesticidal combination of the present invention not only expands insecticidal spectrum on the basis of original preventive effect is kept, and can delay insect generation drug-fast to medicament, also with synergistic effect.The price of trifluoro-benzene pyrimidine is far above bensultap, and the present invention compounds bensultap and a small amount of trifluoro-benzene pyrimidine, and its insecticidal effect reduces production cost apparently higher than alone trifluoro-benzene pyrimidine or bensultap, alleviates the financial burden of peasant.

Description

Pesticidal combination containing trifluoro-benzene pyrimidine and bensultap
Technical field
The invention belongs to pesticide field, and in particular to a kind of Insecticidal combinations containing trifluoro-benzene pyrimidine and bensultap simultaneously Thing.
Background technology
In recent years, science compounding is carried out with two or more insecticide, to expand insecticidal spectrum or improve anti- Effect is controlled, is found broad application.As emamectin-benzoate and Cupric sulfate, imidacloprid and Cupric sulfate, chlopyrifos with The agricultural chemicals of the compoundings such as dimehypo, Methomyl and dimehypo is applied in agricultural production.
Paddy rice is China's staple food crop, and the snout moth's larva of rice and plant hopper are the primary pests in Rice Cropping, wherein and with Striped rice borer and brown paddy plant hopper, white backed planthopper harm is very.
Striped rice borer Chilo suppressalis (Walker) are that Occurrence the most serious is endangered on China paddy rice One of, tillering stage it is aggrieved cause withered sheath, withered heart seedling, ear period it is aggrieved cause insect bite strain and dead ears, the general time underproduction 8%~ 10%, the underproduction is more than 3 one-tenth when serious.Domestic each rice region is distributed, wide compared with yellow rice borer and pink rice borer distribution but main with the Changjiang river Basin and on the south rice region occur heavier, it is in the situation that substantially rises that quantity occurs in recent years.Striped rice borer is in addition to hazard rice, moreover it is possible to Endanger the weeds such as crop and reed, barnyard grass, Leersia Sw such as wild rice stem, corn, sorghum, sugarcane, rape, broad bean, wheat class.
Striped rice borer is not only the important pests in China's Rice Production, and paddy fields distribution is also very wide abroad, for example, The harm of the striped rice borer such as Korea, Japan, Philippine, Vietnam, Thailand, Malaya, Indonesia, India, Egypt is also very tight Weight.
Rice hoppers (rice planthopper) belong to Homoptera Delphacidae.Hazard rice mainly have brown paddy plant hopper, it is white Three kinds of backward flight lice and small brown rice planthopper.It is brown paddy plant hopper and white backed planthopper that harm is heavier, early rice early stage based on white backed planthopper, the later stage with Based on brown paddy plant hopper;Middle late rice is based on brown paddy plant hopper.
Planthopper is caused harm to paddy rice, except directly thorn inhales juice, makes growth retardation, and rice clump is agglomerating withered when serious, even The complete dead stalk lodging in field, spawning can also stab plant, destroy conducting tissue, hinder nutriment transport and transmitted virus disease.
At present, the compounded pesticides of the preventing and treating snout moth's larva of rice and plant hopper mainly have to the preferable imidacloprid of planthopper prevention effect Formula with preventing and treating the pesticide compositionals such as the preferable Cupric sulfate of snout moth's larva effect, Hostathion.
However, because the resistance of imidacloprid increases quickly, with the accumulation of access times, prevention effect constantly declines, mu Dosage is dramatically increased, and not only increases agriculture production cost, and increase the influence to environment.
Particularly imidacloprid not only has resistance, but also seriously, therefore the bee colony that pollen is propagated in nature is killed The bee colony reduced in nature propagates plant pollen, has blocked the breeding chain of plant in nature, various to natural, ecological Property cause serious threat.Therefore can imidacloprid can be continuing with, and be generated in agricultural management department and pesticide producing department sharp Strong arguement.EFSA (EFSA) issues a public proclamation title, will reset the nicotinoids agricultural chemicals such as imidacloprid, Acetamiprid Toxicity criterion.Canadian pest control management organization (PMRA) will be carried out to the environmental risk of nicotinic insecticide imidacloprid Again evaluate.Environmental Protection Agency began to open to the progress review of nicotinic insecticide imidacloprid early in 2009.Brazilian environmental protection Administration (IBAMA) will also reappraise toxicity of the nicotinic insecticide imidacloprid to environmental organism.
Trifluoro-benzene pyrimidine is new mesoionic class or amphion insecticides, is also new pyrimidine ketone compounds, tool Have efficiently, holding effect, dosage is low, the features such as environmentally friendly, mainly prevent and treat water rice hopper, leafhopper etc..It is killed with anabasine Worm agent has the different mechanisms of action, is that insect pollinator is had no adverse effect the characteristics of maximum, can overcome the nicotine such as imidacloprid Critical defect of the insecticides to insect pollinator severe toxicity.Trifluoro-benzene pyrimidine wide spectrum, efficient, holding effect are more to Lepidoptera, Homoptera etc. Plant insect and be respectively provided with good preventive effect, available for cotton, paddy rice, corn and Soybean and Other Crops, particularly prevent and treat Brown Planthopper (Nilaparvata lugens) has special efficacy.
Trifluoro-benzene pyrimidine belongs to ultra high efficiency insecticide, prevents and treats rice hoppers, and spraying is used, and active ingredient dosage is only 15 ~22.5 grams/ha (i.e. 1~1.5 gram/acre).And the insecticide toxicity is extremely low, to mammal acute oral, percutaneously belong to Micro- malicious level, to environmental organism safety, has no adverse effect to insect pollinator.
Bensultap, English name is:bensultap.It is the high-end kind of nereistoxin and similar bionic pesticide, is that selectivity is killed Worm agent, every mu with 40 grams of active ingredient, you can effectively prevents and kill off rice grub.Its mechanism of action is that bensultap intrusion insect is neural The joint portion of cell, blocks the acetylcholine secreted by previous nerve cell and conveys to latter nerve cell, so that nerve is thin The disconnected contact of the embarrassment of fetus, makes insect neural paralysis, it is impossible to nibble food, it is impossible to take action, stops development, so that dead.Bensultap have stomach toxicity, Action of contace poison, can conduct after being absorbed by plants to apical meristem, insect chew suck after poisoning and it is dead.Suitable for paddy rice, jade The crops such as rice, veterinary antibiotics, are mainly used in preventing and treating Lepidoptera and coleopteran pest, such as striped rice borer, yellow rice borer, rice leaf roller, Corn borer, chilo infuscatellus, European red mite, pear leaf worm, citrus leaf-miner, colorado potato bug, cabbage caterpillar, diamondback moth etc., holding effect Phase is 7~14 days.Bensultap is nontoxic to natural enemies such as spiders to birds low toxicity, small to environmental organism lethality.
In summary, both medicaments are all safe efficient, eco-friendly pesticides.But respectively have excellent during both exclusive uses Shortcoming, such as bensultap are good to lepidoptera pest such as striped rice borer, yellow rice borer, rice leaf roller effect, suction mouthful perverse to planthopper etc. Device insect effect is poor, and trifluoro-benzene pyrimidine shows excellent prevention effect to sucking pest such as planthopper etc., but right Lepidoptera pest is substantially invalid.
The content of the invention
The invention aims to overcome or delay insect to develop immunity to drugs there is provided a kind of insecticidal spectrum extensively and with synergy Significant Pesticidal combination is acted on, to expand pest control spectrum, accomplishes a dispenser, it is simultaneous to control various pests.
The purpose of the present invention can be reached by following measures:
A kind of Pesticidal combination containing trifluoro-benzene pyrimidine and bensultap, said composition contains active ingredient trifluoro-benzene pyrimidine And bensultap, the wherein mass ratio of trifluoro-benzene pyrimidine and bensultap is 1:1~100.
The proportioning of trifluoro-benzene pyrimidine and bensultap in the present composition can be according to specific situation of applying in zone of reasonableness Inside it is adjusted, the weight ratio of both such as trifluoro-benzene pyrimidine and bensultap is 1:1~100,1:1~95,1:1~90,1:1~ 85、1:1~80,1:1~75,1:1~70,1:1~65,1:1~60,1:1~55,1:1~50,1:1~45,1:1~40,1: 1~35,1:1~30,1:1~25,1:1~20,1:1~15,1:1~10,1:2~100,1:2~95,1:2~90,1:2~ 85、1:2~80,1:2~75,1:2~70,1:2~65,1:2~60,1:2~55,1:2~50,1:2~45,1:2~40,1: 2~35,1:2~30,1:2~25,1:2~20,1:2~15,1:2~10,1:5~95,1:5~90,1:5~85,1:5~ 80、1:5~75,1:5~70,1:5~65,1:5~60,1:5~55,1:5~50,1:5~45,1:5~40,1:5~35,1: 5~30,1:5~25,1:5~20,1:5~15,1:5~10,1:10~80,1:10~70,1:10~60,1:10~40,1: 10~30,1:20~60,1:20~50, etc..In some preferred schemes, the weight ratio of the two can be 1:100、1:95、1: 90、1:85、1:80、1:75、1:70、1:65、1:60、1:55、1:50、1:45、1:40、1:39、1:38、1:37、1:36、1: 35、1:34、1:33、1:32、1:31、1:30、1:29、1:28、1:27、1:26、1:25、1:24、1:23、1:22、1:21、1: 20、1:19、1:18、1:17、1:16、1:15、1:14、1:13、1:12、1:11、1:10、1:9、1:8、1:7、1:6、1:5、1:4、 1:3、1:2、1:1、2:1、1:1 etc..
The mass content of active ingredient trifluoro-benzene pyrimidine and bensultap can be 1~99%, preferably 5 in the present composition ~90%, further preferred 5~80%.
The composition of the present invention can be equipped with insecticides adjuvant, with this area using trifluoro-benzene pyrimidine and bensultap as active component Method known to interior technical staff, is made acceptable formulation on agricultural chemicals, including wettable powder, solvable pulvis, water-dispersible grain Agent, granule, suspending agent, oil-suspending agent, suspension emulsion, aqueous emulsion, microemulsion, finish or missible oil, preferably solvable pulvis, can WP, water dispersible granules, granule, aqueous emulsion, suspending agent etc..
This Pesticidal combination containing trifluoro-benzene pyrimidine and bensultap can be applied to preventing and treating lepidoptera pest or perverse suction mouthful Device insect is in terms of murrain, being especially applicable to preventing and treating striped rice borer and planthopper in terms of murrain.
The Pesticidal combination containing trifluoro-benzene pyrimidine and bensultap of the present invention has the advantage that to be with beneficial effect:1、 Insecticidal range is expanded, accomplishes a dispenser, rice terrace snout moth's larva, plant hopper are simultaneous to be controlled;2nd, two kinds of trifluoro-benzene pyrimidine and bensultap are killed Worm agent mixture is used, with obvious synergistic effect, is reduced when the consumption of two kinds of insecticides is than single use, and drug effect is carried Height, reduces cost accounting, alleviates environmental pollution.3rd, it will be used after trifluoro-benzene pyrimidine and bensultap mixture, lasting period extension, Security is good, to crop without poisoning.
Embodiment
Below by specific embodiment detailed description come the present invention is furture elucidated, but be not to the present invention limit System, is only illustrated.
Embodiment 1:Trifluoro-benzene pyrimidine is determined with bensultap different ratio to the co-toxicity coefficient of rice-stem borer
In order to confirm trifluoro-benzene pyrimidine and bensultap mixture, be with synergistic effect, summation action or antagonism, I Recipe determination research has been carried out to trifluoro-benzene pyrimidine and bensultap first, the object of indoor biometricses is set to and given birth in China paddy rice The striped rice borer of most serious is endangered in production, specific measure situation and result are as follows:
Reported according to data, the recommended dose of trifluoro-benzene pyrimidine preventing and treating planthopper is 1-1.5 grams of active ingredient/mu, desinsection The recommended dose of sulphur preventing and treating rice-stem borer is 40 grams of effective ingredient/mus, on this basis, and experimental design proportioning is 1: 1,1: 2, 1: 5,1: 10,1: 20,1: 30,1: 40,1: 50,1: 60,1: 70,1: 80,1: 90,1: 100 totally 13 processing, separately set trifluoro-benzene phonetic Pyridine, two single dose processing of bensultap.
Test medication and use trifluoro-benzene pyrimidine active compound and bensultap active compound, dissolved active compound using acetone, according to setting Matched proportion density, concentration liquid needed for being configured to is standby.
The method of indoor biometricses is:Using capillary micro intravenous drip method.With micro intravenous drip device by decoction by head drop in two Change the back side of the instar larvae of snout moth's larva 3, each concentration handles the larva of 30 or so, and every 5 larvas are put into a diameter of 9cm culture Ware, a small amount of feed is another to be used as control with acetone 30 larvas of drop for taking food built in ware.Larva after processing is still placed on raising The death rate is checked after interior, 48h.Data are handled with SPSS software statistics.Obtain toxicity regression formula, the lethal concentration of 50, phase relation Number etc., and obtain co-toxicity coefficient with the abundant methods of Sun Yun.
The co-toxicity of mixture preparation is represented using Sun Yunpei co-toxicity coefficient method:
Theoretical toxicity index TTI=Σ (medicine effective ingredients of the toxicity index ATI of certain medicine × in mixture of mixture preparation Percentage).
Synergistic effect criterion after two kinds of effective ingredient compoundings:
It is synergistic effect when CTC is more than 120, is antagonism during less than 80, is addition when 80~120.
It is 5.84 μ g/mL to the lethal concentration of 50 of striped rice borer that experiment, which determines bensultap, and setting bensultap is to striped rice borer Toxicity index is 100.Respectively handle toxicity index, the co-toxicity coefficient such as table 1 below to striped rice borer:
The trifluoro-benzene pyrimidine of table 1 and toxicity test result of the bensultap different ratio to striped rice borer
Above-mentioned data result is analyzed to show, when trifluoro-benzene pyrimidine is compounded with bensultap by above-mentioned different proportion, all compoundings The co-toxicity coefficient of formula is all higher than 100, shows to be respectively provided with addition.When both are formulated 1: 2~1: 90, co-toxicity coefficient is equal More than 120, illustrate after both the above active ingredient is compounded, there can be preferable synergistic effect to the virulence of striped rice borer.With The increase of bensultap in proportioning, synergistic effect is in notable ascendant trend.When the ratio of trifluoro-benzene pyrimidine and bensultap is 1: 30, Co-toxicity coefficient reaches 238.36, and for highest in all formulas, synergistic effect is the most notable.
Embodiment 2:Trifluoro-benzene pyrimidine is determined with bensultap different ratio to the co-toxicity coefficient of rice hoppers
In order to confirm that trifluoro-benzene pyrimidine and bensultap mixture are with synergistic effect, addition to perverse suction mouthpart insect Or antagonism, we with above trifluoro-benzene pyrimidine and 13 formulas of bensultap mixture, are carried out to rice hoppers again Toxicity Determination.From rice hoppers 3 age nymph, assay method uses infusion process.
Test worm is put into the funnel rolled well with filter paper, taken with liquid-transfering gun as above decoction 3mL in funnel, test worm is existed In decoction keep 30 seconds, be put in after taking-up on filter paper and suck unnecessary decoction, by test worm be transferred to glass support scolite (diameter 1.8cm, High 8cm) in be put into the wet soil and fresh rice leaf of appropriate water content (about 18%), plug is to prevent the worm from escaping beyond the Great Wall Ease, investigates test worm death condition, death standard is that those of skill in the art touch polypide with writing brush, motionless, or can not be normal after 5 days The person of creeping is calculated as death.
It is 4.68 μ g/mL to the lethal concentration of 50 of planthopper that experiment, which determines trifluoro-benzene pyrimidine, sets trifluoro-benzene pyrimidine pair The toxicity index of planthopper is 100.Respectively handle toxicity index, the co-toxicity coefficient such as table 2 below to planthopper:
Table 2, the Toxicity Determination result of trifluoro-benzene pyrimidine, bensultap different ratio to rice hoppers
From table 2 it can be seen that when trifluoro-benzene pyrimidine and bensultap are compounded by above-mentioned different proportion, all compounded formulas Co-toxicity coefficient is all higher than 120, and display has synergistic effect.It is malicious altogether when wherein trifluoro-benzene pyrimidine and bensultap weight ratio are 1: 30 Coefficient reaches 238.90, and synergistic effect is the most notable.
The toxicity test result data of the table of summary two, trifluoro-benzene pyrimidine and bensultap mixture in varing proportions, when two When person's ratio is 1: 2 to 1: 90, synergistic effect is respectively provided with to rice-stem borer and planthopper, the present invention is not merely to reduce Pesticide use amount, it is often more important that expand insecticidal spectrum, accomplish a dispenser, various pests are simultaneous to be controlled, saves agriculture sheet, mitigates peasant's Labor intensity.
For this, we have carried out trial-manufacture of sample from following proportioning, and have carried out field control effectiveness test.
Below with specific embodiment to be further described the present invention, but the present invention be only limited to absolutely not it is following these Embodiment.Percentage is weight percentage in formula.
Embodiment 3:50% trifluoro-benzene pyrimidine bensultap wettable powder
By above active ingredient trifluoro-benzene pyrimidine, bensultap and various insecticides adjuvants, according to the normal of pesticide wettable Advise processing method and carry out formulation, obtain 50% trifluoro-benzene pyrimidine bensultap wettable powder.
Embodiment 4:40% trifluoro-benzene pyrimidine bensultap aqueous emulsion
By above active ingredient trifluoro-benzene pyrimidine and bensultap and various insecticides adjuvants, add according to the routine of pesticide emulsion in water Work method carries out formulation, obtains 40% trifluoro-benzene pyrimidine bensultap aqueous emulsion.
Embodiment 5:80% trifluoro-benzene pyrimidine bensultap water dispersible granules:
By above active ingredient trifluoro-benzene pyrimidine and bensultap and various insecticides adjuvants, according to adding for pesticide water dispersible granules Work method carries out formulation, obtains 80% trifluoro-benzene pyrimidine bensultap water dispersible granules.
Embodiment 6:30% trifluoro-benzene pyrimidine bensultap suspending agent:
By above active ingredient trifluoro-benzene pyrimidine and bensultap and various insecticides adjuvants, add according to the routine of agricultural chemicals suspension agent Work method carries out formulation, obtains 30% trifluoro-benzene pyrimidine bensultap suspending agent.
Embodiment 7:The 50% solvable pulvis of trifluoro-benzene pyrimidine bensultap
By above active ingredient trifluoro-benzene pyrimidine and bensultap and various insecticides adjuvants, according to the routine of pesticide soluble pulvis Processing method carries out formulation, obtains the 50% solvable pulvis of trifluoro-benzene pyrimidine bensultap.
Embodiment 8:5% trifluoro-benzene pyrimidine bensultap granule
By above active ingredient trifluoro-benzene pyrimidine and bensultap and various insecticides adjuvants, add according to the routine of granular pesticide Work method carries out formulation, obtains 5% trifluoro-benzene pyrimidine bensultap granule.
Trifluoro-benzene pyrimidine bensultap composition pesticide of the present invention, the formulations of pesticide that can be processed into are included but not limited 6 kinds of formulations more than.
By 6 embodiments of the above made from trifluoro-benzene pyrimidine and the various different ratios of bensultap, carry out preventing and treating paddy rice two and change Snout moth's larva and the field control effectiveness test of planthopper, at the same by with 10% trifluoro-benzene pyrimidine suspending agent, the solvable pulvis of 50% bensultap Synergistic effect after Contrast on effect, checking compounding.Test site is Jiangsu Province Xiangshui County, and the time is August in 2016 20,
Experiment totally 8 processing, each three repetitions of processing, cell random alignment, plot area 9*5m2, all cells Planting habit is identical with local planting habit.
Investigation standard is:By 5 point samplings, random 5 points of samplings per cell, every is investigated 5 clumps, totally 25 clumps.In before dispenser With the 1st after dispenser, the quantity of 7,15 days Chilo spp larvaes for investigating the 25 clumps of paddy rice respectively and planthopper adult, carry out detailed note Record, calculates prevention effect.Specific data (data are the average value of three repetitions) are as follows:
Table 3:Trifluoro-benzene pyrimidine, bensultap single dose and complex preparation are to rice-stem borer, planthopper test of pesticide effectiveness result
As can be seen from the above data, used after trifluoro-benzene pyrimidine and the use of bensultap single dose and different ratio compounding, its Being used after compounding will have bright to the integrated control effect of rice-stem borer and planthopper apparently higher than two kinds of single doses, all formulas Aobvious synergistic effect.When bensultap content is high in formula, the prevention effect to striped rice borer is preferable, to the prevention effect of planthopper More relatively poor, when trifluoro-benzene pyrimidine content is high in formula, the prevention effect to striped rice borer is declined slightly, but to planthopper Prevention effect it is preferable.This result also truly reflects the characteristic of the two medicaments.Find out that complex preparation exists from upper table data The preventive effect of 7 days is higher than the preventive effect that the preventive effect of 15 days after the preventive effect of 1 day after medicine, medicine is slightly less than 7 days after medicine after medicine.With single dose phase Than complex preparation reduces the consumption of pesticide activity composition, saves drug cost, alleviates environmental pollution;System is compounded simultaneously Agent extends the lasting period, reduces times for spraying, save recruitment in use, expand insecticidal spectrum, alleviates peasant's work strong Degree.

Claims (10)

1. a kind of Pesticidal combination containing trifluoro-benzene pyrimidine and bensultap, it is characterised in that said composition contains active component three Fluorobenzene pyrimidine and bensultap, the wherein mass ratio of trifluoro-benzene pyrimidine and bensultap are 1:1~100.
2. composition according to claim 1, it is characterised in that the quality of trifluoro-benzene pyrimidine and bensultap in said composition Than for 1:2~90.
3. composition according to claim 2, it is characterised in that the quality of trifluoro-benzene pyrimidine and bensultap in said composition Than for 1::5~80.
4. composition according to claim 3, it is characterised in that the quality of trifluoro-benzene pyrimidine and bensultap in said composition Than for 1:10~70.
5. composition according to claim 1, it is characterised in that active component trifluoro-benzene pyrimidine and desinsection in said composition The mass content of sulphur is 1~99%.
6. composition according to claim 5, it is characterised in that active component trifluoro-benzene pyrimidine and desinsection in said composition The mass content of sulphur is 5~80%.
7. composition according to claim 1, it is characterised in that said composition is using trifluoro-benzene pyrimidine and bensultap as activity Composition, is equipped with insecticides adjuvant, and acceptable formulation on agricultural chemicals is made.
8. composition according to claim 7, it is characterised in that the formulation is selected from wettable powder, solvable pulvis, water Dispersible granule, granule, suspending agent, oil-suspending agent, suspension emulsion, aqueous emulsion, microemulsion, finish or missible oil.
9. the composition described in claim 1 is in terms of preventing and treating lepidoptera pest and perverse suction mouthpart insect are to murrain Using.
10. the composition described in claim 1 is in preventing and treating striped rice borer and planthopper to the application in terms of murrain.
CN201710479388.1A 2017-06-22 2017-06-22 Pesticidal combination containing trifluoro-benzene pyrimidine and bensultap Pending CN107156152A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2023047294A1 (en) * 2021-09-21 2023-03-30 Rajiv Rathod Novel pesticidal composition

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102665415A (en) * 2009-08-05 2012-09-12 杜邦公司 Mixtures of mesoionic pesticides
CN103459387A (en) * 2010-12-29 2013-12-18 杜邦公司 Mesoionic pyrido [1,2 -A] pyrimidine pesticides
CN104509534A (en) * 2013-09-27 2015-04-15 陕西韦尔奇作物保护有限公司 Insect disinfestation composition containing trifluorobenzene pyrimidine and nereistoxin

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102665415A (en) * 2009-08-05 2012-09-12 杜邦公司 Mixtures of mesoionic pesticides
CN103459387A (en) * 2010-12-29 2013-12-18 杜邦公司 Mesoionic pyrido [1,2 -A] pyrimidine pesticides
CN104509534A (en) * 2013-09-27 2015-04-15 陕西韦尔奇作物保护有限公司 Insect disinfestation composition containing trifluorobenzene pyrimidine and nereistoxin

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2023047294A1 (en) * 2021-09-21 2023-03-30 Rajiv Rathod Novel pesticidal composition

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Application publication date: 20170915