CN107853338A - A kind of medicament for walking quickly and keeping away ant and preparation method thereof - Google Patents

A kind of medicament for walking quickly and keeping away ant and preparation method thereof Download PDF

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Publication number
CN107853338A
CN107853338A CN201711343892.5A CN201711343892A CN107853338A CN 107853338 A CN107853338 A CN 107853338A CN 201711343892 A CN201711343892 A CN 201711343892A CN 107853338 A CN107853338 A CN 107853338A
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Prior art keywords
parts
medicament
keeping away
ant
standby
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李文
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Liuzhou Liu Ke Science And Technology Co Ltd
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Liuzhou Liu Ke Science And Technology Co Ltd
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    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N65/00Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N63/00Biocides, pest repellants or attractants, or plant growth regulators containing microorganisms, viruses, microbial fungi, animals or substances produced by, or obtained from, microorganisms, viruses, microbial fungi or animals, e.g. enzymes or fermentates
    • A01N63/10Animals; Substances produced thereby or obtained therefrom
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N65/00Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
    • A01N65/40Liliopsida [monocotyledons]
    • A01N65/44Poaceae or Gramineae [Grass family], e.g. bamboo, lemon grass or citronella grass
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A50/00TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
    • Y02A50/30Against vector-borne diseases, e.g. mosquito-borne, fly-borne, tick-borne or waterborne diseases whose impact is exacerbated by climate change

Abstract

The present invention relates to ant technical field of insecticide, more particularly to a kind of medicament for walking quickly and keeping away ant and preparation method thereof, mainly it is made up of raw materials such as 20 25 parts of 16 17 parts of camphortree leaf, 15 17 parts of Walnut Leaves, 16 18 parts of tobacco leaf, 13 15 parts of Basil, 14 16 parts of flame nettle, 10 15 parts of freshwater mussel orchid, 11 12 parts of lantana, 10 13 parts of canna, 10 11 parts of tansy, 9 10 parts of rue, 8 10 parts of peppermint, 68 parts of cloves, 34 parts of Chinese cassia tree, 57 parts of black green pepper, 57 parts of egg shell powder and organic solvents.The medicament has the effect of significantly walking quickly and keeping away and tag ant, extends the resting period of medicament, reduces the use of chemicals, reduces the security threat to environment, the mankind, and its preparation method is simple, easily production.

Description

A kind of medicament for walking quickly and keeping away ant and preparation method thereof
Technical field
The present invention relates to ant technical field of insecticide, and in particular to a kind of medicament for walking quickly and keeping away ant and preparation method thereof.
Background technology
Ant is one of main cities insect, and its species is various, and ant can enter in room, kitchen, toilet and balcony Cement (cemented) joint in, ceramic tile behind, flowerpot nearby be all they survive hotbed.Due to indoor ant meeting contaminated food, destruction is built Build, spread germs, bite human body, therefore human lives can be caused with certain harm.The existing articles for use species for killing ant is very It is more, have various granules, tablet, propellant etc., but it is but and few to walk quickly and keep away the medicine of ant, and the ant medicament of in the market into Divide mainly synthetics, medicament is expensive, and also has to environment and pollute, it could even be possible to ant takes medicine to people Things in, the health of people will be damaged.
The content of the invention
The goal of the invention of the present invention is:For above-mentioned problem, there is provided a kind of medicament and its system for walking quickly and keeping away ant Preparation Method, the medicament have the effect of significantly walking quickly and keeping away and tag ant, extend the resting period of medicament, reduce chemicals Use, reduce the security threat to environment, the mankind, and its preparation method is simple, easily production.
To achieve these goals, the technical solution adopted by the present invention is as follows:
A kind of medicament for walking quickly and keeping away ant, is mainly made up of following raw material:Camphortree leaf 16-17 parts, Walnut Leaves 15-17 Part, tobacco leaf 16-18 parts, Basil 13-15 parts, flame nettle 14-16 parts, freshwater mussel orchid 10-15 parts, lantana 11-12 parts, canna 10-13 parts, tansy 10-11 parts, rue 9-10 parts, peppermint 8-10 parts, cloves 6-8 parts, Chinese cassia tree 3-4 parts, black green pepper 5-7 parts, egg Shell powder 5-7 parts and organic solvent 20-25 parts.
Preferably, mainly it is made up of following raw material:16.5 parts of camphortree leaf, 16 parts of Walnut Leaves, 17 parts, nine layers of tobacco leaf 14 parts of tower, 15 parts of flame nettle, 13 parts of freshwater mussel orchid, 11.5 parts of lantana, 12 parts of canna, 10.5 parts of tansy, 9.5 parts of rue, peppermint 9 23 parts of part, 7 parts of cloves, 3.5 parts of Chinese cassia tree, 6 parts of black green pepper, 6 parts of egg shell powder and organic solvent.
Preferably, the organic solvent includes polyethylene glycol, ethylene glycol ether acetate and light-coloured vinegar.
Preferably, the volume ratio of polyethylene glycol, ethylene glycol ether acetate and light-coloured vinegar is 1-2:1:2-3.
The preparation method of the medicament as described above for walking quickly and keeping away ant, specifically includes following steps:
(1) fresh camphortree leaf, Walnut Leaves, tobacco leaf, Basil, flame nettle, freshwater mussel orchid, lantana, canna, Chinese mugwort are plucked The branches and leaves removal of impurities of chrysanthemum, rue, peppermint, cloves and Chinese cassia tree is cleaned, and chopping is standby;
(2) raw material after step (1) is shredded smashs filtered juice to pieces, obtains juice and filter residue, standby;
(3) filter residue in step (2) is added into distilled water and is heated to 40- in evaporimeter to filter residue surface, transposition is not crossed 60 DEG C, water soldier takes 20-30min, obtains water soldier and takes liquid and soldier to take slag charge, standby;
(4) taken toward the soldier in step (3) and organic solvent is added in slag charge, 15-20min is stood after being uniformly mixed, then Transposition finally takes 40-50min in Rotary Evaporators at 40-50 DEG C, obtains solvent soldier and takes liquid, standby;
(5) after taking liquid and the solvent of step (4) finally to take liquid well mixed the water soldier of the juice of step (2), step (3), 20-30min is stood, through centrifugal filtration, obtains plant extraction liquid, it is standby;
(6) plant extraction liquid of step (5) is subjected to vacuum refrigeration concentration, concentrate is granulated, sieved, obtained Grain, it is standby;
(7) by egg shell burn it is defocused be ground into egg shell powder, black green pepper is ground into black after drying and being less than 4% to moisture Green pepper powder, egg shell powder and black green pepper powder are uniformly mixed, obtain mixed powder, it is standby;
(8) particle in step (6) and the mixed powder in step (7) are well mixed, obtain the medicine for walking quickly and keeping away ant Agent.
Preferably, the solid material concentration of concentrate described in step (6) is 60-70%, grain diameter 0.7-1mm.
In summary, by adopting the above-described technical solution, the beneficial effects of the invention are as follows:
The medicament for walking quickly and keeping away ant of the present invention is mainly by camphortree leaf, Walnut Leaves, tobacco leaf, Basil, flame nettle, freshwater mussel orchid, horse The raw materials such as tassel pellet, canna, tansy, rue, peppermint, cloves, Chinese cassia tree, black green pepper, egg shell powder, organic solvent are made.Wherein, camphor tree Leaf has the effect of dispelling wind and eliminating dampness, clearing heat and detoxicating, antibacterial desinsection, and it has more endurable Volatilized smell, effectively extends and walks quickly and keeps away Time;Walnut Leaves are poisonous, have the function that desinsection, there is volatile flavor;Tobacco leaf has the function that subdhing swelling and detoxicating, desinsection, waves Hair property smell;Basil has a strong Chinese anise taste, tool expelling wind to resolve the exterior, dampness elimination and in, the promoting flow of qi and blood circulation, the work(of removing toxicity for detumescence Effect;Flame nettle is slightly poisonous, and touching back causes itch;Freshwater mussel is blue to have clearing heat and detoxicating, removing blood stasis and hemostasis and other effects;Part contained by it has Effect composition can effectively walk quickly and keep away ant;Lantana has toxicity, there is pesticide-germicide;Canna contains volatile flavor;Chinese mugwort Chrysanthemum contains insect killing substance, poisonous, contains volatile flavor;Rue contains distinctive fragrance, there is desinsection insect-expelling function;Peppermint, which contains, to be waved Hair property smell, green gas fragrance, there is anthelminthic effect;Cloves contains distinctive fragrance, there is pesticide-germicide effect;Chinese cassia tree tool fragrance, taste Sweet tea and it is peppery, it is slightly poisonous, have anthelminthic effect;Black pepper-flavor is peppery, there is anthelminthic effect;Egg shell powder has insecticidal action after burning;It is organic molten The soldier that agent can improve active ingredient takes rate, moreover it is possible to improves the volatility of medicament, propagates smell farther;The phase between last material Mutually synergy so that medicament has special volatile flavor, and these special odors can effectively walk quickly and keep away ant, toxic, energy Directly tag ant, is also acted on restraining and sterilizing bacteria, extends the resting period of medicament, reduces the use of chemicals, reduction pair Environment, the security threat of the mankind.
Embodiment
Technical scheme will be clearly and completely described below, it is clear that described embodiment is only Part of the embodiment of the present invention, rather than whole embodiments.Based on the embodiment in the present invention, those of ordinary skill in the art The every other embodiment obtained under the premise of creative work is not made, belongs to the scope of protection of the invention.
Unless otherwise defined, all of technologies and scientific terms used here by the article is with belonging to technical field of the invention The implication that technical staff is generally understood that is identical.Term used in the description of the invention herein is intended merely to description tool The purpose of the embodiment of body, it is not intended that in the limitation present invention.Term as used herein " and/or " include one or more phases The arbitrary and all combination of the Listed Items of pass.
Embodiment 1
A kind of medicament for walking quickly and keeping away ant, is mainly made up of following raw material:16 parts of camphortree leaf, 15 parts of Walnut Leaves, cigarette 16 parts of leaf, 13 parts of Basil, 14 parts of flame nettle, freshwater mussel are blue 10 parts, 11 parts of lantana, 10 parts of canna, 10 parts of tansy, 9 parts of rue, 20 parts of 8 parts of peppermint, 6 parts of cloves, 3 parts of Chinese cassia tree, 5 parts of black green pepper, 5 parts of egg shell powder and organic solvent;
Wherein, organic solvent includes polyethylene glycol, ethylene glycol ether acetate and light-coloured vinegar, and polyethylene glycol, ethylene glycol ethyl ethers The volume ratio of ether acetate and light-coloured vinegar is 1:1:2.
The expectation of said ratio is prepared to the medicament for walking quickly and keeping away ant using following methods, specifically includes following steps:
(1) fresh camphortree leaf, Walnut Leaves, tobacco leaf, Basil, flame nettle, freshwater mussel orchid, lantana, canna, Chinese mugwort are plucked The branches and leaves removal of impurities of chrysanthemum, rue, peppermint, cloves and Chinese cassia tree is cleaned, and chopping is standby;
(2) raw material after step (1) is shredded smashs filtered juice to pieces, obtains juice and filter residue, standby;
(3) filter residue in step (2) is added into distilled water and is heated to 40 in evaporimeter to filter residue surface, transposition is not crossed DEG C, water soldier takes 20min, obtains water soldier and takes liquid and soldier to take slag charge, standby;
(4) taken toward the soldier in step (3) and organic solvent is added in slag charge, 15min, then transposition are stood after being uniformly mixed In in Rotary Evaporators, 40min is finally taken at 40 DEG C, solvent soldier is obtained and takes liquid, it is standby;
(5) after taking liquid and the solvent of step (4) finally to take liquid well mixed the water soldier of the juice of step (2), step (3), 20min is stood, through centrifugal filtration, obtains plant extraction liquid, it is standby;
(6) plant extraction liquid of step (5) is subjected to vacuum refrigeration concentration, the solid material concentration of obtained concentrate is 60%, concentrate is granulated, sieved, obtains the particle that particle diameter is 0.7mm, it is standby;
(7) by egg shell burn it is defocused be ground into egg shell powder, black green pepper is ground into black after drying and being less than 4% to moisture Green pepper powder, egg shell powder and black green pepper powder are uniformly mixed, obtain mixed powder, it is standby;
(8) particle in step (6) and the mixed powder in step (7) are well mixed, obtain the medicine for walking quickly and keeping away ant Agent.
Embodiment 2
A kind of medicament for walking quickly and keeping away ant, is mainly made up of following raw material:16.5 parts of camphortree leaf, 16 parts of Walnut Leaves, 17 parts of tobacco leaf, 14 parts of Basil, 15 parts of flame nettle, 13 parts of freshwater mussel orchid, 11.5 parts of lantana, 12 parts of canna, 10.5 parts of tansy, rue 23 parts of fragrant 9.5 parts, 9 parts of peppermint, 7 parts of cloves, 3.5 parts of Chinese cassia tree, 6 parts of black green pepper, 6 parts of egg shell powder and organic solvent;
Wherein, organic solvent includes polyethylene glycol, ethylene glycol ether acetate and light-coloured vinegar, and polyethylene glycol, ethylene glycol ethyl ethers The volume ratio of ether acetate and light-coloured vinegar is 1.5:1:2.5.
The expectation of said ratio is prepared to the medicament for walking quickly and keeping away ant using following methods, specifically includes following steps:
(1) fresh camphortree leaf, Walnut Leaves, tobacco leaf, Basil, flame nettle, freshwater mussel orchid, lantana, canna, Chinese mugwort are plucked The branches and leaves removal of impurities of chrysanthemum, rue, peppermint, cloves and Chinese cassia tree is cleaned, and chopping is standby;
(2) raw material after step (1) is shredded smashs filtered juice to pieces, obtains juice and filter residue, standby;
(3) filter residue in step (2) is added into distilled water and is heated to 45 in evaporimeter to filter residue surface, transposition is not crossed DEG C, water soldier takes 25min, obtains water soldier and takes liquid and soldier to take slag charge, standby;
(4) taken toward the soldier in step (3) and organic solvent is added in slag charge, 17min, then transposition are stood after being uniformly mixed In in Rotary Evaporators, 45min is finally taken at 45 DEG C, solvent soldier is obtained and takes liquid, it is standby;
(5) after taking liquid and the solvent of step (4) finally to take liquid well mixed the water soldier of the juice of step (2), step (3), 25min is stood, through centrifugal filtration, obtains plant extraction liquid, it is standby;
(6) plant extraction liquid of step (5) is subjected to vacuum refrigeration concentration, the solid material concentration of obtained concentrate is 65%, concentrate is granulated, sieved, obtains the particle that particle diameter is 0.85mm, it is standby;
(7) by egg shell burn it is defocused be ground into egg shell powder, black green pepper is ground into black after drying and being less than 4% to moisture Green pepper powder, egg shell powder and black green pepper powder are uniformly mixed, obtain mixed powder, it is standby;
(8) particle in step (6) and the mixed powder in step (7) are well mixed, obtain the medicine for walking quickly and keeping away ant Agent.
Embodiment 3
A kind of medicament for walking quickly and keeping away ant, is mainly made up of following raw material:17 parts of camphortree leaf, 17 parts of Walnut Leaves, cigarette 18 parts of leaf, 15 parts of Basil, 16 parts of flame nettle, 15 parts of freshwater mussel orchid, 12 parts of lantana, 13 parts of canna, 11 parts of tansy, rue 10 25 parts of part, 10 parts of peppermint, 8 parts of cloves, 4 parts of Chinese cassia tree, 7 parts of black green pepper, 7 parts of egg shell powder and organic solvent;
Wherein, organic solvent includes polyethylene glycol, ethylene glycol ether acetate and light-coloured vinegar, and polyethylene glycol, ethylene glycol ethyl ethers The volume ratio of ether acetate and light-coloured vinegar is 2:1:3.
The expectation of said ratio is prepared to the medicament for walking quickly and keeping away ant using following methods, specifically includes following steps:
(1) fresh camphortree leaf, Walnut Leaves, tobacco leaf, Basil, flame nettle, freshwater mussel orchid, lantana, canna, Chinese mugwort are plucked The branches and leaves removal of impurities of chrysanthemum, rue, peppermint, cloves and Chinese cassia tree is cleaned, and chopping is standby;
(2) raw material after step (1) is shredded smashs filtered juice to pieces, obtains juice and filter residue, standby;
(3) filter residue in step (2) is added into distilled water and is heated to 60 in evaporimeter to filter residue surface, transposition is not crossed DEG C, water soldier takes 30min, obtains water soldier and takes liquid and soldier to take slag charge, standby;
(4) taken toward the soldier in step (3) and organic solvent is added in slag charge, 20min, then transposition are stood after being uniformly mixed In in Rotary Evaporators, 50min is finally taken at 50 DEG C, solvent soldier is obtained and takes liquid, it is standby;
(5) after taking liquid and the solvent of step (4) finally to take liquid well mixed the water soldier of the juice of step (2), step (3), 30min is stood, through centrifugal filtration, obtains plant extraction liquid, it is standby;
(6) plant extraction liquid of step (5) is subjected to vacuum refrigeration concentration, the solid material concentration of obtained concentrate is 70%, concentrate is granulated, sieved, obtains the particle that particle diameter is 1mm, it is standby;
(7) by egg shell burn it is defocused be ground into egg shell powder, black green pepper is ground into black after drying and being less than 4% to moisture Green pepper powder, egg shell powder and black green pepper powder are uniformly mixed, obtain mixed powder, it is standby;
(8) particle in step (6) and the mixed powder in step (7) are well mixed, obtain the medicine for walking quickly and keeping away ant Agent.
In order to prove the effect of medicament of the present invention, medicament made from embodiment 1-3 and commercially available medicament experiment pair has been subjected to Than carry out ant daily walks quickly and keeps away rate, the statistics of the death rate, and test period is 3 days, as a result as shown in table 1.
As known from Table 1, medicament of the invention have it is significant walk quickly and keep away and tag ant the effect of, ant walks quickly and keeps away rate and dead The rate of dying is significantly improved, and extends the effective storage life of medicament, and drug effect is still notable after three days, reduces making for chemicals With reducing the security threat to environment, the mankind.
The ant of table 1 walks quickly and keeps away rate and the death rate
Described above is the detailed description for the present invention preferably possible embodiments, but embodiment is not limited to this hair Bright patent claim, the equal change completed or modification change under the technical spirit suggested by all present invention, all should belong to Cover the scope of the claims in the present invention.

Claims (6)

1. a kind of medicament for walking quickly and keeping away ant, it is characterised in that be mainly made up of following raw material:Camphortree leaf 16-17 parts, core Peach leaf 15-17 parts, tobacco leaf 16-18 parts, Basil 13-15 parts, flame nettle 14-16 parts, freshwater mussel orchid 10-15 parts, lantana 11-12 Part, canna 10-13 parts, tansy 10-11 parts, rue 9-10 parts, peppermint 8-10 parts, cloves 6-8 parts, Chinese cassia tree 3-4 parts, black green pepper 5- 7 parts, egg shell powder 5-7 parts and organic solvent 20-25 parts.
2. the medicament according to claim 1 for walking quickly and keeping away ant, it is characterised in that be mainly made up of following raw material: 16.5 parts of camphortree leaf, 16 parts of Walnut Leaves, 17 parts of tobacco leaf, 14 parts of Basil, 15 parts of flame nettle, freshwater mussel are blue 13 parts, 11.5 parts of lantana, 12 parts of canna, 10.5 parts of tansy, 9.5 parts of rue, 9 parts of peppermint, 7 parts of cloves, 3.5 parts of Chinese cassia tree, 6 parts of black green pepper, 6 parts of egg shell powder And 23 parts of organic solvent.
3. the medicament according to claim 1 or 2 for walking quickly and keeping away ant, it is characterised in that:The organic solvent includes poly- second two Alcohol, ethylene glycol ether acetate and light-coloured vinegar.
4. the medicament according to claim 3 for walking quickly and keeping away ant, it is characterised in that:Polyethylene glycol, ethylene glycol ether acetate And the volume ratio of light-coloured vinegar is 1-2:1:2-3.
5. the preparation method of the medicament for walking quickly and keeping away ant according to any one of claim 1-4, it is characterised in that specific bag Include following steps:
(1) fresh camphortree leaf, Walnut Leaves, tobacco leaf, Basil, flame nettle, freshwater mussel orchid, lantana, canna, tansy, rue are plucked Perfume, peppermint, cloves and the removal of impurities of the branches and leaves of Chinese cassia tree are cleaned, and chopping is standby;
(2) raw material after step (1) is shredded smashs filtered juice to pieces, obtains juice and filter residue, standby;
(3) filter residue in step (2) is added into distilled water and is heated to 40-60 in evaporimeter to filter residue surface, transposition is not crossed DEG C, water soldier takes 20-30min, obtains water soldier and takes liquid and soldier to take slag charge, standby;
(4) taken toward the soldier in step (3) and organic solvent is added in slag charge, 15-20min, then transposition are stood after being uniformly mixed In in Rotary Evaporators, 40-50min is finally taken at 40-50 DEG C, solvent soldier is obtained and takes liquid, it is standby;
(5) after taking liquid and the solvent of step (4) finally to take liquid well mixed the water soldier of the juice of step (2), step (3), stand 20-30min, through centrifugal filtration, plant extraction liquid is obtained, it is standby;
(6) plant extraction liquid of step (5) is subjected to vacuum refrigeration concentration, concentrate is granulated, sieved, obtains particle, It is standby;
(7) by egg shell burn it is defocused be ground into egg shell powder, black green pepper is ground into black green pepper after drying and being less than 4% to moisture Powder, egg shell powder and black green pepper powder are uniformly mixed, obtain mixed powder, it is standby;
(8) particle in step (6) and the mixed powder in step (7) are well mixed, obtain the medicament for walking quickly and keeping away ant.
6. the preparation method of the medicament according to claim 5 for walking quickly and keeping away ant, it is characterised in that:It is dense described in step (6) The solid material concentration of contracting liquid is 60-70%, grain diameter 0.7-1mm.
CN201711343892.5A 2017-12-15 2017-12-15 A kind of medicament for walking quickly and keeping away ant and preparation method thereof Pending CN107853338A (en)

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CN109527002A (en) * 2018-12-13 2019-03-29 集美大学 Plant source repellent and its preparation method and application and red fire ant walk quickly and keep away method
CN112293432A (en) * 2020-11-27 2021-02-02 中国热带农业科学院椰子研究所 Ant blocking agent
CN115553162A (en) * 2021-07-01 2023-01-03 深圳小洲生态环境有限公司 Prevention and treatment method for solenopsis invicta in forest farmland

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Application publication date: 20180330