CN107601569A - 一种带状钠锰氧化物及其制备方法与应用 - Google Patents
一种带状钠锰氧化物及其制备方法与应用 Download PDFInfo
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- CN107601569A CN107601569A CN201710917633.2A CN201710917633A CN107601569A CN 107601569 A CN107601569 A CN 107601569A CN 201710917633 A CN201710917633 A CN 201710917633A CN 107601569 A CN107601569 A CN 107601569A
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- Prior art keywords
- manganese oxide
- sodium manganese
- banding
- sodium
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- IKULXUCKGDPJMZ-UHFFFAOYSA-N sodium manganese(2+) oxygen(2-) Chemical compound [O-2].[Mn+2].[Na+] IKULXUCKGDPJMZ-UHFFFAOYSA-N 0.000 title claims abstract description 46
- 238000002360 preparation method Methods 0.000 title claims abstract description 20
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims abstract description 30
- 239000000203 mixture Substances 0.000 claims abstract description 24
- 239000011572 manganese Substances 0.000 claims abstract description 17
- 239000011734 sodium Substances 0.000 claims abstract description 13
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical class C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims abstract description 10
- 238000001291 vacuum drying Methods 0.000 claims abstract description 9
- 239000003990 capacitor Substances 0.000 claims abstract description 7
- 238000005119 centrifugation Methods 0.000 claims abstract description 7
- 239000000725 suspension Substances 0.000 claims abstract description 7
- AMWRITDGCCNYAT-UHFFFAOYSA-L hydroxy(oxo)manganese;manganese Chemical compound [Mn].O[Mn]=O.O[Mn]=O AMWRITDGCCNYAT-UHFFFAOYSA-L 0.000 claims abstract description 6
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims abstract description 4
- 229910052708 sodium Inorganic materials 0.000 claims abstract description 4
- 238000005406 washing Methods 0.000 claims abstract description 4
- 239000000376 reactant Substances 0.000 claims abstract description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 18
- 238000002156 mixing Methods 0.000 claims description 14
- 239000007772 electrode material Substances 0.000 claims description 9
- 238000000034 method Methods 0.000 claims description 8
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical class CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 claims description 7
- 239000006230 acetylene black Substances 0.000 claims description 6
- 229910002804 graphite Inorganic materials 0.000 claims description 6
- 239000010439 graphite Substances 0.000 claims description 6
- 229920001343 polytetrafluoroethylene Polymers 0.000 claims description 6
- 239000004810 polytetrafluoroethylene Substances 0.000 claims description 6
- 239000002002 slurry Substances 0.000 claims description 6
- 238000001035 drying Methods 0.000 claims description 5
- 150000002500 ions Chemical group 0.000 claims description 3
- -1 polytetrafluoroethylene Polymers 0.000 claims description 3
- 239000000843 powder Substances 0.000 claims description 3
- 238000003756 stirring Methods 0.000 claims description 3
- 239000003011 anion exchange membrane Substances 0.000 claims description 2
- 238000009413 insulation Methods 0.000 claims description 2
- 239000007788 liquid Substances 0.000 claims description 2
- 239000007787 solid Substances 0.000 claims description 2
- 125000006850 spacer group Chemical group 0.000 claims description 2
- 238000005516 engineering process Methods 0.000 abstract description 11
- FKNQFGJONOIPTF-UHFFFAOYSA-N Sodium cation Chemical compound [Na+] FKNQFGJONOIPTF-UHFFFAOYSA-N 0.000 abstract description 3
- 229910001415 sodium ion Inorganic materials 0.000 abstract description 3
- 238000012360 testing method Methods 0.000 description 9
- 238000002242 deionisation method Methods 0.000 description 8
- 239000000463 material Substances 0.000 description 7
- 239000000243 solution Substances 0.000 description 7
- 238000011056 performance test Methods 0.000 description 5
- 102100028565 Epimerase family protein SDR39U1 Human genes 0.000 description 4
- 101000915432 Homo sapiens Epimerase family protein SDR39U1 Proteins 0.000 description 4
- 230000003647 oxidation Effects 0.000 description 4
- 238000007254 oxidation reaction Methods 0.000 description 4
- 230000009467 reduction Effects 0.000 description 4
- 150000003839 salts Chemical class 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 230000008901 benefit Effects 0.000 description 3
- 238000003837 high-temperature calcination Methods 0.000 description 3
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 2
- 230000007812 deficiency Effects 0.000 description 2
- 238000010612 desalination reaction Methods 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 238000007599 discharging Methods 0.000 description 2
- 238000001027 hydrothermal synthesis Methods 0.000 description 2
- 229910052744 lithium Inorganic materials 0.000 description 2
- MIVBAHRSNUNMPP-UHFFFAOYSA-N manganese(II) nitrate Inorganic materials [Mn+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O MIVBAHRSNUNMPP-UHFFFAOYSA-N 0.000 description 2
- OXHNLMTVIGZXSG-UHFFFAOYSA-N 1-Methylpyrrole Chemical class CN1C=CC=C1 OXHNLMTVIGZXSG-UHFFFAOYSA-N 0.000 description 1
- GFORUURFPDRRRJ-UHFFFAOYSA-N [Na].[Mn] Chemical compound [Na].[Mn] GFORUURFPDRRRJ-UHFFFAOYSA-N 0.000 description 1
- DMPVSURQCULMSQ-UHFFFAOYSA-N [O].[Mn].[Na] Chemical compound [O].[Mn].[Na] DMPVSURQCULMSQ-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 150000002642 lithium compounds Chemical class 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 150000002736 metal compounds Chemical class 0.000 description 1
- 239000011259 mixed solution Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012805 post-processing Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000012266 salt solution Substances 0.000 description 1
- 239000013535 sea water Substances 0.000 description 1
- 238000010189 synthetic method Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108264135A (zh) * | 2018-03-26 | 2018-07-10 | 宁夏大学 | 电容脱盐电极及其制备方法 |
CN109830384A (zh) * | 2019-01-30 | 2019-05-31 | 绍兴文理学院 | 一种Na2Mn8O16/Mn2O3复合材料的制备及其电化学性能的测试方法 |
CN112707498A (zh) * | 2020-12-31 | 2021-04-27 | 南京师范大学 | 一种缓解厌氧正渗透膜生物反应器盐累积并控制污染物的装置及使用方法 |
CN113387392A (zh) * | 2021-06-09 | 2021-09-14 | 南昌大学 | 一种钠锰氧化物制备方法及在超级电容中的应用 |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1944544A (zh) * | 2006-09-22 | 2007-04-11 | 北京化工大学 | 一种含二氧化锰纳米片的紫外屏蔽剂及其制备、使用方法 |
CN101585555A (zh) * | 2009-06-08 | 2009-11-25 | 浙江工业大学 | 一种单层二氧化锰纳米片的制备方法 |
CN104716317A (zh) * | 2015-03-09 | 2015-06-17 | 郑州大学 | 一种钠离子电池NaxMnO2正极材料的合成方法 |
CN104828869A (zh) * | 2015-05-08 | 2015-08-12 | 湖南汇通科技有限责任公司 | 一种钠锰氧化物微粉及其制备方法 |
KR101613435B1 (ko) * | 2014-11-26 | 2016-04-20 | 한국생산기술연구원 | 전극제조를 위한 Na0.44MnO2 나노로드의 제조방법 및 이를 이용한 수계 나트륨 이차전지의 제조방법 |
CN103896339B (zh) * | 2012-12-27 | 2016-08-24 | 北京汉能创昱科技有限公司 | 一种钠锰氧化物的制备方法 |
-
2017
- 2017-09-27 CN CN201710917633.2A patent/CN107601569B/zh active Active
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1944544A (zh) * | 2006-09-22 | 2007-04-11 | 北京化工大学 | 一种含二氧化锰纳米片的紫外屏蔽剂及其制备、使用方法 |
CN101585555A (zh) * | 2009-06-08 | 2009-11-25 | 浙江工业大学 | 一种单层二氧化锰纳米片的制备方法 |
CN103896339B (zh) * | 2012-12-27 | 2016-08-24 | 北京汉能创昱科技有限公司 | 一种钠锰氧化物的制备方法 |
KR101613435B1 (ko) * | 2014-11-26 | 2016-04-20 | 한국생산기술연구원 | 전극제조를 위한 Na0.44MnO2 나노로드의 제조방법 및 이를 이용한 수계 나트륨 이차전지의 제조방법 |
CN104716317A (zh) * | 2015-03-09 | 2015-06-17 | 郑州大学 | 一种钠离子电池NaxMnO2正极材料的合成方法 |
CN104828869A (zh) * | 2015-05-08 | 2015-08-12 | 湖南汇通科技有限责任公司 | 一种钠锰氧化物微粉及其制备方法 |
Non-Patent Citations (2)
Title |
---|
O. PRIETO, ET AL.: "Characterisation of K, Na, and Li birnessites prepared by oxidation with H2O2 in a basic medium. Ion exchange properties and study of the calcined products", 《JOURNAL OF MATERIALS SCIENCE》 * |
QI FENG, ET AL.: "Synthesis of Birnessite-Type Sodium Manganese Oxides by Solution Reaction and Hydrothermal Methods", 《JOURNAL OF THE CERAMIC OF JAPAN》 * |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108264135A (zh) * | 2018-03-26 | 2018-07-10 | 宁夏大学 | 电容脱盐电极及其制备方法 |
CN108264135B (zh) * | 2018-03-26 | 2020-07-07 | 宁夏大学 | 电容脱盐电极及其制备方法 |
CN109830384A (zh) * | 2019-01-30 | 2019-05-31 | 绍兴文理学院 | 一种Na2Mn8O16/Mn2O3复合材料的制备及其电化学性能的测试方法 |
CN109830384B (zh) * | 2019-01-30 | 2021-02-26 | 绍兴文理学院 | 一种Na2Mn8O16/Mn2O3复合材料的制备及其电化学性能的测试方法 |
CN112707498A (zh) * | 2020-12-31 | 2021-04-27 | 南京师范大学 | 一种缓解厌氧正渗透膜生物反应器盐累积并控制污染物的装置及使用方法 |
CN113387392A (zh) * | 2021-06-09 | 2021-09-14 | 南昌大学 | 一种钠锰氧化物制备方法及在超级电容中的应用 |
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Inventor after: Dan Yuanyuan Inventor after: Teng Teng Inventor after: Gu Leixiang Inventor after: Sha Chunfan Inventor after: Ge Chichao Inventor after: Hu Ronghua Inventor before: Teng Teng Inventor before: Gu Leixiang Inventor before: Sha Chunfan Inventor before: Ge Chichao Inventor before: Hu Ronghua Inventor before: Dan Yuanyuan |