CN106298887A - A kind of preparation method of high threshold voltage high mobility notched gates MOSFET - Google Patents

A kind of preparation method of high threshold voltage high mobility notched gates MOSFET Download PDF

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CN106298887A
CN106298887A CN201610868777.9A CN201610868777A CN106298887A CN 106298887 A CN106298887 A CN 106298887A CN 201610868777 A CN201610868777 A CN 201610868777A CN 106298887 A CN106298887 A CN 106298887A
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CN106298887B (en
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李柳暗
刘扬
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National Sun Yat Sen University
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L29/00Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
    • H01L29/66Types of semiconductor device ; Multistep manufacturing processes therefor
    • H01L29/66007Multistep manufacturing processes
    • H01L29/66075Multistep manufacturing processes of devices having semiconductor bodies comprising group 14 or group 13/15 materials
    • H01L29/66227Multistep manufacturing processes of devices having semiconductor bodies comprising group 14 or group 13/15 materials the devices being controllable only by the electric current supplied or the electric potential applied, to an electrode which does not carry the current to be rectified, amplified or switched, e.g. three-terminal devices
    • H01L29/66409Unipolar field-effect transistors
    • H01L29/66477Unipolar field-effect transistors with an insulated gate, i.e. MISFET
    • H01L29/66568Lateral single gate silicon transistors
    • H01L29/66575Lateral single gate silicon transistors where the source and drain or source and drain extensions are self-aligned to the sides of the gate
    • H01L29/6659Lateral single gate silicon transistors where the source and drain or source and drain extensions are self-aligned to the sides of the gate with both lightly doped source and drain extensions and source and drain self-aligned to the sides of the gate, e.g. lightly doped drain [LDD] MOSFET, double diffused drain [DDD] MOSFET
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L29/00Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
    • H01L29/40Electrodes ; Multistep manufacturing processes therefor
    • H01L29/41Electrodes ; Multistep manufacturing processes therefor characterised by their shape, relative sizes or dispositions
    • H01L29/423Electrodes ; Multistep manufacturing processes therefor characterised by their shape, relative sizes or dispositions not carrying the current to be rectified, amplified or switched
    • H01L29/42312Gate electrodes for field effect devices
    • H01L29/42316Gate electrodes for field effect devices for field-effect transistors
    • H01L29/4232Gate electrodes for field effect devices for field-effect transistors with insulated gate

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  • Engineering & Computer Science (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Power Engineering (AREA)
  • Physics & Mathematics (AREA)
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  • General Physics & Mathematics (AREA)
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  • Junction Field-Effect Transistors (AREA)
  • Insulated Gate Type Field-Effect Transistor (AREA)

Abstract

The present invention relates to the technical field of semiconductor epitaxial process, more particularly, to the preparation method of a kind of high threshold voltage high mobility notched gates MOSFET.Comprise the steps: first to provide the heterojunction material with low al composition AlGaN/GaN/ high aluminium component AlGaN lamination barrier layer, at described material surface one layer of dielectric layer of deposition as mask layer, photoetching development technology and wet etching is used to remove area of grid dielectric layer, realize graphical to mask layer, utilize wet-dry change to combine to be removed by the top layer high aluminium component AlGaN of area of grid and obtain groove, GaN thin layer removes groove surfaces damage as wet etching stop layer, and the low al composition AlGaN potential barrier of reservation can realize high channel mobility and high threshold voltage.Threshold voltage is regulated and controled further by depositing p-type oxide as grid.Finally form source electrode and drain region at two ends and cover metal formation source electrode and drain electrode.Present invention process is simple, can solve damage during conventional dry etched recesses caused area of grid well, can form the raceway groove of low two-dimensional electron gas simultaneously, thus obtain high threshold voltage while improving channel mobility.

Description

A kind of preparation method of high threshold voltage high mobility notched gates MOSFET
Technical field
The present invention relates to the technical field of semiconductor epitaxial process, migrate more particularly, to a kind of high threshold voltage height The preparation method of rate notched gates MOSFET.
Background technology
Gallium nitride (GaN) material has that energy gap is big, breakdown field strength is high, electronics saturation drift velocity is big, thermal conductance Rate advantages of higher, is very suitable for making high-power, high frequency, high temperature power electronic devices.In applied power electronics field, in order to full Foot fail safe, field-effect transistor (FET) device must realize normally-off (also known as enhancement mode) work, and in some occasion Threshold voltage needs at least 4-5V.And for conventional AlGaN/GaN HFET (HFET), due to interface High concentration, the existence of two-dimensional electron gas (2DEG) of high mobility, even if when additional grid voltage is zero, device is also at opening shape State (normally on device).In order to solve these problems, the isolated-gate field effect transistor (IGFET) (MOSFET) using MOS structure is one Effective technology path.
GaN base notched gates MOSFET element is retaining the premise of access area 2DEG concentration (not sacrificing break-over of device characteristic) Under, grid when removing zero-bias the most completely is reduced by partly or completely etching grid region AlGaN potential barrier The 2DEG of lower section, and MOS structure grid can be used to achieve normally-off, low-leakage current and the high grid voltage amplitude of oscillation.Part is carved Erosion barrier layer can be effectively retained electron channel and obtain high field-effect mobility, but the barrier layer meeting of residual and gate metal And gate dielectric layer forms MOSHFET and reduces threshold voltage.On the contrary, etching barrier layer completely can obtain high threshold voltage, But electron channel produces between gate dielectric layer and GaN, and strong interface scattering causes field-effect mobility on the low side.Additionally, it is recessed In groove etched technique, the lattice of channel region can be caused damage by traditional plasma dry etch, although wet etching energy But effectively remove plasma damage long time treatment and also can observe substantial amounts of etching hole on the surface of GaN channel layer, enter And affect the reliability and stability at MOS interface.It is therefore desirable to seek the preparation side of a kind of new GaN base notched gates MOSFET Method, to overcome the shortcoming in traditional handicraft, thus obtains higher mobility and threshold voltage.
Summary of the invention
The present invention is to overcome at least one defect described in above-mentioned prior art, it is provided that a kind of high threshold voltage high mobility The preparation method of notched gates MOSFET, can be effectively improved channel mobility and threshold voltage.The technical solution used in the present invention Being: utilize lamination barrier layer construction, GaN interposed layer can remove plasma damage as wet etching stop layer, the most permissible Retain low al composition AlGaN and form the raceway groove of low two-dimensional electron gas, and combine p-type oxide grid to channel carrier Concentration regulates and controls, thus obtains high threshold voltage while improving channel mobility.
Specifically include following steps:
S1, at Grown stress-buffer layer;
S2, on stress-buffer layer grow GaN epitaxial layer;
S3, in GaN epitaxial layer grow one layer low al composition AlGaN potential barrier;
S4, in low al composition AlGaN potential barrier deposit one layer of GaN etch stop layer;
S5, on GaN etch stop layer, grow a floor height al composition AlGaN potential barrier;
S6, in AlGaN potential barrier deposit one layer of SiO2, as mask layer;
S7, method by photoetching and wet etching, remove the mask layer of area of grid;
S8, utilize dry/wet method to combine to remove the high aluminium component AlGaN potential barrier of area of grid;
S9, dry etching complete device isolation, clean surface depositing p-type oxide gate;
S10, on source electrode and drain region are deposited with source electrode and drain ohmic contact metal;
S11, form Ohmic contact in groove grids region evaporation metal and p-type oxide.
Concrete, described step S3-S5 grows low al composition AlGaN/GaN/ high aluminium component AlGaN lamination barrier layer Heterojunction material;In described step S9, channel electrons concentration is modulated by depositing p-type oxide gate, and then regulation and control threshold Threshold voltage.
Described substrate is any one in Si substrate, Sapphire Substrate, silicon carbide substrates, GaN self-supported substrate.
Described stress-buffer layer is any one of AlN, AlGaN, GaN or combines;Stress buffer layer thickness is 10 nm ~ 5 μm。
Described GaN epitaxial layer is GaN epitaxial layer or the high resistant GaN epitaxial layer of doping, the described doping of involuntary doping The doped chemical of resistive formation is carbon or ferrum;GaN epitaxial layer thickness is 100 nm ~ 20 μm.
Described AlGaN epitaxial layer is low al composition AlGaN, and AlGaN layer thickness is 0-20 nm, and al composition concentration can Change at 0-15%.
Described interposed layer is the GaN etch stop layer of high-quality, low-dislocation-density;Stop layer thickness is 0 nm ~ 20nm.
Described AlGaN epitaxial layer is high aluminium component AlGaN, and AlGaN layer thickness is 0-50 nm, and al composition concentration can Change at 15-40%.
Described AlGaN potential barrier material can also be a kind of or the most several in AlInN, InGaN, AlInGaN, AlN The combination planted.
In described AlGaN potential barrier, and can also insert an AlN thin layer between GaN layer, thickness is 1-10 nm;
Described p-type oxide gate electrode is high-quality NiO, Cu2The materials such as O, ZnO or a combination thereof, thickness is 1-500 nm;
Source electrode and drain material are Ti/Al/Ni/Au alloy, Ti/Al/Ti/Au alloy, Ti/Al/Mo/Au alloy or Ti/Al/ Ti/TiN alloy;It is Ni/Au alloy, In/Au alloy or Pd/Au alloy that gate electrode thickeies metal material;
AlGaN epitaxial layer in stress-buffer layer in described step S1, the GaN epitaxial layer in step S2, step S3, step S4 In GaN epitaxial layer and the growing method of AlGaN epitaxial layer in step S5 be Metalorganic Chemical Vapor Deposition, molecular beam Epitaxy contour quality film formation method;In described step S6, the growing method of mask layer is plasma enhanced chemical vapor deposition Method, atomic layer deposition method, physical vaporous deposition or magnetron sputtering method.
Additionally, it is possible to be summarized as following step:
1. provide and need the AlGaN/GaN/AlGaN heterojunction material carrying out groove grids etching;
2., at described deposited on materials one dielectric layer, form mask layer;
3. on described mask layer, utilize photoetching development technology, manifest area of grid;
4. use chemical solution to remove the mask material of area of grid, retain the mask material in other regions, it is achieved mask layer figure Shape;
5. under the auxiliary of described mask pattern, it is achieved recess etch.
6. utilize photoetching development technology, manifest area of grid and grow one layer of p-type oxide thin layer.
Further, in described step 1, described substrate is the epitaxial layer substrate with heterogeneity.
In described step 2, dielectric layer is by plasma enhanced chemical vapor deposition or ald or physics Vapour deposition or magnetron sputtering are formed.Described dielectric layer is SiO2Or SiN.
In described step 3, described photoresist is positivity or negative photoresist.
In described step 4, described dielectric layer remove the chemical solution used be hydrofluoric acid aqueous solution or Fluohydric acid. and The mixed solution of ammonium fluoride.
In described step 5, described recess etch is inductively coupled plasma (ICP) or reactive ion etching (RIE). Reacting gas is Cl2、BCl3、SiCl4Or its mixed gas.
In described step 6, described p-type oxide thin layer be grown to Metalorganic Chemical Vapor Deposition, sputtering method, Thermal oxidation method or molecular beam epitaxy.
Compared with prior art, provide the benefit that: the present invention provides the preparation side of a kind of novel GaN base notched gates MOSFET Method, owing to utilizing lamination barrier layer construction, GaN interposed layer can remove plasma damage as wet etching stop layer, again Low al composition AlGaN can be retained and form the raceway groove of low two-dimensional electron gas, and combine p-type oxide grid to raceway groove load Flow sub-concentration to regulate and control, thus obtain high threshold voltage while improving channel mobility.
Accompanying drawing explanation
Fig. 1-11 is the device manufacture method process schematic representation of the embodiment of the present invention 1.
Figure 12 is the device architecture schematic diagram of the embodiment of the present invention 2.
Figure 13 is the device architecture schematic diagram of the embodiment of the present invention 3.
Detailed description of the invention
Accompanying drawing being merely cited for property explanation, it is impossible to be interpreted as the restriction to this patent;In order to the present embodiment is more preferably described, attached Scheme some parts to have omission, zoom in or out, do not represent the size of actual product;To those skilled in the art, In accompanying drawing, some known features and explanation thereof may be omitted and be will be understood by.Being merely cited for property of position relationship described in accompanying drawing Explanation, it is impossible to be interpreted as the restriction to this patent.
Embodiment 1
Being the device architecture schematic diagram of the present embodiment as shown in figure 11, its structure includes substrate (1) the most successively, and stress delays Rush layer (2), GaN epitaxial layer (3), low al composition AlGaN potential barrier (4), GaN interposed layer (5), high aluminium component AlGaN potential barrier (6), p-type oxide grid (7), two ends form source electrode and drain electrode (8), and the upper deposition of oxide gate (7) thickeies metal (9).
The manufacture method of the device field-effect transistor of above-mentioned GaN base notched gates MOSFET as Figure 1-Figure 11, including Following steps:
S1, utilize mocvd method, at Si substrate (1) upper growth one ply stress cushion (2), such as Fig. 1 Shown in;
S2, utilize mocvd method, stress-buffer layer (2) grows GaN epitaxial layer (3), such as Fig. 2 institute Show;
S3, utilize mocvd method, grow low al composition AlGaN potential barrier GaN epitaxial layer (3) is upper (4), as shown in Figure 3;
S4, utilize mocvd method, at low al composition AlGaN potential barrier (4) upper growth GaN interposed layer (5), as shown in Figure 4;
S5, utilize mocvd method, in GaN interposed layer (5) upper growth high aluminium component AlGaN potential barrier (6), as shown in Figure 5;
S6, by one layer of SiO of plasma enhanced chemical vapor deposition2, as mask layer (10), as shown in Figure 6;
S7, by photoetching method select region etch, remove the mask layer (10) of area of grid, as shown in Figure 7;
S8, inductively coupled plasma (ICP) or reactive ion etching (RIE) is utilized to remove area of grid high aluminium component AlGaN Barrier layer (6) forms groove, as shown in Figure 8;
S9, removal mask layer (10), complete device isolation, utilize sputtering method, grow one layer of high-quality p-type oxide thin layer (7), as shown in Figure 9;
S10, photoetching development go out source electrode and drain ohmic contact region, and on evaporation, Ti/Al/Ni/Au alloy is as source electrode and drain electrode Metal ohmic contact (8), as shown in Figure 10;
S11, thicken metal (9) as grid, as shown in figure 11 at p-type oxide grid (7) upper evaporation Ni/Au alloy.
So far, the preparation process of whole device is completed.Figure 11 is the device architecture schematic diagram of embodiment 1.
Embodiment 2
Being the device architecture schematic diagram of the present embodiment as shown in figure 12, it differs only in embodiment 1 structure: in embodiment 1 Grid is single oxide, and utilizes two kinds or more of oxide to form stack gate electrode structure in embodiment 2.
Embodiment 3
Being the device architecture schematic diagram of the present embodiment as shown in figure 13, it differs only in embodiment 1 structure: in embodiment 1 Grid is p-type oxide, and embodiment 3 introduces insulating medium layer (11) below p-type oxide gate electrode, and dielectric layer is Al2O3Or HfO2, thickness is 1-100 nm;Form dielectric layer/oxide stack structure.
Furthermore, it is necessary to explanation, the accompanying drawing of above example merely to the purpose of signal, therefore there is no need by than Example is drawn.
Obviously, the above embodiment of the present invention is only for clearly demonstrating example of the present invention, and is not right The restriction of embodiments of the present invention.For those of ordinary skill in the field, the most also may be used To make other changes in different forms.Here without also cannot all of embodiment be given exhaustive.All at this Any amendment, equivalent and the improvement etc. made within the spirit of invention and principle, should be included in the claims in the present invention Protection domain within.

Claims (10)

1. a preparation method for high threshold voltage high mobility notched gates MOSFET, utilizes low al composition AlGaN/GaN/ high alumina The heterojunction material of component AlGaN lamination barrier layer, specifically includes following steps:
S1, at the upper growth stress cushion (2) of substrate (1);
S2, growth GaN epitaxial layer (3) on stress-buffer layer;
S3, GaN epitaxial layer (3) one layer low al composition AlGaN potential barrier (4) of upper growth;
S4, low al composition AlGaN potential barrier (4) one layer of GaN etch stop layer (5) of upper deposition;
S5, at GaN etch stop layer (5) upper growth one floor height al composition AlGaN potential barrier (6);
S6, in AlGaN potential barrier deposit one layer of SiO2, as mask layer (10);
S7, method by photoetching and wet etching, remove the mask layer (10) of area of grid;
S8, utilize dry/wet method to combine to remove the high aluminium component AlGaN potential barrier (6) of area of grid;
S9, dry etching complete device isolation, clean surface depositing p-type oxide gate (7);
S10, on source electrode and drain region are deposited with source electrode and drain ohmic contact metal (8);
S11, form Ohmic contact in groove grids region evaporation metal (9) and p-type oxide.
The preparation method of a kind of high threshold voltage high mobility notched gates MOSFET the most according to claim 1, its feature It is: described step S3-S5 grows the hetero-junctions material of low al composition AlGaN/GaN/ high aluminium component AlGaN lamination barrier layer Material;In described step S9, channel electrons concentration is modulated by depositing p-type oxide gate, and then regulation and control threshold voltage.
The preparation method of a kind of high threshold voltage high mobility notched gates MOSFET the most according to claim 1, its feature It is: described substrate (1) is any one in Si substrate, Sapphire Substrate, silicon carbide substrates, GaN self-supported substrate.
The preparation method of a kind of high threshold voltage high mobility notched gates MOSFET the most according to claim 1, its feature It is: any one that stress-buffer layer (2) is AlN, AlGaN, GaN described or combination;Stress buffer layer thickness is 10 nm ~ 5 μm。
The preparation method of a kind of high threshold voltage high mobility notched gates MOSFET the most according to claim 1, its feature It is: the described GaN epitaxial layer that GaN epitaxial layer (3) is involuntary doping or the high resistant GaN epitaxial layer of doping, described doping The doped chemical of resistive formation is carbon or ferrum;GaN epitaxial layer thickness is 100 nm ~ 20 μm.
The preparation method of a kind of high threshold voltage high mobility notched gates MOSFET the most according to claim 1, its feature It is: described AlGaN epitaxial layer (4) is low al composition AlGaN, and AlGaN layer thickness is 0-20 nm, and al composition concentration can Change at 0-15%.
The preparation method of a kind of high threshold voltage high mobility notched gates MOSFET the most according to claim 1, its feature It is: the described GaN etch stop layer that interposed layer (5) is high-quality, low-dislocation-density;Stop layer thickness is 0 nm ~ 20nm.
The preparation method of a kind of high threshold voltage high mobility notched gates MOSFET the most according to claim 1, its feature It is: described AlGaN epitaxial layer (6) is high aluminium component AlGaN, and AlGaN layer thickness is 0-50 nm, and al composition concentration can Change at 15-40%.
The preparation method of a kind of high threshold voltage high mobility notched gates MOSFET the most according to claim 1, its feature It is: described AlGaN potential barrier material can also a kind of or the most several in AlInN, InGaN, AlInGaN, AlN Combination.
The preparation method of a kind of high threshold voltage high mobility notched gates MOSFET the most according to claim 1, its feature It is: in described AlGaN potential barrier (6), and can also insert an AlN thin layer between GaN layer, thickness is 1-10 nm;
Described p-type oxide gate electrode (7) is high-quality NiO, Cu2The materials such as O, ZnO or a combination thereof, thickness is 1-500 nm;
Source electrode and drain electrode (8) material are Ti/Al/Ni/Au alloy, Ti/Al/Ti/Au alloy, Ti/Al/Mo/Au alloy or Ti/ Al/Ti/TiN alloy;It is Ni/Au alloy, In/Au alloy or Pd/Au alloy that gate electrode thickeies metal material (9);
AlGaN epitaxial layer in stress-buffer layer (2) in described step S1, the GaN epitaxial layer (3) in step S2, step S3 (4), the growing method of the AlGaN epitaxial layer (6) in the GaN epitaxial layer in step S4 (5) and step S5 is Organometallic Chemistry Vapour deposition process, molecular beam epitaxy contour quality film formation method;In described step S6, the growing method of mask layer (10) is Gas ions strengthens chemical vapour deposition technique, atomic layer deposition method, physical vaporous deposition or magnetron sputtering method.
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CN108666359A (en) * 2017-03-29 2018-10-16 北京大学 A kind of device architecture and implementation method improving GaN enhancement type channel mobilities using novel barrier layer
CN107316806A (en) * 2017-07-07 2017-11-03 西安电子科技大学 The preparation method of injection integral high frequency high threshold GaN base enhancement device is etched based on ICP F ions
CN108321256A (en) * 2018-03-29 2018-07-24 中山大学 A kind of preparation method based on p-type transparent grid electrode GaN base ultraviolet detector
WO2019241905A1 (en) * 2018-06-19 2019-12-26 深圳大学 Heterojunction field effect transistor and preparation method therefor
CN108807530A (en) * 2018-06-19 2018-11-13 深圳大学 Heterojunction field effect transistor and preparation method thereof
CN108807530B (en) * 2018-06-19 2021-02-09 深圳大学 Heterojunction field effect transistor and preparation method thereof
CN108950504A (en) * 2018-08-03 2018-12-07 江苏环奥金属材料科技有限公司 A kind of alloy target material and preparation method thereof forming Ohmic contact on N-type compound semiconductor materials surface
CN109540988A (en) * 2018-11-09 2019-03-29 中山大学 Based on interdigital groove structure without reference electrode GaN base pH sensor and preparation method thereof
CN109540987B (en) * 2018-11-09 2020-12-04 中山大学 Reference electrode-free GaN-based pH sensor based on groove structure and preparation method thereof
CN109540988B (en) * 2018-11-09 2020-12-29 中山大学 No reference electrode GaN base pH sensor based on interdigital electrode and groove structure
CN109540987A (en) * 2018-11-09 2019-03-29 中山大学 Based on groove structure without reference electrode GaN base pH sensor and preparation method thereof
CN109887818A (en) * 2019-03-13 2019-06-14 西安众力为半导体科技有限公司 A kind of electron beam device and preparation method thereof
CN109887818B (en) * 2019-03-13 2024-03-12 西安众力为半导体科技有限公司 Electron beam device and manufacturing method thereof

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