CN106661652A - 用于制造超高强度涂覆或未涂覆钢板的方法和获得的板 - Google Patents
用于制造超高强度涂覆或未涂覆钢板的方法和获得的板 Download PDFInfo
- Publication number
- CN106661652A CN106661652A CN201480080347.XA CN201480080347A CN106661652A CN 106661652 A CN106661652 A CN 106661652A CN 201480080347 A CN201480080347 A CN 201480080347A CN 106661652 A CN106661652 A CN 106661652A
- Authority
- CN
- China
- Prior art keywords
- steel
- seconds
- steel plate
- partition
- temperature
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229910000831 Steel Inorganic materials 0.000 title claims abstract description 91
- 239000010959 steel Substances 0.000 title claims abstract description 91
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 11
- 238000000137 annealing Methods 0.000 claims abstract description 19
- 239000000203 mixture Substances 0.000 claims abstract description 19
- 238000000034 method Methods 0.000 claims abstract description 18
- 238000010791 quenching Methods 0.000 claims abstract description 13
- 239000010960 cold rolled steel Substances 0.000 claims abstract description 9
- 239000012535 impurity Substances 0.000 claims abstract description 7
- 239000000126 substance Substances 0.000 claims abstract description 7
- 238000005192 partition Methods 0.000 claims description 32
- 229910052750 molybdenum Inorganic materials 0.000 claims description 16
- 229910052804 chromium Inorganic materials 0.000 claims description 15
- 229910001566 austenite Inorganic materials 0.000 claims description 11
- 239000011248 coating agent Substances 0.000 claims description 9
- 238000000576 coating method Methods 0.000 claims description 9
- 229910000734 martensite Inorganic materials 0.000 claims description 8
- 230000007704 transition Effects 0.000 claims description 8
- 230000000717 retained effect Effects 0.000 claims description 4
- 230000000171 quenching effect Effects 0.000 abstract description 9
- 238000001816 cooling Methods 0.000 abstract description 3
- 238000000638 solvent extraction Methods 0.000 abstract 3
- 238000003303 reheating Methods 0.000 abstract 1
- 230000009466 transformation Effects 0.000 abstract 1
- 239000011651 chromium Substances 0.000 description 23
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 10
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 10
- 239000011733 molybdenum Substances 0.000 description 10
- 229910052799 carbon Inorganic materials 0.000 description 6
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 4
- 238000003618 dip coating Methods 0.000 description 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- 239000011572 manganese Substances 0.000 description 4
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 3
- 238000005097 cold rolling Methods 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 238000005096 rolling process Methods 0.000 description 3
- 239000011701 zinc Substances 0.000 description 3
- 229910052725 zinc Inorganic materials 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 229910045601 alloy Inorganic materials 0.000 description 2
- 239000000956 alloy Substances 0.000 description 2
- 229910052796 boron Inorganic materials 0.000 description 2
- 238000005253 cladding Methods 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 238000009792 diffusion process Methods 0.000 description 2
- 238000010304 firing Methods 0.000 description 2
- 229910052748 manganese Inorganic materials 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 229910052698 phosphorus Inorganic materials 0.000 description 2
- 229910052710 silicon Inorganic materials 0.000 description 2
- 229910052717 sulfur Inorganic materials 0.000 description 2
- 229910052720 vanadium Inorganic materials 0.000 description 2
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 238000005098 hot rolling Methods 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 229910052758 niobium Inorganic materials 0.000 description 1
- 238000005554 pickling Methods 0.000 description 1
- 238000005204 segregation Methods 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 238000009628 steelmaking Methods 0.000 description 1
- 238000005728 strengthening Methods 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 229910000859 α-Fe Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
- C21D9/46—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for sheet metals
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B15/00—Layered products comprising a layer of metal
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B15/00—Layered products comprising a layer of metal
- B32B15/01—Layered products comprising a layer of metal all layers being exclusively metallic
- B32B15/013—Layered products comprising a layer of metal all layers being exclusively metallic one layer being formed of an iron alloy or steel, another layer being formed of a metal other than iron or aluminium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B15/00—Layered products comprising a layer of metal
- B32B15/04—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B15/00—Layered products comprising a layer of metal
- B32B15/04—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B15/043—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of metal
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B15/00—Layered products comprising a layer of metal
- B32B15/18—Layered products comprising a layer of metal comprising iron or steel
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
- C21D1/18—Hardening; Quenching with or without subsequent tempering
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
- C21D1/18—Hardening; Quenching with or without subsequent tempering
- C21D1/19—Hardening; Quenching with or without subsequent tempering by interrupted quenching
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
- C21D1/18—Hardening; Quenching with or without subsequent tempering
- C21D1/25—Hardening, combined with annealing between 300 degrees Celsius and 600 degrees Celsius, i.e. heat refining ("Vergüten")
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
- C21D1/78—Combined heat-treatments not provided for above
- C21D1/785—Thermocycling
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
- C21D8/0205—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips of ferrous alloys
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
- C21D8/0221—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the working steps
- C21D8/0236—Cold rolling
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
- C21D8/0247—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the heat treatment
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
- C21D8/0278—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips involving a particular surface treatment
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
- C21D8/04—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips to produce plates or strips for deep-drawing
- C21D8/0447—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips to produce plates or strips for deep-drawing characterised by the heat treatment
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
- C21D9/46—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for sheet metals
- C21D9/48—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for sheet metals deep-drawing sheets
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/02—Ferrous alloys, e.g. steel alloys containing silicon
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/04—Ferrous alloys, e.g. steel alloys containing manganese
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/06—Ferrous alloys, e.g. steel alloys containing aluminium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/12—Ferrous alloys, e.g. steel alloys containing tungsten, tantalum, molybdenum, vanadium, or niobium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/22—Ferrous alloys, e.g. steel alloys containing chromium with molybdenum or tungsten
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/26—Ferrous alloys, e.g. steel alloys containing chromium with niobium or tantalum
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/34—Ferrous alloys, e.g. steel alloys containing chromium with more than 1.5% by weight of silicon
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/38—Ferrous alloys, e.g. steel alloys containing chromium with more than 1.5% by weight of manganese
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
- C23C2/04—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor characterised by the coating material
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
- C23C2/04—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor characterised by the coating material
- C23C2/06—Zinc or cadmium or alloys based thereon
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
- C23C2/04—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor characterised by the coating material
- C23C2/12—Aluminium or alloys based thereon
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
- C23C2/26—After-treatment
- C23C2/28—Thermal after-treatment, e.g. treatment in oil bath
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
- C23C2/26—After-treatment
- C23C2/28—Thermal after-treatment, e.g. treatment in oil bath
- C23C2/29—Cooling or quenching
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
- C23C2/34—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor characterised by the shape of the material to be treated
- C23C2/36—Elongated material
- C23C2/40—Plates; Strips
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C30/00—Coating with metallic material characterised only by the composition of the metallic material, i.e. not characterised by the coating process
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C30/00—Coating with metallic material characterised only by the composition of the metallic material, i.e. not characterised by the coating process
- C23C30/005—Coating with metallic material characterised only by the composition of the metallic material, i.e. not characterised by the coating process on hard metal substrates
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D3/00—Electroplating: Baths therefor
- C25D3/02—Electroplating: Baths therefor from solutions
- C25D3/22—Electroplating: Baths therefor from solutions of zinc
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D5/00—Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
- C25D5/34—Pretreatment of metallic surfaces to be electroplated
- C25D5/36—Pretreatment of metallic surfaces to be electroplated of iron or steel
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D7/00—Electroplating characterised by the article coated
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D7/00—Electroplating characterised by the article coated
- C25D7/06—Wires; Strips; Foils
- C25D7/0614—Strips or foils
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D2211/00—Microstructure comprising significant phases
- C21D2211/001—Austenite
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D2211/00—Microstructure comprising significant phases
- C21D2211/008—Martensite
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/12—All metal or with adjacent metals
- Y10T428/12493—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
- Y10T428/12736—Al-base component
- Y10T428/1275—Next to Group VIII or IB metal-base component
- Y10T428/12757—Fe
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/12—All metal or with adjacent metals
- Y10T428/12493—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
- Y10T428/12771—Transition metal-base component
- Y10T428/12785—Group IIB metal-base component
- Y10T428/12792—Zn-base component
- Y10T428/12799—Next to Fe-base component [e.g., galvanized]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/12—All metal or with adjacent metals
- Y10T428/12493—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
- Y10T428/12771—Transition metal-base component
- Y10T428/12861—Group VIII or IB metal-base component
- Y10T428/12951—Fe-base component
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/12—All metal or with adjacent metals
- Y10T428/12493—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
- Y10T428/12771—Transition metal-base component
- Y10T428/12861—Group VIII or IB metal-base component
- Y10T428/12951—Fe-base component
- Y10T428/12972—Containing 0.01-1.7% carbon [i.e., steel]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/26—Web or sheet containing structurally defined element or component, the element or component having a specified physical dimension
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Mechanical Engineering (AREA)
- Thermal Sciences (AREA)
- Physics & Mathematics (AREA)
- Crystallography & Structural Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Heat Treatment Of Sheet Steel (AREA)
- Coating With Molten Metal (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
Abstract
用于制造拉伸强度≥1470MPa且总延伸率TE≥19%的冷轧钢板的方法,所述方法包括以下步骤:使未经处理的钢板在退火温度AT≥Ac3下退火,以重量%计,所述钢板的化学组成包含:0.34%≤C≤0.40%,1.50%≤Mn≤2.30%,1.50%≤Si≤2.40%,0%<Cr≤0.5%,0%<Mo≤0.3%,0.01%≤Al≤0.07%,剩余部分为Fe和不可避免的杂质,通过使退火钢板冷却至<Ms转变点且在150℃与250℃之间的淬火温度QT来使所述退火钢板淬火,通过将淬火钢板再加热至350℃至420℃的配分温度PT并在15秒至120秒的配分时间Pt期间将钢板保持在此温度下来进行配分处理。
Description
本发明涉及制造具有改进的拉伸强度和改进的总延伸率的涂覆或未涂覆高强度钢板以及通过此方法获得的板。
为了制造各种设备,例如机动车辆的车身结构构件和车身面板的部件,现在通常使用由DP(双相)钢多相、复相或马氏体钢制成的裸露的电镀锌、镀锌或镀锌层扩散退火处理的板。
例如,高强度多相可包含具有/不具有一些残留奥氏体的贝氏体-马氏体组织,并且包含约0.2%的C,约2%的Mn,约1.5%的Si,这将导致约750MPa的屈服强度,约980MPa的拉伸强度,约10%的总延伸率。这些板在连续退火线上通过从高于Ac3转变点的退火温度淬火至Ms转变点以上的过时效温度并将板保持在此温度下给定时间来制造。任选地对板进行镀锌或镀锌层扩散退火处理。
鉴于全球环境保护,为了减轻汽车部件的重量以提高其燃料效率,期望具有改进的强度-延展性平衡的板。但是这样的板还必须具有良好的可成形性。
在这方面,提出了使用所谓的淬火和配分制造由钢制成的具有改进的机械特性和良好的可成形性的板。以拉伸强度TS为约1470MPa且总延伸率至少为19%的涂覆或未涂覆(裸露)板为目标。
因此,本发明的目的是提供这样的板及其制造方法。
为此,本发明涉及用于制造拉伸强度TS至少为1470MPa且总延伸率TE至少为19%的冷轧钢板的方法,所述方法包括以下顺序步骤:
-使由钢制成的冷轧钢板在退火温度AT下退火,以重量%计,所述钢的化学组成包含:
0.34%≤C≤0.40%
1.50%≤Mn≤2.30%
1.50%≤Si≤2.40%
0%<Cr≤0.5%
0%<Mo≤0.3%
0.01%≤Al≤0.08%
剩余部分为Fe和不可避免的杂质,退火温度AT等于或高于所述钢的Ac3转变点以获得退火钢板,
通过使退火钢板冷却至低于钢的Ms转变点的淬火温度QT(通常在150℃与250℃之间)来使退火钢板淬火以获得淬火钢板,以及
通过在350℃至450℃的配分温度PT下再加热淬火钢板并在15秒至150秒的配分时间Pt期间将钢板保持在此温度下来进行配分处理。
优选地,退火温度AT在870℃与930℃之间。
在两个实施方案中,在配分后,使钢板冷却至室温以获得未涂覆钢板:
在第一实施方案中,钢的组成使得0.36%≤C≤0.40%,Cr<0.05%且Mo<0.05%,淬火温度在190℃与210℃之间且配分时间Pt在90秒与110秒之间。
在第二实施方案中,钢的组成使得0.34%≤C≤0.37%,0.35%≤Cr≤0.45%且0.07%≤Mo≤0.20%,淬火温度在200℃与230℃之间且配分时间Pt在25秒与120秒之间。
优选地,随后对裸露的冷轧钢进行电镀锌。
在一个实施方案中,在配分后,对钢板进行镀锌,然后使其冷却至室温,以获得涂覆钢板,钢的组成使得0.34%≤C≤0.37%,0.35%≤Cr≤0.45%且0.07%≤Mo≤0.20%,淬火温度在200℃与230℃之间且配分时间Pt在25秒与55秒之间。
本发明还涉及由钢制成的涂覆或未涂覆钢板,以重量%计,所述钢的化学组成包含:
0.34%≤C≤0.40%
1.50%≤Mn≤2.30%
1.50%≤Si≤2.40%
0%<Cr≤0.5%
0%<Mo≤0.3%
0.01%≤Al≤0.08%
剩余部分为Fe和不可避免的杂质,组织包含至少60%的马氏体和12%至15%的残留奥氏体,拉伸强度至少为1470MPa且总延伸率至少为19%。
在一个具体实施方案中,钢板为未涂覆的,钢的组成使得0<Cr<0.05%且0<Mo<0.05%,并且屈服强度高于1150MPa。
在另一个实施方案中,钢板为未涂覆的,钢的组成使得0.35%<Cr<0.45%且0.07%<Mo<0.20%,并且屈服强度高于880MPa,拉伸强度高于1520MPa,且总延伸率至少为20%。
在另一个实施方案中,钢板为镀锌的,钢的组成使得0.35%≤Cr≤0.45%且0.07%≤Mo≤0.20%,拉伸强度高于1510MPa且总延伸率至少为20%。
现在将详细描述本发明,但不引入限制。
根据本发明,通过热处理由钢制成的热轧或优选冷轧的钢板来获得板,以重量%计,钢的化学组成包含:
-0.34%至0.40%的碳,以确保令人满意的强度和改进残留奥氏体的稳定性。这是获得足够的延伸率所必需的。如果碳含量太高,则热轧板太硬而不能冷轧并且可焊接性不足。
-1.50%至2.40%的硅以使奥氏体稳定,以提供固溶强化和延迟具有合适步骤的配分期间碳化物的形成,以防止在板的表面上形成对涂布性能不利的氧化硅。
-1.50%至2.30%的锰以具有足够的淬透性,以获得包含至少60%的马氏体的组织,大于1470MPa的拉伸强度和避免对延展性不利的偏析问题。
-0%至0.3%的钼和0%至0.5%的铬以提高淬透性和使残留奥氏体稳定,以便大大减少配分期间奥氏体分解。由于残留量,排除绝对零值。当钢板为未涂覆的时,可以排除钼和铬并且它们的含量可以各自保持小于0.05%。当通过镀锌涂覆钢板时,钼含量优选为0.07%至0.20%而铬含量优选为0.35%至0.45%。
-优选地,0.01%至0.08%的铝,其通常被添加到液态钢中用于脱氧目的。
剩余部分为铁和由炼钢造成的残余元素或不可避免的杂质。在这方面,Ni、Cu、V、Ti、B、S、P和N至少被认为是残余元素(其是不可避免的杂质)。因此,通常,它们的含量为Ni小于0.05%,Cu小于0.05%,V小于0.007%,B小于0.001%,S小于0.005%,P小于0.02%且N小于0.010%。添加微合金元素(例如0%至0.05%的Nb和/或0%至0.1%的Ti)可用于获得期望的显微组织和产品特性的最佳组合。
未经处理的钢板是根据本领域技术人员已知的方法制备的冷轧钢板。
在轧制之后,将板酸洗或清洗,然后进行热处理和任选地热浸涂覆。
当未涂覆板时优选在连续退火上进行的热处理和当涂覆钢板时优选在热浸涂覆线上进行的热处理包括以下顺序步骤:
-使冷轧板在等于或高于钢的Ac3转变点,并且优选高于Ac3+15℃(以获得具有完全奥氏体的钢板)但小于1000℃(以便不使奥氏体晶粒过于粗化)的退火温度AT下退火。通常,高于870℃的温度对于根据本发明的钢是足够的并且该温度不需要高于930℃。然后将钢板保持在此温度下(即保持在AT-5℃与AT+10℃之间)持续足以使钢中的温度均匀的时间。优选地,该时间大于30秒但不需要大于300秒。为了加热至退火温度,例如,将冷轧钢板首先以通常小于20℃/秒的速度加热到约600℃的温度,然后以通常小于10℃/秒的速度再次加热到约800℃的温度,并且最后以小于5℃/秒的加热速度加热至退火温度。在这种情况下,将板保持在退火温度下40秒至150秒的持续时间。
-通过使退火板以足够快以避免在冷却后形成铁素体并且优选大于35℃/秒的冷却速率冷却至低于Ms转变点的淬火温度QT(在150℃与250℃之间)来使退火板淬火,以获得具有由马氏体和奥氏体组成的组织的淬火板,然后最终组织包含至少60%的马氏体和12%至15%的奥氏体。如果钢包含小于0.05%的钼和小于0.05%的铬,则淬火温度优选在190℃与210℃之间。当必须对钢板进行镀锌时和当钢的化学组成使得0.34%≤C≤0.37%,0.35%≤Cr≤0.45%且0.07%≤Mo≤0.20%时,淬火温度优选在200℃与230℃之间。
-将淬火板再加热到350℃与450℃之间的配分温度PT。加热速度优选至少为30℃/秒。
-将板保持在配分温度PT下持续15秒至150秒的配分时间Pt。在配分步骤期间,将碳配分(即从马氏体扩散到奥氏体(因此富集碳)中)。
-任选地,如果不期望涂覆,则使板冷却至室温,或者如果期望涂覆,则将板加热至涂覆温度,对板进行热浸涂覆并冷却至室温。如本领域中已知的,热浸涂覆是例如镀锌,并且涂覆温度为约460℃。
加热至涂覆温度优选以至少30℃/秒的加热速度进行并且涂覆需要2秒至10秒。
无论是否施加涂覆,到室温的冷却速度优选为3℃/秒至20℃/秒。
当板未被涂覆且钢优选包含小于0.05%的铬和小于0.05%的钼时,配分时间优选为90秒至110秒。通过这样的处理,可以获得屈服强度大于1150MPa,拉伸强度大于1470MPa且总延伸率大于19%的板。
当板未被涂覆且钢包含0.35%至0.45%的铬和0.07%至0.20%的钼时,配分时间优选为15秒至120秒。通过这样的处理,可以获得屈服强度大于880MPa,拉伸强度大于1520MPa且总延伸率大于20%的板。
当板被涂覆时,钢优选包含0.35%至0.45%的铬和0.07%至0.20%的钼,并且配分时间Pt优选为25秒至55秒。在这些条件下,甚至可以获得拉伸强度高于1510MPa且总延伸率至少为20%的涂覆钢板。
作为一些实施例和比较,制造由钢制成的板,按重量计钢的组成和特征温度(例如Ac3和Ms)列于表I中。
将板冷轧、退火、淬火、配分并冷却至室温或者在配分之后且在冷却至室温之前镀锌。
在相对于轧制方向的横向方向上测量机械特性。如本领域中公知的,对于这样的高强度钢,在轧制方向上的延展性水平略好于在横向方向上的延展性水平。测量的特性是根据标准ISO16630:2009测量的扩孔率HER、屈服强度YS、拉伸应力TS、均匀延伸率UE和总延伸率TE。
未涂覆板的处理条件和机械特性列于表II中而涂覆板的处理条件和机械特性列于表III中。
在这些表中,AT是退火温度,QT是淬火温度,PT是配分温度。在表II中,GI是镀锌的温度。
表I
表II
表III
实施例1至14表明,只有用既不含铬也不含钼的钢S181和包含铬和钼两者的钢S80才能达到期望的性能,即,TS≥1470MPa且TE≥19%。在合金S181中,对于200℃的淬火温度QT和100秒的配分时间实现了期望的性能。在这种情况下,屈服强度高于1150MPa。
在包含铬和钼的合金S80中,对于220℃的淬火温度QT和30秒至100秒的配分时间(实施例7至10)达到了期望的性能。在这种情况下,拉伸强度高于1520MPa且总延伸率大于20%。此外,值得注意的是,所有包含Cr和Mo的实施例(7至14)具有显著低于实施例1至6(涉及不含Cr和Mo的钢)的屈服强度。
实施例15至33表明,当对板进行镀锌时(实施例27和28),仅对应于包含Cr和Mo的钢的实施例能够达到期望的性能。对于钢S80,淬火温度必须为220℃,且10秒的配分太短而100秒的配分时间太长。当钢不含Cr且不含Mo时,拉伸强度总是保持低于1470MPa。
Claims (11)
1.一种用于制造拉伸强度TS至少为1470MPa且总延伸率TE至少为19%的冷轧钢板的方法,所述方法包括以下顺序步骤:
-使由钢制成的冷轧钢板在退火温度AT下退火,以重量%计,所述钢的化学组成包含:
0.34%≤C≤0.40%
1.50%≤Mn≤2.30%
1.50%≤Si≤2.40%
0%<Cr≤0.5%
0%<Mo≤0.3%
0.01%≤Al≤0.08%
剩余部分为Fe和不可避免的杂质,所述退火温度AT高于所述钢的Ac3转变点,
-通过使退火钢板冷却至低于所述钢的Ms转变点且在150℃与250℃之间的淬火温度QT来使所述退火钢板淬火,以及
-通过在350℃与450℃之间的配分温度PT下再加热淬火钢板并将所述钢板保持在此温度下15秒至150秒的配分时间Pt来进行配分处理。
2.根据权利要求1所述的方法,其特征在于,所述退火温度AT在870℃与930℃之间。
3.根据权利要求1或2所述的方法,其特征在于,在配分后,使所述钢板冷却至室温以获得未涂覆钢板,所述钢的组成为使得0.36%≤C≤0.40%,Cr<0.05%且Mo<0.05%,所述淬火温度在190℃与210℃之间且所述配分时间Pt在90秒与110秒之间。
4.根据权利要求1或2所述的方法,其特征在于,在配分后,使所述钢板冷却至室温以获得未涂覆钢板,所述钢的组成使得0.34%≤C≤0.37%,0.35%≤Cr≤0.45%且0.07%≤Mo≤0.20%,所述淬火温度在200℃与230℃之间且所述配分时间Pt在15秒与120秒之间。
5.根据权利要求1或2所述的方法,其特征在于,在配分后,对所述钢板进行镀锌然后冷却至室温以获得涂覆钢板,所述钢的组成使得0.34%≤C≤0.37%,0.35%≤Cr≤0.45%且0.07%≤Mo≤0.20%,所述淬火温度在200℃与230℃之间且所述配分时间Pt在25秒与55秒之间。
6.根据权利要求1至3中任一项所述的方法,其特征在于,对所述冷轧钢板进行电镀锌。
7.一种由钢制成的涂覆或未涂覆钢板,以重量%计,所述钢的化学组成包含:
0.34%≤C≤0.40%
1.50%≤Mn≤2.30%
1.50%≤Si≤2.40%
0%<Cr≤0.5%
0%<Mo≤0.3%
0.01%≤Al≤0.08%
剩余部分为Fe和不可避免的杂质,组织包含至少60%的马氏体和12%至15%的残留奥氏体,拉伸强度至少为1470MPa且总延伸率至少为19%。
8.根据权利要求7所述的钢板,其特征在于,所述钢板为未涂覆的,所述钢的组成使得Cr<0.05%且Mo<0.05%,并且所述屈服强度高于1150MPa。
9.根据权利要求7所述的钢板,其特征在于,所述钢板为未涂覆的,所述钢的组成使得0.35%≤Cr≤0.45%且0.07%≤Mo≤0.20%,所述屈服强度高于880MPa,所述拉伸强度高于1520MPa且所述总延伸率至少为20%。
10.根据权利要求7所述的钢板,其特征在于,所述钢板为镀锌的,所述钢的组成使得0.35%≤Cr≤0.45%且0.07%≤Mo≤0.20%,所述拉伸强度高于1510MPa且所述总延伸率至少为20%。
11.根据权利要求7所述的钢板,其特征在于,所述钢板为电镀锌的。
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PCT/IB2014/002379 WO2016001707A1 (en) | 2014-07-03 | 2014-07-03 | Method for producing an ultra high strength coated or not coated steel sheet and obtained sheet |
Publications (2)
Publication Number | Publication Date |
---|---|
CN106661652A true CN106661652A (zh) | 2017-05-10 |
CN106661652B CN106661652B (zh) | 2018-10-12 |
Family
ID=52014170
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201480080347.XA Active CN106661652B (zh) | 2014-07-03 | 2014-07-03 | 用于制造超高强度涂覆或未涂覆钢板的方法和获得的板 |
CN201580036402.XA Active CN106471138B (zh) | 2014-07-03 | 2015-07-03 | 用于生产超高强度涂覆钢板或未涂覆钢板的方法和获得的板 |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201580036402.XA Active CN106471138B (zh) | 2014-07-03 | 2015-07-03 | 用于生产超高强度涂覆钢板或未涂覆钢板的方法和获得的板 |
Country Status (16)
Country | Link |
---|---|
US (5) | US10378077B2 (zh) |
EP (4) | EP3164516B1 (zh) |
JP (3) | JP6343688B2 (zh) |
KR (4) | KR20170027744A (zh) |
CN (2) | CN106661652B (zh) |
BR (3) | BR112017000019B1 (zh) |
CA (3) | CA2953741C (zh) |
ES (4) | ES2777835T3 (zh) |
HU (4) | HUE049714T2 (zh) |
MA (1) | MA47181B1 (zh) |
MX (2) | MX2017000188A (zh) |
PL (4) | PL3492608T3 (zh) |
RU (2) | RU2669667C2 (zh) |
UA (2) | UA115745C2 (zh) |
WO (2) | WO2016001707A1 (zh) |
ZA (1) | ZA201700059B (zh) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110892087A (zh) * | 2017-06-20 | 2020-03-17 | 安赛乐米塔尔公司 | 具有高可电阻点焊性的经锌涂覆的钢板 |
CN113166828A (zh) * | 2018-12-18 | 2021-07-23 | 安赛乐米塔尔公司 | 经冷轧和热处理的钢板及其制造方法 |
CN113412340A (zh) * | 2019-02-18 | 2021-09-17 | 株式会社神户制钢所 | 钢板 |
Families Citing this family (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US9814560B2 (en) | 2013-12-05 | 2017-11-14 | W. L. Gore & Associates, Inc. | Tapered implantable device and methods for making such devices |
CA2953741C (en) | 2014-07-03 | 2021-08-10 | Arcelormittal | Method for producing an ultra high strength coated or not coated steel sheet and obtained sheet |
AU2016270380B2 (en) | 2015-06-05 | 2019-04-04 | W. L. Gore & Associates, Inc. | A low bleed implantable prosthesis with a taper |
CN106282494B (zh) * | 2016-09-18 | 2018-12-04 | 扬州大学 | 一种中碳合金钢的q-p热处理工艺 |
CN108018484B (zh) * | 2016-10-31 | 2020-01-31 | 宝山钢铁股份有限公司 | 抗拉强度1500MPa以上成形性优良的冷轧高强钢及其制造方法 |
CA3076994A1 (en) * | 2017-10-24 | 2019-05-02 | Arcelormittal | A method for the manufacture of a coated steel sheet, two spot welded metal sheets and use thereof |
WO2019122957A1 (en) * | 2017-12-19 | 2019-06-27 | Arcelormittal | A coated steel substrate |
US20220205058A1 (en) * | 2019-04-30 | 2022-06-30 | Tata Steel Nederland Technology B.V. | A high strength steel product and a process to produce a high strength steel product |
CN116917519A (zh) * | 2021-03-25 | 2023-10-20 | 日本制铁株式会社 | 钢板 |
DE212023000090U1 (de) | 2022-07-01 | 2024-06-05 | Lg Energy Solution, Ltd. | Zelleneinheit-Transportsystem |
WO2024162176A1 (ja) * | 2023-01-30 | 2024-08-08 | Jfeスチール株式会社 | 鋼板、部材およびそれらの製造方法 |
Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS61157625A (ja) * | 1984-12-29 | 1986-07-17 | Nippon Steel Corp | 高強度鋼板の製造方法 |
WO2004022794A1 (en) * | 2002-09-04 | 2004-03-18 | Colorado School Of Mines | Method for producing steel with retained austenite |
EP2325346A1 (en) * | 2008-09-10 | 2011-05-25 | JFE Steel Corporation | High-strength steel plate and manufacturing method thereof |
CN102884209A (zh) * | 2010-03-09 | 2013-01-16 | 杰富意钢铁株式会社 | 高强度钢板的制造方法 |
CN102884218A (zh) * | 2010-03-09 | 2013-01-16 | 杰富意钢铁株式会社 | 高强度钢板及其制造方法 |
CN103361547A (zh) * | 2012-03-30 | 2013-10-23 | 鞍钢股份有限公司 | 一种冷成型用超高强度钢板的生产方法及钢板 |
EP2660345A2 (en) * | 2010-12-27 | 2013-11-06 | Posco | Steel sheet having enhanced ductility for a molding member, molding member, and method for manufacturing same |
Family Cites Families (27)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB486584A (en) * | 1936-10-06 | 1938-06-07 | Joseph L Herman | Improvements in and relating to a method and apparatus for coating metals by dipping |
AUPM648394A0 (en) * | 1994-06-27 | 1994-07-21 | Tubemakers Of Australia Limited | Method of increasing the yield strength of cold formed steel sections |
US6368728B1 (en) * | 1998-11-18 | 2002-04-09 | Kawasaki Steel Corporation | Galvannealed steel sheet and manufacturing method |
US7090731B2 (en) | 2001-01-31 | 2006-08-15 | Kabushiki Kaisha Kobe Seiko Sho (Kobe Steel, Ltd.) | High strength steel sheet having excellent formability and method for production thereof |
DE10161465C1 (de) * | 2001-12-13 | 2003-02-13 | Thyssenkrupp Stahl Ag | Verfahren zum Herstellen von Warmband |
FR2850671B1 (fr) | 2003-02-05 | 2006-05-19 | Usinor | Procede de fabrication d'une bande d'acier dual-phase a structure ferrito-martensitique, laminee a froid et bande obtenue |
JP4268079B2 (ja) | 2003-03-26 | 2009-05-27 | 株式会社神戸製鋼所 | 伸び及び耐水素脆化特性に優れた超高強度鋼板、その製造方法、並びに該超高強度鋼板を用いた超高強度プレス成形部品の製造方法 |
JP4582707B2 (ja) * | 2005-04-20 | 2010-11-17 | 新日本製鐵株式会社 | 不メッキ欠陥発生のない溶融亜鉛メッキ方法 |
CN101225499B (zh) | 2008-01-31 | 2010-04-21 | 上海交通大学 | 低合金超高强度复相钢及其热处理方法 |
JP5402007B2 (ja) * | 2008-02-08 | 2014-01-29 | Jfeスチール株式会社 | 加工性に優れた高強度溶融亜鉛めっき鋼板およびその製造方法 |
KR20100034118A (ko) | 2008-09-23 | 2010-04-01 | 포항공과대학교 산학협력단 | 마르텐사이트 조직을 가진 초고강도 용융아연도금 강판 및 그 제조 방법 |
JP4924730B2 (ja) | 2009-04-28 | 2012-04-25 | Jfeスチール株式会社 | 加工性、溶接性および疲労特性に優れる高強度溶融亜鉛めっき鋼板およびその製造方法 |
JP5883211B2 (ja) * | 2010-01-29 | 2016-03-09 | 株式会社神戸製鋼所 | 加工性に優れた高強度冷延鋼板およびその製造方法 |
JP5136609B2 (ja) * | 2010-07-29 | 2013-02-06 | Jfeスチール株式会社 | 成形性および耐衝撃性に優れた高強度溶融亜鉛めっき鋼板およびその製造方法 |
EP2524970A1 (de) * | 2011-05-18 | 2012-11-21 | ThyssenKrupp Steel Europe AG | Hochfestes Stahlflachprodukt und Verfahren zu dessen Herstellung |
WO2013047739A1 (ja) * | 2011-09-30 | 2013-04-04 | 新日鐵住金株式会社 | 機械切断特性に優れた高強度溶融亜鉛めっき鋼板、高強度合金化溶融亜鉛めっき鋼板、並びにそれらの製造方法 |
MX2014003712A (es) | 2011-09-30 | 2014-07-09 | Nippon Steel & Sumitomo Metal Corp | Lamina de acero galvanizada por inmersion en caliente, de alta resistencia, y lamina de acero galvanizada por inmersion en caliente, aleada, de alta resistencia, que tiene excelente adhesion de enchapado, formabilidad, y capacidad de expansion de agujero con resistencia a la traccion de 980 mpa o mas y metodo de fabricacion de las mismas. |
KR20140068122A (ko) | 2011-09-30 | 2014-06-05 | 신닛테츠스미킨 카부시키카이샤 | 용융 아연 도금 강판 및 그 제조 방법 |
JP5764549B2 (ja) | 2012-03-29 | 2015-08-19 | 株式会社神戸製鋼所 | 成形性および形状凍結性に優れた、高強度冷延鋼板、高強度溶融亜鉛めっき鋼板および高強度合金化溶融亜鉛めっき鋼板、ならびにそれらの製造方法 |
RU2491357C1 (ru) * | 2012-05-10 | 2013-08-27 | Федеральное государственное автономное образовательное учреждение высшего профессионального образования "Национальный исследовательский технологический университет "МИСиС" | Способ производства листовой стали |
JP2014019928A (ja) | 2012-07-20 | 2014-02-03 | Jfe Steel Corp | 高強度冷延鋼板および高強度冷延鋼板の製造方法 |
CN104508163B (zh) * | 2012-07-31 | 2016-11-16 | 杰富意钢铁株式会社 | 成形性及定形性优异的高强度热浸镀锌钢板及其制造方法 |
BR112015015191A2 (pt) * | 2012-12-25 | 2017-07-11 | Nippon Steel & Sumitomo Metal Corp | chapa de aço galvanizada e recozida e método de produção da mesma |
CN103103435B (zh) | 2013-01-23 | 2015-06-03 | 北京科技大学 | 一种具有trip效应的球墨铸铁的制备工艺 |
WO2015011511A1 (fr) | 2013-07-24 | 2015-01-29 | Arcelormittal Investigación Y Desarrollo Sl | Tôle d'acier à très hautes caractéristiques mécaniques de résistance et de ductilité, procédé de fabrication et utilisation de telles tôles |
WO2015088523A1 (en) | 2013-12-11 | 2015-06-18 | ArcelorMittal Investigación y Desarrollo, S.L. | Cold rolled and annealed steel sheet |
CA2953741C (en) | 2014-07-03 | 2021-08-10 | Arcelormittal | Method for producing an ultra high strength coated or not coated steel sheet and obtained sheet |
-
2014
- 2014-07-03 CA CA2953741A patent/CA2953741C/en active Active
- 2014-07-03 KR KR1020167037088A patent/KR20170027744A/ko active Application Filing
- 2014-07-03 JP JP2016575858A patent/JP6343688B2/ja active Active
- 2014-07-03 EP EP14809104.4A patent/EP3164516B1/en active Active
- 2014-07-03 WO PCT/IB2014/002379 patent/WO2016001707A1/en active Application Filing
- 2014-07-03 HU HUE18213687A patent/HUE049714T2/hu unknown
- 2014-07-03 KR KR1020227018480A patent/KR102464733B1/ko active IP Right Grant
- 2014-07-03 MX MX2017000188A patent/MX2017000188A/es active IP Right Grant
- 2014-07-03 ES ES18213687T patent/ES2777835T3/es active Active
- 2014-07-03 CN CN201480080347.XA patent/CN106661652B/zh active Active
- 2014-07-03 RU RU2016151402A patent/RU2669667C2/ru active
- 2014-07-03 PL PL18213687T patent/PL3492608T3/pl unknown
- 2014-07-03 HU HUE14809104 patent/HUE044411T2/hu unknown
- 2014-07-03 EP EP18213687.9A patent/EP3492608B1/en active Active
- 2014-07-03 PL PL14809104T patent/PL3164516T3/pl unknown
- 2014-07-03 US US15/323,232 patent/US10378077B2/en active Active
- 2014-07-03 UA UAA201613350A patent/UA115745C2/uk unknown
- 2014-07-03 KR KR1020217019746A patent/KR102407064B1/ko active IP Right Grant
- 2014-07-03 ES ES14809104T patent/ES2737601T3/es active Active
- 2014-07-03 BR BR112017000019A patent/BR112017000019B1/pt active IP Right Grant
- 2014-07-03 BR BR122019019513-7A patent/BR122019019513B1/pt active IP Right Grant
-
2015
- 2015-07-03 EP EP15750460.6A patent/EP3164517B1/en active Active
- 2015-07-03 US US15/323,311 patent/US11001904B2/en active Active
- 2015-07-03 EP EP19182667.6A patent/EP3564397B1/en active Active
- 2015-07-03 PL PL19182667T patent/PL3564397T3/pl unknown
- 2015-07-03 UA UAA201613598A patent/UA120185C2/uk unknown
- 2015-07-03 KR KR1020177000025A patent/KR102462277B1/ko active IP Right Grant
- 2015-07-03 JP JP2016575869A patent/JP2017527691A/ja not_active Ceased
- 2015-07-03 HU HUE15750460A patent/HUE048514T2/hu unknown
- 2015-07-03 CA CA2954138A patent/CA2954138C/en active Active
- 2015-07-03 HU HUE19182667A patent/HUE054656T2/hu unknown
- 2015-07-03 MX MX2017000192A patent/MX2017000192A/es unknown
- 2015-07-03 BR BR112017000010-5A patent/BR112017000010B1/pt active IP Right Grant
- 2015-07-03 ES ES15750460T patent/ES2772298T3/es active Active
- 2015-07-03 CA CA3164285A patent/CA3164285C/en active Active
- 2015-07-03 ES ES19182667T patent/ES2866176T3/es active Active
- 2015-07-03 PL PL15750460T patent/PL3164517T3/pl unknown
- 2015-07-03 CN CN201580036402.XA patent/CN106471138B/zh active Active
- 2015-07-03 MA MA47181A patent/MA47181B1/fr unknown
- 2015-07-03 RU RU2016152277A patent/RU2684912C2/ru active
- 2015-07-03 WO PCT/IB2015/055034 patent/WO2016001890A2/en active Application Filing
-
2017
- 2017-01-04 ZA ZA2017/00059A patent/ZA201700059B/en unknown
-
2019
- 2019-05-15 US US16/413,111 patent/US11131003B2/en active Active
- 2019-05-15 US US16/413,163 patent/US11124853B2/en active Active
- 2019-05-17 JP JP2019093514A patent/JP6564963B1/ja active Active
-
2021
- 2021-04-07 US US17/225,033 patent/US20210222267A1/en active Pending
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS61157625A (ja) * | 1984-12-29 | 1986-07-17 | Nippon Steel Corp | 高強度鋼板の製造方法 |
WO2004022794A1 (en) * | 2002-09-04 | 2004-03-18 | Colorado School Of Mines | Method for producing steel with retained austenite |
EP2325346A1 (en) * | 2008-09-10 | 2011-05-25 | JFE Steel Corporation | High-strength steel plate and manufacturing method thereof |
CN102884209A (zh) * | 2010-03-09 | 2013-01-16 | 杰富意钢铁株式会社 | 高强度钢板的制造方法 |
CN102884218A (zh) * | 2010-03-09 | 2013-01-16 | 杰富意钢铁株式会社 | 高强度钢板及其制造方法 |
EP2660345A2 (en) * | 2010-12-27 | 2013-11-06 | Posco | Steel sheet having enhanced ductility for a molding member, molding member, and method for manufacturing same |
CN103361547A (zh) * | 2012-03-30 | 2013-10-23 | 鞍钢股份有限公司 | 一种冷成型用超高强度钢板的生产方法及钢板 |
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110892087A (zh) * | 2017-06-20 | 2020-03-17 | 安赛乐米塔尔公司 | 具有高可电阻点焊性的经锌涂覆的钢板 |
CN110892087B (zh) * | 2017-06-20 | 2022-03-25 | 安赛乐米塔尔公司 | 具有高可电阻点焊性的经锌涂覆的钢板 |
US11649522B2 (en) | 2017-06-20 | 2023-05-16 | Arcelormittal | Zinc-coated steel sheet with high resistance spot weldability |
US12054802B2 (en) | 2017-06-20 | 2024-08-06 | Arcelormittal | Zinc-coated steel sheet with high resistance spot weldability |
CN113166828A (zh) * | 2018-12-18 | 2021-07-23 | 安赛乐米塔尔公司 | 经冷轧和热处理的钢板及其制造方法 |
CN113166828B (zh) * | 2018-12-18 | 2023-12-22 | 安赛乐米塔尔公司 | 经冷轧和热处理的钢板及其制造方法 |
CN113412340A (zh) * | 2019-02-18 | 2021-09-17 | 株式会社神户制钢所 | 钢板 |
US12084739B2 (en) | 2019-02-18 | 2024-09-10 | Kobe Steel, Ltd. | Steel sheet |
Also Published As
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN106661652B (zh) | 用于制造超高强度涂覆或未涂覆钢板的方法和获得的板 | |
JP7166396B2 (ja) | 強度、延性および成形性が改善された高強度鋼板を製造する方法 | |
CN108884512B (zh) | 用于生产具有改善的强度和可成形性的高强度钢板的方法以及所获得的高强度钢板 | |
CN106471139B (zh) | 用于制造具有改进的强度、延展性和可成形性的高强度经涂覆的钢板的方法 | |
KR102455376B1 (ko) | 개선된 강도 및 연성을 갖는 고강도의 코팅된 강 시트의 제조 방법, 및 수득된 시트 | |
CN106661645B (zh) | 用于制造具有改进的强度、延展性和可成形性的经涂覆的钢板的方法 | |
CN108431247B (zh) | 用于生产超高强度镀锌扩散退火钢板的方法和获得的镀锌扩散退火钢板 | |
CN106574315B (zh) | 生产具有改善的强度、可成形性的高强度涂覆钢板的方法及所获得的板 | |
CN106661650A (zh) | 用于制造具有改进的可成形性和延展性的高强度钢板的方法及获得的板 | |
JP6967628B2 (ja) | 超高強度合金化溶融亜鉛めっき鋼板を製造するための方法、及び得られた合金化溶融亜鉛めっき鋼板 | |
JP2016194136A (ja) | 製造安定性に優れた高強度高延性鋼板、及びその製造方法、並びに高強度高延性鋼板の製造に用いられる冷延原板 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PB01 | Publication | ||
PB01 | Publication | ||
SE01 | Entry into force of request for substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
GR01 | Patent grant | ||
GR01 | Patent grant |