CN106282442A - 一种阻燃、耐光和低雾化磷酸化加脂剂的制备方法 - Google Patents
一种阻燃、耐光和低雾化磷酸化加脂剂的制备方法 Download PDFInfo
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- CN106282442A CN106282442A CN201610655761.XA CN201610655761A CN106282442A CN 106282442 A CN106282442 A CN 106282442A CN 201610655761 A CN201610655761 A CN 201610655761A CN 106282442 A CN106282442 A CN 106282442A
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- 239000003795 chemical substances by application Substances 0.000 title claims abstract description 77
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- 238000006366 phosphorylation reaction Methods 0.000 title claims abstract description 57
- 239000003063 flame retardant Substances 0.000 title claims abstract description 42
- 238000002360 preparation method Methods 0.000 title claims abstract description 33
- DLYUQMMRRRQYAE-UHFFFAOYSA-N tetraphosphorus decaoxide Chemical compound O1P(O2)(=O)OP3(=O)OP1(=O)OP2(=O)O3 DLYUQMMRRRQYAE-UHFFFAOYSA-N 0.000 claims abstract description 112
- 239000007788 liquid Substances 0.000 claims abstract description 62
- 238000006243 chemical reaction Methods 0.000 claims abstract description 57
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims abstract description 48
- 239000006185 dispersion Substances 0.000 claims abstract description 48
- 238000010792 warming Methods 0.000 claims abstract description 47
- 238000003756 stirring Methods 0.000 claims abstract description 46
- 238000009413 insulation Methods 0.000 claims abstract description 44
- ZEMPKEQAKRGZGQ-AAKVHIHISA-N 2,3-bis[[(z)-12-hydroxyoctadec-9-enoyl]oxy]propyl (z)-12-hydroxyoctadec-9-enoate Chemical compound CCCCCCC(O)C\C=C/CCCCCCCC(=O)OCC(OC(=O)CCCCCCC\C=C/CC(O)CCCCCC)COC(=O)CCCCCCC\C=C/CC(O)CCCCCC ZEMPKEQAKRGZGQ-AAKVHIHISA-N 0.000 claims abstract description 20
- OXBLHERUFWYNTN-UHFFFAOYSA-M copper(I) chloride Chemical compound [Cu]Cl OXBLHERUFWYNTN-UHFFFAOYSA-M 0.000 claims abstract description 16
- 238000010992 reflux Methods 0.000 claims abstract description 16
- -1 cinnamoyl caffeic acid Chemical compound 0.000 claims abstract description 14
- PCLIMKBDDGJMGD-UHFFFAOYSA-N N-bromosuccinimide Chemical compound BrN1C(=O)CCC1=O PCLIMKBDDGJMGD-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000000203 mixture Substances 0.000 claims description 30
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 12
- 239000011574 phosphorus Substances 0.000 claims description 12
- 229910052698 phosphorus Inorganic materials 0.000 claims description 12
- GFLJTEHFZZNCTR-UHFFFAOYSA-N 3-prop-2-enoyloxypropyl prop-2-enoate Chemical compound C=CC(=O)OCCCOC(=O)C=C GFLJTEHFZZNCTR-UHFFFAOYSA-N 0.000 claims description 8
- RPNUMPOLZDHAAY-UHFFFAOYSA-N Diethylenetriamine Chemical compound NCCNCCN RPNUMPOLZDHAAY-UHFFFAOYSA-N 0.000 claims description 8
- 150000002148 esters Chemical class 0.000 claims description 8
- 229920000371 poly(diallyldimethylammonium chloride) polymer Polymers 0.000 claims description 8
- RYZGGGMGTVKVLI-UHFFFAOYSA-N [Mo].[CH]1C=CC=C1 Chemical compound [Mo].[CH]1C=CC=C1 RYZGGGMGTVKVLI-UHFFFAOYSA-N 0.000 claims description 7
- 125000003963 dichloro group Chemical group Cl* 0.000 claims description 7
- GQOKIYDTHHZSCJ-UHFFFAOYSA-M dimethyl-bis(prop-2-enyl)azanium;chloride Chemical compound [Cl-].C=CC[N+](C)(C)CC=C GQOKIYDTHHZSCJ-UHFFFAOYSA-M 0.000 claims description 7
- 229910052760 oxygen Inorganic materials 0.000 claims description 7
- 239000001301 oxygen Substances 0.000 claims description 7
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 6
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 6
- LJSQFQKUNVCTIA-UHFFFAOYSA-N diethyl sulfide Chemical compound CCSCC LJSQFQKUNVCTIA-UHFFFAOYSA-N 0.000 claims description 6
- DCXXMTOCNZCJGO-UHFFFAOYSA-N tristearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(OC(=O)CCCCCCCCCCCCCCCCC)COC(=O)CCCCCCCCCCCCCCCCC DCXXMTOCNZCJGO-UHFFFAOYSA-N 0.000 claims description 6
- QZCLKYGREBVARF-UHFFFAOYSA-N Acetyl tributyl citrate Chemical compound CCCCOC(=O)CC(C(=O)OCCCC)(OC(C)=O)CC(=O)OCCCC QZCLKYGREBVARF-UHFFFAOYSA-N 0.000 claims description 5
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- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 5
- 239000011591 potassium Substances 0.000 claims description 5
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- BTEISVKTSQLKST-UHFFFAOYSA-N Haliclonasterol Natural products CC(C=CC(C)C(C)(C)C)C1CCC2C3=CC=C4CC(O)CCC4(C)C3CCC12C BTEISVKTSQLKST-UHFFFAOYSA-N 0.000 claims description 4
- 239000002253 acid Substances 0.000 claims description 4
- KFSZGBHNIHLIAA-UHFFFAOYSA-M benzyl(trimethyl)azanium;fluoride Chemical compound [F-].C[N+](C)(C)CC1=CC=CC=C1 KFSZGBHNIHLIAA-UHFFFAOYSA-M 0.000 claims description 4
- SGNBVLSWZMBQTH-PODYLUTMSA-N campesterol Chemical compound C1C=C2C[C@@H](O)CC[C@]2(C)[C@@H]2[C@@H]1[C@@H]1CC[C@H]([C@H](C)CC[C@@H](C)C(C)C)[C@@]1(C)CC2 SGNBVLSWZMBQTH-PODYLUTMSA-N 0.000 claims description 4
- 235000000431 campesterol Nutrition 0.000 claims description 4
- NQMRYBIKMRVZLB-UHFFFAOYSA-N methylamine hydrochloride Chemical compound [Cl-].[NH3+]C NQMRYBIKMRVZLB-UHFFFAOYSA-N 0.000 claims description 4
- WGYKZJWCGVVSQN-UHFFFAOYSA-N mono-n-propyl amine Natural products CCCN WGYKZJWCGVVSQN-UHFFFAOYSA-N 0.000 claims description 4
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- LWEAHXKXKDCSIE-UHFFFAOYSA-M 2,3-di(propan-2-yl)naphthalene-1-sulfonate Chemical compound C1=CC=C2C(S([O-])(=O)=O)=C(C(C)C)C(C(C)C)=CC2=C1 LWEAHXKXKDCSIE-UHFFFAOYSA-M 0.000 claims description 3
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- 229910052782 aluminium Inorganic materials 0.000 claims description 3
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- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 3
- OOBNORVQFIAGPT-UHFFFAOYSA-N antimony manganese Chemical compound [Mn].[Sb] OOBNORVQFIAGPT-UHFFFAOYSA-N 0.000 claims description 3
- JFSHUTJDVKUMTJ-QHPUVITPSA-N beta-amyrin Chemical compound C1C[C@H](O)C(C)(C)[C@@H]2CC[C@@]3(C)[C@]4(C)CC[C@@]5(C)CCC(C)(C)C[C@H]5C4=CC[C@@H]3[C@]21C JFSHUTJDVKUMTJ-QHPUVITPSA-N 0.000 claims description 3
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- PDNLMONKODEGSE-UHFFFAOYSA-N beta-amyrin acetate Natural products CC(=O)OC1CCC2(C)C(CCC3(C)C4(C)CCC5(C)CCC(C)(C)CC5C4=CCC23C)C1(C)C PDNLMONKODEGSE-UHFFFAOYSA-N 0.000 claims description 3
- 239000000460 chlorine Substances 0.000 claims description 3
- 229910052801 chlorine Inorganic materials 0.000 claims description 3
- KSEBMYQBYZTDHS-HWKANZROSA-N ferulic acid Chemical compound COC1=CC(\C=C\C(O)=O)=CC=C1O KSEBMYQBYZTDHS-HWKANZROSA-N 0.000 claims description 3
- 229940114124 ferulic acid Drugs 0.000 claims description 3
- KSEBMYQBYZTDHS-UHFFFAOYSA-N ferulic acid Natural products COC1=CC(C=CC(O)=O)=CC=C1O KSEBMYQBYZTDHS-UHFFFAOYSA-N 0.000 claims description 3
- 235000001785 ferulic acid Nutrition 0.000 claims description 3
- 229910052748 manganese Inorganic materials 0.000 claims description 3
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- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 3
- MHLYOTJKDAAHGI-UHFFFAOYSA-N silver molybdate Chemical compound [Ag+].[Ag+].[O-][Mo]([O-])(=O)=O MHLYOTJKDAAHGI-UHFFFAOYSA-N 0.000 claims description 3
- 239000012312 sodium hydride Substances 0.000 claims description 3
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- QURCVMIEKCOAJU-UHFFFAOYSA-N trans-isoferulic acid Natural products COC1=CC=C(C=CC(O)=O)C=C1O QURCVMIEKCOAJU-UHFFFAOYSA-N 0.000 claims description 3
- OOCCDEMITAIZTP-QPJJXVBHSA-N (E)-cinnamyl alcohol Chemical compound OC\C=C\C1=CC=CC=C1 OOCCDEMITAIZTP-QPJJXVBHSA-N 0.000 abstract description 8
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- FPQQSJJWHUJYPU-UHFFFAOYSA-N 3-(dimethylamino)propyliminomethylidene-ethylazanium;chloride Chemical compound Cl.CCN=C=NCCCN(C)C FPQQSJJWHUJYPU-UHFFFAOYSA-N 0.000 abstract 1
- 229940074360 caffeic acid Drugs 0.000 abstract 1
- QAIPRVGONGVQAS-DUXPYHPUSA-N caffeic acid Natural products OC(=O)\C=C\C1=CC=C(O)C(O)=C1 QAIPRVGONGVQAS-DUXPYHPUSA-N 0.000 abstract 1
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- QAIPRVGONGVQAS-UHFFFAOYSA-N cis-caffeic acid Natural products OC(=O)C=CC1=CC=C(O)C(O)=C1 QAIPRVGONGVQAS-UHFFFAOYSA-N 0.000 abstract 1
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- 229910017083 AlN Inorganic materials 0.000 description 2
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- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
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- 230000009286 beneficial effect Effects 0.000 description 2
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- DCPMPXBYPZGNDC-UHFFFAOYSA-N hydron;methanediimine;chloride Chemical compound Cl.N=C=N DCPMPXBYPZGNDC-UHFFFAOYSA-N 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
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- 239000012321 sodium triacetoxyborohydride Substances 0.000 description 2
- 206010016322 Feeling abnormal Diseases 0.000 description 1
- 229920003180 amino resin Polymers 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
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- 238000005516 engineering process Methods 0.000 description 1
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- 238000004079 fireproofing Methods 0.000 description 1
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C14—SKINS; HIDES; PELTS; LEATHER
- C14C—CHEMICAL TREATMENT OF HIDES, SKINS OR LEATHER, e.g. TANNING, IMPREGNATING, FINISHING; APPARATUS THEREFOR; COMPOSITIONS FOR TANNING
- C14C9/00—Impregnating leather for preserving, waterproofing, making resistant to heat or similar purposes
- C14C9/02—Impregnating leather for preserving, waterproofing, making resistant to heat or similar purposes using fatty or oily materials, e.g. fat liquoring
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Treatment And Processing Of Natural Fur Or Leather (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Fireproofing Substances (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
Description
类型 | 实例1 | 实例2 | 实例3 | 实例4 | 实例5 | 市场磷酸化加脂剂 |
手感 | 好 | 较好 | 较好 | 好 | 好 | 较好 |
丰满性 | 好 | 好 | 好 | 较好 | 好 | 较好 |
柔软性 | 较好 | 较好 | 好 | 好 | 好 | 较好 |
类型 | 实例1 | 实例2 | 实例3 | 实例4 | 实例5 | 市场磷酸化加脂剂 |
断裂伸长率/% | 88.67 | 128.37 | 138.76 | 159.15 | 146.32 | 77.45 |
实例1 | 实例2 | 实例3 | 实例4 | 实例5 | 市场磷酸化加脂剂 | |
最大烟密度 | 12 | 12 | 8 | 7 | 4 | 35 |
达到最大烟密度时间/s | 160 | 245 | 220 | 240 | 220 | 135 |
氧指数/% | 27.6 | 27.4 | 31.9 | 31.6 | 31.2 | 25.1 |
有焰燃烧时间/s | 0.2 | 1.2 | 1.4 | 3.6 | 3.6 | 28.3 |
无焰燃烧时间/s | 0.7 | 5.2 | 1.6 | 0.8 | 0.2 | 13.5 |
时间/min | 实例1 | 实例2 | 实例3 | 实例4 | 实例5 | 市场磷酸化加脂剂 |
90 | 0.3 | 0.1 | 0.3 | 0.2 | 0.1 | 0.3 |
150 | 0.3 | 0.1 | 0.2 | 0.2 | 0.2 | 0.5 |
270 | 0.5 | 0.5 | 0.5 | 0.2 | 0.3 | 0.6 |
330 | 0.6 | 0.4 | 0.6 | 0.4 | 0.3 | 0.7 |
390 | 0.7 | 0.7 | 0.7 | 0.6 | 0.6 | 0.7 |
450 | 1.0 | 1.0 | 0.7 | 0.6 | 0.6 | 0.9 |
510 | 1.0 | 1.1 | 0.8 | 08 | 0.7 | 1.5 |
540 | 1.0 | 1.3 | 1.2 | 1.1 | 0.8 | 1.8 |
600 | 1.4 | 1.3 | 1.3 | 1.1 | 0.9 | 2.1 |
类型 | 实例1 | 实例2 | 实例3 | 实例4 | 实例5 | 市场磷酸化加脂剂 |
雾化值/mg | 1.2 | 1.5 | 0.7 | 0.6 | 1.8 | 3.2 |
Claims (5)
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201711192468.5A CN107723392B (zh) | 2016-08-11 | 2016-08-11 | 一种阻燃、耐光和低雾化磷酸化加脂剂 |
CN201610655761.XA CN106282442B (zh) | 2016-08-11 | 2016-08-11 | 一种阻燃、耐光和低雾化磷酸化加脂剂的制备方法 |
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CN201610655761.XA CN106282442B (zh) | 2016-08-11 | 2016-08-11 | 一种阻燃、耐光和低雾化磷酸化加脂剂的制备方法 |
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CN201711192468.5A Division CN107723392B (zh) | 2016-08-11 | 2016-08-11 | 一种阻燃、耐光和低雾化磷酸化加脂剂 |
Publications (2)
Publication Number | Publication Date |
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CN106282442A true CN106282442A (zh) | 2017-01-04 |
CN106282442B CN106282442B (zh) | 2018-06-12 |
Family
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Family Applications (2)
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CN201610655761.XA Active CN106282442B (zh) | 2016-08-11 | 2016-08-11 | 一种阻燃、耐光和低雾化磷酸化加脂剂的制备方法 |
CN201711192468.5A Active CN107723392B (zh) | 2016-08-11 | 2016-08-11 | 一种阻燃、耐光和低雾化磷酸化加脂剂 |
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CN201711192468.5A Active CN107723392B (zh) | 2016-08-11 | 2016-08-11 | 一种阻燃、耐光和低雾化磷酸化加脂剂 |
Country Status (1)
Country | Link |
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Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2009114244A (ja) * | 2007-11-02 | 2009-05-28 | Yoshihiro Tokunaga | エンボス加工用革素材の製造方法 |
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