CN107727769B - 一种快速筛查与确证牛奶中兽药残留的方法 - Google Patents
一种快速筛查与确证牛奶中兽药残留的方法 Download PDFInfo
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Abstract
Description
中文名称 | 英文名称 | 分子式 | 精确质量数 |
乙酸丙嗪 | Acepromazine | C<sub>19</sub>H<sub>22</sub>N<sub>2</sub>OS | 326.1453 |
阿苯达唑砜 | Albendazole sulfone | C<sub>12</sub>H<sub>15</sub>N<sub>3</sub>O<sub>4</sub>S | 297.0783 |
阿苯达唑亚砜 | Albendazole sulfoxide | C<sub>12</sub>H<sub>15</sub>N<sub>3</sub>O<sub>3</sub>S | 281.0834 |
阿苯达唑 | Albendazole | C<sub>12</sub>H<sub>15</sub>N<sub>3</sub>O<sub>2</sub>S | 265.0885 |
阿苯达唑氨砜 | Albendazole-2-aminosulfone | C<sub>10</sub>H<sub>13</sub>N<sub>3</sub>O<sub>2</sub>S | 239.0728 |
四烯雌酮 | Altrenogest | C<sub>21</sub>H<sub>26</sub>O<sub>2</sub> | 310.1933 |
金刚烷胺 | amantadine | C<sub>10</sub>H<sub>17</sub>N | 151.1361 |
羟氨苄青霉素 | amoxicillin | C<sub>16</sub>H<sub>19</sub>N<sub>3</sub>O<sub>5</sub>S | 365.1045 |
羟氨苄青霉噻唑酸 | amoxicilloic acid | C<sub>16</sub>H<sub>21</sub>N<sub>3</sub>O<sub>6</sub>S | 383.1151 |
去羟基氨苄青霉噻唑酸 | amoxilloic acid | C<sub>15</sub>H<sub>21</sub>N<sub>3</sub>O<sub>4</sub>S | 339.1253 |
氨苄青霉素 | ampicillin | C<sub>16</sub>H<sub>19</sub>N<sub>3</sub>O<sub>4</sub>S | 349.1096 |
氨苄青霉噻唑酸 | ampicilloic acid | C<sub>16</sub>H<sub>21</sub>N<sub>3</sub>O<sub>5</sub>S | 367.1202 |
去羟氨苄青霉噻唑酸 | ampilloic acid | C<sub>15</sub>H<sub>21</sub>N<sub>3</sub>O<sub>3</sub>S | 323.1304 |
去甲雄三烯醇酮 | a-trenholone a | C<sub>18</sub>H<sub>22</sub>O<sub>2</sub> | 270.1620 |
阿托品 | atropine | C<sub>17</sub>H<sub>23</sub>NO<sub>3</sub> | 289.1678 |
阿扎哌隆 | azaperone | C<sub>19</sub>H<sub>22</sub>FN<sub>3</sub>O | 327.1747 |
阿奇霉素 | Azithromycin | C<sub>38</sub>H<sub>72</sub>N<sub>2</sub>O<sub>12</sub> | 748.5085 |
坎苯达唑 | Cambendazole | C<sub>14</sub>H<sub>14</sub>N<sub>4</sub>O<sub>2</sub>S | 302.0837 |
咔唑心安 | Carazolol | C<sub>18</sub>H<sub>22</sub>N<sub>2</sub>O<sub>2</sub> | 298.1681 |
头孢氨苄 | Cefalexin | C<sub>16</sub>H<sub>17</sub>N<sub>3</sub>O<sub>4</sub>S | 347.0940 |
头孢匹林 | Cefapirin | C<sub>17</sub>H<sub>17</sub>N<sub>3</sub>O<sub>6</sub>S<sub>2</sub> | 423.0559 |
头孢唑啉 | Cefazolin | C<sub>14</sub>H<sub>14</sub>N<sub>8</sub>O<sub>4</sub>S<sub>3</sub> | 454.0300 |
头孢匹罗 | Cefpirome | C<sub>22</sub>H<sub>22</sub>N<sub>6</sub>O<sub>5</sub>S<sub>2</sub> | 514.1093 |
头孢喹肟 | Cefquinome | C<sub>23</sub>H<sub>24</sub>N<sub>6</sub>O<sub>5</sub>S<sub>2</sub> | 528.1250 |
头孢洛宁 | Cephalonium | C<sub>20</sub>H<sub>18</sub>N<sub>4</sub>O<sub>5</sub>S<sub>2</sub> | 458.0719 |
金霉素 | Chlorotetracycline | C<sub>22</sub>H<sub>23</sub>ClN<sub>2</sub>O<sub>8</sub> | 478.1143 |
氯丙嗪 | Chlorpromazine | C<sub>17</sub>H<sub>19</sub>ClN<sub>2</sub>S | 318.0957 |
西诺沙星 | Cinoxacin | C<sub>12</sub>H<sub>10</sub>N<sub>2</sub>O<sub>5</sub> | 262.0590 |
环丙沙星 | Ciprofloxacin | C<sub>17</sub>H<sub>18</sub>FN<sub>3</sub>O<sub>3</sub> | 331.1332 |
克仑特罗 | Clenbuterol | C<sub>12</sub>H<sub>18</sub>Cl<sub>2</sub>N<sub>2</sub>O | 276.0796 |
克仑塞罗 | Clencyclohexerol | C<sub>14</sub>H<sub>20</sub>Cl<sub>2</sub>N<sub>2</sub>O<sub>2</sub> | 318.0902 |
克仑潘特 | Clenpenterol | C<sub>13</sub>H<sub>20</sub>Cl<sub>2</sub>N<sub>2</sub>O | 290.0953 |
克林霉素 | Clindamycin | C<sub>18</sub>H<sub>33</sub>ClN<sub>2</sub>O<sub>5</sub>S | 424.1799 |
邻氯青霉素 | cloxacillin | C<sub>19</sub>H<sub>18</sub>Cl<sub>2</sub>N<sub>3</sub>NaO<sub>6</sub>S | 509.0191 |
氯唑西林 | cloxacillin | C<sub>19</sub>H<sub>18</sub>ClN<sub>3</sub>O<sub>5</sub>S | 435.0656 |
邻氯青霉噻唑酸 | cloxacilloic acid | C<sub>19</sub>H<sub>20</sub>ClN<sub>3</sub>O<sub>6</sub>S | 453.0761 |
去羟邻氯青霉噻唑酸 | cloxalloic acid | C<sub>18</sub>H<sub>20</sub>ClN<sub>3</sub>O<sub>4</sub>S | 409.0863 |
达氟沙星 | Danofloxacin | C<sub>19</sub>H<sub>20</sub>FN<sub>3</sub>O<sub>3</sub> | 357.1489 |
地美环素 | Demeclocycline | C<sub>21</sub>H<sub>21</sub>ClN<sub>2</sub>O<sub>8</sub> | 464.0986 |
地塞米松 | Dexamethasone | C<sub>22</sub>H<sub>29</sub>FO<sub>5</sub> | 392.1999 |
地西泮 | Diazepam | C<sub>16</sub>H<sub>13</sub>ClN<sub>2</sub>O | 284.0716 |
双氯西林 | Dicloxacillin | C<sub>19</sub>H<sub>17</sub>Cl<sub>2</sub>N<sub>3</sub>O<sub>5</sub>S | 469.0266 |
二氟沙星 | Ditloxacin | C<sub>21</sub>H<sub>19</sub>F<sub>2</sub>N<sub>3</sub>O<sub>3</sub> | 399.1394 |
强力霉素 | Doxycycline | C<sub>22</sub>H<sub>24</sub>N<sub>2</sub>O<sub>8</sub> | 444.1533 |
氟哌利多 | Droperidol | C<sub>22</sub>H<sub>22</sub>FN<sub>3</sub>O<sub>2</sub> | 379.1696 |
红霉素 | Erythromycin | C<sub>37</sub>H<sub>67</sub>NO<sub>13</sub> | 733.4612 |
泛昔洛韦 | Famciclovir | C<sub>14</sub>H<sub>19</sub>N<sub>5</sub>O<sub>4</sub> | 321.1437 |
非班太尔 | Febantel | C<sub>20</sub>H<sub>22</sub>N<sub>4</sub>O<sub>6</sub>S | 446.1260 |
芬苯哒唑 | Fenbendazole | C<sub>15</sub>H<sub>13</sub>N<sub>3</sub>O<sub>2</sub>S | 299.0728 |
氟罗沙星 | Fleroxacin | C<sub>17</sub>H<sub>18</sub>F<sub>3</sub>N<sub>3</sub>O<sub>3</sub> | 369.1300 |
氟苯达唑氨基代谢产物 | Flubendazole-amine | C<sub>14</sub>H<sub>10</sub>FN<sub>3</sub>O | 255.0808 |
氟甲哇 | Flumequine | C<sub>14</sub>H<sub>12</sub>FNO<sub>3</sub> | 261.0801 |
氟轻松 | Fluocinolone acetonide | C<sub>24</sub>H<sub>30</sub>F<sub>2</sub>O<sub>6</sub> | 452.2010 |
依诺沙星 | Fnoxacm | C<sub>15</sub>H<sub>17</sub>FN<sub>4</sub>O<sub>3</sub> | 320.1285 |
恩诺沙星 | Fnrotloxacin | C<sub>19</sub>H<sub>22</sub>FN<sub>3</sub>O<sub>3</sub> | 359.1645 |
氟哌啶醇 | Haloperidol | C<sub>21</sub>H<sub>23</sub>ClFNO<sub>2</sub> | 375.1401 |
异丙硝唑 | Ipronidazole | C<sub>7</sub>H<sub>11</sub>N<sub>3</sub>O<sub>2</sub> | 169.0851 |
交沙霉素 | Josamycin | C<sub>42</sub>H<sub>69</sub>NO<sub>15</sub> | 827.4667 |
洛美沙星 | Lomefloxacin | C<sub>17</sub>H<sub>19</sub>F<sub>2</sub>N<sub>3</sub>O<sub>3</sub> | 351.1394 |
马普特罗 | Mabuterol | C<sub>13</sub>H<sub>18</sub>ClF<sub>3</sub>N<sub>2</sub>O | 310.1060 |
马喷特罗 | Mapenterol | C<sub>14</sub>H<sub>20</sub>ClF<sub>3</sub>N<sub>2</sub>O | 324.1216 |
麻保沙星 | Marbofloxacin | C<sub>17</sub>H<sub>19</sub>FN<sub>4</sub>O<sub>4</sub> | 362.1390 |
甲苯哒唑 | Mebendazole | C<sub>16</sub>H<sub>13</sub>N<sub>3</sub>O<sub>3</sub> | 295.2927 |
甲苯哒唑羟基代谢产物 | Mebendazole-5-droxy | C<sub>16</sub>H<sub>15</sub>N<sub>3</sub>O<sub>3</sub> | 297.3086 |
甲苯哒唑氨基代谢产物 | Mebendazole-amine | C<sub>14</sub>H<sub>11</sub>N<sub>3</sub>O | 237.0902 |
甲地孕酮 | Megestrol acetate | C<sub>24</sub>H<sub>32</sub>O<sub>4</sub> | 384.2301 |
美仑孕酮乙酸酯 | Melengestrol acetate | C<sub>25</sub>H<sub>32</sub>O<sub>4</sub> | 396.2300 |
甲硝唑 | Metlprednisolone | C<sub>22</sub>H<sub>30</sub>O<sub>5</sub> | 374.2093 |
甲基强的松龙 | Metronidazole | C<sub>6</sub>H<sub>9</sub>N<sub>3</sub>O<sub>3</sub> | 171.0644 |
萘夫西林 | NafcillinSodium | C<sub>21</sub>H<sub>21</sub>N<sub>2</sub>O<sub>5</sub>S | 413.1171 |
诺氟沙星 | Nortloxacin | C<sub>16</sub>H<sub>18</sub>FN<sub>3</sub>O<sub>3</sub> | 319.1332 |
奥比沙星 | Nrbitloxacin | C<sub>19</sub>H<sub>20</sub>F<sub>3</sub>N<sub>3</sub>O<sub>3</sub> | 395.1457 |
奥芬达唑 | Nxfendazole | C<sub>15</sub>H<sub>13</sub>N<sub>3</sub>O<sub>3</sub>S | 315.0678 |
奥苯达唑 | Nxibendazole | C<sub>12</sub>H<sub>15</sub>N<sub>3</sub>O<sub>3</sub>S | 281.0834 |
氧氟沙星 | Otloxacin | C<sub>18</sub>H<sub>20</sub>FN<sub>3</sub>O<sub>4</sub> | 361.1438 |
苯唑西林 | Oxacillin | C<sub>19</sub>H<sub>18</sub>N<sub>3</sub>NaO<sub>5</sub>S | 423.0865 |
土霉素 | Oxytetracycline | C<sub>22</sub>H<sub>24</sub>N<sub>2</sub>O<sub>9</sub> | 460.1482 |
喷布洛尔 | Penhutolol | C<sub>18</sub>H<sub>29</sub>NO<sub>2</sub> | 291.2198 |
苄青霉素 | penicillin G | C<sub>16</sub>H<sub>18</sub>N<sub>2</sub>O<sub>4</sub>S | 334.0987 |
苄青霉噻唑酸 | penicilloic acid G | C<sub>16</sub>H<sub>20</sub>N<sub>2</sub>O<sub>5</sub>S | 352.1093 |
去羟苄青霉噻唑酸 | penilloic acid G | C<sub>15</sub>H<sub>20</sub>N<sub>2</sub>O<sub>3</sub>S | 308.1195 |
奋乃静 | Perphenazine | C<sub>21</sub>H<sub>26</sub>ClN<sub>3</sub>OS | 403.1485 |
培氟沙星 | Petloxacin | C<sub>17</sub>H<sub>20</sub>FN<sub>3</sub>O<sub>3</sub> | 333.1489 |
青霉素 | Phenoxymethylpenicillin V | C<sub>16</sub>H<sub>17</sub>KN<sub>2</sub>O<sub>5</sub>S | 388.0495 |
毗呱酸 | Pipemidic acid | C<sub>14</sub>H<sub>17</sub>N<sub>5</sub>O<sub>3</sub> | 303.1331 |
哌拉西林 | Piperacillin | C<sub>23</sub>H<sub>27</sub>N<sub>5</sub>O<sub>7</sub>S | 517.1631 |
泼尼松龙 | Prednisolone | C<sub>21</sub>H<sub>28</sub>O<sub>5</sub> | 360.1937 |
孕酮 | Progesterone | C<sub>21</sub>H<sub>30</sub>O<sub>2</sub> | 314.2246 |
莱克多巴胺 | Ractopamine | C<sub>18</sub>H<sub>23</sub>NO<sub>3</sub> | 301.1678 |
班布特罗 | Rambuterol | C<sub>18</sub>H<sub>29</sub>N<sub>3</sub>O<sub>5</sub> | 367.2107 |
倍氯米松 | Reclomethasone | C<sub>28</sub>H<sub>37</sub>ClO<sub>7</sub> | 520.2228 |
倍他米松 | Retamethasone | C<sub>22</sub>H<sub>29</sub>FO<sub>5</sub> | 392.1999 |
利巴韦林 | ribavirin | C<sub>8</sub>H<sub>12</sub>N<sub>4</sub>O<sub>5</sub> | 244.0808 |
罗红霉素 | Roxithromycin | C<sub>41</sub>H<sub>76</sub>N<sub>2</sub>O<sub>15</sub> | 836.5246 |
溴布特罗 | Rrombuterol | C<sub>12</sub>H<sub>18</sub>Br<sub>2</sub>N<sub>2</sub>O | 363.9786 |
沙拉沙星 | Sarafloxacin | C<sub>20</sub>H<sub>17</sub>F<sub>2</sub>N<sub>3</sub>O<sub>3</sub> | 385.1238 |
司帕沙星 | Sparfloxacin | C<sub>19</sub>H<sub>22</sub>F<sub>2</sub>N<sub>4</sub>O<sub>8</sub> | 472.1406 |
螺旋霉素 | Spiramycin | C<sub>43</sub>H<sub>74</sub>N<sub>2</sub>O<sub>14</sub> | 842.5140 |
康力龙 | stanozolol | C<sub>21</sub>H<sub>32</sub>N<sub>2</sub>O | 328.2515 |
苯甲酸磺胺 | Sulfabenzamide | C<sub>13</sub>H<sub>12</sub>N<sub>2</sub>O<sub>3</sub>S | 276.0569 |
磺胺醋酸 | Sulfacetamide | C<sub>8</sub>H<sub>10</sub>N<sub>2</sub>O<sub>3</sub>S | 214.0412 |
磺胺喹恶琳 | Sulfachinoxaline | C<sub>14</sub>H<sub>12</sub>N<sub>4</sub>O<sub>2</sub>S | 300.0681 |
磺胺氯哒嗪 | Sulfachloropyridazine | C<sub>10</sub>H<sub>9</sub>ClN<sub>4</sub>O<sub>2</sub>S | 284.0135 |
磺胺氯毗嗪 | Sulfaclozine | C<sub>10</sub>H<sub>9</sub>ClN<sub>4</sub>O<sub>2</sub>S | 284.0135 |
磺胺嘧啶 | Sulfadiazine | C<sub>10</sub>H<sub>10</sub>N<sub>4</sub>O<sub>2</sub>S | 250.0524 |
磺胺二甲氧嗪 | Sulfadimethoxine | C<sub>12</sub>H<sub>14</sub>N<sub>4</sub>O<sub>4</sub>S | 310.0736 |
周效磺胺 | Sulfadoxine | C<sub>12</sub>H<sub>14</sub>N<sub>4</sub>O<sub>4</sub>S | 310.0736 |
磺胺甲基嘧啶 | Sulfamerazine | C<sub>11</sub>H<sub>12</sub>N<sub>4</sub>O<sub>2</sub>S | 264.0681 |
磺胺对甲氧嘧啶 | Sulfameter | C<sub>11</sub>H<sub>12</sub>N<sub>4</sub>O<sub>2</sub>S | 264.0681 |
磺胺二甲嘧啶 | Sulfamethazine | C<sub>12</sub>H<sub>14</sub>N<sub>4</sub>O<sub>2</sub>S | 278.0837 |
磺胺甲二唑 | Sulfamethizole | C<sub>9</sub>H<sub>10</sub>N<sub>4</sub>O<sub>2</sub>S<sub>2</sub> | 270.0245 |
磺胺甲恶唑 | Sulfamethoxazole | C<sub>10</sub>H<sub>11</sub>N<sub>3</sub>O<sub>3</sub>S | 253.0521 |
磺胺甲氧哒嗪 | Sulfamethoxypyridazine | C<sub>11</sub>H<sub>12</sub>N<sub>4</sub>O<sub>3</sub>S | 280.0630 |
磺胺间甲氧嘧啶 | Sulfamonomethoxine | C<sub>11</sub>H<sub>12</sub>N<sub>4</sub>O<sub>3</sub>S | 280.0630 |
磺胺苯吡唑 | Sulfaphenazole | C<sub>15</sub>H<sub>14</sub>N<sub>4</sub>O<sub>2</sub>S | 314.0837 |
磺胺吡啶 | Sulfapyridine | C<sub>11</sub>H<sub>11</sub>N<sub>3</sub>O<sub>2</sub>S | 249.0572 |
柳氮磺胺吡啶 | Sulfasalazine | C<sub>18</sub>H<sub>14</sub>N<sub>4</sub>O<sub>5</sub>S | 398.0685 |
磺胺噻唑 | Sulfathiazole | C<sub>9</sub>H<sub>9</sub>N<sub>3</sub>O<sub>2</sub>S<sub>2</sub> | 255.0136 |
磺胺二甲异嘧啶 | Sultisomidin | C<sub>12</sub>H<sub>14</sub>N<sub>4</sub>O<sub>2</sub>S | 278.0837 |
磺胺二甲异唑 | Sultisoxazole | C<sub>11</sub>H<sub>13</sub>N<sub>3</sub>O<sub>3</sub>S | 267.0678 |
左旋咪唑 | levamisole | C<sub>11</sub>H<sub>12</sub>N<sub>2</sub>S | 204.0721 |
特硝唑 | Ternidazole | C<sub>7</sub>H<sub>11</sub>N<sub>3</sub>O<sub>3</sub> | 185.0800 |
睾酮 | Testosterone | C<sub>19</sub>H<sub>28</sub>O<sub>2</sub> | 288.2089 |
四环素 | Tetracycline | C<sub>22</sub>H<sub>24</sub>N<sub>2</sub>O<sub>8</sub> | 444.1533 |
噻苯咪唑 | Thiabendazole | C<sub>10</sub>H<sub>7</sub>N<sub>3</sub>S | 201.0361 |
5-羟基噻苯咪唑 | Thiabendazole-5-hydroxy | C<sub>10</sub>H<sub>7</sub>N<sub>3</sub>OS | 217.0310 |
泰妙菌素 | Tiamulin | C<sub>28</sub>H<sub>47</sub>NO<sub>4</sub>S | 493.3226 |
替硝唑 | Tinidazole | C<sub>8</sub>H<sub>13</sub>N<sub>3</sub>O<sub>4</sub>S | 247.0627 |
群勃龙乙酸酯 | Trenbolone acetate | C<sub>20</sub>H<sub>24</sub>O<sub>3</sub> | 312.1725 |
甲氧苄啶 | Trimethoprim | C<sub>14</sub>H<sub>18</sub>N<sub>4</sub>O<sub>3</sub> | 290.1379 |
妥布特罗 | Tulohuterol | C<sub>12</sub>H<sub>18</sub>ClNO | 227.1077 |
泰乐菌素 | Tylosin | C<sub>46</sub>H<sub>77</sub>NO<sub>17</sub> | 915.5192 |
甲苯噻嗪 | Xvlazine | C<sub>12</sub>H<sub>16</sub>N<sub>2</sub>S | 220.1034 |
赛拉嗪 | Xylazine | C<sub>12</sub>H<sub>16</sub>N<sub>2</sub>S | 220.1034 |
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Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102128891A (zh) * | 2010-12-20 | 2011-07-20 | 新疆出入境检验检疫局检验检疫技术中心 | 同时测定鸡肝中磺胺类、喹诺酮类、苯并咪唑类药物及其代谢物残留的分析方法 |
CN104764816A (zh) * | 2015-03-05 | 2015-07-08 | 中国农业科学院北京畜牧兽医研究所 | 生鲜乳中多组类兽药残留的uplc-ms/ms同时通量检测方法 |
CN105259288A (zh) * | 2015-10-30 | 2016-01-20 | 四川新希望畜牧科技有限公司 | 一种同时检测禽肉组织中多种药物残留量的方法 |
CN105319292A (zh) * | 2014-08-04 | 2016-02-10 | 天津市农业质量标准与检测技术研究所 | 一种分析动物性食品中四类29种限用兽药残留的uplc-ms/ms方法 |
CN106290659A (zh) * | 2016-10-28 | 2017-01-04 | 陕西科技大学 | 婴幼儿配方食品中农药与兽药的超高效液相色谱‑四级杆静电场轨道离子阱质谱筛查方法 |
CN106596819A (zh) * | 2016-11-23 | 2017-04-26 | 宁波出入境检验检疫局检验检疫技术中心 | 一种动物源食品中99种兽药残留的高通量检测方法 |
CN107167539A (zh) * | 2017-06-27 | 2017-09-15 | 中山出入境检验检疫局检验检疫技术中心 | 一种快速筛查鱼肉中多种兽药残留的检测方法 |
CN107219310A (zh) * | 2017-05-16 | 2017-09-29 | 河南省兽药饲料监察所 | 一种饲料中110种药物的筛查方法 |
-
2017
- 2017-10-24 CN CN201711003795.1A patent/CN107727769B/zh active Active
Patent Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102128891A (zh) * | 2010-12-20 | 2011-07-20 | 新疆出入境检验检疫局检验检疫技术中心 | 同时测定鸡肝中磺胺类、喹诺酮类、苯并咪唑类药物及其代谢物残留的分析方法 |
CN105319292A (zh) * | 2014-08-04 | 2016-02-10 | 天津市农业质量标准与检测技术研究所 | 一种分析动物性食品中四类29种限用兽药残留的uplc-ms/ms方法 |
CN104764816A (zh) * | 2015-03-05 | 2015-07-08 | 中国农业科学院北京畜牧兽医研究所 | 生鲜乳中多组类兽药残留的uplc-ms/ms同时通量检测方法 |
CN105259288A (zh) * | 2015-10-30 | 2016-01-20 | 四川新希望畜牧科技有限公司 | 一种同时检测禽肉组织中多种药物残留量的方法 |
CN106290659A (zh) * | 2016-10-28 | 2017-01-04 | 陕西科技大学 | 婴幼儿配方食品中农药与兽药的超高效液相色谱‑四级杆静电场轨道离子阱质谱筛查方法 |
CN106596819A (zh) * | 2016-11-23 | 2017-04-26 | 宁波出入境检验检疫局检验检疫技术中心 | 一种动物源食品中99种兽药残留的高通量检测方法 |
CN107219310A (zh) * | 2017-05-16 | 2017-09-29 | 河南省兽药饲料监察所 | 一种饲料中110种药物的筛查方法 |
CN107167539A (zh) * | 2017-06-27 | 2017-09-15 | 中山出入境检验检疫局检验检疫技术中心 | 一种快速筛查鱼肉中多种兽药残留的检测方法 |
Non-Patent Citations (8)
Title |
---|
Agilent Bond Elut QuEChERS EMR-Lipid——样品前处理中去除脂质的利器;申海鹏等;《食品安全导刊》;20150930(第25期);第26-29页 * |
Comparison of veterinary drug residue results in animal tissues by ultrahigh-performance liquid chromatography coupled to triple quadrupole or quadrupole–time-of-flight tandem mass spectrometry after different sample preparation methods;Tarun Anumol等;《Anal Bioanal Chem》;20170221(第409期);第2639-2653页 * |
Multiresidue Analysis of Pesticides in Avocado with Agilent Bond Elut EMR-Lipid by GC/MS/MS;Limian Zhao等;《Agilent Technologies》;20150821;第1-15页 * |
液相色谱-四极杆-静电场轨道阱质谱结合改进的QuEChERS方法快速测定鸡蛋中多种抗病毒药物残留;曲娬等;《2 0 1 6 年动物药品学分会学术年会优秀论文集》;20161231;第298-313页 * |
蜂王浆和牛奶中兽药残留分析方法研究;张亚欠;《中国优秀硕士学位论文全文数据库 工程科技Ⅰ辑》;20170315(第03期);第B024-232页 * |
超高效液相色谱-四极杆-飞行时间质谱法快速筛查牛奶中的农药和兽药残留;高馥蝶等;《色谱》;20120630;第30卷(第6期);第560-567页 * |
超高效液相色谱-四极杆飞行时间质谱法快速筛查生鲜牛乳中的14种磺胺类药物;贡松松等;《分析测试学报》;20141231;第33卷(第12期);第1342-1348页 * |
超高效液相色谱-四级杆-飞行时间质谱法快速筛查与确证蔬菜水果中的多种农药残留;蒋万枫等;《中国食品卫生杂志》;20170730;第29卷(第4期);第26-29页 * |
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