CN104872218B - A kind of natural family's insecticide containing Tsubaki-saponin - Google Patents
A kind of natural family's insecticide containing Tsubaki-saponin Download PDFInfo
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- CN104872218B CN104872218B CN201510316256.8A CN201510316256A CN104872218B CN 104872218 B CN104872218 B CN 104872218B CN 201510316256 A CN201510316256 A CN 201510316256A CN 104872218 B CN104872218 B CN 104872218B
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
- Y02A50/30—Against vector-borne diseases, e.g. mosquito-borne, fly-borne, tick-borne or waterborne diseases whose impact is exacerbated by climate change
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Abstract
The invention discloses a kind of natural family's insecticide containing Tsubaki-saponin, it is mixed and made into the natural family insecticide using Tsubaki-saponin, subprostrate sophora, south Sinkiang ziziphora herb, eucalyptus citriodora, rhizoma zingiberis, hairyvein agrimony, tomato, polygonum flaccidum, marigold as primary raw material after extracted.Contain the main components such as alkaloid, flavones, saponin(e in plant used in the present invention, make the natural family's insecticide of gained that there is good bactericidal, above all to mosquitos and flies in family, spider and it is potted plant in insect have and preferably walk quickly and keep away, kill except effect, and its security is good, it is free from environmental pollution, one good family life environment can be provided, there are preferable market prospects.
Description
Technical field
The invention belongs to daily-use chemical industry technical field, and in particular to a kind of natural family's insecticide containing Tsubaki-saponin.
Background technology
Many insects and bacterium, the growth and breeding meeting of insect are often concealed with the environment such as food in the family, potted plant
Have a strong impact on the health and quality of life of human body, and the method for wiping out and treating insect pests and plant diseases of these insects is mainly used and synthesized with artificial chemistry at present
Compound insecticide is made for raw material.However, touching insecticide for a long time by modes such as breathing, skins, influence whether
The health of people, increasing the P of their respiratory disorders, the particularly influence to children and the elderly is bigger, meanwhile, chemistry
A large amount of use of insecticide not only makes the resistance of insect constantly strengthen, insecticide deinsectization decreased effectiveness, and chemical insecticide poison
Property it is big, the residence time length, very big harm is often brought to environment.Prepared using natural plant extracts as main raw material(s)
Insecticide is safe, good disinsection effect, while Activities of Some Plants used contains volatile ingredient, when in use can be with pure and fresh sky
Gas, there is the characteristics of green, safe and environment-friendly, efficient non-resistant, be the new focus for developing Domestic two insecticide.
The content of the invention
It is an object of the invention to provide a kind of natural family's insecticide containing Tsubaki-saponin, it is using natural plants as former material
Material, the natural family's insecticide of gained contain abundant expelling parasite, deinsectization, sterilization, antibacterial active component, it is most important that in family
Mosquitos and flies, spider and it is potted plant in insect have and preferably walk quickly and keep away, kill except effect, and its security is good, free from environmental pollution, can be with
One good family life environment is provided.
To achieve the above object, the present invention adopts the following technical scheme that：
A kind of natural family's insecticide containing Tsubaki-saponin, its primary raw material used include by weight：Tsubaki-saponin
4-8 parts, subprostrate sophora 3-6 parts, south Sinkiang ziziphora herb 1-3 parts, eucalyptus citriodora 1-3 parts, rhizoma zingiberis 1-3 parts, hairyvein agrimony 1-3 parts, tomato 1-3 parts,
Polygonum flaccidum 1-3 parts, marigold 1-3 parts, enpara class propellant 65-75 parts.
The preparation method of the Tsubaki-saponin is：Oleifera dry cake after crushing is pressed into solid-liquid ratio 1:12, which add mass concentrations, is
65% ethanol solution extraction 1.6h, extraction temperature is 60 DEG C, and ultrafiltration is carried out after extraction, collects filtrate.
Natural family's method for producing insecticide containing Tsubaki-saponin comprises the following steps：
1）The processing of subprostrate sophora：It is 1 that drying subprostrate sophora powder after crushing is pressed into solid-liquid ratio:10 add mass concentration as 70%
Ethanol solution, and adjust its pH as 3.1, ultrasound extraction 3 times, each 1.2h, Extracting temperature is 35 DEG C, is carried out after extract smart
Filter, and concentrate the filtrate to the 1/4 of former filtrate volume；
2）Hairyvein agrimony, the processing of rhizoma zingiberis, south Sinkiang ziziphora herb, eucalyptus citriodora, tomato, polygonum flaccidum：Respectively by hairyvein agrimony, rhizoma zingiberis, leaflet
Peppermint, eucalyptus citriodora, tomato, polygonum flaccidum are dry, crush, by solid-liquid ratio 1:10 add the ethanol solution that mass concentration is 70%, extraction
1.5h, extraction temperature are 80 DEG C, are then filtered, and filter residue extracts one again with the ethanol solution that mass concentration is 40% with similarity condition
It is secondary, filtering, ultrafiltration is carried out after merging filtrate twice；
3）The processing of marigold：Dry marigold is pressed into solid-liquid ratio 1:30 add alcoholic solution, ultrasound extraction 40min, carry
It is 50 DEG C to take temperature, filtering after having extracted, and ultrafiltration is once, then concentrates filtrate to the 1/3 of former filtrate volume；The alcohol
Methanol content is 30wt%, ethanol content 40wt% in solution；
4）The preparation of insecticide：By subprostrate sophora, south Sinkiang ziziphora herb, eucalyptus citriodora, rhizoma zingiberis, hairyvein agrimony, tomato, polygonum flaccidum, marigold
Extract solution add 3 ~ 5 times of extracting liquid volume deionized water in, add Tsubaki-saponin stirring 30min, then by mixed liquor
Injected by specification in container, valve system is loaded onto, evacuated, enpara propellant is injected by valve, by upper promotion button, system
Obtain finished product.
The use of Tsubaki-saponin can not only influence the nervous system of insect in the present invention, have an effect on a series of its Physiology and biochemistry
Function, so as to reach expelling parasite, desinsection effect；The compositions such as the alkaloid that contains in subprostrate sophora, flavones, saponin(e, contain in rhizoma zingiberis
Gingerol, the dilute phenol of ginger, zingiberone, the agrimophol contained in hairyvein agrimony, the guaiol contained in eucalyptus citriodora, contain in Azalea pontica
Chinese azalea extract, eicolin, the alkaloid contained in tomato, the herba sophorae alopecuroide alkaloid contained in herba sophorae alopecuroide, the sugar contained in polygonum flaccidum
Glycosides, dehydrogenation flavones, three thiophene, the furans acetylene contained in marigold, the pulegone contained in south Sinkiang ziziphora herb etc. are respectively provided with not
Expelling parasite, insecticidal action with degree, particularly to the mosquitos and flies in family, spider and it is potted plant in insect have preferably walk quickly and keep away,
Kill except effect.Meanwhile insecticide of the present invention is using botanical extract as main component, not only good disinsection effect, and security
Preferably, it is free from environmental pollution, a good family life environment can be provided.
Embodiment
In order that content of the present invention easily facilitates understanding, with reference to embodiment to of the present invention
Technical scheme is described further, but the present invention is not limited only to this.
A kind of natural family's insecticide containing Tsubaki-saponin, its primary raw material used include by weight：Tsubaki-saponin
4-8 parts, subprostrate sophora 3-6 parts, south Sinkiang ziziphora herb 1-3 parts, eucalyptus citriodora 1-3 parts, rhizoma zingiberis 1-3 parts, hairyvein agrimony 1-3 parts, tomato 1-3 parts,
Polygonum flaccidum 1-3 parts, marigold 1-3 parts, enpara class propellant 65-75 parts.
The preparation method of the Tsubaki-saponin is：Oleifera dry cake after crushing is pressed into solid-liquid ratio 1:12, which add mass concentrations, is
65% ethanol solution extraction 1.6h, extraction temperature is 60 DEG C, and ultrafiltration is carried out after extraction, collects filtrate.
Natural family's method for producing insecticide containing Tsubaki-saponin comprises the following steps：
1）The processing of subprostrate sophora：It is 1 that drying subprostrate sophora powder after crushing is pressed into solid-liquid ratio:10 add mass concentration as 70%
Ethanol solution, and adjust its pH as 3.1, ultrasound extraction 3 times, each 1.2h, Extracting temperature is 35 DEG C, is carried out after extract smart
Filter, and concentrate the filtrate to the 1/4 of former filtrate volume；
2）Hairyvein agrimony, the processing of rhizoma zingiberis, south Sinkiang ziziphora herb, eucalyptus citriodora, tomato, polygonum flaccidum：Respectively by hairyvein agrimony, rhizoma zingiberis, leaflet
Peppermint, eucalyptus citriodora, tomato, polygonum flaccidum are dry, crush, by solid-liquid ratio 1:10 add the ethanol solution that mass concentration is 70%, extraction
1.5h, extraction temperature are 80 DEG C, are then filtered, and filter residue extracts one again with the ethanol solution that mass concentration is 40% with similarity condition
It is secondary, filtering, ultrafiltration is carried out after merging filtrate twice；
3）The processing of marigold：Dry marigold is pressed into solid-liquid ratio 1:30 add alcoholic solution, ultrasound extraction 40min, carry
It is 50 DEG C to take temperature, filtering after having extracted, and ultrafiltration is once, then concentrates filtrate to the 1/3 of former filtrate volume；The alcohol
Methanol content is 30wt%, ethanol content 40wt% in solution；
4）The preparation of insecticide：By subprostrate sophora, south Sinkiang ziziphora herb, eucalyptus citriodora, rhizoma zingiberis, hairyvein agrimony, tomato, polygonum flaccidum, marigold
Extract solution add 3 ~ 5 times of extracting liquid volume deionized water in, then add Tsubaki-saponin stirring 30min, then will mixing
Valve system is loaded onto as in specification injection container, is evacuated, enpara propellant is injected by valve by liquid, by upper promotion button,
Finished product.
Embodiment 1
A kind of natural family's insecticide containing Tsubaki-saponin, its primary raw material used include：The kg of Tsubaki-saponin 4, subprostrate sophora
3 kg, the kg of south Sinkiang ziziphora herb 1, the kg of eucalyptus citriodora 1, the kg of rhizoma zingiberis 1, the kg of hairyvein agrimony 1, the kg of tomato 1, the kg of polygonum flaccidum 1, marigold 1
Kg, the kg of enpara class propellant 65.
Natural family's method for producing insecticide containing Tsubaki-saponin comprises the following steps：
1）The processing of subprostrate sophora：It is 1 that drying subprostrate sophora powder after crushing is pressed into solid-liquid ratio:10 add mass concentration as 70%
Ethanol solution, and adjust its pH as 3.1, ultrasound extraction 3 times, each 1.2h, Extracting temperature is 35 DEG C, is carried out after extract smart
Filter, and concentrate the filtrate to the 1/4 of former filtrate volume；
2）Hairyvein agrimony, the processing of rhizoma zingiberis, south Sinkiang ziziphora herb, eucalyptus citriodora, tomato, polygonum flaccidum：Respectively by hairyvein agrimony, rhizoma zingiberis, leaflet
Peppermint, eucalyptus citriodora, tomato, polygonum flaccidum are dry, crush, by solid-liquid ratio 1:10 add the ethanol solution that mass concentration is 70%, extraction
1.5h, extraction temperature are 80 DEG C, are then filtered, and filter residue extracts one again with the ethanol solution that mass concentration is 40% with similarity condition
It is secondary, filtering, ultrafiltration is carried out after merging filtrate twice；
3）The processing of marigold：Dry marigold is pressed into solid-liquid ratio 1:30 add alcoholic solution, ultrasound extraction 40min, carry
It is 50 DEG C to take temperature, filtering after having extracted, and ultrafiltration is once, then concentrates filtrate to the 1/3 of former filtrate volume；The alcohol
Methanol content is 30wt%, ethanol content 40wt% in solution；
4）The preparation of insecticide：By subprostrate sophora, south Sinkiang ziziphora herb, eucalyptus citriodora, rhizoma zingiberis, hairyvein agrimony, tomato, polygonum flaccidum, marigold
Extract solution add 3 times of extracting liquid volume deionized water in, then add Tsubaki-saponin stirring 30min, then by mixed liquor
Injected by specification in container, valve system is loaded onto, evacuated, enpara propellant is injected by valve, by upper promotion button, system
Obtain finished product.
Embodiment 2
A kind of natural family's insecticide containing Tsubaki-saponin, its primary raw material used include：The kg of Tsubaki-saponin 6, subprostrate sophora
5 kg, the kg of south Sinkiang ziziphora herb 2, the kg of eucalyptus citriodora 2, the kg of rhizoma zingiberis 2, the kg of hairyvein agrimony 2, the kg of tomato 2, the kg of polygonum flaccidum 2, marigold 2
Kg, the kg of enpara class propellant 70.
The preparation method of the Tsubaki-saponin is：Oleifera dry cake after crushing is pressed into solid-liquid ratio 1:12, which add mass concentrations, is
65% ethanol solution extraction 1.6h, extraction temperature is 60 DEG C, and ultrafiltration is carried out after extraction, collects filtrate.
Natural family's method for producing insecticide containing Tsubaki-saponin is：By the step 1 of embodiment 1）-3）Respectively to mountain
After beans root, hairyvein agrimony, rhizoma zingiberis, south Sinkiang ziziphora herb, eucalyptus citriodora, tomato, polygonum flaccidum, marigold are handled, by gained subprostrate sophora, leaflet
Peppermint, eucalyptus citriodora, rhizoma zingiberis, hairyvein agrimony, tomato, polygonum flaccidum, the extract solution of marigold add the deionized water of 4 times of extracting liquid volume
In, Tsubaki-saponin stirring 30min is then added, then valve system is loaded onto, taken out as in specification injection container by mixed liquor
Sky, enpara propellant is injected by valve, by upper promotion button, finished product.
Embodiment 3
A kind of natural family's insecticide containing Tsubaki-saponin, its primary raw material used include：The kg of Tsubaki-saponin 8, subprostrate sophora
6 kg, the kg of south Sinkiang ziziphora herb 3, the kg of eucalyptus citriodora 3, the kg of rhizoma zingiberis 3, the kg of hairyvein agrimony 3, the kg of tomato 3, the kg of polygonum flaccidum 3, marigold 3
Kg, the kg of enpara class propellant 75.
The preparation method of the Tsubaki-saponin is：Oleifera dry cake after crushing is pressed into solid-liquid ratio 1:12, which add mass concentrations, is
65% ethanol solution extraction 1.6h, extraction temperature is 60 DEG C, and ultrafiltration is carried out after extraction, collects filtrate.
Natural family's method for producing insecticide containing Tsubaki-saponin is：By the step 1 of embodiment 1）-3）Respectively to mountain
After beans root, hairyvein agrimony, rhizoma zingiberis, south Sinkiang ziziphora herb, eucalyptus citriodora, tomato, polygonum flaccidum, marigold are handled, by gained subprostrate sophora, leaflet
Peppermint, eucalyptus citriodora, rhizoma zingiberis, hairyvein agrimony, tomato, polygonum flaccidum, the extract solution of marigold add the deionized water of 5 times of extracting liquid volume
In, Tsubaki-saponin stirring 30min is then added, then valve system is loaded onto, taken out as in specification injection container by mixed liquor
Sky, enpara propellant is injected by valve, by upper promotion button, finished product.
Insecticide insecticidal activity assay
（1）Drosophila is tested：Insecticide is taken respectively（Propellant part is not added）100 times of dilutions, 50 times of dilutions, 20 times
Dilution, 10 times of dilutions, 5 times of dilutions, each 10ml of stoste, and using commercially available insecticidal solution as control, be sprayed on be placed with respectively
In the 8L glass boxs of 100 drosophilas, the death rate of drosophila, result of the test such as table 1 are observed after 5min.
Various concentrations insecticide the killing except rate to drosophila of table 1
（2）Mosquito is tested：Insecticide is taken respectively（Propellant part is not added）100 times of dilutions, 50 times of dilutions, 20 times
Dilution, 10 times of dilutions, 5 times of dilutions, each 10ml of stoste, and using commercially available insecticidal solution as control, be sprayed on be placed with respectively
In the 8L glass boxs of 50 mosquitoes, the death rate of mosquito, result of the test such as table 2 are observed after 5min.
Insecticide the killing except rate to mosquito of the various concentrations of table 2
（3）Fly is tested：Insecticide is taken respectively（Propellant part is not added）100 times of dilutions, 50 times of dilutions, 20 times
Dilution, 10 times of dilutions, 5 times of dilutions, stostes, and using commercially available insecticidal solution as control, 20 flies are dropped in respectively
Back, the death rate of fly, result of the test such as table 3 are observed after 10min.
Insecticide the killing except rate to fly of the various concentrations of table 3
（4）Spider is tested：Insecticide is taken respectively（Propellant part is not added）100 times of dilutions, 50 times of dilutions, 20 times
Dilution, 10 times of dilutions, 5 times of dilutions, stostes, and using commercially available insecticidal solution as control, 20 spiders are dropped in respectively
Back, the death rate of spider, result of the test such as table 4 are observed after 10min.
Insecticide the killing except rate to spider of the various concentrations of table 4
Median lethal can reach to drosophila, mosquito, fly, spider after table 1-4,20 times of desinsection dilution agent of the present invention
Dosage, illustrate that the insecticide has good killing action, in actual applications using 10 times of dilutions with regard to order can be basically reached
People's satisfaction is killed except effect.
The foregoing is only presently preferred embodiments of the present invention, all equivalent changes done according to scope of the present invention patent with
Modification, it should all belong to the covering scope of the present invention.
Claims (1)
- A kind of 1. natural family's insecticide containing Tsubaki-saponin, it is characterised in that：Primary raw material used includes by weight：Mountain Tea saponin 4-8 parts, subprostrate sophora 3-6 parts, south Sinkiang ziziphora herb 1-3 parts, eucalyptus citriodora 1-3 parts, rhizoma zingiberis 1-3 parts, hairyvein agrimony 1-3 parts, tomato 1-3 parts, polygonum flaccidum 1-3 parts, marigold 1-3 parts, enpara class propellant 65-75 parts；Hairyvein agrimony, rhizoma zingiberis, south Sinkiang ziziphora herb, eucalyptus citriodora, tomato, the processing method of polygonum flaccidum are：By each raw material drying, crushing, by material Liquor ratio 1:10 add the ethanol solution that mass concentration is 70%, extract 1.5h, and extraction temperature is 80 DEG C, is then filtered, filter residue matter The ethanol solution that amount concentration is 40% is extracted once again with similarity condition, is filtered, and ultrafiltration is carried out after merging filtrate twice；The preparation method of the Tsubaki-saponin is：Oleifera dry cake after crushing is pressed into solid-liquid ratio 1:12 add mass concentration as 65% Ethanol solution, extract 1.6h, extraction temperature is 60 DEG C, carries out ultrafiltration after extraction, collects filtrate；The processing method of subprostrate sophora is：It is 1 that drying subprostrate sophora powder after crushing is pressed into solid-liquid ratio:10 add mass concentration as 70% Ethanol solution, and adjust its pH as 3.1, ultrasound extraction 3 times, each 1.2h, Extracting temperature is 35 DEG C, is carried out after extract smart Filter, and concentrate the filtrate to the 1/4 of former filtrate volume；The processing method of marigold is：Dry marigold is pressed into solid-liquid ratio 1:30 add alcoholic solution ultrasound extraction 40min, extraction Temperature is 50 DEG C, filtering after having extracted, and ultrafiltration is once, then concentrates filtrate to the 1/3 of former filtrate volume；Methanol content is 30wt%, ethanol content 40wt% in the alcoholic solution.
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| CN106135315A (en) * | 2016-06-29 | 2016-11-23 | 辽宁科技学院 | A kind of natural botanical insecticide |
| CN107307014A (en) * | 2017-07-17 | 2017-11-03 | 铜仁市万山区大坪乡瓮岩村俊峰精果有限公司 | A kind of apple tree insecticide and preparation method thereof |
| CN107960287A (en) * | 2017-11-24 | 2018-04-27 | 恭城福茂生油茶文化产业发展有限公司 | A kind of high-yield planting method of glutinous rice |
| CN109287671A (en) * | 2018-08-13 | 2019-02-01 | 张济瑶 | A kind of household plant source pest repellant and preparation method, application containing caraway |
| CN110477033A (en) * | 2019-08-20 | 2019-11-22 | 贵州省烟草公司铜仁市公司 | A kind of tobacco insecticide and preparation method thereof |
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