CN105685042B - Pesticidal combination containing ethyl pleocidin and dimehypo - Google Patents

Pesticidal combination containing ethyl pleocidin and dimehypo Download PDF

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Publication number
CN105685042B
CN105685042B CN201610110707.7A CN201610110707A CN105685042B CN 105685042 B CN105685042 B CN 105685042B CN 201610110707 A CN201610110707 A CN 201610110707A CN 105685042 B CN105685042 B CN 105685042B
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China
Prior art keywords
dimehypo
ethyl pleocidin
composition according
composition
pesticidal combination
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CN201610110707.7A
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Chinese (zh)
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CN105685042A (en
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许网保
虞国新
魏明阳
臧伟新
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JIANGSU TIANRONG GROUP CO Ltd
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JIANGSU TIANRONG GROUP CO Ltd
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    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/02Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
    • A01N43/04Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
    • A01N43/22Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom rings with more than six members
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N41/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom
    • A01N41/02Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom containing a sulfur-to-oxygen double bond

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  • Life Sciences & Earth Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The invention discloses a kind of Pesticidal combination containing ethyl pleocidin and dimehypo, said composition contains effective ingredient ethyl pleocidin and dimehypo, and the wherein weight ratio of ethyl pleocidin and dimehypo is 1:60~60:1.The Pesticidal combination of the present invention has that insecticidal range is wide, and lasting period length, low toxicity, low-residual is nuisanceless, environmentally safe, using compound formulation, improves insecticidal effect, adds security, the advantages that reducing environmental pollution.

Description

Pesticidal combination containing ethyl pleocidin and dimehypo
Technical field
The invention belongs to pesticide field, relates in particular to a kind of Pesticidal combination of ethyl pleocidin and dimehypo.
Background technology
Ethyl pleocidin is new biological insecticides, is mainly used in preventing and treating lepidopterous larvae, thrips and Liriomyza etc., The prevention effect having had to the snout moth's larva of rice, diamondback moth, beet armyworm, Liriomyza, thrips, prodenia litura, bean-pod borer.
Ethyl pleocidin insecticide is environmentally friendly:It is to birds, fish, earthworm and water plant low toxicity;In reality It is almost non-toxic to honeybee in;Beneficial to the influence of arthropod it is slight, of short duration to field;Suitable for harmful organism The comprehensive regulation.
Ethyl pleocidin has the advantage that:
1st, bioactivity is high:It is significantly good compared with Methomyl, pyrethroid insecticides, can be with emerging insecticide such as indenes Worm prestige, emamectin benzoate etc. match in excellence or beauty.
2nd, insecticidal spectrum is wide:Can prevent and treat rice, vegetables, fruit tree, etc. lepidoptera pest in various crop.
3rd, quick-acting is good:A few minutes to a few hours take effect.
4th, the lasting period is grown:Lasting period is longer compared with pleocidin.
5th, safety:To people and mammal low toxicity, no chronic toxicity.
6th, without poisoning:Poisoning will not be produced using crop.
Dimehypo belongs to nereistoxin and similar bionic insecticide, and its mechanism of action is that dimehypo invades insect nerve cell Joint portion, block the acetylcholine secreted by previous nerve cell and be communicated to latter nerve cell, so that nerve cell blocks Contact, makes insect neural paralysis, it is impossible to nibble food, it is impossible to takes action, stops development, so that dead.Dimehypo is used as insecticide, has Efficiently, the advantages that wide spectrum, low toxicity, low-residual, there are interior suctions, stomach toxicity, a variety of effects such as tag, also with the work such as food refusal, ovicidal With.Insect is knocked down soon, longevity of residure length, desinsection wide spectrum.The snout moth's larva of rice, rice plant skipper, paddy stem maggot, rice straw rope and vegetables can be prevented and treated The insects such as cabbage caterpillar, pickles butterfly, oriental fruit months, citrus leaf-miner.There is special efficacy to the snout moth's larva of rice, and simultaneous can control leafhopper, armyworm It is also effective to diamondback moth, striped flea-beetle Deng insect.It is nontoxic to natural enemies such as spiders to birds low toxicity.To environmental organism lethality It is small.
Due to the harm of agricultural pestses, very big loss is caused to production estimation every year, agricultural chemicals is as chemical prevention farmland The Main Means of insect, application is very extensive at present.As agricultural chemicals is long-term, substantial amounts of single use, insect can be caused to produce anti- Property, in order to effectively control the harm of insect, it has to increase pesticide dosage, therefore bigger pollution is caused to environment.
Striped rice borer Chilo suppressalis (Walker) belong to Lepidoptera, Pyralidae, are endangered the most on China's rice One of serious Occurrence, tillering stage it is aggrieved cause withered sheath, withered heart seedling, cause insect bite strain and dead ears ear period is aggrieved, The general time underproduction 8%~10%, the underproduction is more than 3 one-tenth when serious.Each rice region is distributed striped rice borer at home, compared with yellow rice borer It is wide with pink rice borer distribution, but mainly with the Yangtze river basin and on the south rice region occur heavier, it is in the state substantially risen that quantity occurs in recent years Gesture.Striped rice borer is in addition to hazard rice, moreover it is possible to endanger wild rice stem, corn, sorghum, sugarcane, rape, broad bean, wheat class and reed, barnyard grass, The weeds such as Leersia Sw.Striped rice borer is not only the important pests in China's Rice Production, and paddy fields distribution is also very wide abroad, For example, the harm such as Korea, Japan, Philippine, Vietnam, Thailand, Malaya, Indonesia, India, Egypt is extremely serious.
The content of the invention
It is an object of the invention to provide a kind of insecticidal activity is efficient, lasting effect is long, quick-acting is fast, less toxic, environmental protection with second Quito bacteriocidin and the Pesticidal combination that dimehypo is active ingredient.
It is a further object of the present invention to provide a kind of application of above-mentioned Pesticidal combination in terms of agricultural production.
The purpose of the present invention can be reached by following measures:
A kind of Pesticidal combination containing ethyl pleocidin and dimehypo, said composition contains effective ingredient ethyl sterilizes more Element and dimehypo, wherein the weight ratio of ethyl pleocidin and dimehypo are 1:60~60:1.
The proportioning of ethyl pleocidin and dimehypo in the present composition can be according to specifically using situation in reasonable model It is adjusted in enclosing, such as ethyl pleocidin and weight ratio both dimehypo are 1:60~60:1、1:60~55:1、1:60 ~50:1、1:60~45:1、1:60~40:1、1:60~35:1、1:60~30:1、1:60~25:1、1:60~20:1、1:60 ~15:1、1:60~10:1、1:60~5:1、1:60~1:1、1:55~60:1、1:50~60:1、1:45~60:1、1:40~ 60:1、1:35~60:1、1:30~60:1、1:25~60:1、1:20~60:1、1:15~60:1、1:10~60:1、1:5~ 60:1、1:1~60:1、1:50~50:1、1:40~40:1、1:30~30:1、1:30~5:1、1:10~2:1 etc..At some In preferred scheme, the weight ratio of the two can be 1:60、1:50、1:45、1:40、1:39、1:38、1:37、1:36、1:35、1: 34、1:33、1:32、1:31、1:30、1:29、1:28、1:27、1:26、1:25、1:24、1:23、1:22、1:21、1:20、1: 19、1:18、1:17、1:16、1:15、1:14、1:13、1:12、1:11、1:10、1:9、1:8、1:7、1:6、1:5、1:4、1:3、 1:2、1:1、2:1、3:1、4:1、5:1、6:1、7:1、8:1、9:1、10:1、11:1、12:1、13:1、14:1、15:1、16:1、 17:1、18:1、19:1、20:1、21:1、22:1、23:1、24:1、25:1、26:1、27:1、28:1、29:1、30:1、35:1、 40:1、45:1、50:1 etc..
The mass content of active ingredient ethyl pleocidin and dimehypo can be 1~99% in the present composition, excellent Select 5~90%, further preferred 10~80%.
The composition of the present invention can be equipped with insecticides adjuvant, with ability using ethyl pleocidin and dimehypo as active ingredient Method known to technical staff in domain, acceptable formulation on agricultural chemicals is made, such as wettable powder, solvable pulvis, moisture dissipate Granula or suspending agent etc..
The composition of the present invention can be applied to prevent and treat striped rice borer in terms of murrain.
Field test shows, the existing medicament another mixed pesticide different from mechanism of action, can not only postpone resistance production It is raw, moreover it is possible to improve drug effect holding effect period, reduce usage amount, reduce times for spraying, reduce the dispenser cost of peasant, it is of the invention by second Quito bacteriocidin is compounded with dimehypo to expand insecticidal spectrum.Two kinds of effective ingredients are compounded, not only can effectively prevent and treat big portion Divide insect, reduce environmental pollution, additionally it is possible to improve drug effect and lasting period, reduce the labour cost of peasant, there is good warp Ji benefit.
The present invention is had the advantage that containing spinetoram insecticidal composition and beneficial effect:1st, insecticidal range is wide;2nd, hold The effect phase is grown;3rd, less toxic, low-residual is nuisanceless, environmentally safe;4th, using compound formulation, the dosage of two kinds of insecticides is than list One reduces when using, and so as to improve insecticidal effect, adds security, reduces environmental pollution.
Embodiment
In order to confirm ethyl pleocidin and dimehypo mixture, be with synergistic effect, summation action or antagonism, We have carried out recipe determination research to ethyl pleocidin and dimehypo first, and the object of indoor biometricses is set in China's water The striped rice borer of most serious is endangered in rice production, specific test situation and result are as follows:
Experiment medication uses 95% ethyl pleocidin active compound and 42% dimehypo mother's medicine, is dissolved active compound using solvent, According to the matched proportion density of setting, be configured to needed for concentration liquid it is standby, used dimehypo mother medicine is voluntarily produced by our company, Ethyl pleocidin and auxiliary agent are outsourcing.
The method of indoor biometricses is:Using capillary micro intravenous drip method, capillary micro intravenous drip device volume is 1.0 μ L.With Micro intravenous drip device by decoction by head drop in the back side of the instar larvae of striped rice borer 3, each concentration handles the larva of 30 or so, every 5 Head larva is put into a diameter of 9cm culture dish, and a small amount of feed built in ware supply feeding, separately by the use of 30 larvas of acetone drop as Control.Larva after processing is still placed in receptacle, and the death rate is checked after 48h.Data are handled with SPSS software statistics.Obtain Toxicity regression formula, the lethal concentration of 50, coefficient correlation etc., and obtain co-toxicity coefficient with the abundant methods of Sun Yun.
The co-toxicity of mixture preparation is represented using Sun Yunpei co-toxicity coefficient method:
Theoretical toxicity index TTI=Σ (medicine effective ingredients of the toxicity index ATI of certain medicine × in mixture of mixture preparation Percentage).
CTC is synergistic effect when being more than 120, is antagonism during less than 80, is addition when 80~120.
The ethyl pleocidin of table 1, dimehypo different ratio are to the toxicity test result of striped rice borer
Analyze above-mentioned data result to show, when ethyl pleocidin is compounded with dimehypo by different proportion, except A:B is 50:1 With 60:Outside 1 proportioning, the co-toxicity coefficient of all compounded formulas is all higher than 120, shows to be respectively provided with obvious synergistic effect.Explanation After two kinds of effective part compoundings, there can be good synergistic effect.Wherein proportioning 4, the co-toxicity coefficient of proportioning 5 are even more to be more than 200, For highest in all proportionings.
In order to verify the practical application effect of above formula, we carry out trial-manufacture of sample of knowing clearly from following proportioning, And field control effectiveness test is carried out.
Below with specific example of formulations to be further described the present invention, but the present invention be only limited to absolutely not it is following These embodiments.Percentage is weight percentage in formula.
Embodiment 1:30% ethyl pleocidin dimehypo wettable powder
Embodiment 2:50% ethyl pleocidin dimehypo water dispersible granules
Embodiment 3:30% ethyl pleocidin dimehypo suspending agent
Embodiment 4:50% ethyl pleocidin dimehypo water solution
Embodiment 5:11% ethyl pleocidin dimehypo suspending agent
Embodiment 6:80% ethyl pleocidin dimehypo water dispersible granules
By six embodiments of the above made from ethyl pleocidin and the various different ratios of dimehypo, carry out preventing and treating rice two Change the field control effectiveness test of snout moth's larva, while pass through the effect with 60 g/l of ethyl pleocidin suspending agents, the solvable aqua of 29% dimehypo Fruit contrasts, the synergistic effect after checking compounding.Test site is Jiangsu Province Xiangshui County Chen Jia Gang Hexin villages, and the time is 2015 7 The moon 15, experiment totally eight processing, a blank control, each handle three repetitions, cell random alignment, plot area 9* 5m2, the planting habits of all cells is identical with the planting habit of locality.
Investigation standard is:By 5 point samplings, random 5 points of samplings per cell, every is investigated 5 clumps, totally 25 clumps.Before dispenser With the 1st, 7,15 day after the dispenser Chilo spp larvae quantity for investigating 25 clumps of rice respectively, each instar larvae number is recorded, insect population is calculated and subtracts Move back rate prevention effect.Specific data (data are the average value of three repetitions) are as follows:
Table 2:The field control effectiveness test result of ethyl pleocidin, dimehypo single dose and complex preparation to rice-stem borer
As can be seen from the above data, under using identical effective ingredient dosage, ethyl pleocidin and dimehypo are not After proportioning compounding, Revision insect recluced rate, prevention effect will have obvious synergy to make apparently higher than two kinds of single doses, all formulas With.Revision insect recluced rate, prevention effect between each formula, without notable difference.When dimehypo content is high in formula, quick-acting compared with Good, lasting effect is general, and when ethyl pleocidin content is high in formula, quick-acting is general, and lasting effect is preferable, and this result is also true The characteristic of the two medicaments is reflected in fact.Find out from upper table data, complex preparation preventive effect of 7 days after medicine is higher than after medicine 1 day Preventive effect, the preventive effect of 15 days is greater than the preventive effect of 7 days after medicine after medicine.Compared with single dose, complex preparation extends the lasting period, reduces Times for spraying, alleviates peasant's amount of labour, reduces peasant's drug cost, there is preferable economic benefit.

Claims (10)

1. a kind of Pesticidal combination containing ethyl pleocidin and dimehypo, it is characterised in that said composition contains effective ingredient second The weight ratio of Quito bacteriocidin and dimehypo, wherein ethyl pleocidin and dimehypo is 1:60~30:1.
2. composition according to claim 1, it is characterised in that the weight of ethyl pleocidin and dimehypo ratio is 1:50 ~30:1.
3. composition according to claim 2, it is characterised in that the weight of ethyl pleocidin and dimehypo ratio is 1:30 ~30:1.
4. composition according to claim 3, it is characterised in that the weight of ethyl pleocidin and dimehypo ratio is 1:30 ~5:1.
5. composition according to claim 4, it is characterised in that the weight of ethyl pleocidin and dimehypo ratio is 1:20 ~2:1.
6. composition according to claim 1, it is characterised in that the matter of ethyl pleocidin and dimehypo in said composition It is 5~90% to measure content.
7. composition according to claim 6, it is characterised in that the matter of ethyl pleocidin and dimehypo in said composition It is 10~80% to measure content.
8. composition according to claim 1, it is characterised in that said composition is using ethyl pleocidin and dimehypo to have Composition is imitated, insecticides adjuvant is equipped with, acceptable formulation on agricultural chemicals is made.
9. composition according to claim 8, it is characterised in that the formulation is selected from wettable powder, solvable pulvis, water Dispersible granule or suspending agent.
10. the Pesticidal combination containing ethyl pleocidin and dimehypo described in claim 1 is in preventing and treating striped rice borer to crops Application in terms of harm.
CN201610110707.7A 2016-02-27 2016-02-27 Pesticidal combination containing ethyl pleocidin and dimehypo Expired - Fee Related CN105685042B (en)

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Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103651362A (en) * 2013-12-10 2014-03-26 济南凯因生物科技有限公司 Spinosad and bisultap suspoemulsion and application

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103651362A (en) * 2013-12-10 2014-03-26 济南凯因生物科技有限公司 Spinosad and bisultap suspoemulsion and application

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
绿色环保生物杀虫剂多杀霉素和乙基多杀菌素的述评;华乃震;《农药》;20150110;第54卷(第1期);第5页右栏 *

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Granted publication date: 20180327