CN106313646A - 一种高耐磨树脂地板 - Google Patents
一种高耐磨树脂地板 Download PDFInfo
- Publication number
- CN106313646A CN106313646A CN201610845220.3A CN201610845220A CN106313646A CN 106313646 A CN106313646 A CN 106313646A CN 201610845220 A CN201610845220 A CN 201610845220A CN 106313646 A CN106313646 A CN 106313646A
- Authority
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- China
- Prior art keywords
- resin
- layer
- fixing groove
- floor
- inorganic filler
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
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- 239000000463 material Substances 0.000 claims description 27
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 claims description 24
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 24
- 238000005859 coupling reaction Methods 0.000 claims description 24
- 238000005299 abrasion Methods 0.000 claims description 22
- 239000003063 flame retardant Substances 0.000 claims description 17
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- 238000010168 coupling process Methods 0.000 claims description 16
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- 239000011159 matrix material Substances 0.000 claims description 10
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- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Chemical compound CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 claims description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 6
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- 102100035474 DNA polymerase kappa Human genes 0.000 claims description 5
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- 230000002787 reinforcement Effects 0.000 claims description 5
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- RPNUMPOLZDHAAY-UHFFFAOYSA-N Diethylenetriamine Chemical compound NCCNCCN RPNUMPOLZDHAAY-UHFFFAOYSA-N 0.000 claims description 4
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 4
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 claims description 4
- 125000004836 hexamethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 claims description 4
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- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 claims description 3
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- VILCJCGEZXAXTO-UHFFFAOYSA-N 2,2,2-tetramine Chemical compound NCCNCCNCCN VILCJCGEZXAXTO-UHFFFAOYSA-N 0.000 claims description 2
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- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 claims description 2
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims description 2
- 239000003822 epoxy resin Substances 0.000 claims description 2
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- 239000004408 titanium dioxide Substances 0.000 claims description 2
- 229960001124 trientine Drugs 0.000 claims description 2
- PQUXFUBNSYCQAL-UHFFFAOYSA-N 1-(2,3-difluorophenyl)ethanone Chemical compound CC(=O)C1=CC=CC(F)=C1F PQUXFUBNSYCQAL-UHFFFAOYSA-N 0.000 claims 1
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- 238000006243 chemical reaction Methods 0.000 claims 1
- 229920002647 polyamide Polymers 0.000 claims 1
- 239000000377 silicon dioxide Substances 0.000 claims 1
- 235000012239 silicon dioxide Nutrition 0.000 claims 1
- 229940047670 sodium acrylate Drugs 0.000 claims 1
- 239000002689 soil Substances 0.000 claims 1
- 239000004575 stone Substances 0.000 claims 1
- 239000004566 building material Substances 0.000 abstract description 3
- 239000010410 layer Substances 0.000 abstract 10
- 238000010521 absorption reaction Methods 0.000 abstract 4
- 239000002344 surface layer Substances 0.000 abstract 3
- 239000007788 liquid Substances 0.000 abstract 2
- 239000007767 bonding agent Substances 0.000 abstract 1
- 238000007599 discharging Methods 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 7
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 7
- USNWAMPROKAEIT-UHFFFAOYSA-N [Na].C(C=C)(=O)O Chemical compound [Na].C(C=C)(=O)O USNWAMPROKAEIT-UHFFFAOYSA-N 0.000 description 7
- 229910021502 aluminium hydroxide Inorganic materials 0.000 description 7
- 229960000935 dehydrated alcohol Drugs 0.000 description 7
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- 239000000945 filler Substances 0.000 description 5
- 229920000609 methyl cellulose Polymers 0.000 description 4
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- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- 229920002292 Nylon 6 Polymers 0.000 description 2
- 239000004927 clay Substances 0.000 description 2
- 241000790917 Dioxys <bee> Species 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
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- 229910003978 SiClx Inorganic materials 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- FYHXNYLLNIKZMR-UHFFFAOYSA-N calcium;carbonic acid Chemical compound [Ca].OC(O)=O FYHXNYLLNIKZMR-UHFFFAOYSA-N 0.000 description 1
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- 238000002485 combustion reaction Methods 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
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- 238000002372 labelling Methods 0.000 description 1
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- 238000000034 method Methods 0.000 description 1
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- 238000012856 packing Methods 0.000 description 1
- 229920001721 polyimide Polymers 0.000 description 1
- AGGKEGLBGGJEBZ-UHFFFAOYSA-N tetramethylenedisulfotetramine Chemical compound C1N(S2(=O)=O)CN3S(=O)(=O)N1CN2C3 AGGKEGLBGGJEBZ-UHFFFAOYSA-N 0.000 description 1
Classifications
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Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Architecture (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Civil Engineering (AREA)
- Structural Engineering (AREA)
- Ceramic Engineering (AREA)
- Mechanical Engineering (AREA)
- Floor Finish (AREA)
Abstract
本发明公开了一种高耐磨树脂地板，属于建筑材料领域，旨在解决现有的地板耐磨性差、水分不容易排出、制作成本高的问题，包括具有高耐磨性的表层、本体层、具有高隔热效果的底层，所述的本体层位于表层和底层之间，所述的表层、本体层与底层相互之间通过粘合剂粘接，树脂地板的一个侧面加工有固定槽，所述的侧面可以为任一侧面，加工有固定槽侧面的对侧面加工有定位卡柱，所述的固定槽和相邻地板的定位卡柱配合，固定槽加工有沿高度方向和水平方向的微导液槽，所述微导液槽的横截面为弧形，所述的固定槽内壁设有一层吸水层，所述的吸水层和固定槽通过粘接的方向连接，所述的吸水层内部有开孔的微孔结构，孔内含有吸水树脂。
Description
技术领域
本发明涉及建筑材料领域，具体来讲是一种高耐磨树脂地板。
背景技术
地板（或地砖）是家庭用重要建筑材料，一般而言，地板都是由无机材料制备。但是现有的无机地板由于其材料的成本高、且韧性差，容易出现裂缝，且维修不方便，严重影响到正常的使用，一直是使用过程中长期存在的问题，通过引起高分子材料(主要为树脂)，能有效的解决了上述存在的问题，但是同时也产生了新的问题，如树脂地板的一般耐磨性都比较差，表面及其容易损坏，不仅影响到正常的使用，同时也影响外观，现有的树脂地板一般排水性都比较差，当地板上有水份时，要经过长时间才能排掉。
发明内容
本发明的目的在于：针对上述存在的问题，提供一种高耐磨树脂地板，不仅耐磨性高于现有的地板，同时成本也得到了降低。
本发明采用的技术方案如下：
本发明公开了一种高耐磨树脂地板，包括具有高耐磨性的表层、本体层、具有高隔热效果的底层，所述的本体层位于表层和底层之间，所述的表层、本体层与底层相互之间通过粘合剂粘接。
进一步的，所述树脂地板的一个侧面加工有固定槽，所述的侧面可以为任一侧面，加工有固定槽侧面的对侧面加工有定位卡柱，所述的固定槽和相邻地板的定位卡柱配合。
进一步的，所述的固定槽加工有沿高度方向和水平方向的微导液槽，所述微导液槽的横截面为弧形，所述的固定槽内壁设有一层吸水层，所述的吸水层和固定槽通过粘接的方向连接，所述的吸水层内部有微孔结构，所述的微孔结构为开孔，所述的孔内含有吸水树脂。
进一步的，所述的吸水树脂选自淀粉接枝丙烯酸钠树脂类、淀粉接枝丙烯酰胺树脂、交联羧甲基纤维素接枝丙烯酰胺树脂、交联型羟乙基纤维素接枝丙烯酰胺树脂。
进一步的，所述的的表层（1）由纤维增强树脂材料制备，所述本体层（2）由无机材料制备，所述的底层（3）由PVC海绵体制备。
进一步的，所述的纤维增强树脂材料包括树脂基体100份、纤维20-30份、无机填料20-50份、偶联剂0.2-2份、固化剂0.2-2份、脱膜剂0.2-2份、阻燃剂0.2-2份、增塑剂0.2-2份。
进一步的，所述的树脂选自酚醛树脂、尼龙6、尼龙66、聚丙烯、ABS、聚砜、聚四氟乙烯、聚苯醚、三聚氰胺甲醛树脂、环氧树脂、聚酰亚胺。
进一步的，所述的纤维选自玻璃纤维、石英玻璃纤维、硼纤维、陶瓷纤维、铜纤维、醋酸纤维、菠萝纤维、香蕉纤维。
进一步的，所述的无机填料选自木粉、陶土、碳酸钙、石墨、磁粉、云母、炭黑、二氧化硅、钛白粉、滑石粉、硫酸钡，所述的偶联剂选自KH550，KH560，KH570，KH792，DL602，DL171；所述的固化剂选自乙烯基三胺、二氨基环己烷、亚甲基双环己烷胺、二乙烯三胺、三乙烯四胺；脱膜剂为硅橡胶甲苯溶液；阻燃剂为氢氧化铝；增塑剂选自DINP、DNOP、DBP、DMP、DEP。
进一步的，纤维增强树脂材料及其表层制备方法如下：
步骤1：将无机填料加入到偶联反应罐中，打开搅拌装置，搅拌使无机填料旋转，将偶联剂与水、无水乙醇按照1:1:0.5配置成溶液后，直接喷洒在无机填料中，控制搅拌装置的旋转速度为4000转/分钟-6000转/分钟，使得混合物的温度达到120摄氏度，反应10-20分钟后，在100-150℃下烘干10-30分钟制得偶联改性过的无机填料；
步骤2：将步骤1后的无机填料和树脂基体、纤维、紫外线吸收剂、脱膜剂、阻燃剂加入到双螺杆挤出机，进行挤出切粒。
步骤3：将步骤2后的粒子加入到地板模具中，加入固化剂，固化成型。
由于采用了上述结构，。
综上所述，由于采用了上述技术方案，本发明的有益效果在于：
一、本发明提供的树脂地板相互之间通过可固定的固定槽和卡柱配合，地板之间位置固定，不容易出现滑落、地板翘起等现象的发生；
二、所提供的树脂地板表面的耐磨性好，在长久使用后表面也不会出现磨损；
三、树脂地板具有优异的排水功能，当有水洒在上面的时候，水分可以较快的从槽内流下，并且通过吸水树脂快速吸收；
四、相对于现有的树脂地板，本发明提供的地板在同等质量下下降了20%-30%。。
附图说明
图1是本发明高耐磨树脂地板的结构图；
图2是本发明定位卡扣的结构图；
图中标记：1-表层，2-本体层，3-底层，4-微导液槽，5-固定槽，6-定位卡柱。
具体实施方式
下面结合附图，对本发明作详细的说明。
为了使本发明的目的、技术方案及优点更加清楚明白，以下结合附图及实施例，对本发明进行进一步详细说明。应当理解，此处所描述的具体实施例仅仅用以解释本发明，并不用于限定本发明。
具体实施例1：一种高耐磨树脂地板，包括具有高耐磨性的表层1、本体层2、具有高隔热效果的底层3，本体层2位于表层1和底层3之间，所述的表层1、本体层2与底层3相互之间通过粘合剂粘接，树脂地板的一个侧面加工有固定槽5，所述的侧面可以为任一侧面，加工有固定槽5侧面的对侧面加工有定位卡柱6，固定槽5和相邻地板的定位卡柱6配合，固定槽5加工有沿高度方向和水平方向的微导液槽4，微导液槽4的横截面为弧形，固定槽内壁设有一层吸水层，所述的吸水层和固定槽通过粘接的方向连接，吸水层内部有微孔结构，所述的微孔结构为开孔，孔内含有吸水树脂，吸水树脂选自淀粉接枝丙烯酸钠树脂类、淀粉接枝丙烯酰胺树脂、交联羧甲基纤维素接枝丙烯酰胺树脂、交联型羟乙基纤维素接枝丙烯酰胺树脂，表层1由纤维增强树脂材料制备，本体层2由无机材料制备，底层3由PVC海绵体制备。
在本实施例中，所述的纤维增强树脂材料包括三聚氰胺甲醛树脂100份、醋酸纤维20份、云母填料20份、偶联剂DL171 0.2份、固化剂三乙烯四胺1份、脱膜剂硅橡胶甲苯溶液1份、阻燃剂氢氧化铝1份、增塑剂DINP 1份。
纤维增强树脂材料及其表层制备方法如下：
步骤1：将无机填料加入到偶联反应罐中，打开搅拌装置，搅拌使无机填料旋转，将偶联剂与水、无水乙醇按照1:1:0.5配置成溶液后，直接喷洒在无机填料中，控制搅拌装置的旋转速度为5200转/分钟，使得混合物的温度达到120摄氏度，反应15分钟后，在140℃下烘干18分钟制得偶联改性过的无机填料；
步骤2：将步骤1后的无机填料和树脂基体、纤维、紫外线吸收剂、脱膜剂、阻燃剂加入到双螺杆挤出机，进行挤出切粒。
步骤3：将步骤2后的粒子加入到地板模具中，加入固化剂，固化成型。
具体实施例1：一种高耐磨树脂地板，包括具有高耐磨性的表层1、本体层2、具有高隔热效果的底层3，本体层2位于表层1和底层3之间，所述的表层1、本体层2与底层3相互之间通过粘合剂粘接，树脂地板的一个侧面加工有固定槽5，所述的侧面可以为任一侧面，加工有固定槽5侧面的对侧面加工有定位卡柱6，固定槽5和相邻地板的定位卡柱6配合，固定槽5加工有沿高度方向和水平方向的微导液槽4，微导液槽4的横截面为弧形，固定槽内壁设有一层吸水层，所述的吸水层和固定槽通过粘接的方向连接，吸水层内部有微孔结构，所述的微孔结构为开孔，孔内含有吸水树脂，吸水树脂选自淀粉接枝丙烯酸钠树脂类、淀粉接枝丙烯酰胺树脂、交联羧甲基纤维素接枝丙烯酰胺树脂、交联型羟乙基纤维素接枝丙烯酰胺树脂，表层1由纤维增强树脂材料制备，本体层2由无机材料制备，底层3由PVC海绵体制备。
在本实施例中，所述的纤维增强树脂材料包括聚砜100份、铜纤维25份、磁粉填料20份、偶联剂DL171 0.2份、固化剂二乙烯三胺0.9份、脱膜剂硅橡胶甲苯溶液0.2份、阻燃剂氢氧化铝2份、增塑剂DINP 0.8份。
纤维增强树脂材料及其表层制备方法如下：
步骤1：将无机填料加入到偶联反应罐中，打开搅拌装置，搅拌使无机填料旋转，将偶联剂与水、无水乙醇按照1:1:0.5配置成溶液后，直接喷洒在无机填料中，控制搅拌装置的旋转速度为4500转/分钟，使得混合物的温度达到120摄氏度，反应12分钟后，在130℃下烘干18分钟制得偶联改性过的无机填料；
步骤2：将步骤1后的无机填料和树脂基体、纤维、紫外线吸收剂、脱膜剂、阻燃剂加入到双螺杆挤出机，进行挤出切粒。
步骤3：将步骤2后的粒子加入到地板模具中，加入固化剂，固化成型。具体实施例1：一种高耐磨树脂地板，包括具有高耐磨性的表层1、本体层2、具有高隔热效果的底层3，本体层2位于表层1和底层3之间，所述的表层1、本体层2与底层3相互之间通过粘合剂粘接，树脂地板的一个侧面加工有固定槽5，所述的侧面可以为任一侧面，加工有固定槽5侧面的对侧面加工有定位卡柱6，固定槽5和相邻地板的定位卡柱6配合，固定槽5加工有沿高度方向和水平方向的微导液槽4，微导液槽4的横截面为弧形，固定槽内壁设有一层吸水层，所述的吸水层和固定槽通过粘接的方向连接，吸水层内部有微孔结构，所述的微孔结构为开孔，孔内含有吸水树脂，吸水树脂选自淀粉接枝丙烯酸钠树脂类、淀粉接枝丙烯酰胺树脂、交联羧甲基纤维素接枝丙烯酰胺树脂、交联型羟乙基纤维素接枝丙烯酰胺树脂，表层1由纤维增强树脂材料制备，本体层2由无机材料制备，底层3由PVC海绵体制备。
在本实施例中，所述的纤维增强树脂材料包括聚丙烯100份、陶瓷纤维、20份、石墨填料50份、偶联剂DL602 0.2份、固化剂二乙烯三胺0.2份、脱膜剂硅橡胶甲苯溶液2份、阻燃剂氢氧化铝0.2份、增塑剂DEP 2份。
纤维增强树脂材料及其表层制备方法如下：
步骤1：将无机填料加入到偶联反应罐中，打开搅拌装置，搅拌使无机填料旋转，将偶联剂与水、无水乙醇按照1:1:0.5配置成溶液后，直接喷洒在无机填料中，控制搅拌装置的旋转速度为4000转/分钟，使得混合物的温度达到120摄氏度，反应20分钟后，在100℃下烘干30分钟制得偶联改性过的无机填料；
步骤2：将步骤1后的无机填料和树脂基体、纤维、紫外线吸收剂、脱膜剂、阻燃剂加入到双螺杆挤出机，进行挤出切粒。
步骤3：将步骤2后的粒子加入到地板模具中，加入固化剂，固化成型。具体实施例1：一种高耐磨树脂地板，包括具有高耐磨性的表层1、本体层2、具有高隔热效果的底层3，本体层2位于表层1和底层3之间，所述的表层1、本体层2与底层3相互之间通过粘合剂粘接，树脂地板的一个侧面加工有固定槽5，所述的侧面可以为任一侧面，加工有固定槽5侧面的对侧面加工有定位卡柱6，固定槽5和相邻地板的定位卡柱6配合，固定槽5加工有沿高度方向和水平方向的微导液槽4，微导液槽4的横截面为弧形，固定槽内壁设有一层吸水层，所述的吸水层和固定槽通过粘接的方向连接，吸水层内部有微孔结构，所述的微孔结构为开孔，孔内含有吸水树脂，吸水树脂选自淀粉接枝丙烯酸钠树脂类、淀粉接枝丙烯酰胺树脂、交联羧甲基纤维素接枝丙烯酰胺树脂、交联型羟乙基纤维素接枝丙烯酰胺树脂，表层1由纤维增强树脂材料制备，本体层2由无机材料制备，底层3由PVC海绵体制备。
在本实施例中，所述的纤维增强树脂材料包括酚醛树脂100份、玻璃纤维、20份、木粉填料20份、偶联剂KH550 0.2份、固化剂乙烯基三胺0.2份、脱膜剂硅橡胶甲苯溶液0.2份、阻燃剂氢氧化铝0.2份、增塑剂DINP 0.2份。
纤维增强树脂材料及其表层制备方法如下：
步骤1：将无机填料加入到偶联反应罐中，打开搅拌装置，搅拌使无机填料旋转，将偶联剂与水、无水乙醇按照1:1:0.5配置成溶液后，直接喷洒在无机填料中，控制搅拌装置的旋转速度为4000转/分钟，使得混合物的温度达到120摄氏度，反应10分钟后，在100℃下烘干10分钟制得偶联改性过的无机填料；
步骤2：将步骤1后的无机填料和树脂基体、纤维、紫外线吸收剂、脱膜剂、阻燃剂加入到双螺杆挤出机，进行挤出切粒。
步骤3：将步骤2后的粒子加入到地板模具中，加入固化剂，固化成型。具体实施例2：一种高耐磨树脂地板，包括具有高耐磨性的表层1、本体层2、具有高隔热效果的底层3，本体层2位于表层1和底层3之间，所述的表层1、本体层2与底层3相互之间通过粘合剂粘接，树脂地板的一个侧面加工有固定槽5，所述的侧面可以为任一侧面，加工有固定槽5侧面的对侧面加工有定位卡柱6，固定槽5和相邻地板的定位卡柱6配合，固定槽5加工有沿高度方向和水平方向的微导液槽4，微导液槽4的横截面为弧形，固定槽内壁设有一层吸水层，所述的吸水层和固定槽通过粘接的方向连接，吸水层内部有微孔结构，所述的微孔结构为开孔，孔内含有吸水树脂，吸水树脂选自淀粉接枝丙烯酸钠树脂类、淀粉接枝丙烯酰胺树脂、交联羧甲基纤维素接枝丙烯酰胺树脂、交联型羟乙基纤维素接枝丙烯酰胺树脂，表层1由纤维增强树脂材料制备，本体层2由无机材料制备，底层3由PVC海绵体制备。
在本实施例中，所述的纤维增强树脂材料包括尼龙6 100份、石英玻璃纤维20份、陶土填料50份、偶联剂KH560 2份、固化剂二氨基环己烷2份、脱膜剂硅橡胶甲苯溶液2份、阻燃剂氢氧化铝2份、增塑剂DNOP 2份。
纤维增强树脂材料及其表层制备方法如下：
步骤1：将无机填料加入到偶联反应罐中，打开搅拌装置，搅拌使无机填料旋转，将偶联剂与水、无水乙醇按照1:1:0.5配置成溶液后，直接喷洒在无机填料中，控制搅拌装置的旋转速度为6000转/分钟，使得混合物的温度达到120摄氏度，反应20分钟后，在150℃下烘干30分钟制得偶联改性过的无机填料；
步骤2：将步骤1后的无机填料和树脂基体、纤维、紫外线吸收剂、脱膜剂、阻燃剂加入到双螺杆挤出机，进行挤出切粒。
步骤3：将步骤2后的粒子加入到地板模具中，加入固化剂，固化成型。具体实施例3：一种高耐磨树脂地板，包括具有高耐磨性的表层1、本体层2、具有高隔热效果的底层3，本体层2位于表层1和底层3之间，所述的表层1、本体层2与底层3相互之间通过粘合剂粘接，树脂地板的一个侧面加工有固定槽5，所述的侧面可以为任一侧面，加工有固定槽5侧面的对侧面加工有定位卡柱6，固定槽5和相邻地板的定位卡柱6配合，固定槽5加工有沿高度方向和水平方向的微导液槽4，微导液槽4的横截面为弧形，固定槽内壁设有一层吸水层，所述的吸水层和固定槽通过粘接的方向连接，吸水层内部有微孔结构，所述的微孔结构为开孔，孔内含有吸水树脂，吸水树脂选自淀粉接枝丙烯酸钠树脂类、淀粉接枝丙烯酰胺树脂、交联羧甲基纤维素接枝丙烯酰胺树脂、交联型羟乙基纤维素接枝丙烯酰胺树脂，表层1由纤维增强树脂材料制备，本体层2由无机材料制备，底层3由PVC海绵体制备。
在本实施例中，所述的纤维增强树脂材料包括尼龙66 100份、硼纤维、25份、碳酸钙填料30份、偶联剂KH570 1份、固化剂亚甲基双环己烷胺0.8份、脱膜剂硅橡胶甲苯溶液0.8份、阻燃剂氢氧化铝0.8份、增塑剂DMP 0.8份。
纤维增强树脂材料及其表层制备方法如下：
步骤1：将无机填料加入到偶联反应罐中，打开搅拌装置，搅拌使无机填料旋转，将偶联剂与水、无水乙醇按照1:1:0.5配置成溶液后，直接喷洒在无机填料中，控制搅拌装置的旋转速度为5000转/分钟，使得混合物的温度达到120摄氏度，反应15分钟后，在120℃下烘干10-30分钟制得偶联改性过的无机填料；
步骤2：将步骤1后的无机填料和树脂基体、纤维、紫外线吸收剂、脱膜剂、阻燃剂加入到双螺杆挤出机，进行挤出切粒。
步骤3：将步骤2后的粒子加入到地板模具中，加入固化剂，固化成型。
以上所述仅为本发明的较佳实施例而已，并不用以限制本发明，凡在本发明的精神和原则之内所作的任何修改、等同替换和改进等，均应包含在本发明的保护范围之内。
Claims (10)
1.一种高耐磨树脂地板，包括具有耐磨性的表层（1）、本体层（2）、具有隔热效果的底层（3），所述的本体层（2）位于表层（1）和底层（3）之间，所述的表层（1）、本体层（2）与底层（3）相互之间通过粘合剂粘接。
2.根据权利要求1所述的高耐磨树脂地板，其特征在于所述树脂地板的一个侧面加工有固定槽（5），所述的侧面可以为任一侧面，加工有固定槽（5）侧面的对侧面加工有定位卡柱（6），一个地板的固定槽（5）和相邻地板的定位卡柱（6）配合。
3.根据权利要求1所述的高耐磨树脂地板，其特征在于，所述的固定槽（5）加工有沿高度方向和水平方向的微导液槽（4），所述微导液槽（4）的横截面为弧形，所述的固定槽内壁设有一层吸水层，所述的吸水层和固定槽通过粘接的方向连接，所述的吸水层内部有开孔微孔结构，孔内充塞有吸水树脂。
4.根据权利要求3所述的高耐磨树脂地板，其特征在于，所述的吸水树脂选自淀粉接枝丙烯酸钠树脂类、淀粉接枝丙烯酰胺树脂、交联羧甲基纤维素接枝丙烯酰胺树脂、交联型羟乙基纤维素接枝丙烯酰胺树脂。
5.根据权利要求1-3所述的高耐磨树脂地板，其特征在于，所述的表层（1）由纤维增强树脂材料制备，所述本体层（2）由无机材料制备，所述的底层（3）由PVC海绵体制备。
6.根据权利要求5所述的高耐磨树脂地板，其特征在于，所述的纤维增强树脂材料包括树脂基体100份、纤维20-30份、无机填料20-50份、偶联剂0.2-2份、固化剂0.2-2份、脱膜剂0.2-2份、阻燃剂0.2-2份、增塑剂0.2-2份。
7.根据权利要求6所述的高耐磨树脂地板，其特征在于，所述的树脂选自酚醛树脂、尼龙6、尼龙66、聚丙烯、ABS、聚砜、聚四氟乙烯、聚苯醚、三聚氰胺甲醛树脂、环氧树脂、聚酰亚胺。
8.根据权利要求6所述的高耐磨树脂地板，其特征在于，所述的纤维选自玻璃纤维、石英玻璃纤维、硼纤维、陶瓷纤维、铜纤维、醋酸纤维、菠萝纤维、香蕉纤维。
9.根据权利要求6所述的高耐磨树脂地板，其特征在于，所述的无机填料选自木粉、陶土、碳酸钙、石墨、磁粉、云母、炭黑、二氧化硅、钛白粉、滑石粉、硫酸钡，所述的偶联剂选自KH550，KH560，KH570，KH792，DL602，DL171；所述的固化剂选自乙烯基三胺、二氨基环己烷、亚甲基双环己烷胺、二乙烯三胺、三乙烯四胺；脱膜剂为硅橡胶甲苯溶液；阻燃剂为氢氧化铝；增塑剂选自DINP、DNOP、DBP、DMP、DEP。
10.根据权利要求5-9所述的高耐磨树脂地板，其特征在于，纤维增强树脂材料及其表层制备方法如下：
步骤1：将无机填料加入到偶联反应罐中，打开搅拌装置，搅拌使无机填料旋转，将偶联剂与水、环己烷按照重量份1:1:0.5配置成溶液后，直接喷洒在无机填料中，控制搅拌装置的旋转速度为4000转/分钟-6000转/分钟，使得混合物的温度达到120摄氏度，反应10-20分钟后，在100-150℃下烘干10-30分钟制得偶联改性过的无机填料；
步骤2：将步骤1后的无机填料和树脂基体、纤维、紫外线吸收剂、脱膜剂、阻燃剂加入到双螺杆挤出机，进行挤出切粒;
步骤3：将步骤2后的粒子加入到地板模具中，加入固化剂，固化成型。
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