CN107530766B - 酚醛树脂组合物和相应的双组分粘合剂体系,应用及方法 - Google Patents
酚醛树脂组合物和相应的双组分粘合剂体系,应用及方法 Download PDFInfo
- Publication number
- CN107530766B CN107530766B CN201680022280.3A CN201680022280A CN107530766B CN 107530766 B CN107530766 B CN 107530766B CN 201680022280 A CN201680022280 A CN 201680022280A CN 107530766 B CN107530766 B CN 107530766B
- Authority
- CN
- China
- Prior art keywords
- phenolic resin
- resin composition
- acidic
- formaldehyde
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22C—FOUNDRY MOULDING
- B22C1/00—Compositions of refractory mould or core materials; Grain structures thereof; Chemical or physical features in the formation or manufacture of moulds
- B22C1/16—Compositions of refractory mould or core materials; Grain structures thereof; Chemical or physical features in the formation or manufacture of moulds characterised by the use of binding agents; Mixtures of binding agents
- B22C1/20—Compositions of refractory mould or core materials; Grain structures thereof; Chemical or physical features in the formation or manufacture of moulds characterised by the use of binding agents; Mixtures of binding agents of organic agents
- B22C1/22—Compositions of refractory mould or core materials; Grain structures thereof; Chemical or physical features in the formation or manufacture of moulds characterised by the use of binding agents; Mixtures of binding agents of organic agents of resins or rosins
- B22C1/2233—Compositions of refractory mould or core materials; Grain structures thereof; Chemical or physical features in the formation or manufacture of moulds characterised by the use of binding agents; Mixtures of binding agents of organic agents of resins or rosins obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- B22C1/2246—Condensation polymers of aldehydes and ketones
- B22C1/2253—Condensation polymers of aldehydes and ketones with phenols
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22C—FOUNDRY MOULDING
- B22C1/00—Compositions of refractory mould or core materials; Grain structures thereof; Chemical or physical features in the formation or manufacture of moulds
- B22C1/16—Compositions of refractory mould or core materials; Grain structures thereof; Chemical or physical features in the formation or manufacture of moulds characterised by the use of binding agents; Mixtures of binding agents
- B22C1/20—Compositions of refractory mould or core materials; Grain structures thereof; Chemical or physical features in the formation or manufacture of moulds characterised by the use of binding agents; Mixtures of binding agents of organic agents
- B22C1/22—Compositions of refractory mould or core materials; Grain structures thereof; Chemical or physical features in the formation or manufacture of moulds characterised by the use of binding agents; Mixtures of binding agents of organic agents of resins or rosins
- B22C1/2233—Compositions of refractory mould or core materials; Grain structures thereof; Chemical or physical features in the formation or manufacture of moulds characterised by the use of binding agents; Mixtures of binding agents of organic agents of resins or rosins obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- B22C1/2273—Polyurethanes; Polyisocyanates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/54—Polycondensates of aldehydes
- C08G18/542—Polycondensates of aldehydes with phenols
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
- C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
- C08G18/7657—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings
- C08G18/7664—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings containing alkylene polyphenyl groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G8/00—Condensation polymers of aldehydes or ketones with phenols only
- C08G8/04—Condensation polymers of aldehydes or ketones with phenols only of aldehydes
- C08G8/08—Condensation polymers of aldehydes or ketones with phenols only of aldehydes of formaldehyde, e.g. of formaldehyde formed in situ
- C08G8/10—Condensation polymers of aldehydes or ketones with phenols only of aldehydes of formaldehyde, e.g. of formaldehyde formed in situ with phenol
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L61/00—Compositions of condensation polymers of aldehydes or ketones; Compositions of derivatives of such polymers
- C08L61/04—Condensation polymers of aldehydes or ketones with phenols only
- C08L61/06—Condensation polymers of aldehydes or ketones with phenols only of aldehydes with phenols
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Phenolic Resins Or Amino Resins (AREA)
- Polyurethanes Or Polyureas (AREA)
- Mold Materials And Core Materials (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP15305547 | 2015-04-14 | ||
| EP15305547.0 | 2015-04-14 | ||
| PCT/EP2016/056120 WO2016165916A1 (de) | 2015-04-14 | 2016-03-21 | Phenolharz-komposition zur verwendung im polyurethan-cold-box- und/oder no-bake-verfahren sowie entsprechende zweikomponenten-bindemittelsysteme, verwendungen und verfahren |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN107530766A CN107530766A (zh) | 2018-01-02 |
| CN107530766B true CN107530766B (zh) | 2019-09-10 |
Family
ID=52946501
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201680022280.3A Active CN107530766B (zh) | 2015-04-14 | 2016-03-21 | 酚醛树脂组合物和相应的双组分粘合剂体系,应用及方法 |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US10835949B2 (https=) |
| EP (1) | EP3283541B1 (https=) |
| JP (1) | JP6887595B2 (https=) |
| KR (1) | KR102492617B1 (https=) |
| CN (1) | CN107530766B (https=) |
| BR (1) | BR112017022183B8 (https=) |
| CA (1) | CA2982681C (https=) |
| EA (1) | EA037245B1 (https=) |
| ES (1) | ES2946902T3 (https=) |
| MX (1) | MX2017013161A (https=) |
| WO (1) | WO2016165916A1 (https=) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| MX2017013161A (es) * | 2015-04-14 | 2018-02-21 | Huettenes Albertus France | Composicion de resina fenolica para uso en el proceso de caja fria y/o autofraguante de poliuretano y correspondientes sistemas aglomerantes de dos componentes, usos y procesos. |
| DE102016125702A1 (de) * | 2016-12-23 | 2018-06-28 | Ask Chemicals Gmbh | Komponentenystem zur Herstellung von Kernen und Formen |
| DE102016125624A1 (de) | 2016-12-23 | 2018-06-28 | HÜTTENES-ALBERTUS Chemische Werke Gesellschaft mit beschränkter Haftung | Phenolharz zur Verwendung in der Phenolharzkomponente eines Zweikomponenten- Bindemittelsystems |
| DE102018100694A1 (de) | 2018-01-12 | 2019-07-18 | Ask Chemicals Gmbh | Formaldehydreduziertes Phenolharzbindemittel |
| DE102018120993A1 (de) | 2018-08-28 | 2020-03-05 | Fritz Winter Eisengiesserei Gmbh & Co. Kg | Verfahren zur Begasung von für die Herstellung von Gießkernen in einen Kernkasten eingeschossenem Formstoff mit einem Katalysatorgas |
| DE102018133239A1 (de) | 2018-12-20 | 2020-06-25 | HÜTTENES-ALBERTUS Chemische Werke Gesellschaft mit beschränkter Haftung | Isocyanat-Komposition und Bindemittelsystem enthaltend diese Isocyanat-Komposition |
| DE102019106021A1 (de) * | 2019-03-08 | 2020-09-10 | HÜTTENES-ALBERTUS Chemische Werke Gesellschaft mit beschränkter Haftung | Formaldehyd-Fänger für Bindemittelsysteme |
| DE102019116846A1 (de) | 2019-06-21 | 2020-12-24 | HÜTTENES-ALBERTUS Chemische Werke Gesellschaft mit beschränkter Haftung | Schussdüse mit Spülfunktion |
| DE102019135605A1 (de) * | 2019-12-20 | 2021-06-24 | Ask Chemicals Gmbh | Verfahren zum schichtweisen Aufbau von Körpern umfassend feuerfesten Formgrundstoff und Resole, nach diesem Verfahren hergestellte dreidimensionale Körper sowie ein Bindemittel für den 3-dimensionalen Aufbau von Körpern |
| DE102022110540A1 (de) * | 2022-04-29 | 2023-11-02 | tooz technologies GmbH | Verfahren zur anpassung des brechungsindex |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5160503A (en) * | 1989-11-13 | 1992-11-03 | West Point Pepperell | Water-soluble blends of active methylene compounds and polyhydric alcohols as formaldehyde scavengers |
| US5795933A (en) * | 1996-12-19 | 1998-08-18 | The Dexter Corporation | Waterborne coating compositions having ultra low formaldehyde concentration |
| DE102004057671B4 (de) * | 2004-11-29 | 2007-04-26 | Hüttenes-Albertus Chemische Werke GmbH | Phenol-Formaldehydharze und Verfahren zu deren Herstellung |
| CN103314026A (zh) * | 2010-11-19 | 2013-09-18 | 胡坦斯·阿尔伯图斯化学厂有限公司 | 供用于制造模具和型芯的造型材料混合物的包含磺酸的粘合剂 |
| CN104114614A (zh) * | 2012-02-09 | 2014-10-22 | 胡坦斯·阿尔伯图斯化学厂有限公司 | 冷芯盒黏合剂体系和用于用作为用于这种黏合剂体系的添加剂的混合物 |
Family Cites Families (38)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2212506A (en) | 1939-08-15 | 1940-08-27 | Eastman Kodak Co | Preparation of methylene dialkyl malonates |
| FR1056171A (fr) | 1950-12-29 | 1954-02-24 | Philips Nv | Procédé de préparation de solutions contenant un produit de précondensation de résine synthétique |
| DE1595206A1 (de) | 1964-08-12 | 1970-04-16 | Reichhold Albert Chemie Ag | Verfahren zur Herstellung formaldehydarmer,veraetherter Aminotriazinharze |
| US3485797A (en) | 1966-03-14 | 1969-12-23 | Ashland Oil Inc | Phenolic resins containing benzylic ether linkages and unsubstituted para positions |
| US3429848A (en) * | 1966-08-01 | 1969-02-25 | Ashland Oil Inc | Foundry binder composition comprising benzylic ether resin,polyisocyanate,and tertiary amine |
| JPS4817755B1 (https=) * | 1970-08-12 | 1973-05-31 | ||
| US3676392A (en) * | 1971-01-26 | 1972-07-11 | Ashland Oil Inc | Resin compositions |
| FR2389409B1 (https=) * | 1977-05-02 | 1980-02-01 | Rhone Poulenc Ind | |
| DE2759262C2 (de) | 1977-12-31 | 1983-04-28 | Hüttenes-Albertus Chemische Werke GmbH, 4000 Düsseldorf | Bindemittelsystem auf Polyurethan- Basis für Formstoff-Mischungen zur Herstellung von Gießformen und Kernen |
| US4273179A (en) | 1978-08-16 | 1981-06-16 | Ashland Oil, Inc. | Phenolic resin-polyisocyanate binder systems containing dibasic ester solvents |
| FR2486835A1 (fr) * | 1980-07-18 | 1982-01-22 | Rhone Poulenc Ind | Nouvelles compositions pour moules et noyaux en fonderie liees par des silicates |
| US4481310A (en) * | 1981-09-30 | 1984-11-06 | Cl Industries, Inc. | Furfuryl esters and resins |
| EP0084689B1 (en) * | 1981-12-21 | 1985-06-12 | Akzo N.V. | Process for the manufacture of a foundry core or mould |
| US4474904A (en) * | 1982-01-21 | 1984-10-02 | Lemon Peter H R B | Foundry moulds and cores |
| US4529807A (en) * | 1983-06-14 | 1985-07-16 | Cl Industries, Inc. | Furfuryl esters and resins |
| GB8326902D0 (en) | 1983-10-07 | 1983-11-09 | Wiggins Teape Group Ltd | Removal of formaldehyde from micro-capsules |
| US4590229A (en) | 1984-06-04 | 1986-05-20 | Ashland Oil, Inc. | Phenolic resin-polyisocyanate binder systems |
| US4546124A (en) | 1984-10-12 | 1985-10-08 | Acme Resin Corporation | Polyurethane binder compositions |
| US4862948A (en) * | 1988-02-24 | 1989-09-05 | Borden, Inc. | Phenolic resin adhesive pastes, assemblies prepared therefrom, and processes for preparing cast metal articles using these pastes |
| AU655813B2 (en) * | 1991-04-05 | 1995-01-12 | Barry William Ryan | Improved phenol formaldehyde resins |
| US5189079A (en) | 1991-06-12 | 1993-02-23 | Acme Resin Corp. | Low free formaldehyde phenolic polyol formulation |
| ES2164664T3 (es) * | 1991-08-15 | 2002-03-01 | Basf Corp | Procedimiento para la produccion de un polimero reticulado mediante la utilizacion de un compuesto beta-dicarbonilico. |
| US5358748A (en) | 1992-05-19 | 1994-10-25 | Schuller International, Inc. | Acidic glass fiber binding composition, method of use and curable glass fiber compositions |
| JP3562878B2 (ja) | 1995-07-07 | 2004-09-08 | 丸尾カルシウム株式会社 | 花弁状多孔質ヒドロキシアパタイト微粒子及びその製造方法 |
| DK0771599T4 (da) | 1995-11-01 | 2004-05-17 | Huettenes Albertus | Bindemiddel-system på polyurethan-basis til stöbe-sands-blandinger til fremstilling af stöbeforme og -kerner |
| DE19540831C2 (de) | 1995-11-02 | 1998-07-16 | Henkel Kgaa | Kosmetische und pharmazeutische Emulsionen |
| US5908914A (en) * | 1996-07-17 | 1999-06-01 | Ashland Inc. | Benzylic ether phenolic resole resins and their uses |
| DE19925115A1 (de) * | 1999-06-01 | 2000-12-07 | Huettenes Albertus | Bindemittelsystem für Formstoff-Mischungen zur Herstellung von Formen und Kernen |
| US6365646B1 (en) * | 1999-12-08 | 2002-04-02 | Borden Chemical, Inc. | Method to improve humidity resistance of phenolic urethane foundry binders |
| ATE384578T1 (de) | 2000-06-30 | 2008-02-15 | Ecole Polytech | Carboxylat-enthaltender photokatalytischer körper,seine herstellung und verwendung |
| WO2008086555A1 (de) | 2007-01-19 | 2008-07-24 | Dynea Oy | Phenol-formaldehyd-harze, verfahren zu deren herstellung sowie deren verwendung als bindemittel |
| DE102008007181A1 (de) | 2008-02-01 | 2009-08-06 | Ashland-Südchemie-Kernfest GmbH | Verwendung von verzweigten Alkandiolcarbonsäurediestern in Gießereibindemitteln auf Polyurethanbasis |
| FR2929952B1 (fr) * | 2008-04-11 | 2011-02-11 | Saint Gobain Isover | Composition d'encollage pour fibres minerales et produits resultants |
| US8975435B2 (en) | 2009-05-07 | 2015-03-10 | Optmed, Inc. | Methylidene malonate process |
| FR2948307B1 (fr) * | 2009-07-24 | 2014-07-25 | Huettenes Albertus France | Procede d'obtention d'un corps forme a partir d'un melange granulaire |
| FR2952067B1 (fr) | 2009-11-03 | 2012-05-25 | Saint Gobain Technical Fabrics | Composition filmogene renfermant un agent apte a pieger le formaldehyde |
| FR2995234B1 (fr) * | 2012-09-10 | 2014-12-19 | Huettenes Albertus France | Procede d'obtention d'un corps pour fonderie a partir d'un melange granulaire comprenant une resine polycondensee contenant des motifs aromatiques et un capteur de formaldehyde |
| MX2017013161A (es) * | 2015-04-14 | 2018-02-21 | Huettenes Albertus France | Composicion de resina fenolica para uso en el proceso de caja fria y/o autofraguante de poliuretano y correspondientes sistemas aglomerantes de dos componentes, usos y procesos. |
-
2016
- 2016-03-21 MX MX2017013161A patent/MX2017013161A/es unknown
- 2016-03-21 BR BR112017022183A patent/BR112017022183B8/pt active IP Right Grant
- 2016-03-21 CA CA2982681A patent/CA2982681C/en active Active
- 2016-03-21 ES ES16713787T patent/ES2946902T3/es active Active
- 2016-03-21 US US15/566,416 patent/US10835949B2/en active Active
- 2016-03-21 EP EP16713787.6A patent/EP3283541B1/de active Active
- 2016-03-21 WO PCT/EP2016/056120 patent/WO2016165916A1/de not_active Ceased
- 2016-03-21 JP JP2018505527A patent/JP6887595B2/ja active Active
- 2016-03-21 CN CN201680022280.3A patent/CN107530766B/zh active Active
- 2016-03-21 KR KR1020177032579A patent/KR102492617B1/ko active Active
- 2016-03-21 EA EA201792280A patent/EA037245B1/ru not_active IP Right Cessation
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5160503A (en) * | 1989-11-13 | 1992-11-03 | West Point Pepperell | Water-soluble blends of active methylene compounds and polyhydric alcohols as formaldehyde scavengers |
| US5795933A (en) * | 1996-12-19 | 1998-08-18 | The Dexter Corporation | Waterborne coating compositions having ultra low formaldehyde concentration |
| DE102004057671B4 (de) * | 2004-11-29 | 2007-04-26 | Hüttenes-Albertus Chemische Werke GmbH | Phenol-Formaldehydharze und Verfahren zu deren Herstellung |
| CN103314026A (zh) * | 2010-11-19 | 2013-09-18 | 胡坦斯·阿尔伯图斯化学厂有限公司 | 供用于制造模具和型芯的造型材料混合物的包含磺酸的粘合剂 |
| CN104114614A (zh) * | 2012-02-09 | 2014-10-22 | 胡坦斯·阿尔伯图斯化学厂有限公司 | 冷芯盒黏合剂体系和用于用作为用于这种黏合剂体系的添加剂的混合物 |
Also Published As
| Publication number | Publication date |
|---|---|
| WO2016165916A1 (de) | 2016-10-20 |
| ES2946902T3 (es) | 2023-07-28 |
| EA201792280A1 (ru) | 2018-05-31 |
| JP6887595B2 (ja) | 2021-06-16 |
| KR20170137823A (ko) | 2017-12-13 |
| US20180126449A1 (en) | 2018-05-10 |
| MX2017013161A (es) | 2018-02-21 |
| CA2982681A1 (en) | 2016-10-20 |
| EP3283541A1 (de) | 2018-02-21 |
| EA037245B1 (ru) | 2021-02-25 |
| BR112017022183B1 (pt) | 2022-08-23 |
| BR112017022183B8 (pt) | 2023-05-16 |
| CA2982681C (en) | 2022-04-05 |
| JP2018517047A (ja) | 2018-06-28 |
| KR102492617B1 (ko) | 2023-01-27 |
| EP3283541B1 (de) | 2023-06-07 |
| EP3283541C0 (de) | 2023-06-07 |
| CN107530766A (zh) | 2018-01-02 |
| BR112017022183A2 (pt) | 2018-07-03 |
| US10835949B2 (en) | 2020-11-17 |
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