CN107108433A - 生产具有低乙酸丁酯含量的乙酸产物的方法 - Google Patents

生产具有低乙酸丁酯含量的乙酸产物的方法 Download PDF

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Publication number
CN107108433A
CN107108433A CN201580068310.XA CN201580068310A CN107108433A CN 107108433 A CN107108433 A CN 107108433A CN 201580068310 A CN201580068310 A CN 201580068310A CN 107108433 A CN107108433 A CN 107108433A
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CN
China
Prior art keywords
acetic acid
acid product
stream
equal
reaction medium
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Pending
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CN201580068310.XA
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English (en)
Chinese (zh)
Inventor
Y-H·刘
M·O·斯凯特斯
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Celanese International Corp
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Celanese International Corp
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Priority to CN202310216130.8A priority Critical patent/CN116143604A/zh
Publication of CN107108433A publication Critical patent/CN107108433A/zh
Pending legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/10—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide
    • C07C51/12—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide on an oxygen-containing group in organic compounds, e.g. alcohols
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/46—Ruthenium, rhodium, osmium or iridium
    • B01J23/464—Rhodium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/42—Separation; Purification; Stabilisation; Use of additives
    • C07C51/43—Separation; Purification; Stabilisation; Use of additives by change of the physical state, e.g. crystallisation
    • C07C51/44—Separation; Purification; Stabilisation; Use of additives by change of the physical state, e.g. crystallisation by distillation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/42—Separation; Purification; Stabilisation; Use of additives
    • C07C51/50—Use of additives, e.g. for stabilisation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C53/00—Saturated compounds having only one carboxyl group bound to an acyclic carbon atom or hydrogen
    • C07C53/08—Acetic acid

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
CN201580068310.XA 2014-11-14 2015-10-02 生产具有低乙酸丁酯含量的乙酸产物的方法 Pending CN107108433A (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202310216130.8A CN116143604A (zh) 2014-11-14 2015-10-02 生产具有低乙酸丁酯含量的乙酸产物的方法

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US201462079991P 2014-11-14 2014-11-14
US62/079,991 2014-11-14
US14/694,932 US9260369B1 (en) 2014-11-14 2015-04-23 Processes for producing acetic acid product having low butyl acetate content
US14/694,932 2015-04-23
PCT/US2015/053843 WO2016076972A1 (en) 2014-11-14 2015-10-02 Processes for producing an acetic acid product having low butyl acetate content

Related Child Applications (1)

Application Number Title Priority Date Filing Date
CN202310216130.8A Division CN116143604A (zh) 2014-11-14 2015-10-02 生产具有低乙酸丁酯含量的乙酸产物的方法

Publications (1)

Publication Number Publication Date
CN107108433A true CN107108433A (zh) 2017-08-29

Family

ID=55275322

Family Applications (2)

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CN201580068310.XA Pending CN107108433A (zh) 2014-11-14 2015-10-02 生产具有低乙酸丁酯含量的乙酸产物的方法
CN202310216130.8A Pending CN116143604A (zh) 2014-11-14 2015-10-02 生产具有低乙酸丁酯含量的乙酸产物的方法

Family Applications After (1)

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Country Status (12)

Country Link
US (4) US9260369B1 (enExample)
EP (1) EP3218344B1 (enExample)
JP (3) JP2016094384A (enExample)
KR (1) KR102465082B1 (enExample)
CN (2) CN107108433A (enExample)
ES (1) ES2846182T3 (enExample)
MX (1) MX380593B (enExample)
MY (1) MY181881A (enExample)
RS (1) RS61473B1 (enExample)
SA (1) SA517381516B1 (enExample)
SG (1) SG11201703427QA (enExample)
WO (1) WO2016076972A1 (enExample)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110325503A (zh) * 2018-05-29 2019-10-11 株式会社大赛璐 乙酸的制备方法
CN110869342A (zh) * 2018-05-29 2020-03-06 株式会社大赛璐 乙酸的制备方法
TWI778256B (zh) * 2018-05-02 2022-09-21 日商大賽璐股份有限公司 醋酸之製造方法

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9540304B2 (en) 2014-11-14 2017-01-10 Celanese International Corporation Processes for producing an acetic acid product having low butyl acetate content
US9260369B1 (en) 2014-11-14 2016-02-16 Celanese International Corporation Processes for producing acetic acid product having low butyl acetate content
MX374711B (es) 2017-01-18 2025-03-06 Daicel Corp Metodo para la produccion de acido acetico
MY189056A (en) * 2017-03-08 2022-01-24 Daicel Corp Method for producing acetic acid
US10457622B2 (en) 2017-03-08 2019-10-29 Daicel Corporation Method for producing acetic acid
MX374127B (es) 2017-03-22 2025-03-05 Daicel Corp Método para producir ácido acético .

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5001259A (en) * 1984-05-03 1991-03-19 Hoechst Celanese Corporation Methanol carbonylation process
CN1126195A (zh) * 1994-06-15 1996-07-10 大赛璐化学工业株式会社 高纯乙酸的生产方法
CN1371352A (zh) * 1999-08-31 2002-09-25 国际人造丝公司 改进甲醇羰基化方法中杂质分布的铑/无机碘化物催化剂体系
CN1491199A (zh) * 2001-02-07 2004-04-21 ����˹���ʹ�˾ 低能量羰基化方法
WO2008153708A2 (en) * 2007-05-21 2008-12-18 Celanese International Corporation Reaction product of rhodium-catalyzed methanol carbonylation

Family Cites Families (57)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3769329A (en) 1970-03-12 1973-10-30 Monsanto Co Production of carboxylic acids and esters
FR2496644A1 (fr) 1980-12-24 1982-06-25 Rhone Poulenc Ind Procede de preparation de l'anhydride acetique
US4733006A (en) 1980-12-29 1988-03-22 Monsanto Company Carbonylation process with an alkali metal acetate as catalyst stabilizer
US4792620A (en) * 1983-10-14 1988-12-20 Bp Chemicals Limited Carbonylation catalysts
US5026908A (en) 1984-05-03 1991-06-25 Hoechst Celanese Corporation Methanol carbonylation process
US5144068A (en) 1984-05-03 1992-09-01 Hoechst Celanese Corporation Methanol carbonylation process
US4615806B1 (en) 1985-03-07 1994-05-03 Hoechst Co American Removal of iodide compounds from non-aqueous organic media
JPH0487284A (ja) 1990-07-30 1992-03-19 Mitsubishi Electric Corp 避雷器切離し装置
AU8790391A (en) 1990-11-19 1992-05-21 Hoechst Celanese Corporation Removal of carbonyl impurities from a carbonylation process stream
CA2093752C (en) 1992-04-15 1999-06-15 David W. Studer Integrated process for oxygenated acetyl compounds from synthesis gas via dimethyl ether
GB9211671D0 (en) 1992-06-02 1992-07-15 Bp Chem Int Ltd Process
US5672743A (en) 1993-09-10 1997-09-30 Bp Chemicals Limited Process for the production of acetic acid
JP3377555B2 (ja) 1993-05-31 2003-02-17 ダイセル化学工業株式会社 カルボニル化反応生成物に含有されるヨウ素化合物の除去方法
JP3244350B2 (ja) 1993-07-08 2002-01-07 ダイセル化学工業株式会社 高純度酢酸の製造方法
JP3244351B2 (ja) 1993-07-08 2002-01-07 ダイセル化学工業株式会社 高純度酢酸の製造方法
TW283702B (enExample) 1993-07-08 1996-08-21 Daicel Chem
JP3244385B2 (ja) * 1994-06-15 2002-01-07 ダイセル化学工業株式会社 高純度酢酸の製造方法
JP3581725B2 (ja) * 1994-06-30 2004-10-27 ダイセル化学工業株式会社 アセトアルデヒドとヨウ化メチルの分離方法
US5696284A (en) 1995-06-21 1997-12-09 Bp Chemicals Limited Process for the carbonylation of alkyl alcohols and/or reactive derivatives thereof
US5783731A (en) 1995-09-11 1998-07-21 Hoechst Celanese Corporation Removal of carbonyl impurities from a carbonylation process stream
CN1092179C (zh) 1995-10-27 2002-10-09 赫希斯特人造丝公司 除去腐蚀金属以改善羰基化催化剂溶液生产率的方法
IN192600B (enExample) 1996-10-18 2004-05-08 Hoechst Celanese Corp
US6339171B1 (en) 1996-10-18 2002-01-15 Celanese International Corporation Removal or reduction of permanganate reducing compounds and alkyl iodides from a carbonylation process stream
GB9625335D0 (en) 1996-12-05 1997-01-22 Bp Chem Int Ltd Process
GB9626429D0 (en) 1996-12-19 1997-02-05 Bp Chem Int Ltd Process
GB9626317D0 (en) 1996-12-19 1997-02-05 Bp Chem Int Ltd Process
GB9626428D0 (en) 1996-12-19 1997-02-05 Bp Chem Int Ltd Process
JPH10231267A (ja) 1997-02-19 1998-09-02 Chiyoda Corp 有機カルボン酸の製造方法
US6066762A (en) 1996-12-30 2000-05-23 Chiyoda Corporation Process for the production of carbonyl compound
JPH10237009A (ja) 1997-02-28 1998-09-08 Mitsubishi Gas Chem Co Inc ギ酸メチルからの酢酸の製造方法
US6573403B1 (en) 1998-03-31 2003-06-03 Haldor Topsoe A/S Process for production of acetic acid
US6211405B1 (en) 1998-10-23 2001-04-03 Celanese International Corporation Addition of iridium to the rhodium/inorganic iodide catalyst system
US6225498B1 (en) 2000-03-24 2001-05-01 Celanese International Corporation Method of removing organic iodides from organic media
JP2004131389A (ja) 2002-10-08 2004-04-30 Daicel Chem Ind Ltd カルボン酸の製造方法及び製造システム
US7005541B2 (en) 2002-12-23 2006-02-28 Celanese International Corporation Low water methanol carbonylation process for high acetic acid production and for water balance control
US7223886B2 (en) 2004-03-02 2007-05-29 Celanese International Corporation Removal of permanganate reducing compounds from methanol carbonylation process stream
US7223883B2 (en) 2004-03-02 2007-05-29 Celanese International Corporation Removal of permanganate reducing compounds from methanol carbonylation process stream
JP4526381B2 (ja) 2004-12-27 2010-08-18 ダイセル化学工業株式会社 酢酸の製造方法
US7855306B2 (en) 2005-04-28 2010-12-21 Celanese International Corporation Process for the production of acetic acid
US7989659B2 (en) 2007-05-17 2011-08-02 Celanese International Corporation Method and apparatus for making acetic acid with improved light ends column productivity
US8062482B2 (en) 2007-10-30 2011-11-22 Celanese International Corporation Acetaldehyde removal from methyl acetate by distillation at elevated pressure
MY175851A (en) 2008-04-29 2020-07-13 Celanese Int Corp Methanol carbonylation system having absorber with multiple solvent options
US7884237B2 (en) 2008-11-07 2011-02-08 Celanese International Corp. Methanol carbonylation with improved aldehyde removal
US8889904B2 (en) 2010-05-18 2014-11-18 Celanese International Corporation Processes for producing acetic acid
EP2598467B1 (en) 2010-07-26 2017-09-06 Daicel Corporation Process for producing acetic acid
SG189063A1 (en) 2010-10-06 2013-05-31 Daicel Corp Process for producing acetic acid
USRE47569E1 (en) 2010-12-15 2019-08-13 Daicel Corporation Process for producing acetic acid
MX340954B (es) 2010-12-15 2016-07-29 Daicel Corp Procedimiento para producir acido acetico.
MX340955B (es) 2010-12-15 2016-07-29 Daicel Corp Procedimiento para producir acido acetico.
JP6007108B2 (ja) 2010-12-24 2016-10-12 株式会社ダイセル 酢酸の製造方法
TWI547477B (zh) 2012-03-14 2016-09-01 大賽璐股份有限公司 醋酸之製造方法
US9193657B2 (en) 2012-08-17 2015-11-24 Celanese International Corporation Catalyst stability in carbonylation processes
JP6291420B2 (ja) * 2012-12-21 2018-03-14 株式会社ダイセル 酢酸の製造方法
AR094541A1 (es) 2013-01-25 2015-08-12 Daicel Corp Procedimiento para producir ácido carboxílico
US9260369B1 (en) 2014-11-14 2016-02-16 Celanese International Corporation Processes for producing acetic acid product having low butyl acetate content
SG11201707623QA (en) 2015-09-29 2017-10-30 Daicel Corp Method of producing acetic acid
US11014868B2 (en) 2016-03-01 2021-05-25 Daicel Corporation Method for producing acetic acid

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5001259A (en) * 1984-05-03 1991-03-19 Hoechst Celanese Corporation Methanol carbonylation process
CN1126195A (zh) * 1994-06-15 1996-07-10 大赛璐化学工业株式会社 高纯乙酸的生产方法
CN1371352A (zh) * 1999-08-31 2002-09-25 国际人造丝公司 改进甲醇羰基化方法中杂质分布的铑/无机碘化物催化剂体系
CN1491199A (zh) * 2001-02-07 2004-04-21 ����˹���ʹ�˾ 低能量羰基化方法
WO2008153708A2 (en) * 2007-05-21 2008-12-18 Celanese International Corporation Reaction product of rhodium-catalyzed methanol carbonylation

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TWI778256B (zh) * 2018-05-02 2022-09-21 日商大賽璐股份有限公司 醋酸之製造方法
TWI828204B (zh) * 2018-05-02 2024-01-01 日商大賽璐股份有限公司 醋酸之製造方法
CN110325503A (zh) * 2018-05-29 2019-10-11 株式会社大赛璐 乙酸的制备方法
CN110869342A (zh) * 2018-05-29 2020-03-06 株式会社大赛璐 乙酸的制备方法
CN110869342B (zh) * 2018-05-29 2022-07-12 株式会社大赛璐 乙酸的制备方法
CN110325503B (zh) * 2018-05-29 2023-05-02 株式会社大赛璐 乙酸的制备方法

Also Published As

Publication number Publication date
MX2017006297A (es) 2017-08-21
US11014867B2 (en) 2021-05-25
RS61473B1 (sr) 2021-03-31
US20190119190A1 (en) 2019-04-25
EP3218344B1 (en) 2020-11-25
MY181881A (en) 2021-01-12
KR20170083617A (ko) 2017-07-18
US10173955B2 (en) 2019-01-08
JP2022110086A (ja) 2022-07-28
US9260369B1 (en) 2016-02-16
US20170349522A1 (en) 2017-12-07
WO2016076972A1 (en) 2016-05-19
CN116143604A (zh) 2023-05-23
ES2846182T3 (es) 2021-07-28
MX380593B (es) 2025-03-12
EP3218344A1 (en) 2017-09-20
JP2016094384A (ja) 2016-05-26
JP7108385B2 (ja) 2022-07-28
US20160159721A1 (en) 2016-06-09
KR102465082B1 (ko) 2022-11-09
US9776942B2 (en) 2017-10-03
SA517381516B1 (ar) 2021-11-24
SG11201703427QA (en) 2017-05-30
JP2018030831A (ja) 2018-03-01

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Application publication date: 20170829

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