CN106517285B - 一种棒状纳米碳酸钙的制备方法 - Google Patents
一种棒状纳米碳酸钙的制备方法 Download PDFInfo
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- CN106517285B CN106517285B CN201611039149.6A CN201611039149A CN106517285B CN 106517285 B CN106517285 B CN 106517285B CN 201611039149 A CN201611039149 A CN 201611039149A CN 106517285 B CN106517285 B CN 106517285B
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- Prior art keywords
- calcium carbonate
- carbonation reaction
- calcium hydroxide
- rod
- kiln gas
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- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 title claims abstract description 93
- 229910000019 calcium carbonate Inorganic materials 0.000 title claims abstract description 47
- 238000002360 preparation method Methods 0.000 title claims abstract description 19
- 238000006243 chemical reaction Methods 0.000 claims abstract description 41
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 claims abstract description 34
- 239000000920 calcium hydroxide Substances 0.000 claims abstract description 34
- 229910001861 calcium hydroxide Inorganic materials 0.000 claims abstract description 34
- 239000000839 emulsion Substances 0.000 claims abstract description 25
- 238000000034 method Methods 0.000 claims abstract description 25
- 239000000654 additive Substances 0.000 claims abstract description 20
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 20
- 239000000126 substance Substances 0.000 claims abstract description 19
- 235000008733 Citrus aurantifolia Nutrition 0.000 claims abstract description 18
- 235000011941 Tilia x europaea Nutrition 0.000 claims abstract description 18
- 150000001875 compounds Chemical class 0.000 claims abstract description 18
- 239000004571 lime Substances 0.000 claims abstract description 18
- 238000003756 stirring Methods 0.000 claims abstract description 15
- 239000000725 suspension Substances 0.000 claims abstract description 15
- 230000008569 process Effects 0.000 claims abstract description 11
- 239000002245 particle Substances 0.000 claims description 11
- 238000009826 distribution Methods 0.000 claims description 10
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid group Chemical group C(CC(O)(C(=O)O)CC(=O)O)(=O)O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 9
- 230000033228 biological regulation Effects 0.000 claims description 7
- 239000012295 chemical reaction liquid Substances 0.000 claims description 7
- 238000002156 mixing Methods 0.000 claims description 7
- 238000000746 purification Methods 0.000 claims description 7
- 238000012216 screening Methods 0.000 claims description 7
- 239000013078 crystal Substances 0.000 claims description 5
- APSBXTVYXVQYAB-UHFFFAOYSA-M sodium docusate Chemical group [Na+].CCCCC(CC)COC(=O)CC(S([O-])(=O)=O)C(=O)OCC(CC)CCCC APSBXTVYXVQYAB-UHFFFAOYSA-M 0.000 claims description 4
- 239000002202 Polyethylene glycol Substances 0.000 claims description 3
- 229930006000 Sucrose Natural products 0.000 claims description 3
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 claims description 3
- 229920001223 polyethylene glycol Polymers 0.000 claims description 3
- 239000005720 sucrose Substances 0.000 claims description 3
- IMQLKJBTEOYOSI-GPIVLXJGSA-N Inositol-hexakisphosphate Chemical compound OP(O)(=O)O[C@H]1[C@H](OP(O)(O)=O)[C@@H](OP(O)(O)=O)[C@H](OP(O)(O)=O)[C@H](OP(O)(O)=O)[C@@H]1OP(O)(O)=O IMQLKJBTEOYOSI-GPIVLXJGSA-N 0.000 claims description 2
- RCEAADKTGXTDOA-UHFFFAOYSA-N OS(O)(=O)=O.CCCCCCCCCCCC[Na] Chemical compound OS(O)(=O)=O.CCCCCCCCCCCC[Na] RCEAADKTGXTDOA-UHFFFAOYSA-N 0.000 claims description 2
- 229910019142 PO4 Inorganic materials 0.000 claims description 2
- IMQLKJBTEOYOSI-UHFFFAOYSA-N Phytic acid Natural products OP(O)(=O)OC1C(OP(O)(O)=O)C(OP(O)(O)=O)C(OP(O)(O)=O)C(OP(O)(O)=O)C1OP(O)(O)=O IMQLKJBTEOYOSI-UHFFFAOYSA-N 0.000 claims description 2
- 239000010452 phosphate Substances 0.000 claims description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 2
- 239000000467 phytic acid Substances 0.000 claims description 2
- 229940068041 phytic acid Drugs 0.000 claims description 2
- 235000002949 phytic acid Nutrition 0.000 claims description 2
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 claims description 2
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical group [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 claims description 2
- 125000000020 sulfo group Chemical group O=S(=O)([*])O[H] 0.000 claims description 2
- 239000003795 chemical substances by application Substances 0.000 claims 1
- 239000002131 composite material Substances 0.000 claims 1
- 229940088417 precipitated calcium carbonate Drugs 0.000 claims 1
- 229940030188 solu-delta-cortef Drugs 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 abstract description 8
- 230000008901 benefit Effects 0.000 abstract description 6
- 238000005516 engineering process Methods 0.000 abstract description 4
- 238000007873 sieving Methods 0.000 abstract 1
- 239000000047 product Substances 0.000 description 13
- 230000018044 dehydration Effects 0.000 description 6
- 238000006297 dehydration reaction Methods 0.000 description 6
- 239000004033 plastic Substances 0.000 description 6
- 229920003023 plastic Polymers 0.000 description 6
- 239000000945 filler Substances 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 5
- 239000004576 sand Substances 0.000 description 5
- 239000000123 paper Substances 0.000 description 4
- 238000001514 detection method Methods 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- QJZYHAIUNVAGQP-UHFFFAOYSA-N 3-nitrobicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic acid Chemical compound C1C2C=CC1C(C(=O)O)C2(C(O)=O)[N+]([O-])=O QJZYHAIUNVAGQP-UHFFFAOYSA-N 0.000 description 2
- 229910021532 Calcite Inorganic materials 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 235000019738 Limestone Nutrition 0.000 description 2
- 241000276489 Merlangius merlangus Species 0.000 description 2
- 239000011575 calcium Substances 0.000 description 2
- 229910052791 calcium Inorganic materials 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 239000010419 fine particle Substances 0.000 description 2
- 239000004021 humic acid Substances 0.000 description 2
- 239000006028 limestone Substances 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 239000005060 rubber Substances 0.000 description 2
- 239000001836 Dioctyl sodium sulphosuccinate Substances 0.000 description 1
- 241000533901 Narcissus papyraceus Species 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000001354 calcination Methods 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 235000019329 dioctyl sodium sulphosuccinate Nutrition 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 125000003827 glycol group Chemical group 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000011147 inorganic material Substances 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 1
- 239000000347 magnesium hydroxide Substances 0.000 description 1
- 229910001862 magnesium hydroxide Inorganic materials 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 239000004579 marble Substances 0.000 description 1
- 230000035800 maturation Effects 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000000565 sealant Substances 0.000 description 1
- 239000011257 shell material Substances 0.000 description 1
- 239000001488 sodium phosphate Substances 0.000 description 1
- 229910000162 sodium phosphate Inorganic materials 0.000 description 1
- 229940074404 sodium succinate Drugs 0.000 description 1
- ZDQYSKICYIVCPN-UHFFFAOYSA-L sodium succinate (anhydrous) Chemical compound [Na+].[Na+].[O-]C(=O)CCC([O-])=O ZDQYSKICYIVCPN-UHFFFAOYSA-L 0.000 description 1
- DAJSVUQLFFJUSX-UHFFFAOYSA-M sodium;dodecane-1-sulfonate Chemical compound [Na+].CCCCCCCCCCCCS([O-])(=O)=O DAJSVUQLFFJUSX-UHFFFAOYSA-M 0.000 description 1
- 238000005728 strengthening Methods 0.000 description 1
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
- C01F11/00—Compounds of calcium, strontium, or barium
- C01F11/18—Carbonates
- C01F11/182—Preparation of calcium carbonate by carbonation of aqueous solutions and characterised by an additive other than CaCO3-seeds
- C01F11/183—Preparation of calcium carbonate by carbonation of aqueous solutions and characterised by an additive other than CaCO3-seeds the additive being an organic compound
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/01—Particle morphology depicted by an image
- C01P2004/03—Particle morphology depicted by an image obtained by SEM
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/10—Particle morphology extending in one dimension, e.g. needle-like
- C01P2004/16—Nanowires or nanorods, i.e. solid nanofibres with two nearly equal dimensions between 1-100 nanometer
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/60—Particles characterised by their size
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/12—Surface area
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Inorganic Chemistry (AREA)
- Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
- Paper (AREA)
Abstract
Description
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CN201611039149.6A CN106517285B (zh) | 2016-11-21 | 2016-11-21 | 一种棒状纳米碳酸钙的制备方法 |
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CN201611039149.6A CN106517285B (zh) | 2016-11-21 | 2016-11-21 | 一种棒状纳米碳酸钙的制备方法 |
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CN106517285A CN106517285A (zh) | 2017-03-22 |
CN106517285B true CN106517285B (zh) | 2017-11-14 |
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Families Citing this family (13)
Publication number | Priority date | Publication date | Assignee | Title |
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CN107555459A (zh) * | 2017-09-13 | 2018-01-09 | 泰兴市诚盛化工有限公司 | 一种纳米纺锤体沉淀碳酸钙的制备方法 |
CN107445188B (zh) * | 2017-09-18 | 2019-03-15 | 广西华纳新材料科技有限公司 | 一种棒状沉淀碳酸钙的制备方法 |
CN109956490B (zh) * | 2017-12-14 | 2022-06-10 | 东升新材料(山东)有限公司 | 一种以超细研磨重钙做晶种制备花球状轻质碳酸钙的方法 |
CN109516485A (zh) * | 2018-12-06 | 2019-03-26 | 河南省科学院高新技术研究中心 | 一种自乳化体系制备棒状改性碳酸钙的方法 |
CN111317123A (zh) * | 2018-12-14 | 2020-06-23 | 解冰 | 一种用于改善和促进消化吸收系统功能的木瓜酵素组合物及制备方法和复合纳米制剂 |
CN109516486B (zh) * | 2018-12-19 | 2021-05-25 | 广西华纳新材料科技有限公司 | 一种无碳复写纸用轻质碳酸钙的制备方法 |
CN110482586B (zh) * | 2019-08-28 | 2021-11-05 | 广西合山市华纳新材料科技有限公司 | 一种无碳复写纸用轻质碳酸钙的制备方法 |
CN111439769A (zh) * | 2020-04-28 | 2020-07-24 | 广西夏阳环保科技有限公司 | 一种高纯度、高活性纳米氧化钙的制备方法 |
CN113856236B (zh) * | 2021-10-14 | 2023-06-23 | 昆明理工大学 | 多物理场调控钙基固废溶解结晶制备纳米材料的方法 |
CN114212812B (zh) * | 2021-11-01 | 2023-11-21 | 山东宇信纳米科技有限公司 | 一种用于pvc封边条的纳米碳酸钙的制备方法 |
CN114291835B (zh) * | 2021-12-31 | 2023-08-29 | 广西华纳新材料科技有限公司 | 一种大小立方分散沉淀碳酸钙的制备方法 |
CN114684840A (zh) * | 2022-04-02 | 2022-07-01 | 山西大学 | 一种杂质自诱导制备纳米棒状碳酸钙的方法 |
CN117682544B (zh) * | 2024-02-04 | 2024-05-24 | 山东宇信纳米科技有限公司 | 一种复合晶形纳米碳酸钙的制备方法及应用 |
Family Cites Families (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2826950B1 (fr) * | 2001-07-04 | 2004-09-10 | Solvay | Procede pour l'obtention de particules de carbonate de calcium precipite structurees a l'echelle nanometrique |
CN1211286C (zh) * | 2001-08-03 | 2005-07-20 | 上海华明高技术(集团)有限公司 | 一种纳米活性碳酸钙的工业制备方法 |
CN100372773C (zh) * | 2003-12-30 | 2008-03-05 | 上海华明高技术(集团)有限公司 | 一种油墨用纳米级碳酸钙颗粒的制造方法 |
CN1253373C (zh) * | 2004-06-14 | 2006-04-26 | 上海华明高技术(集团)有限公司 | 一种制造超细碳酸钙分散性颗粒的方法 |
CN102674425B (zh) * | 2012-05-19 | 2013-12-18 | 湖南金箭新材料科技有限公司 | 一种常温法纳米级碳酸钙生产工艺 |
CN103508479A (zh) * | 2013-10-22 | 2014-01-15 | 山西兰花华明纳米材料有限公司 | 一种电子胶用纳米碳酸钙的生产方法 |
CN103693668B (zh) * | 2013-11-28 | 2015-09-16 | 广西华纳新材料科技有限公司 | 一种米粒状微细碳酸钙及其制备方法 |
CN105417569A (zh) * | 2015-12-28 | 2016-03-23 | 常熟市宏宇钙化物有限公司 | 棒状纳米碳酸钙的制备方法 |
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Denomination of invention: A preparation method of rod-shaped nano calcium carbonate Effective date of registration: 20220715 Granted publication date: 20171114 Pledgee: Guangxi Guihui Financing Guarantee Co.,Ltd. Pledgor: Guangxi Warner New Material Co.,Ltd. Registration number: Y2022450000115 |
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