CN107096551A - 一种2,2,4‑三甲基‑1,3‑戊二醇双异丁酸酯酯化反应催化剂及制备方法和用途 - Google Patents
一种2,2,4‑三甲基‑1,3‑戊二醇双异丁酸酯酯化反应催化剂及制备方法和用途 Download PDFInfo
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- CN107096551A CN107096551A CN201710190274.5A CN201710190274A CN107096551A CN 107096551 A CN107096551 A CN 107096551A CN 201710190274 A CN201710190274 A CN 201710190274A CN 107096551 A CN107096551 A CN 107096551A
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/14—Phosphorus; Compounds thereof
- B01J27/16—Phosphorus; Compounds thereof containing oxygen, i.e. acids, anhydrides and their derivates with N, S, B or halogens without carriers or on carriers based on C, Si, Al or Zr; also salts of Si, Al and Zr
- B01J27/18—Phosphorus; Compounds thereof containing oxygen, i.e. acids, anhydrides and their derivates with N, S, B or halogens without carriers or on carriers based on C, Si, Al or Zr; also salts of Si, Al and Zr with metals other than Al or Zr
- B01J27/1802—Salts or mixtures of anhydrides with compounds of other metals than V, Nb, Ta, Cr, Mo, W, Mn, Tc, Re, e.g. phosphates, thiophosphates
- B01J27/1806—Salts or mixtures of anhydrides with compounds of other metals than V, Nb, Ta, Cr, Mo, W, Mn, Tc, Re, e.g. phosphates, thiophosphates with alkaline or alkaline earth metals
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/02—Sulfur, selenium or tellurium; Compounds thereof
- B01J27/053—Sulfates
- B01J27/055—Sulfates with alkali metals, copper, gold or silver
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/08—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides with the hydroxy or O-metal group of organic compounds
Abstract
Description
序号 | 十二碳醇酯转化率% | 2,2,4-三甲基-1,3-戊二醇双异丁酸酯选择性% |
1 | 94.2 | 96.5 |
2 | 94.2 | 96.5 |
3 | 94.2 | 96.3 |
4 | 94.0 | 96.4 |
5 | 92.9 | 96.4 |
6 | 92.9 | 96.1 |
7 | 92.5 | 96.0 |
Claims (6)
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CN201710190274.5A CN107096551B (zh) | 2017-03-28 | 2017-03-28 | 一种2,2,4-三甲基-1,3-戊二醇双异丁酸酯酯化反应催化剂及制备方法和用途 |
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Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109369384A (zh) * | 2018-11-06 | 2019-02-22 | 安徽省化工设计院 | 一种txib的生产工艺 |
CN110423196A (zh) * | 2019-07-25 | 2019-11-08 | 润泰化学(泰兴)有限公司 | 一种微波反应合成1,3-二醇双酯的方法 |
CN111393288A (zh) * | 2020-04-30 | 2020-07-10 | 润泰化学(泰兴)有限公司 | 一种2,2,4-三甲基-1,3戊二醇二丁酸酯的合成工艺及其在内墙乳胶漆中的应用 |
CN113024376A (zh) * | 2021-03-12 | 2021-06-25 | 润泰化学(泰兴)有限公司 | 十六碳双酯的生产工艺 |
CN115433083A (zh) * | 2022-09-30 | 2022-12-06 | 润泰新材料股份有限公司 | 一种十六碳醇酯的生产工艺 |
Citations (2)
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CN105396446A (zh) * | 2015-10-15 | 2016-03-16 | 南京工业大学 | 一种复合无机盐氨气洗消剂及其制备方法和应用 |
CN105399603A (zh) * | 2015-12-22 | 2016-03-16 | 山东理工大学 | 同时合成2,2,4-三甲基-1,3-戊二醇双异丁酸酯和2,2,4-三甲基-1,3-戊二醇的方法 |
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2017
- 2017-03-28 CN CN201710190274.5A patent/CN107096551B/zh active Active
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
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CN105396446A (zh) * | 2015-10-15 | 2016-03-16 | 南京工业大学 | 一种复合无机盐氨气洗消剂及其制备方法和应用 |
CN105399603A (zh) * | 2015-12-22 | 2016-03-16 | 山东理工大学 | 同时合成2,2,4-三甲基-1,3-戊二醇双异丁酸酯和2,2,4-三甲基-1,3-戊二醇的方法 |
Non-Patent Citations (2)
Title |
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汪艳飞: "醇酸酯化反应催化剂研究进展", 《广东化工》 * |
訾俊峰等: "复合无机盐CuSO4/Fe2(SO4)3催化合成乙酸异戊酯", 《工业催化》 * |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109369384A (zh) * | 2018-11-06 | 2019-02-22 | 安徽省化工设计院 | 一种txib的生产工艺 |
CN110423196A (zh) * | 2019-07-25 | 2019-11-08 | 润泰化学(泰兴)有限公司 | 一种微波反应合成1,3-二醇双酯的方法 |
CN111393288A (zh) * | 2020-04-30 | 2020-07-10 | 润泰化学(泰兴)有限公司 | 一种2,2,4-三甲基-1,3戊二醇二丁酸酯的合成工艺及其在内墙乳胶漆中的应用 |
CN113024376A (zh) * | 2021-03-12 | 2021-06-25 | 润泰化学(泰兴)有限公司 | 十六碳双酯的生产工艺 |
CN115433083A (zh) * | 2022-09-30 | 2022-12-06 | 润泰新材料股份有限公司 | 一种十六碳醇酯的生产工艺 |
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Inventor after: Lu Mohong Inventor after: Liu Ping Inventor after: Du Hu Inventor after: Li Mingshi Inventor after: Zhang Wei Inventor before: Lu Mohong Inventor before: Du Hu Inventor before: Li Mingshi Inventor before: Zhang Wei |
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