CN1061982C - 制造n-膦酰甲基甘氨酸的方法 - Google Patents

制造n-膦酰甲基甘氨酸的方法 Download PDF

Info

Publication number
CN1061982C
CN1061982C CN95196267A CN95196267A CN1061982C CN 1061982 C CN1061982 C CN 1061982C CN 95196267 A CN95196267 A CN 95196267A CN 95196267 A CN95196267 A CN 95196267A CN 1061982 C CN1061982 C CN 1061982C
Authority
CN
China
Prior art keywords
phosphonomethylglycine
alkali metal
phosphonic acids
formaldehyde
aminomethyl phosphonic
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CN95196267A
Other languages
English (en)
Chinese (zh)
Other versions
CN1163617A (zh
Inventor
J·H·艾瑟顿
I·霍奇金森
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
SINZETA Ltd
Original Assignee
Zeneca Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Zeneca Ltd filed Critical Zeneca Ltd
Publication of CN1163617A publication Critical patent/CN1163617A/zh
Application granted granted Critical
Publication of CN1061982C publication Critical patent/CN1061982C/zh
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02Phosphorus compounds
    • C07F9/28Phosphorus compounds with one or more P—C bonds
    • C07F9/38Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02Phosphorus compounds
    • C07F9/28Phosphorus compounds with one or more P—C bonds
    • C07F9/38Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
    • C07F9/3804Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)] not used, see subgroups
    • C07F9/3808Acyclic saturated acids which can have further substituents on alkyl
    • C07F9/3813N-Phosphonomethylglycine; Salts or complexes thereof

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Preparation Of Compounds By Using Micro-Organisms (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
CN95196267A 1994-11-16 1995-11-02 制造n-膦酰甲基甘氨酸的方法 Expired - Fee Related CN1061982C (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB9423254A GB9423254D0 (en) 1994-11-16 1994-11-16 Process
GB9423254.3 1994-11-16

Publications (2)

Publication Number Publication Date
CN1163617A CN1163617A (zh) 1997-10-29
CN1061982C true CN1061982C (zh) 2001-02-14

Family

ID=10764573

Family Applications (1)

Application Number Title Priority Date Filing Date
CN95196267A Expired - Fee Related CN1061982C (zh) 1994-11-16 1995-11-02 制造n-膦酰甲基甘氨酸的方法

Country Status (29)

Country Link
US (1) US5679843A (enExample)
EP (1) EP0792277B1 (enExample)
JP (1) JP3576169B2 (enExample)
KR (1) KR100362553B1 (enExample)
CN (1) CN1061982C (enExample)
AR (1) AR000087A1 (enExample)
AT (1) ATE181554T1 (enExample)
AU (1) AU697316B2 (enExample)
BG (1) BG101523A (enExample)
BR (1) BR9509691A (enExample)
CA (1) CA2203553C (enExample)
CZ (1) CZ149097A3 (enExample)
DE (1) DE69510466T2 (enExample)
DK (1) DK0792277T3 (enExample)
ES (1) ES2133819T3 (enExample)
FI (1) FI972065A0 (enExample)
GB (1) GB9423254D0 (enExample)
GR (1) GR3030456T3 (enExample)
HU (1) HU217301B (enExample)
IL (1) IL115793A (enExample)
MA (1) MA23714A1 (enExample)
MY (1) MY112939A (enExample)
NO (1) NO972240D0 (enExample)
NZ (1) NZ294891A (enExample)
PL (1) PL187068B1 (enExample)
SK (1) SK61297A3 (enExample)
TW (1) TW296385B (enExample)
WO (1) WO1996015135A1 (enExample)
ZA (1) ZA959527B (enExample)

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB9515265D0 (en) * 1995-07-25 1995-09-20 Zeneca Ltd Chemical process
DE19629870A1 (de) * 1996-07-24 1998-01-29 Sueddeutsche Kalkstickstoff Verfahren zur Herstellung von N-Phosphonomethylglycin
IL128858A0 (en) * 1996-09-12 2000-01-31 Monsanto Co Method for producing N-phosphonomethylglycine and its salts
US5948937A (en) * 1996-09-12 1999-09-07 Monsanto Company Method for producing N-phosphonomethylglycine and its salts
US5859290A (en) * 1996-12-30 1999-01-12 Monsanto Company Hydrogenation of cyanophosphonate derivatives in the presence of a glycine derivative
JP2001507707A (ja) * 1996-12-30 2001-06-12 モンサント・カンパニー リン酸エステルおよびシアン化物からのシアノホスホネートの調製方法
CA2276187A1 (en) * 1996-12-30 1998-07-09 Monsanto Company Hydrogenation of cyanophosphonate derivatives
WO1998029419A1 (en) * 1996-12-30 1998-07-09 Monsanto Company Cyanophosphorus compounds and their preparation
IL130703A0 (en) * 1996-12-30 2000-06-01 Monsanto Co Method for preparing cyanophosphonate derivatives from phosphoric anhydride and cyanide
CA2276166A1 (en) * 1996-12-30 1998-07-09 Monsanto Company Method for preparing cyanophosphonate derivatives from pyrophosphate o r polyphosphate esters and cyanide
EP0948506A1 (en) * 1996-12-30 1999-10-13 Monsanto Company Cyanophosphonate derivatives
EP1135398A1 (en) 1998-12-03 2001-09-26 Monsanto Technology LLC Cyanophosphonamides and method for preparation
US6916638B2 (en) * 1999-12-27 2005-07-12 Asahi Kasei Kabushiki Kaisha Process for producing glycine

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4221583A (en) * 1978-12-22 1980-09-09 Monsanto Company N-Phosphonomethylglycinonitrile and certain derivatives thereof
EP0537786A1 (en) * 1991-10-17 1993-04-21 Showa Denko Kabushiki Kaisha Preparation of N-acylaminomethylphosphonic acid
WO1994022881A1 (en) * 1993-04-07 1994-10-13 Zeneca Limited Process for preparing n-phosphonomethylglycinonitrile or derivatives thereof

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
PL156933B1 (pl) * 1988-02-16 1992-04-30 Politechnika Wroclawska Sposób wytwarzania N-(1-fosfonoalkilo) glicyn, zwlaszcza N-(fosfonometylo) glicyny PL
CA2053362A1 (en) * 1990-10-15 1992-04-16 Druce K. Crump Preparation of aminonitriles

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4221583A (en) * 1978-12-22 1980-09-09 Monsanto Company N-Phosphonomethylglycinonitrile and certain derivatives thereof
EP0537786A1 (en) * 1991-10-17 1993-04-21 Showa Denko Kabushiki Kaisha Preparation of N-acylaminomethylphosphonic acid
WO1994022881A1 (en) * 1993-04-07 1994-10-13 Zeneca Limited Process for preparing n-phosphonomethylglycinonitrile or derivatives thereof

Also Published As

Publication number Publication date
SK61297A3 (en) 1997-11-05
NZ294891A (en) 1998-12-23
HUT77022A (hu) 1998-03-02
BG101523A (en) 1998-01-30
IL115793A0 (en) 1996-05-14
NO972240L (no) 1997-05-15
CN1163617A (zh) 1997-10-29
CA2203553C (en) 2005-01-18
MA23714A1 (fr) 1996-07-01
IL115793A (en) 1999-10-28
JP3576169B2 (ja) 2004-10-13
ZA959527B (en) 1996-06-18
CA2203553A1 (en) 1996-05-23
JPH10509705A (ja) 1998-09-22
HU217301B (hu) 1999-12-28
WO1996015135A1 (en) 1996-05-23
NO972240D0 (no) 1997-05-15
EP0792277B1 (en) 1999-06-23
DE69510466D1 (de) 1999-07-29
TW296385B (enExample) 1997-01-21
PL321158A1 (en) 1997-11-24
PL187068B1 (pl) 2004-05-31
DK0792277T3 (da) 1999-12-13
ATE181554T1 (de) 1999-07-15
AU697316B2 (en) 1998-10-01
KR970707136A (ko) 1997-12-01
BR9509691A (pt) 1997-10-14
GR3030456T3 (en) 1999-09-30
GB9423254D0 (en) 1995-01-04
EP0792277A1 (en) 1997-09-03
DE69510466T2 (de) 1999-11-18
MY112939A (en) 2001-10-31
AU3810495A (en) 1996-06-06
US5679843A (en) 1997-10-21
CZ149097A3 (en) 1997-08-13
FI972065A7 (fi) 1997-05-14
ES2133819T3 (es) 1999-09-16
AR000087A1 (es) 1997-05-21
FI972065L (fi) 1997-05-14
FI972065A0 (fi) 1997-05-14
KR100362553B1 (ko) 2003-01-24

Similar Documents

Publication Publication Date Title
CN1061982C (zh) 制造n-膦酰甲基甘氨酸的方法
CN1261442C (zh) 用于制备草胺膦的方法以及中间体
CN1232523C (zh) 制备二烷基次膦酸的方法
US6278012B1 (en) Process for preparing phosphinate esters
JP2001002686A (ja) ジアルキルホスフィン酸及びそれの塩の製造方法
CN1280582A (zh) 二烷基次膦酸盐的制备方法
EP2435450A1 (en) Method for the manufacture of amino alkylene phosphonic acids
CN102399239A (zh) 一种草铵膦及类似物的合成方法
CN1062855C (zh) 羟甲基-亚氨基二乙酸的碱金属盐的制备方法
CN102639546B (zh) 制备膦酰基烷基亚氨基二乙酸的方法
CN101048344A (zh) 高纯度二烷基亚膦酸的制备方法
WO2000014093A1 (en) Synthesis of phosphonomethyliminodiacetic acid with reduced effluent
CN1044250C (zh) 氨基甲膦酸的生产方法
AU2010251897A1 (en) Method for the manufacture of phosphonoalkyl iminodiacetic acids
EP0717046B1 (en) Process for producing phosphonic acid derivative
CN1296376C (zh) 双甘膦的制备方法
JP4320343B2 (ja) アルコール性ヒドロキシ基を有するホスホネートの製造方法
CN1216888C (zh) 制备n-膦酰基甲基甘氨酸及其盐的方法
CN85108853A (zh) α-氨基烷基膦酸和α-氨基烷基次膦酸的生产方法
SU1016292A1 (ru) Способ получени @ -дифенилфосфинокарбоновых кислот
JP3823327B2 (ja) N−ホスホノメチルグリシンの製造方法
CN1072932A (zh) 氨基链烷膦酸及其盐和/或酯的生产
JPS6356219B2 (enExample)
CN117700450A (zh) 一种4-(羟基甲基膦酰基)-2-羰基丁酸的制备方法
Watanabe et al. The syntheses and decompositions of strontium and barium tetraphosphates

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
C56 Change in the name or address of the patentee

Owner name: SIGENTIS CO., LTD.

Free format text: FORMER NAME OR ADDRESS: ZENECA LTD

CP03 Change of name, title or address

Address after: surrey

Patentee after: Sinzeta Ltd.

Address before: London, England, England

Patentee before: Zeneca Limited

C17 Cessation of patent right
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20010214

Termination date: 20111102