CN102007909B - Spinosad-containing pesticidal composition - Google Patents
Spinosad-containing pesticidal composition Download PDFInfo
- Publication number
- CN102007909B CN102007909B CN 201010548727 CN201010548727A CN102007909B CN 102007909 B CN102007909 B CN 102007909B CN 201010548727 CN201010548727 CN 201010548727 CN 201010548727 A CN201010548727 A CN 201010548727A CN 102007909 B CN102007909 B CN 102007909B
- Authority
- CN
- China
- Prior art keywords
- multiple killing
- killing teichomycin
- prescription
- spinosad
- effect
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Abstract
The invention relates to a spinosad-containing pesticidal composition. The active ingredients of the spinosad-containing pesticidal composition comprise monosultap and spinosad. The spinosad-containing pesticidal composition has obvious synergy on prevention and control of chilo supperssalis, improves the preventive effect, reduces using amount, delays medicine resistance, reduces environmental pollution and has high practicability.
Description
Technical field
The invention belongs to pesticide field, relate in particular to a kind of Pesticidal combination that contains multiple killing teichomycin.
Background technology
It is a kind of macrolides Nuisanceless high-efficient biological insecticides that extract in the sugared many born of the same parents fermented liquid of thorn that multiple killing teichomycin has another name called pleocidin (Spinosad).Produce parent strain soil actinomycetes thorniness saccharopolyspora strain (the Saccharopolyspora spinosa Metrz﹠amp of pleocidin; Yao) initial separation is from one of the Caribbean discarded wine brewing field.The mode of action of multiple killing teichomycin is novel, can sustained activation target insect acetylcholine nicotine receptor, but its binding site is different from nicotine and Imidacloprid.Pleocidin also can affect the GABA acceptor, but mechanism of action is unclear.Whether also do not know at present has cross tolerance with the insecticide of other types.These compounds can cause that target plant-feed insect such as caterpillar, leaf miner, thrips and leaf-feeding beetle are dead rapidly, although administrative department's strong request is not used when resistance occurs, the moderate residual activity of this compound has reduced the possibility of resistance and Swarms.The acting body of nicotinic acid acetylcholinergic receptor can sustained activation target insect acetylcholine nicotine receptor, but its binding site is different from nicotine and Imidacloprid.Multiple killing teichomycin also can affect the GABA acceptor, insect is had tag fast and stomach poison function, and blade is had stronger osmosis, can kill subepidermal insect, and the longevity of residure is longer, and some insects are had certain ovicidal action.Without systemic action.Can effectively preventing Lepidoptera, diptera and thrips insect, can prevent and treat well also that some takes food the pest species of blade in a large number in coleoptera and the orthoptera, relatively poor to the control efficiency of sucking pest and mite class.Safer to predatory natural enemy insect, unique because of insecticidal action mechanism, not yet find at present to have mutual drug-fast report with other insecticides.Safe without poisoning to plant.Be suitable for using on vegetables, fruit tree, gardening, the crops.Can make insect benumb rapidly, paralyse, cause at last death.Its desinsection speed can compare favourably with chemical pesticide.Safe, and with present common insecticide be the biological insecticides of low toxicity, efficient, low-residual without cross resistance, existing efficient insecticidal properties has again the characteristic of beneficial insect and mammalian safe is arranged, the most suitable pollution-free vegetable, Production of fruit are used.
The desinsection list is a kind of analog of the artificial nereistoxin that synthesizes, and enters and is converted into rapidly clam worm element or Dihydronereistoxin element in the insect bodies.This medicine is the acetylcholine competitive inhibitor, have stronger tag, stomach toxicity and interior suction conduction, the larva of lepidoptera pest is had preferably preventive and therapeutic effect, this medicine is mainly used in preventing and treating the insect on the crops such as sugarcane, paddy rice.
Because agricultural pests causes very large loss to crops production every year, consider the agricultural chemicals of long-term use single variety, impel easily insect to produce resistance, environment is caused larger pollution, field trial shows, the existing medicament another kind of mixed pesticide different from mechanism of action, can not only postpone resistance and produce, can also improve drug effect and residual period, reduce usage amount, Cost reduction, so we are with desinsection list and the composite expansion insecticidal spectrum of multiple killing teichomycin.Not only can effectively prevent and treat most of insect, environmental contamination reduction has also improved drug effect and lasting period.
Summary of the invention
The purpose of this invention is to provide that a kind of insecticidal activity is efficient, lasting effect is long, the Pesticidal combination of the high and low poison of quick-acting, environmental protection.Be specifically related to the pesticidal preparations that desinsection list and multiple killing teichomycin are basis.
Above-mentioned Pesticidal combination contains desinsection list 1%～35%, multiple killing teichomycin 0.5%～10%.
Utilize the described insecticides of the invention described above, be equipped with the known auxiliary agent of those skilled in that art, can make formulation of the present invention with the known method of those skilled in that art.Its formulation that can process is suspending agent, wetting powder, water dispersible granules.
The advantage that the present invention has and beneficial effect: 1. the desinsection scope is wide, to the Lepidoptera super-high-efficient; 2. the lasting period is long; 3. low toxicity, noresidue, nuisanceless, environmentally safe; 4. use compound formulation, two kinds of insecticides also have synergistic effect, and the consumption of two kinds of insecticides reduces during all than single use, thereby has improved insecticidal effect, has increased safety, has reduced environmental pollution.
Embodiment
Following instantiation is in order to further describing the present invention, but the present invention absolutely not only only limits to following these embodiment.Percentage all is weight percentage in the prescription, and employed former medicine and auxiliary agent are other producers and buy.
Formulation examples is as follows:
1, the preparation of suspending agent
According to the prescription requirement, take water as medium, will grind in the adding sand mills such as active ingredient, wetting agent, dispersant, thickener, defoamer, emulsification in the rear adding high-shear emulsifying still makes suspending agent.
Prescription 1 (7% suspending agent)
Component weight percent content
Desinsection list 5%
Multiple killing teichomycin 2%
Lauryl sodium sulfate 3%
Sodium lignin sulfonate 4%
Carboxymethyl cellulose 0.2%
Xanthans 0.2%
Defoamer 0.15%
Water supplies 100%
Prescription 2 (12.5% suspending agents)
Component weight percent content
Desinsection list 10%
Multiple killing teichomycin 2.5%
Dodecyl sodium sulfate 3%
Sodium lignin sulfonate 4%
Carboxymethyl cellulose 0.2%
Aluminium-magnesium silicate 0.1%
Defoamer 0.1%
Water supplies 100%
2, the preparation of wetting powder
Active ingredient, wetting agent, dispersant, filler etc. are fully mixed in the ratio of prescription, and behind ultra-fine pulverizer disintegrating, fineness reaches 98% by 325 mesh standard sieves, namely gets wetting powder.
Prescription 3 (33% wetting powders)
Component weight percent content
Desinsection list 30%
Multiple killing teichomycin 3%
Dodecyl sodium sulfate 3%
Polyvinylpyrrolidone 4%
Carboxymethyl cellulose 0.2%
Ammonium sulfate 10%
Sodium bentonite complements to 100%
3, the preparation of water dispersible granules
Active ingredient, wetting agent, dispersant, adhesive, filler etc. are fully mixed in the ratio of prescription, behind ultra-fine pulverizer disintegrating, add an amount of purified water, make water dispersible granules through kneading, granulation, drying, screening.
Prescription 4 (13% water dispersible granules)
Component weight percent content
Desinsection list 12%
Multiple killing teichomycin 1%
Lauryl sodium sulfate 3%
Polyvinylpyrrolidone 5%
Carboxymethyl cellulose 0.2%
Pull open powder 0.3%
Ammonium sulfate 8%
Kaolin complements to 100%
Prescription 5 (35.5% water dispersible granules)
Component weight percent content
Desinsection list 35%
Multiple killing teichomycin 0.5%
Dodecyl sodium sulfate 3%
Polyvinylpyrrolidone 6%
Carboxymethyl cellulose 0.2%
Aluminium-magnesium silicate 0.5%
Polyvinyl alcohol 0.2%
Kaolin surplus 1/2
Sodium bentonite surplus 1/2
Rice-stem borer (Chilo suppressalis) popular name borer, borer, moth stalk worms etc. are the formidable opponents of paddy rice.Larva moth food stem stalk causes the withered heart, and striped rice borer has the strain of turning harm habit, and a Chilo spp larvae can endanger many strains paddy rice, causes dead leaf sheath, the withered heart.If a lot of withered heart seedlings often can appear in untimely control, field, the part field is not is not prevented and treated striped rice borer because of nursery period, and field withered heart seedling ratio is up to 30% now, and part location, field withered heart seedling ratio surpasses 50%, causes very large loss.Desinsection list, multiple killing teichomycin are two kinds of compositions that insecticidal activity is very high, according to their effect characteristics and mechanism of action, the object of indoor biometrics are decided to be rice-stem borer (Chilo suppressalis).
The method of indoor biometrics is: adopt capillary micro intravenous drip method, capillary micro intravenous drip device volume is 1.0 μ L.With the micro intravenous drip device liquid is pursued a drop in the back side of striped rice borer 6 instar larvaes, the larva that each concentration place is about 30, the culture dish that it is 9cm that per 5 larvas are put into a diameter, the built-in a small amount of feed of ware is for taking food, in addition with 30 larvas of acetone drop in contrast.Larva after treatment still is placed in the receptacle, checks lethality behind the 48h.Data are processed with the SPSS software statistics.Obtain toxicity regression formula, the lethal concentration of 50, correlation coefficient etc., and obtain co-toxicity coefficient with the abundant method of Sun Yun.
The co-toxicity of mixture preparation adopts the abundant co-toxicity coefficient method representation of Sun Yun:
The theoretical toxicity index A=∑ of mixture preparation (toxicity index of certain medicine * percentage of this pharmaceutically active ingredient in mixture).
C was synergistic effect greater than 120 o'clock, less than 80 o'clock be antagonism, 80～120 o'clock is addition.
The different proportionings of table 1 are to the toxicity test result of striped rice borer
Table 2 desinsection list is tested the test of giving birth to of striped rice borer
| Dosage (mg/l) | The examination borer population | Death toll | Lethality (%) | Corrected mortality (%) |
| 50 | 50 | 20 | 40.00 | 40.00 |
| 40 | 50 | 31 | 62.00 | 62.00 |
| 20 | 50 | 39 | 78.00 | 78.00 |
| 10 | 50 | 43 | 86.00 | 86.00 |
| 5 | 50 | 46 | 92.00 | 92.00 |
| CK | 50 | 0 |
Table 3 multiple killing teichomycin is tested the test of giving birth to of striped rice borer
| Dosage (mg/l) | The examination borer population | Death toll | Lethality (%) | Corrected mortality (%) |
| 50 | 50 | 21 | 42.00 | 42.00 |
| 40 | 50 | 33 | 66.00 | 66.00 |
| 20 | 50 | 41 | 82.00 | 82.00 |
| 10 | 50 | 44 | 88.00 | 88.00 |
| 5 | 50 | 47 | 94.00 | 94.00 |
| CK | 50 | 0 |
The test of giving birth to of a pair of striped rice borer of table 4 prescription is tested
| Dosage (mg/l) | The examination borer population | Death toll | Lethality (%) | Corrected mortality (%) |
| 50 | 50 | 10 | 20.00 | 20.00 |
| 40 | 50 | 18 | 36.00 | 36.00 |
| 20 | 50 | 30 | 60.00 | 60.00 |
| 10 | 50 | 39 | 78.00 | 78.00 |
| 5 | 50 | 43 | 86.00 | 86.00 |
| CK | 50 | 0 |
The test of giving birth to of two pairs of striped rice borer of table 5 prescription is tested
| Dosage (mg/l) | The examination borer population | Death toll | Lethality (%) | Corrected mortality (%) |
| 50 | 50 | 17 | 34.00 | 34.00 |
| 40 | 50 | 28 | 56.00 | 56.00 |
| 20 | 50 | 37 | 74.00 | 74.00 |
| 10 | 50 | 41 | 82.00 | 82.00 |
| 5 | 50 | 45 | 90.00 | 90.00 |
| CK | 50 | 0 |
The test of giving birth to of three pairs of striped rice borer of table 6 prescription is tested
| Dosage (mg/l) | The examination borer population | Death toll | Lethality (%) | Corrected mortality (%) |
| 50 | 50 | 20 | 40.00 | 40.00 |
| 40 | 50 | 33 | 66.00 | 66.00 |
| 20 | 50 | 40 | 80.00 | 80.00 |
| 10 | 50 | 44 | 88.00 | 88.00 |
| 5 | 50 | 47 | 94.00 | 94.00 |
| CK | 50 | 0 |
The test of giving birth to of four pairs of striped rice borer of table 7 prescription is tested
| Dosage (mg/l) | The examination borer population | Death toll | Lethality (%) | Corrected mortality (%) |
| 50 | 50 | 17 | 34.00 | 34.00 |
| 40 | 50 | 26 | 52.00 | 52.00 |
| 20 | 50 | 39 | 78.00 | 78.00 |
| 10 | 50 | 43 | 86.00 | 86.00 |
| 5 | 50 | 46 | 92.00 | 92.00 |
| CK | 50 | 0 |
The test of giving birth to of five pairs of striped rice borer of table 8 prescription is tested
| Dosage (mg/l) | The examination borer population | Death toll | Lethality (%) | Corrected mortality (%) |
| 50 | 50 | 21 | 42.00 | 42.00 |
| 40 | 50 | 31 | 62.00 | 62.00 |
| 20 | 50 | 43 | 86.00 | 86.00 |
| 10 | 50 | 47 | 94.00 | 94.00 |
| 5 | 50 | 49 | 98.00 | 98.00 |
| CK | 50 | 0 |
Analyze above-mentioned data, measurement result shows that when desinsection list and multiple killing teichomycin different proportion were composite, the co-toxicity coefficient of prescription all had obvious synergistic effect all greater than 120.Wherein fill a prescription 5 and prescription 3 co-toxicity coefficients maximum, be respectively 167.38 and 175.16.
By the indoor biometrics test, select the field trial that the larger prescription of CTC 3, prescription 5 and the less prescription 1 of CTC are prevented and treated rice-stem borer, determine the effect of prescription control rice-stem borer; Simultaneously by with the Contrast on effect of desinsection list, multiple killing teichomycin single dose, verify the synergistic effect after composite.Concrete test method and data are as follows:
Test the test of pesticide effectiveness that one: 35% desinsection list, 0.5% multiple killing teichomycin WDG, 33% desinsection list WDG, 3% multiple killing teichomycin WDG do the field control striped rice borer.Test site be Hanchuan City Liu of Xiaogan Prefecture, Hubei Province every the town, the time is on June 14th, 2009, the test totally four processing, each processes three repetitions, residential quarter randomized arrangement, residential quarter area 67m
2, the planting habit of all residential quarters all planting habit with local is identical, and the record dispenser same day and the synoptic data in a week thereafter are specific as follows:
Table 9 duration of test meteorological data
The investigation standard is: 7d gets killed strain 50 strains at random behind the medicine in each residential quarter, and the life or death number of Chilo spp larvae is looked in stripping, calculates lethality; 15d, 25d adopt every residential quarter 150 clumps of parallel sampling method samplings behind the medicine, investigate withered calculation, calculate at last withered heart rate and seedling protecting effect.Concrete data (data are the mean value of three repetitions) are as follows:
The effect table of table 1035% desinsection list 0.5% multiple killing teichomycin WDG and other chemical control striped rice borer
Annotate: data are the mean value that repeats for 3 times in the table, and letter is all Duncan testing differentia remarkable time mutually: in June, 2009 place: the Hubei Xiaogan
As can be seen from the above data, in the situation of using same dose, 35% desinsection list, 0.5% multiple killing teichomycin 25d control rate behind medicine can reach 96.1%, the effect when preventive effect is higher than 33% desinsection list and the use of 3% multiple killing teichomycin single dose far away, and difference is extremely remarkable.
Test two: test method, investigation method and meteorological data are the same, and concrete test data is as follows:
The effect table of table 1130% desinsection list 3% multiple killing teichomycin and other chemical control striped rice borer
Annotate: data are the mean value that repeats for 3 times in the table, and letter is all Duncan testing differentia remarkable time mutually: in June, 2006 place: the Jianli, Hubei
As can be seen from the above data, in the situation of identical using dosage, 30% desinsection list, 3% multiple killing teichomycin 25d control rate behind medicine can reach 95.7%, the effect when preventive effect is higher than 77.5% desinsection list WDG and the use of 2.5% multiple killing teichomycin WDG single dose far away, and difference is extremely remarkable.
Test three: test method, investigation method and meteorological data are the same, and concrete test data is as follows:
The effect table of table 125% desinsection list 2% multiple killing teichomycin and other chemical control striped rice borer
Annotate: data are the mean value that repeats for 3 times in the table, and letter is all Duncan testing differentia remarkable time mutually: in June, 2009 place: the Hubei Xiaogan
As can be seen from the above data, in the situation of identical using dosage, 5% desinsection list, 2% multiple killing teichomycin 25d control rate behind medicine can reach 86.1%, the effect when preventive effect is higher than 5% desinsection list WDG and the use of 2.5% multiple killing teichomycin WDG single dose far away, and difference is extremely remarkable.
By above-mentioned three field control effectiveness tests, the effect that can find out prescription 3, prescription 5 control rice-stem borers is best, this also matches with the result of indoor biometrics, and (CTC is larger, synergistic effect is larger), but the two difference is not remarkable, as considering the factor of pesticide cost, prescription 3 is best, the most economical proportionings of effect again; Also verified simultaneously when desinsection list and multiple killing teichomycin are composite by different proportion, the control efficiency of rice-stem borer all has been better than the effect of desinsection list and the use of multiple killing teichomycin single dose, certain synergistic effect has been arranged.
By above-mentioned three field control effectiveness tests, can determine to fill a prescription 3 for preventing and treating the more suitable prescription of rice-stem borer, 30% desinsection list, 3% multiple killing teichomycin WDG (prescription 3) has been carried out further test, filter out the optium concentration of control striped rice borer.Experimental scheme 4g/ mu, 5g/ mu, 6g/ mu and 4 concentration tonsures of 7g/ mu are also done contrast with the effect of 50% desinsection list (5g/ mu), 5% multiple killing teichomycin (5g/ mu), test method and investigation method are the same, and concrete data (mean values of three repetitions) are as follows:
Table 13 prescription 3 different amounts control striped rice borer effect table
Annotate: data are the mean value that repeats for 3 times in the table, and letter is all Duncan testing differentia remarkable time mutually: in June, 2009 place: the Hubei Xiaogan
Can find out that from the result of the above-mentioned test of pesticide effectiveness along with the increase of prescription dosage, drug effect also increases to some extent, 30% desinsection list, 3% multiple killing teichomycin WDG consumption is 5g/ mu, the seedling protecting effect of 25d is 96.4% behind the medicine, and apparently higher than 50% desinsection list and 5% multiple killing teichomycin, difference is extremely remarkable; When the mu consumption was 6g and 7g, 25 days seedling protecting effect and 5g/ mu was roughly the same after medication, and difference is not remarkable.Therefore, under the prerequisite of considering the mu cost, should advocate mu usage amount is 5g/ mu.
Claims (2)
1. Pesticidal combination that contains multiple killing teichomycin, it is characterized in that: described Pesticidal combination active ingredient is desinsection list and multiple killing teichomycin, and described desinsection simple substance amount percentage is 1%～35%, and multiple killing teichomycin is 0.5%～10%.
2. Pesticidal combination according to claim 1, the formulation that it is characterized in that described Pesticidal combination is suspending agent, wetting powder, water dispersible granules.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201010548727 CN102007909B (en) | 2010-11-18 | 2010-11-18 | Spinosad-containing pesticidal composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201010548727 CN102007909B (en) | 2010-11-18 | 2010-11-18 | Spinosad-containing pesticidal composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102007909A CN102007909A (en) | 2011-04-13 |
| CN102007909B true CN102007909B (en) | 2013-03-13 |
Family
ID=43838415
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 201010548727 Active CN102007909B (en) | 2010-11-18 | 2010-11-18 | Spinosad-containing pesticidal composition |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102007909B (en) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103329902B (en) * | 2013-07-03 | 2014-12-24 | 江苏龙灯化学有限公司 | Insecticidal composition containing spinetoram and monosultap |
| CN103704228B (en) * | 2013-12-10 | 2015-08-05 | 徐茂航 | The suspension emulsion of a kind of multiple killing teichomycin and cartap and application |
| CN103651362B (en) * | 2013-12-10 | 2015-05-20 | 济南凯因生物科技有限公司 | Spinosad and bisultap suspoemulsion and application |
| CN107821400A (en) * | 2017-11-15 | 2018-03-23 | 惠州市永耐宝新材料有限公司 | A kind of composition pesticide |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1471822A (en) * | 2003-07-15 | 2004-02-04 | 江苏省农药研究所有限公司 | Composition with insect killing activity |
| CN101091490A (en) * | 2007-01-12 | 2007-12-26 | 南开大学 | New type heterocycle bactericide and composition |
| CN101305732A (en) * | 2007-12-27 | 2008-11-19 | 天津市兴光农药厂 | Pesticide combination containing thiacloprid |
| CN101589722A (en) * | 2009-06-26 | 2009-12-02 | 南开大学 | Insecticides of a kind of chloride worm benzamide and its production and use |
| CN101796949A (en) * | 2009-12-31 | 2010-08-11 | 青岛星牌作物科学有限公司 | Plant insecticidal protective agent and application thereof |
| WO2010126580A1 (en) * | 2009-04-27 | 2010-11-04 | Dow Agrosciences, Llc | Insecticidal pyridine compounds |
-
2010
- 2010-11-18 CN CN 201010548727 patent/CN102007909B/en active Active
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1471822A (en) * | 2003-07-15 | 2004-02-04 | 江苏省农药研究所有限公司 | Composition with insect killing activity |
| CN101091490A (en) * | 2007-01-12 | 2007-12-26 | 南开大学 | New type heterocycle bactericide and composition |
| CN101305732A (en) * | 2007-12-27 | 2008-11-19 | 天津市兴光农药厂 | Pesticide combination containing thiacloprid |
| WO2010126580A1 (en) * | 2009-04-27 | 2010-11-04 | Dow Agrosciences, Llc | Insecticidal pyridine compounds |
| CN101589722A (en) * | 2009-06-26 | 2009-12-02 | 南开大学 | Insecticides of a kind of chloride worm benzamide and its production and use |
| CN101796949A (en) * | 2009-12-31 | 2010-08-11 | 青岛星牌作物科学有限公司 | Plant insecticidal protective agent and application thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN102007909A (en) | 2011-04-13 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102308805A (en) | Compound pesticide | |
| CN102302022A (en) | Insecticidal composition | |
| CN101803605B (en) | Insecticidal composition of butene-fipronil and spinosad | |
| CN102007909B (en) | Spinosad-containing pesticidal composition | |
| CN102986707A (en) | Complex insecticide | |
| CN102318620A (en) | Insecticidal composition | |
| CN103947647A (en) | Insecticidal composition | |
| CN102308812B (en) | Insecticidal composition | |
| CN102428932B (en) | Insecticidal composition | |
| CN101755817B (en) | Insecticidal composition for controlling underground pest | |
| CN102657193A (en) | Complex insecticide | |
| CN102599170A (en) | Insecticidal composition | |
| CN102805098B (en) | Insecticidal composition | |
| CN102067846B (en) | Buprofezin-containing pesticide composition | |
| CN102239840B (en) | Compound insecticidal and acaricidal agent | |
| CN102027958A (en) | Insecticidal composition consisting of spinosad and fenobucarb | |
| CN102939983A (en) | Compound pesticide | |
| CN102027926A (en) | Pesticidal composition of ethiprole and spinosad | |
| CN102613211B (en) | Compound insecticide | |
| CN103651386A (en) | Insecticidal composition containing chlorfenapyr | |
| CN102302029A (en) | Compounded pesticide | |
| CN105707096B (en) | Agricultural insecticidal composite | |
| CN107494585A (en) | A kind of Pesticidal combination containing effective cypermethrin and Rynaxypyr | |
| CN105685042B (en) | Pesticidal combination containing ethyl pleocidin and dimehypo | |
| CN102657182A (en) | Insecticidal composite |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C56 | Change in the name or address of the patentee |
Owner name: BEIJING YANHUA YONGLE BIOTECHNOLOGY CO., LTD. Free format text: FORMER NAME: BEIJING YOLOO PESTICIDE CO., LTD. |
|
| CP01 | Change in the name or title of a patent holder |
Address after: 102488 No. 8, Liangxiang, Beijing, Fangshan District Patentee after: Beijing Yanhua Yongle Biotechnology Co., Ltd. Address before: 102488 No. 8, Liangxiang, Beijing, Fangshan District Patentee before: Beijing Yoloo Pesticide Co., Ltd. |
|
| C56 | Change in the name or address of the patentee | ||
| CP02 | Change in the address of a patent holder |
Address after: 102488, Beijing, Fangshan District Star Street, No. 1 hospital green sail, No. 16, building 8 Patentee after: Beijing Yanhua Yongle Biotechnology Co., Ltd. Address before: 102488 No. 8, Liangxiang, Beijing, Fangshan District Patentee before: Beijing Yanhua Yongle Biotechnology Co., Ltd. |
|
| TR01 | Transfer of patent right |
Effective date of registration: 20180105 Address after: 063600 Leting County Economic Development Zone, Tangshan City, Hebei Patentee after: Yanhua Yongle (Leting) Biological Technology Co. Ltd. Address before: 102488, Beijing, Fangshan District Star Street, No. 1 hospital green sail, No. 16, building 8 Patentee before: Beijing Yanhua Yongle Biotechnology Co., Ltd. |
|
| TR01 | Transfer of patent right |