CN105707096B - Agricultural insecticidal composite - Google Patents

Agricultural insecticidal composite Download PDF

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Publication number
CN105707096B
CN105707096B CN201610109387.3A CN201610109387A CN105707096B CN 105707096 B CN105707096 B CN 105707096B CN 201610109387 A CN201610109387 A CN 201610109387A CN 105707096 B CN105707096 B CN 105707096B
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China
Prior art keywords
cartap
ethyl pleocidin
agricultural insecticidal
insecticidal composite
composite according
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Expired - Fee Related
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CN201610109387.3A
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Chinese (zh)
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CN105707096A (en
Inventor
许网保
虞国新
魏明阳
臧伟新
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JIANGSU TIANRONG GROUP CO Ltd
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JIANGSU TIANRONG GROUP CO Ltd
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    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/10Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
    • A01N47/12Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof containing a —O—CO—N< group, or a thio analogue thereof, neither directly attached to a ring nor the nitrogen atom being a member of a heterocyclic ring
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/02Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
    • A01N43/04Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
    • A01N43/22Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom rings with more than six members

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  • Life Sciences & Earth Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The invention discloses a kind of agricultural insecticidal composites, and containing active component ethyl pleocidin and cartap, the wherein weight ratio of ethyl pleocidin and cartap is 1:1~100.The composition can be applied in terms of the prevention snout moth's larva of rice is to crop pests.The present invention have many advantages, such as insecticidal range is wide, the lasting period is long, less toxic, low-residual, it is nuisanceless, environmentally safe, improve insecticidal effect, alleviate environmental pollution.

Description

Agricultural insecticidal composite
Technical field
The invention belongs to pesticide fields, relate in particular to a kind of Pesticidal combination of ethyl pleocidin and cartap.
Background technology
Since agricultural pests cause very big loss, master of the pesticide as chemical prevention agricultural pests to production estimation every year Means are wanted, are widely used at present general.With pesticide a large amount of single use for a long time, pest can be caused to generate resistance, to environment Cause the pollution of bigger.
Ethyl pleocidin is novel biological insecticides, is mainly used for preventing lepidopterous larvae, thrips and Liriomyza etc., The control effect having had to the snout moth's larva of rice, diamondback moth, beet armyworm, Liriomyza, thrips, prodenia litura, bean-pod borer.
Ethyl pleocidin insecticide is environmentally friendly:It is to birds, fish, earthworm and water plant low toxicity;In reality It is almost non-toxic to honeybee in;Beneficial to the influence of arthropod it is slight, of short duration to field;Suitable for harmful organism Comprehensive treatment.
Ethyl pleocidin has the advantage that:
1, bioactivity is high:It is significantly good compared with Methomyl, pyrethroid insecticides, it can be with emerging insecticide such as indenes Worm prestige, emamectin benzoate etc. match in excellence or beauty.
2, insecticidal spectrum is wide:Can prevent rice, vegetables, fruit tree, etc. lepidoptera pest in various crops.
3, quick-acting is good:A few minutes to a few hours take effect.
4, the lasting period is long:Lasting period is longer compared with pleocidin.
5, safety:To people and mammal low toxicity, no chronic toxicity.
6, without poisoning:Poisoning is not will produce using crop.
Cartap (Cartap) belongs to nereistoxin and similar bionic insecticide, and the mechanism of action is that cartap invades insect god Engaging portion through cell blocks the acetylcholine secreted by previous nerve cell and is communicated to latter nerve cell, to make nerve Cells blocks are got in touch with, and are made insect neural paralysis, cannot be nibbled food, cannot take action, and stop development, so that dead.Cartap is used as killing Worm agent, have many advantages, such as efficiently, wide spectrum, low toxicity, low-residual, there are interior suction, stomach toxicity, a variety of effects such as tag, also have food refusal, The effects that ovicidal.Cartap knocks down soon pest, and the lasting period is long, desinsection wide spectrum, can prevent the snout moth's larva of rice, rice plant skipper, rice leaf mining The pests such as fly, rice straw rope and vegetables cabbage caterpillar, pickles butterfly, oriental fruit months, citrus leaf-miner.There is special efficacy to the snout moth's larva of rice, and Simultaneous the pests such as leafhopper, armyworm can be controlled, it is also effective to diamondback moth, striped flea-beetle.It is nontoxic to natural enemies such as spiders to birds low toxicity.It is right Environmental organism lethality is small.
Since cartap is in agricultural production using for many years, pest produces certain drug resistance, and dosage also exists Increase year by year.
Striped rice borer Chilo suppressalis (Walker) are that Occurrence the most serious is endangered on China's rice One of, tillering stage it is aggrieved cause withered sheath, withered heart seedling, cause insect bite strain and dead ears ear period is aggrieved, the general time underproduction 8%~ 10%, the underproduction is more than 3 one-tenth when serious.Domestic each rice region is distributed, wide compared with yellow rice borer and pink rice borer distribution, but mainly with the Changjiang river Basin and on the south rice region occur heavier, it is in the situation that obviously rises that quantity occurs in recent years.Striped rice borer is in addition to hazard rice, moreover it is possible to Endanger the weeds such as the crops such as wild rice stem, corn, sorghum, sugarcane, rape, broad bean, wheat and reed, barnyard grass, Leersia Sw.
Striped rice borer is not only the important pests in China's Rice Production, and in external paddy fields, distribution is also very wide, for example, The harm of the striped rice borer such as Korea, Japan, Philippine, Vietnam, Thailand, Malaya, Indonesia, India, Egypt is also very tight Weight.
Invention content
The object of the present invention is to provide it is a kind of it is efficient to rice-stem borer insecticidal activity, lasting effect is long, quick-acting is fast, low Poison, environmentally friendly Pesticidal combination are specifically related to pesticide of the ethyl pleocidin with cartap for active ingredient.
The purpose of the present invention can be achieved by the following measures:
A kind of Pesticidal combination, containing active component ethyl pleocidin and cartap, wherein ethyl pleocidin and The weight ratio of cartap is 1:1~100.The composition can be applied in terms of prevention rice-stem borer is to crop pests.
The proportioning of ethyl pleocidin and cartap in the present composition can be according to specifically using situation in reasonable model It is adjusted in enclosing, such as the weight ratio of both ethyl pleocidin and cartap is 1:1~100,1:1~90,1:1~80, 1:1~50,1:1~45,1:1~40,1:1~35,1:1~30,1:1~25,1:1~20,1:1~15,1:1~10,1:5~ 80、1:5~70,1:5~60,1:5~50,1:5~45,1:5~40,1:5~35,1:5~30,1:5~25,1:5~20,1: 5~15,1:5~10,1:10~50,1:10~40,1:10~30 etc..In some preferred embodiments, the weight ratio of the two can be with It is 1:90、1:80、1:70、1:60、1:50、1:45、1:40、1:39、1:38、1:37、1:36、1:35、1:34、1:33、1:32、 1:31、1:30、1:29、1:28、1:27、1:26、1:25、1:24、1:23、1:22、1:21、1:20、1:19、1:18、1:17、1: 16、1:15、1:14、1:13、1:12、1:11、1:10、1:9、1:8、1:7、1:6、1:5、1:4、1:3、1:2、1:1、2:1 etc..
The mass content of active ingredient ethyl pleocidin and cartap can be 1~99% in the present composition, excellent Select 5~90%, further preferred 10~80%.
The composition of the present invention can be equipped with insecticides adjuvant, with ability using ethyl pleocidin and cartap as active ingredient Method well known to technical staff in domain, is made dosage form pesticide-acceptable, such as solvable pulvis, wettable powder, water-dispersed Granula, aqua, suspending agent etc..
Field trial shows the existing medicament another mixed pesticide different from mechanism of action, can not only expand insecticidal spectrum, Resistance is postponed to generate, moreover it is possible to it improves drug effect holding effect period, reduces usage amount, reduce times for spraying, reduce the dispenser cost of peasant, The present invention compounds ethyl pleocidin and cartap, not only can effectively prevent most of pest, reduce environmental pollution, moreover it is possible to Drug effect and lasting period are enough improved, delays drug resistance, reduces the labour cost of peasant, it is with good economic efficiency.This desinsection Composition further has the advantage that and advantageous effect:1, insecticidal range is wide;2, the lasting period is long;3, less toxic, low-residual, no public affairs Evil, it is environmentally safe;4, using compound formulation, the dosage of two kinds of insecticides is killed than being reduced when single use to improve Worm effect reduces peasant's drug cost, alleviates environmental pollution.
Specific implementation mode
Embodiment 1:The co-toxicity coefficient of ethyl pleocidin and cartap different ratio measures
In order to confirm ethyl pleocidin and cartap mixture, be with synergistic effect, summation action or antagonism, We have carried out recipe determination research to ethyl pleocidin and cartap first, and the object of indoor biometrics is set in China's water The striped rice borer of most serious is endangered in rice production, specific test situation and result are as follows:
According to the Ministry of Agriculture's data, the recommended dose that ethyl pleocidin prevents striped rice borer is 2 grams of effective ingredient/mus, Cartap is 40 grams of effective ingredient/mus to the recommended dose of rice-stem borer, and on this basis, experimental design proportioning is 1: 1,1: 2,1: 5,1: 10,1: 20,1: 30,1: 40,1: 50,1: 60,1: 70,1: 80 totally 11 processing, separately set ethyl pleocidin, kill snout moth's larva Red two single doses processing.
It tests medication and uses ethyl pleocidin active compound and cartap active compound, dissolved active compound using solvent, according to setting Matched proportion density, it is spare to be configured to required concentration liquid.
The method of indoor biometrics is:Using capillary micro intravenous drip method, capillary micro intravenous drip device volume is 1.0 μ L.With Micro intravenous drip device is by liquid by head drop in the back side of 3 instar larvae of striped rice borer, 30 larvas of each concentration processing, every 5 larvas It is put into the culture dish of an a diameter of 9cm, a small amount of feed is for feeding built in ware, separately as a contrast with 30 larvas of acetone drop. Larva after processing is still placed in receptacle, and the death rate is checked after 48h.Data are handled with SPSS software statistics.Find out virulence Regression equation, the lethal concentration of 50, related coefficient etc., are used in combination Sun Yunpei's Method to find out co-toxicity coefficient.
The co-toxicity of mixture preparation is indicated using the co-toxicity coefficient method of Sun Yunpei:
Theoretical toxicity index TTI=Σ (medicine effective ingredients of the toxicity index ATI of certain medicine × in mixture of mixture preparation Percentage).
Synergistic effect criterion after two kinds of effective ingredient compoundings:
CTC is synergistic effect when being more than 120, is antagonism when being less than 80, is addition when 80~120.
It is 5.68 μ g/mL to the lethal concentration of 50 of striped rice borer that experiment, which determines ethyl pleocidin, and setting ethyl is sterilized more Element is 100 to the toxicity index of striped rice borer.Toxicity index, co-toxicity coefficient such as following table of each processing to striped rice borer:
1 ethyl pleocidin of table, cartap different ratio are to the toxicity test result of striped rice borer
When analyzing above-mentioned data result and showing that ethyl pleocidin and cartap are compounded by different proportion, except No. 1, No. 2 are matched Side is outer, and the co-toxicity coefficient of remaining compounded formula is all higher than 120, shows to all have apparent synergistic effect.Illustrate two kinds effectively After part compounding, there can be good synergistic effect.With the increase of ethyl pleocidin in proportioning, synergistic effect is in significantly rise Trend.When the ratio of ethyl pleocidin and cartap be 1: 20 when, co-toxicity coefficient reaches 220.65, in all formulas most It is high.When ratio of the ethyl pleocidin in compounding continues growing, co-toxicity coefficient is gradually reduced, and synergistic effect reduces.Work as second When the ratio of Quito bacteriocidin and cartap is 1: 1, co-toxicity coefficient further declines, and synergistic effect further decreases.
We select following proportioning to carry out trial-manufacture of sample thus, and have carried out field control effectiveness test.
Below with specific example of formulations to present invention be described in more detail, but the present invention be only limited to absolutely not it is following These embodiments.Percentage is weight percentage in formula.
Embodiment 2:30% ethyl pleocidin cartap wettable powder
Embodiment 3:The 50% solvable pulvis of ethyl pleocidin cartap
Embodiment 4:60% ethyl pleocidin cartap suspending agent
Embodiment 5:30% ethyl pleocidin cartap aqua
Embodiment 6:20% ethyl pleocidin cartap wettable powder
Embodiment 7:80% ethyl pleocidin cartap water dispersible granules
By above six embodiments made from ethyl pleocidin and the various different ratios of cartap, prevention rice two is carried out Change the field control effectiveness test of snout moth's larva, while passing through the effect with 60 grams per liter ethyl pleocidin suspending agents, the solvable pulvis of 50% cartap Fruit compares, the synergistic effect after verification compounding.Test site is the Jiangsu Province Xiangshui County ports Chen Jia bight village, and the time is 2015 8 The moon 12, experiment totally eight processing, a blank control each handle three repetitions, cell random alignment, plot area 9* 5m2, the planting habits of all cells is identical as local planting habit.
Investigation standard is:By 5 point samplings, random 5 points of samplings per cell, every is investigated 5 clumps, totally 25 clumps.Before dispenser The Chilo spp larvae quantity for investigating 25 clumps of rice respectively with the 1st, 7,15 day after dispenser, records each instar larvae number, calculates insect population and subtracts Move back rate, control effect.Specific data (data are the average value of three repetitions) are as follows:
Table:The field control effectiveness test result of ethyl pleocidin, cartap single dose and complex preparation to rice-stem borer
As can be seen from the above data, under using identical effective ingredient dosage, ethyl pleocidin and cartap are not After proportioning compounding, Revision insect recluced rate, control effect will be apparently higher than two kinds of single doses, and all formulas have apparent synergy to make With.When cartap content is high in formula, quick-acting is preferable, and lasting effect is general, when ethyl pleocidin content is high in formula, Quick-acting is general, and lasting effect is preferable, this result also really reflects the characteristic of the two medicaments.Compared with single dose, ethyl is more Bacteriocidin improves control effect with each complex preparation of cartap, extends the lasting period, reduces times for spraying, alleviates peasant The amount of labour reduces peasant's drug cost, there is preferable economic benefit.

Claims (9)

1. a kind of agricultural insecticidal composite, it is characterised in that it contains active component ethyl pleocidin and cartap, wherein second The weight ratio of Quito bacteriocidin and cartap is 1:1~60.
2. agricultural insecticidal composite according to claim 1, it is characterised in that the weight of ethyl pleocidin and cartap Than being 1:5~60.
3. agricultural insecticidal composite according to claim 1, it is characterised in that the weight of ethyl pleocidin and cartap Than being 1:1~50.
4. agricultural insecticidal composite according to any one of claims 1 to 3, it is characterised in that ethyl pleocidin and The weight ratio of cartap is 1:5~40.
5. agricultural insecticidal composite according to claim 1, it is characterised in that ethyl pleocidin and killed in the composition The mass content of snout moth's larva pellet is 5~90%.
6. agricultural insecticidal composite according to claim 4, it is characterised in that ethyl pleocidin and killed in the composition The mass content of snout moth's larva pellet is 10~80%.
7. agricultural insecticidal composite according to claim 1, it is characterised in that the composition is with ethyl pleocidin and kills Snout moth's larva pellet is active component, is equipped with insecticides adjuvant, dosage form pesticide-acceptable is made.
8. agricultural insecticidal composite according to claim 7, it is characterised in that the dosage form is selected from solvable pulvis, wettable Pulvis, water dispersible granules, aqua, suspending agent.
9. agricultural insecticidal composite described in claim 1 is in prevention rice-stem borer to the application in terms of crop pests.
CN201610109387.3A 2016-02-27 2016-02-27 Agricultural insecticidal composite Expired - Fee Related CN105707096B (en)

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CN105707096B true CN105707096B (en) 2018-09-25

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CN103704228B (en) * 2013-12-10 2015-08-05 徐茂航 The suspension emulsion of a kind of multiple killing teichomycin and cartap and application

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