CN107869074A - 一种用于纺织品印花的糊料的制备方法 - Google Patents

一种用于纺织品印花的糊料的制备方法 Download PDF

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CN107869074A
CN107869074A CN201711224361.4A CN201711224361A CN107869074A CN 107869074 A CN107869074 A CN 107869074A CN 201711224361 A CN201711224361 A CN 201711224361A CN 107869074 A CN107869074 A CN 107869074A
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劳吉清
姚金荣
毕晓芳
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Suzhou Runhong Trade Co Ltd
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    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/46General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing natural macromolecular substances or derivatives thereof
    • D06P1/48Derivatives of carbohydrates
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/46General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing natural macromolecular substances or derivatives thereof
    • D06P1/48Derivatives of carbohydrates
    • D06P1/50Derivatives of cellulose
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/64General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
    • D06P1/651Compounds without nitrogen
    • D06P1/65106Oxygen-containing compounds
    • D06P1/65125Compounds containing ester groups
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/653Nitrogen-free carboxylic acids or their salts
    • D06P1/6533Aliphatic, araliphatic or cycloaliphatic
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P3/00Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
    • D06P3/02Material containing basic nitrogen
    • D06P3/04Material containing basic nitrogen containing amide groups
    • D06P3/24Polyamides; Polyurethanes
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P3/00Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
    • D06P3/34Material containing ester groups
    • D06P3/52Polyesters

Abstract

本发明属于纺织助剂和精细化工技术领域,具体涉及一种用于纺织品印花的糊料的制备方法。本方法包括如下步骤:(1)将刺云实胶、瓜尔胶、罗望子胶和关华豆胶混合加入反应釜中,再加入水性增稠剂、乳化剂和分散剂,50℃下反应3小时;(2)加入油性乳化糊、醋酸铀酰锌钠和流变改性剂,40℃下反应2小时;(3)加入螯合剂(软水)、消泡剂及溶剂;(4)加入杀菌剂;(5)加入中和剂中和,然后加入去离子水,高速搅拌进行水分散;(6)加入后亲水扩链剂即得所述纺织糊料。通过不同的成胶材料的组合,在使用时糊料不会出现粘度降低的现象,不妨碍染料固着到纤维内,印花的花纹精细,品质优秀和成本较低。

Description

一种用于纺织品印花的糊料的制备方法
技术领域
本发明属于纺织助剂和精细化工技术领域,具体涉及一种用于纺织品印花的糊料的制备方法。
背景技术
纺织印花行业中的糊料,常指原糊,是纺织印花行业中的一种重要的原料,糊料是一种液相分散介质,是染料和填充料的载体,必须具有一定的粘性。糊料印花的印制效果与被印织物、印花方法以及由糊料和染料构成的印花色浆有密切的关系。近年来,用于印花糊料主成份的主要有淀粉、改性淀粉和海藻酸钠等。
但是目前的印花糊料适应性比较单一,仍然有很多的缺点。
发明内容
本发明要解决的技术问题是,针对现有技术不足,提出一种用于纺织品印花的糊料的制备方法。
本发明为解决上述技术问题提出的技术方案是:
一种用于纺织品印花的糊料的制备方法的制备方法,包括如下步骤:
(1)将刺云实胶、瓜尔胶、罗望子胶和关华豆胶四种单体按质量比3:5:6:6混合加入反应釜中,50℃下搅拌均匀,再加入水性增稠剂、乳化剂和分散剂,50℃下反应3小时;
(2)加入油性乳化糊、醋酸铀酰锌钠和流变改性剂,40℃下反应2小时;
(3)加入螯合剂(软水)、消泡剂及溶剂,30℃下反应3小时;
(4)加入杀菌剂,50℃下反应4小时,形成初步混合物;
(5)将所述混合物降温至40℃,加入中和剂中和,然后加入去离子水,高速搅拌进行水分散;
(6)加入后亲水扩链剂,恒温搅拌3小时,即得所述纺织糊料。
本发明中,以印花糊料总重量计算,所述油性乳化糊、醋酸铀酰锌钠和流变改性剂加入量为10~20%,所述杀菌剂总为0.2~0.9%的。
本发明中,所述流变改性剂为三甘油酯,以印花糊料总重量计算,再加入用量为0.3‰~2%,所述杀菌剂为苯酚;
本发明中,以印花糊料的总重量计算,所述成胶部分的含量不低于80%,所述印花糊料的成糊率是在6~10%。
本发明中,所述醋酸铀酰锌钠加入量为4~10%,以印花糊料总重量计算。
本发明中,所述印花糊料用于锦纶和涤纶的印花。
本发明中,所述水性增稠剂为取代度在0.6-3之间的羧甲基纤维素。
本发明中,所述印花糊料用于锦纶和涤纶的印花。
本发明的有益效果在于:通过不同的成胶材料的组合,在使用时糊料不会出现粘度降低的现象,不妨碍染料固着到纤维内,印花的花纹精细,品质优秀和成本较低。
具体实施方式
下面通过具体的实施例对本发明进行详细说明,但这些例举性实施方式的用途和目的仅用来例举本发明,并非对本发明的实际保护范围构成任何形式的任何限定,更非将本发明的保护范围局限于此。
一种用于纺织品印花的糊料的制备方法的制备方法,包括如下步骤:
(1)将刺云实胶、瓜尔胶、罗望子胶和关华豆胶四种单体按质量比3:5:6:6混合加入反应釜中,50℃下搅拌均匀,再加入水性增稠剂、乳化剂和分散剂,50℃下反应3小时;
(2)加入油性乳化糊、醋酸铀酰锌钠和流变改性剂,40℃下反应2小时;
(3)加入螯合剂(软水)、消泡剂及溶剂,30℃下反应3小时;
(4)加入杀菌剂,50℃下反应4小时,形成初步混合物;
(5)将所述混合物降温至40℃,加入中和剂中和,然后加入去离子水,高速搅拌进行水分散;
(6)加入后亲水扩链剂,恒温搅拌3小时,即得所述纺织糊料。
本发明中,以印花糊料总重量计算,所述油性乳化糊、醋酸铀酰锌钠和流变改性剂加入量为10~20%,所述杀菌剂总为0.2~0.9%的。
本发明中,所述流变改性剂为三甘油酯,以印花糊料总重量计算,再加入用量为0.3‰~2%,所述杀菌剂为苯酚;
本发明中,以印花糊料的总重量计算,所述成胶部分的含量不低于80%,所述印花糊料的成糊率是在6~10%。
所述醋酸铀酰锌钠加入量为4~10%,以印花糊料总重量计算。
所述印花糊料用于锦纶和涤纶的印花。
所述水性增稠剂为取代度在0.6-3之间的羧甲基纤维素。
本发明中,所述印花糊料用于锦纶和涤纶的印花。
本发明不局限于上述实施例,凡采用等同替换形成的技术方案,均落在本发明的保护范围。

Claims (6)

1.一种用于纺织品印花的糊料的制备方法的制备方法,其特征在于:
(1)将刺云实胶、瓜尔胶、罗望子胶和关华豆胶四种单体按质量比3:5:6:6混合加入反应釜中,50℃下搅拌均匀,再加入水性增稠剂、乳化剂和分散剂,50℃下反应3小时;
(2)加入油性乳化糊、醋酸铀酰锌钠和流变改性剂,40℃下反应2小时;
(3)加入螯合剂(软水)、消泡剂及溶剂,30℃下反应3小时;
(4)加入杀菌剂,50℃下反应4小时,形成初步混合物;
(5)将所述混合物降温至40℃,加入中和剂中和,然后加入去离子水,高速搅拌进行水分散;
(6)加入后亲水扩链剂,恒温搅拌3小时,即得所述纺织糊料。
2.根据权利要求1所述的一种用于纺织品印花的糊料的制备方法,其特征在于:以印花糊料总重量计算,所述油性乳化糊、醋酸铀酰锌钠和流变改性剂加入量为10~20%,所述杀菌剂总为0.2~0.9%的。
3.根据权利要求1所述的一种用于纺织品印花的糊料的制备方法,其特征在于:所述流变改性剂为三甘油酯,以印花糊料总重量计算,再加入用量为0.3‰~2%,所述杀菌剂为苯酚;
根据权利要求1所述的一种用于纺织品印花的糊料的制备方法,其特征在于:以印花糊料的总重量计算,所述成胶部分的含量不低于80%,所述印花糊料的成糊率是在6~10%。
4.根据权利要求1所述的一种用于纺织品印花的糊料的制备方法,其特征在于:所述醋酸铀酰锌钠加入量为4~10%,以印花糊料总重量计算。
5.根据权利要求1所述的一种用于纺织品印花的糊料的制备方法,其特征在于:所述印花糊料用于锦纶和涤纶的印花。
6.根据权利要求1所述的一种用于纺织品印花的糊料的制备方法,其特征在于:所述水性增稠剂为取代度在0.6-3之间的羧甲基纤维素。
CN201711224361.4A 2017-11-29 2017-11-29 一种用于纺织品印花的糊料的制备方法 Pending CN107869074A (zh)

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Application publication date: 20180403